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Sökning: WFRF:(Vall llosera Gemma)

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1.
  • Almlof, Jonas, et al. (författare)
  • Creating and detecting specious randomness
  • 2023
  • Ingår i: EPJ QUANTUM TECHNOLOGY. - : Springer Nature. - 2662-4400 .- 2196-0763. ; 10:1
  • Tidskriftsartikel (refereegranskat)abstract
    • We present a new test of non-randomness that tests both the lower and the upper critical limit of a chi 2-statistic. While checking the upper critical value has been employed by other tests, we argue that also the lower critical value should be examined for non-randomness. To this end, we prepare a binary sequence where all possible bit strings of a certain length occurs the same number of times and demonstrate that such sequences pass a well-known suite of tests for non-randomness. We show that such sequences can be compressed, and therefore are somewhat predictable and thus not fully random. The presented test can detect such non-randomness, and its novelty rests on analysing fixed-length bit string frequencies that lie closer to the a priori probabilities than could be expected by chance alone.
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2.
  • Almlöf, Jonas, et al. (författare)
  • Creating and detecting specious randomness
  • Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
    • We present a new test of non-randomness that tests both the lower and the upper critical limit of aχ2-statistic. While checking the upper critical value has been employed by other tests, we argue that also the lower critical value should be examined for non-randomness. To this end, we prepare a binary sequence where all possible bit strings of a certain length occurs the same number of times and demonstrate that such sequences pass a well-known suite of tests for non-randomness. We show that such sequences can be compressed, and therefore are somewhat predictable and thus not fully random. The presented test can detect such non-randomness, and its novelty rests on analysing fixed-length bit string frequencies that lie closer to the a priori probabilities than could be expected by chance 
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4.
  • Feyer, Vitaliy, et al. (författare)
  • Tautomerism in Cytosine and Uracil : An Experimental and Theoretical Core Level Spectroscopic Study
  • 2009
  • Ingår i: Journal of Physical Chemistry A. - : American Chemical Society (ACS). - 1089-5639 .- 1520-5215. ; 113:19, s. 5736-5742
  • Tidskriftsartikel (refereegranskat)abstract
    • The O, N, and C 1s core level photoemission spectra of the nucleobases cytosine and uracil have been measured in the vapor phase, and the results have been interpreted via theoretical calculations. Our calculations accurately predict the relative binding energies of the core level features observed in the experimental photoemission results and provide a full assignment. In agreement with previous work, a single tautomer of uracil is populated at 405 K, giving rise to relatively simple spectra. At 450 K, three tautomers of cytosine, one of which may consist of two rotamers, are identified, and their populations are determined. This resolves inconsistencies between recent laser studies of this molecule in which the rare imino-oxo tautomer was not observed and older microwave spectra in which it was reported.
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5.
  • Gyger, Samuel, et al. (författare)
  • Metropolitan single-photon distribution at 1550 nm for random number generation
  • 2022
  • Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 121:19, s. 194003-
  • Tidskriftsartikel (refereegranskat)abstract
    • Quantum communication networks will connect future generations of quantum processors, enable metrological applications, and provide security through quantum key distribution. We present a testbed that is part of the municipal fiber network in the greater Stockholm metropolitan area for quantum resource distribution through a 20 km long fiber based on semiconductor quantum dots emitting in the telecom C-band. We utilize the service to generate random numbers passing the NIST test suite SP800-22 at a subscriber 8 km outside of the city with a bit rate of 23.4 kbit/s.
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6.
  • Gyger, Samuel, et al. (författare)
  • Metropolitan Single-Photon Distribution at 1550 nm for Random Number Generation
  • 2023
  • Ingår i: 2023 Conference on Lasers and Electro-Optics, CLEO 2023. - : Institute of Electrical and Electronics Engineers Inc..
  • Konferensbidrag (refereegranskat)abstract
    • Quantum communication networks are used for QKD and metrological applications. We present research connecting two nodes ≈ 20 kilometers apart over the municipal fiber network using semiconductor quantum dots emitting at 1550 nm.
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7.
