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Sökning: WFRF:(Ullsten Henrik)

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  • Cho, Sung-Woo, et al. (författare)
  • Heat-sealing properties of compression-molded wheat gluten films
  • 2007
  • Ingår i: Journal of Biobased Materials and Bioenergy. - : American Scientific Publishers. - 1556-6560 .- 1556-6579. ; 1:1, s. 56-63
  • Tidskriftsartikel (refereegranskat)abstract
    • The impulse heat-sealing properties of wheat gluten films were investigated. Films containing 30 wt% glycerol were compression molded at 100-130 °C and then sealed in a lap-shear or peel-test geometry at 120-175 °C. The tensile properties of the pristine films and the lap-shear and peel strength of the sealed films were evaluated and the seals were examined by scanning electron microscopy. Glycerol was added to the film surfaces prior to sealing in an attempt to enhance the seal strength. It was observed that the wheat gluten films were readily sealable. At a 120 °C sealing temperature and without glycerol as adhesive, the lap-shear strength was greater than or similar to that of polyethylene film, although the peel strength was poorer. The sealing temperature had a negligible effect on the lap-shear strength, but the peel strength increased with sealing temperature. The lap-shear strength increased with increasing mold temperature and the failure mode changed, especially in the absence of glycerol adhesive, from a cohesive (material failure) to an adhesive type. From previous results, it is known that the high-temperature (130 °C) compression-molded film was highly cross-linked and aggregated, and this prevents molecular interdiffusion and entanglement and thus leads to incomplete seal fusion and, in general, adhesive failure. The presence of glycerol adhesive had a beneficial affect on the peel strength but no, or only a minor, effect on the lap-shear strength.
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  • Christophliemk, Hanna, 1973-, et al. (författare)
  • Oxygen and water vapor transmission rates of starch-poly(vinyl alcohol) barrier coatings for flexible packaging paper
  • 2017
  • Ingår i: Progress in organic coatings. - : Elsevier. - 0300-9440 .- 1873-331X. ; 113, s. 218-224
  • Tidskriftsartikel (refereegranskat)abstract
    • Creating efficient water-borne dispersions based mainly on renewable materials for coating of flexible packaging paper was the aim of this study. The effects of an ethylene modified poly(vinyl alcohol) grade and a standard poly(vinyl alcohol) on the oxygen and water vapor barrier performance of corn starch and potato starch coatings was studied. The results showed that a coating composition with a high fraction of a renewable polymer was effective in keeping the oxygen barrier at a technically and commercially applicable level. An ethylene modified poly(vinyl alcohol) grade was found to provide lower oxygen transmission rates at high relative humidity, as compared to a standard poly(vinyl alcohol) grade. The oxygen barrier properties of blends of starch and poly (vinyl alcohol) were similar to that of the pure modified poly(vinyl alcohol) in the range from 0% starch to 60% starch. This was observed with both hydroxypropylated and octenyl succinate modified starch grades. The drying conditions of the mixed starch:poly(vinyl alcohol) coatings were based on drying trials with pure poly (vinyl alcohol) coatings. Drying at moderate temperatures indicated the possibility to slightly decrease water vapor transmission rate by higher drying temperature. Several secondary effects of increased drying temperature such as coating hold-out and formation of defects may also be of importance.
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