| 1. |
- Gardiner, N.J., et al.
(författare)
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Contrasting Granite Metallogeny through the Zircon Record: A Case Study from Myanmar
- 2017
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Ingår i: Scientific Reports. - 2045-2322. ; 7
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Tidskriftsartikel (refereegranskat)abstract
- Granitoid-hosted mineral deposits are major global sources of a number of economically important metals. The fundamental controls on magma metal fertility are tectonic setting, the nature of source rocks, and magma differentiation. A clearer understanding of these petrogenetic processes has been forged through the accessory mineral zircon, which has considerable potential in metallogenic studies. We present an integrated zircon isotope (U-Pb, Lu-Hf, O) and trace element dataset from the paired Cu-Au (copper) and Sn-W (tin) magmatic belts in Myanmar. Copper arc zircons have juvenile εHf (+7.6 to +11.5) and mantle-like δ18O (5.2–5.5‰), whereas tin belt zircons have low εHf (−7 to −13) and heavier δ18O (6.2–7.7‰). Variations in zircon Hf and U/Yb reaffirm that tin belt magmas contain greater crustal contributions than copper arc rocks. Links between whole-rock Rb/Sr and zircon Eu/Eu* highlight that the latter can monitor magma fractionation in these systems. Zircon Ce/Ce* and Eu/Eu* are sensitive to redox and fractionation respectively, and here are used to evaluate zircon sensitivity to the metallogenic affinity of their host rock. Critical contents of Sn in granitic magmas, which may be required for the development of economic tin deposits, are marked by zircon Eu/Eu* values of ca. ≤0.08.
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| 2. |
- Merle, Renaud E., 1976-, et al.
(författare)
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Pb-Pb ages and initial Pb isotopic composition of lunar meteorites : NWA 773 clan, NWA 4734, and Dhofar 287
- 2020
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Ingår i: Meteoritics and Planetary Science. - : John Wiley & Sons, Ltd. - 1086-9379 .- 1945-5100. ; 55:8
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Tidskriftsartikel (refereegranskat)abstract
- Abstract Constraining the duration of magmatic activity on the Moon is essential to understand how the lunar mantle evolved chemically through time. Determining age and initial isotopic compositions of mafic lunar meteorites is a critical step in defining the periods of magmatic activity that occurred during the history of the Moon and to constrain the chemical characteristics of mantle components involved in the sources of the magmas. We have used the in situ Pb-Pb SIMS technique to investigate eight lunar gabbros and basalts, including six meteorites from the Northwest Africa (NWA) 773 clan (NWA 2727, NWA 2700, NWA 3333, NWA 2977, NWA 773, and NWA 3170), NWA 4734, and Dhofar 287A. These samples have been selected as there is no clear agreement on their age and they are all from the dominant low titanium chemical group. We have obtained ages of 2981 ± 12 Ma for NWA 4734 and 3208 ± 22 Ma for Dhofar 287. For the NWA 773 clan, four samples (the fine-grained basalt NWA 2727 and the three gabbros NWA 773, NWA 2977, NWA 3170) out of six yielded isochron-calculated ages that are identical within uncertainties and yielding an average age of 3086 ± 5 Ma. The age obtained for the fine-grained basalt NWA 2700 is not precise enough for comparison with the other samples. The gabbroic sample NWA 3333 yielded an age of 3038 ± 20 Ma suggesting that two distinct magmatic events may be recorded in the meteorites of the NWA 773 clan. The present study aims to identify and assess all potential issues that are associated with different ways to date lunar rocks using U-Pb?based methods. To achieve this, we have compared the new ages with the previously published data set. The entire age data set from lunar mafic meteorites was also screened to identify data showing analytical issues and evidence of resetting and terrestrial contamination. The data set combining the ages of mafic lunar meteorites and Apollo rocks suggests pulses of magmatic activity with two distinct phases between 3950 and 3575 Ma and between 3375 and 3075 Ma with the two phases separated by a gap of approximately 200 Ma. The evolution of the Pb initial ratios of the low-Ti mare basalts between approximately 3400 and 3100 Ma suggests that these rocks were progressively contaminated by a KREEP-like component.