  • Jakubowska, Katarzyna, et al. (författare)
  • Lyman and Balmer emission following core excitations in methane and ammonia molecules
  • 2007
  • Ingår i: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 40:8, s. 1489-1500
  • Tidskriftsartikel (refereegranskat)abstract
    • The intensities of hydrogen Lyman-alpha and Balmer series emission lines as a result of photoexcitation of free CH4 and NH3 molecules at the C 1s and N 1s edges have been measured. For methane, the total fluorescence yield in the visible region ( 300 - 650 nm) was also recorded. Excitation functions of the Balmer lines show relative intensity enhancement of Balmer-beta emission in comparison with Balmer-alpha at higher core- to- Rydberg excitations. The Lyman-alpha emission intensity, in general, follows the relations observed in the corresponding total ion yield measurements. Additionally, the Balmer-gamma and -delta yields were measured for ammonia molecules and they show intensity maxima at photon energies shifted closer to the N 1s threshold than Balmer-alpha and -beta. A quantum defect analysis is performed to find out which core excitations are responsible for this enhanced intensity. Dissociation pathways leading to the emission in H atoms are discussed.
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8.
  • Kivimaki, A., et al. (författare)
  • Fluorescence emission at core-to-Rydberg excitations in the N-2 molecule
  • 2009
  • Ingår i: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 42:18
  • Tidskriftsartikel (refereegranskat)abstract
    • Fluorescence emission at the N 1s edge of the N-2 molecule has been studied with synchrotron radiation excitation. The partial fluorescence yields in the ultraviolet (250-320 nm) and visible (300-650 nm) wavelengths were collected by scanning the photon energy across the core-to-Rydberg excitations and the N 1s ionization potential (IP). When compared to the total ion yield, both fluorescence yields are most enhanced at the excitations to high Rydberg orbitals. A discrete structure appears just below the N 1s IP only in the UV yield and is assigned to core-valence doubly excited states. Dispersed fluorescence spectra in selected wavelength windows were measured at several photon energies in order to find out which fragments are responsible for the enhancement of fluorescence emission just below the N 1s IP. The excitation functions determined and considerations on de-excitation pathways indicate that the main responsible is the N+ ion.
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9.
  • Kivimaki, A., et al. (författare)
  • Line shape narrowing in the ultraviolet yield at the N 1s -> pi* resonance of the N-2 molecule
  • 2009
  • Ingår i: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 42:7
  • Tidskriftsartikel (refereegranskat)abstract
    • The intensity of fluorescence emission in the wavelength region of 250-320 nm has been measured across the N 1s -> pi* resonance of the N-2 molecule. It displays a narrower line shape than the total ion yield recorded simultaneously. We explain the finding by the particularities of the resonant Auger transitions from the N 1s(-1) pi* state to the D-2 Pi(g) state in N-2(+) and by the subsequent D-2 Pi(g) -> A(2)Pi(u) emission.
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10.
  • Kivimäki, Antti, et al. (författare)
  • Fluorescence emission following core excitations in the water molecule
  • 2006
  • Ingår i: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 39:5, s. 1101-1112
  • Tidskriftsartikel (refereegranskat)abstract
    • Photon-induced fluorescence spectroscopy has been used to study the fragmentation of the water molecule at the O 1s is edge. Fluorescence emission has been observed from the neutral fragments H, O and OH as well as from the ionic fragments O+ and OH+. The extracted fluorescence yields of the H Lyman-alpha emission and O 2p(3)(S-4)3p(P-3) -> 2p(3)(S-4)3s(S-3) transitions show the same structures as the total ion yield spectrum but with different relative intensities. The most intense fluorescence emission is restricted to the region of the core excitations, while above the O 1s ionization limit the signal is much weaker (in the case of H) or below the detection limit (O, OH and OH+). The fluorescence emission is concluded to follow from the following general cascade: the core-excited states decay by resonant Auger transitions, the final states reached undergo dissociation into ionic and neutral fragments, and fluorescence occurs from excited fragments. In the case of the OH (A(2)Sigma(+) -> X-2 Pi) emission, the decay of core-excited states through soft x-ray emission may also be responsible for the observed fluorescence.
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