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| 3. |
- Virtasalo, J.J., et al.
(författare)
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Pyritic event beds and sulfidized Fe (oxyhydr)oxide aggregates in metalliferous black mudstones of the Paleoproterozoic Talvivaara formation, Finland
- 2015
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Ingår i: Earth and Planetary Science Letters. - : Elsevier BV. - 0012-821X .- 1385-013X. ; 432, s. 449-460
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Tidskriftsartikel (refereegranskat)abstract
- The Paleoproterozoic, 2.0–1.9 Ga Talvivaara formation of Finland was deposited during the Shunga Event, a worldwide episode of enhanced accumulation of organic-rich sediments in the aftermath of the Lomagundi–Jatuli carbon isotope excursion. Sulfidic carbonaceous mudstones in the Talvivaara formation contain one of the largest known shale-hosted nickel deposits. In order to gain new insight into this Shungian sedimentary environment, sedimentological, petrographical and in situ S and Fe isotopic microanalyses were carried out on samples representing depositional and early-diagenetic conditions. The event-bedded lithology with tidal signatures in the organic-rich mudstones strongly indicates deposition from predominantly river-delivered mud on a highly-productive coastal area, below storm-wave base. The riverine supply of phosphorus, sulfate and iron supported high primary productivity and resulted in strong lateral and vertical chemical gradients in the nearshore waters with a shallow oxic surface layer underlain by euxinic water. The stratigraphic upper part of the Talvivaara formation contains banded intervals of thin alternating pyrite beds and carbonaceous mudstone beds. The pyrite beds were deposited by seaward excursions of the concentrated, acidic Fe-rich river plume subsequent to droughts or dry seasons, which led to intense pyrite precipitation upon mixing with euxinic waters. δS34 and δFe56 values of the bedded pyrite (median δS34=−10.3‰ and δFe56=−0.79‰) are consistent with the reaction of dissolved Fe(II) with H2S from bacterial sulfate reduction. Organic-rich clayey Fe-monosulfide-bearing granules were transported from the muddy estuary, and enclosed in Fe (oxyhydr)oxide aggregates that were forming by wave and current reworking in nearshore accumulations of river-delivered iron. The isotopic composition of these presently pyrrhotitic inclusions (median δS34=−3.3‰ and δFe56=−1.6‰) indicates microbial iron reduction. The Fe (oxyhydr)oxide aggregates were transported in muddy debris flows to the distal euxinic seafloor. Their Fe (oxyhydr)oxide matrix was replaced by pyrite (median δS34=+5.8‰ and δFe56=+0.81‰) at shallow sediment depths with 34S and 56Fe-enriched porewater. Wavy-crinkly laminae of possible microbial origin developed on the euxinic seafloor during low sedimentation. These results indicate episodic deposition at seasonal to multiannual time scales. δS34 and δFe56 values in the studied Fe-sulfides provide evidence of microbial isotope fractionation processes and syndepositional and early-diagenetic origin, finding no support for the previously proposed local hydrothermal activity in the Talvivaara mudstones.
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| 4. |
- Bellucci, J. J., et al.
(författare)
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Tracing martian surface interactions with the triple O isotope compositions of meteoritic phosphates
- 2020
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Ingår i: Earth and Planetary Science Letters. - : Elsevier BV. - 0012-821X .- 1385-013X. ; 531
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Tidskriftsartikel (refereegranskat)abstract
- The triple oxygen isotope compositions of phosphate grains in six martian meteorites have been measured by Secondary Ion Mass Spectrometry (SIMS) and combined together with their chlorine isotope and halogen concentrations have been used to constrain hydrosphere-lithosphere interactions on Mars. These samples include three enriched shergottites (Zagami, Roberts Massif 04262 and Larkman Nunatak 12011), one depleted shergottite (Tissint), an orthopyroxenite (Allan Hills 84001), and a regolith breccia (Northwest Africa 7533). The phosphates measured here have a range in δ18O [(18O/16O)sample/(18O/16O)Standard-1] × 103] from +1.0 to +6.8‰ and could be a result of indigenous mantle values, mixing with martian water, or replacement reactions taking place on the surface of Mars. Three samples have a Δ17O [δ17O-1000(1 + δ18O /1000)0.528-1] in equilibrium with the martian mantle (ALH 84001, Tissint, and Zagami), while three samples (LAR 12011, RBT 04262, and NWA 7533) have an elevated positive Δ17O outside of analytical uncertainty of the martian fractionation line (MFL). The phosphates in the latter group also have positive and negative δ37Cl [(37Cl/35Cl)sample/(37Cl/35Cl)standard – 1] × 103] and enrichments in halogens not seen in the rest of the sample suite. Perchlorate formation on Earth fractionates Cl in both positive and negative directions and generates a correlated positive Δ17O. Further, perchlorate has been detected in wt% amounts on the martian surface. Thus, these results strongly suggest the presence of multiple Cl isotope reservoirs on the martian surface that have interacted with the samples studied here over the last ca. 2 Ga of geologic time. The weighted average of Δ17O measurements from phosphate grains (n = 13) in NWA 7533, which are the explicit result of exchange reactions on the martian surface, yields a statistically robust mean value of 1.39 ± 0.19‰ (2σ, MSWD = 1.5, p = 0.13). This value likely represents an accurate estimate for an oxidized surface reservoir on Mars.
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| 5. |
- Bollard, J., et al.
(författare)
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Early formation of planetary building blocks inferred from Pb isotopic ages of chondrules.
- 2017
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Ingår i: Science Advances. - : American Association for the Advancement of Science (AAAS). - 2375-2548. ; 3
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Tidskriftsartikel (refereegranskat)abstract
- The most abundant components of primitive meteorites (chondrites) are millimeter-sized glassy spherical chondrules formed by transient melting events in the solar protoplanetary disk. Using Pb-Pb dates of 22 individual chondrules, we show that primary production of chondrules in the early solar system was restricted to the first million years after the formation of the Sun and that these existing chondrules were recycled for the remaining lifetime of the protoplanetary disk. This finding is consistent with a primary chondrule formation episode during the early high-mass accretion phase of the protoplanetary disk that transitions into a longer period of chondrule reworking. An abundance of chondrules at early times provides the precursor material required to drive the efficient and rapid formation of planetary objects via chondrule accretion.
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| 6. |
- Curran, N. M., et al.
(författare)
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The early geological history of the Moon inferred from ancient lunar meteorite Miller Range 13317
- 2019
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Ingår i: Meteoritics and Planetary Science. - : John Wiley & Sons, Ltd (10.1111). - 1086-9379 .- 1945-5100. ; 54:7, s. 1401-1430
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Tidskriftsartikel (refereegranskat)abstract
- Abstract Miller Range (MIL) 13317 is a heterogeneous basalt-bearing lunar regolith breccia that provides insights into the early magmatic history of the Moon. MIL 13317 is formed from a mixture of material with clasts having an affinity to Apollo ferroan anorthosites and basaltic volcanic rocks. Noble gas data indicate that MIL 13317 was consolidated into a breccia between 2610 ± 780 Ma and 1570 ± 470 Ma where it experienced a complex near-surface irradiation history for ~835 ± 84 Myr, at an average depth of ~30 cm. The fusion crust has an intermediate composition (Al2O3 15.9 wt%; FeO 12.3 wt%) with an added incompatible trace element (Th 5.4 ppm) chemical component. Taking the fusion crust to be indicative of the bulk sample composition, this implies that MIL 13317 originated from a regolith that is associated with a mare-highland boundary that is KREEP-rich (i.e., K, rare earth elements, and P). A comparison of bulk chemical data from MIL 13317 with remote sensing data from the Lunar Prospector orbiter suggests that MIL 13317 likely originated from the northwest region of Oceanus Procellarum, east of Mare Nubium, or at the eastern edge of Mare Frigoris. All these potential source areas are on the near side of the Moon, indicating a close association with the Procellarum KREEP Terrane. Basalt clasts in MIL 13317 are from a very low-Ti to low-Ti (between 0.14 and 0.32 wt%) source region. The similar mineral fractionation trends of the different basalt clasts in the sample suggest they are comagmatic in origin. Zircon-bearing phases and Ca-phosphate grains in basalt clasts and matrix grains yield 207Pb/206Pb ages between 4344 ± 4 and 4333 ± 5 Ma. These ancient 207Pb/206Pb ages indicate that the meteorite has sampled a range of Pre-Nectarian volcanic rocks that are poorly represented in the Apollo, Luna, and lunar meteorite collections. As such, MIL 13317 adds to the growing evidence that basaltic volcanic activity on the Moon started as early as ~4340 Ma, before the main period of lunar mare basalt volcanism at ~3850 Ma.
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| 7. |
- Gardiner, N.J., et al.
(författare)
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The closure of Palaeo-Tethys in Eastern Myanmar and Northern Thailand: New insights from zircon U–Pb and Hf isotope data.
- 2016
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Ingår i: Gondwana Research. - : Elsevier BV. - 1342-937X .- 1878-0571. ; 39, s. 401-422
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Tidskriftsartikel (refereegranskat)abstract
- Two of the major granite belts of Southeast Asia are the Main Range and Eastern Province. Together, these are interpreted to represent the magmatic expression of the closure of Palaeo-Tethys during Late Palaeozoic to Early Mesozoic times. Recent geochronological and geochemical work has better delineated these belts within Peninsular Malaysia, thereby providing important constraints on the timing of Palaeo-Tethys suturing. However, the northern extension of this Palaeo-Tethyan suture is less well understood. Here we present new ion microprobe U–Pb zircon age data from northern Thailand and eastern Myanmar. Measured ages of 219 and 220 Ma from the Kyaing Tong granite imply northern extension of the Main Range Province into eastern Myanmar. The Tachileik granite in far eastern Myanmar yields an age of 266 Ma, consistent with published Eastern Province ages, and this therefore constrains the northern extension of the Palaeo-Tethys suture in eastern Myanmar. We further discuss how this suture may extend northwards into Yunnan. A Late Cretaceous age (70 Ma) measured in Thailand represents later magmatic activity, and is similar to published magmatic ages from central Myanmar. This younger magmatism is interpreted to be related to the subduction of Neo-Tethys prior to India–Asia collision. Further, we present new laser ablation zircon Hf isotope data from eastern Myanmar which suggest that Palaeoproterozoic crust underlies both the Main Range and Eastern Province granites. Our εHf model age of ca. 1750 Ma from Sibumasu, the basement underlying eastern Myanmar, lies within the range of other model ages reported thus far for the Baoshan Block north in Yunnan, interpreted by some to be the northern extension of Sibumasu.
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| 8. |
- Gardiner, Nicholas J., et al.
(författare)
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The crustal architecture of Myanmar imaged through zircon U-Pb, Lu-Hf and O isotopes : Tectonic and metallogenic implications
- 2018
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Ingår i: Gondwana Research. - : Elsevier BV. - 1342-937X .- 1878-0571. ; 62, s. 27-60
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Tidskriftsartikel (refereegranskat)abstract
- The Tethys margin in central and eastern Asia is comprised of continental terranesseparated by suture zones, some of which remain cryptic. Determining the crustal architecture, and therefore the geological history, of the Eastern Tethyan margin remains challenging. Sited in the heart of this region, Myanmar is a highly prospective but poorly explored minerals jurisdiction. A better understanding of Myanmar's mineralization can only be realized through a better understanding of its tectonic history, itself reflected in at least four major magmatic belts. The Eastern and the Main Range Provinces are associated with the Late Permian to Early Triassic closure of Palaeo-Tethys. The Mogok–Mandalay–Mergui Belt and Wuntho–Popa Arc are a response to the Eocene closure of Neo-Tethys. However, magmatic ages outside these two orogenic events are also recorded. We present new zirconU-Pb, Lu-Hf and O isotope data from magmatic rocks across Myanmar, which we append to the existing dataset to isotopically characterize Myanmar's magmatic belts. Eastern Province Permian I-type magmatism has evolved εHf (−10.9 to −6.4), whilst Main Range Province Triassic S-type magmatism also records evolved εHf (−13.5 to −8.8). The Mogok-Mandalay-Mergui Belt is here divided into the Tin Province and the Mogok Metamorphic Belt. The Tin Province hosts ca. 77–50 Ma magmatism with evolved εHf (−1.2 to −15.2), and δ18O of 5.6–8.3‰. The Mogok Metamorphic Belt exhibits a more complex magmatic and metamorphic history, and granitoids record Jurassic, Late Cretaceous, and Eocene to Miocene phases of magmatism, all of which exhibit evolved εHf values between −4.6 and −17.6, and δ18O between 6.3 and 9.2‰. From the Tagaung-Myitkyina Belt, we report a magmatic age of 172 Ma and εHf of 18.1 to 10.8. To accommodate the geological evidence, we propose a tectonic model for Myanmar involving a greater Sibumasu – where the documented zircon isotopic variations reflect compositional variations in magmatic source – and invoke the role of a Tengchong Block. The Baoshan Block and Greater Sibumasu were likely assembled on or before the Triassic, a former Andean margin and suture which may lie across the Northern Shan Plateau, and reflected in isotopic differences between the northern and southern parts of the Mogok Metamorphic Belt. This contiguous Sibumasu–Baoshan Block then sutured onto the Indochina margin in the Late Triassic. We propose that a Tengchong Block within Myanmar provides for a southerly termination of the Meso-Tethys suture immediately north of the Mogok area. A discrete Tengchong Block may explain a discontinuous arc of Late Triassic to Jurassic I-type magmatism in central Myanmar, representing an Andean-type margin sited above a subducting Meso-Tethys on the margin of Sibumasu. The Tengchong Block sutured onto Greater Sibumasu before the Late Cretaceous, after which subduction of Neo-Tethys drove the magmatism of the Wuntho-Popa Arc and ultimately that of the Tin Province. The metallogenic character of granite belts in Myanmar reflects the crustal architecture of the region, which is remarkable for its prolific endowment of granite-hosted Sn-W mineralization in two quite distinct granite belts related to sequential Indosinian and Himalayan orogenesis.
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| 9. |
- Joy, K. H., et al.
(författare)
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Timing of geological events in the lunar highlands recorded in shocked zircon-bearing clasts from Apollo 16
- 2020
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Ingår i: Royal Society Open Science. - : Royal Society. - 2054-5703. ; 7:6
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Tidskriftsartikel (refereegranskat)abstract
- Apollo 16 soil-like regolith breccia 65745,7 contains two zircon-bearing clasts. One of these clasts is a thermally annealed silica-rich rock, which mineralogically has affinities with the High Alkali Suite (Clast 1), and yields zircon dates ranging from 4.08 to 3.38 Ga. The other clast is a KREEP-rich impact melt breccia (Clast 2) and yields zircon dates ranging from 3.97 to 3.91 Ga. The crystalline cores of both grains, which yield dates ofca3.9 Ga, have undergone shock pressure modification at less than 20 GPa. We interpret that the U-Pb chronometer in these zircon grains has been partially reset by the Imbrium basin-forming event when the clasts were incorporated into the Cayley Plains ejecta blanket deposit. The zircon grains in Clast 1 have been partially decomposed, resulting in a breakdown polymineralic texture, with elevated U, Pb and Th abundances compared with those in the crystalline zircon. These decomposed areas exhibit younger dates around 3.4 Ga, suggesting a secondary high-pressure, high-temperature event, probably caused by an impact in the local Apollo 16 highlands area.
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| 10. |
- Ng, S.W.-P., et al.
(författare)
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Petrogenesis of Malaysian granitoids in the Southeast Asian Tin Belt: Part 1. Geochemical and Sr-Nd isotopic characteristics.
- 2015
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Ingår i: Geological Society of America Bulletin. - 0016-7606 .- 1943-2674. ; 127, s. 1209-1237
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Tidskriftsartikel (refereegranskat)abstract
- The Malaysian granitoids of the Southeast Asian tin belt have been traditionally divided into a Permian to Late Triassic “I-type”–dominated arc-related Eastern province (Indochina terrane) and a Late Triassic “S-type”–dominated collision-related Main Range province (Sibumasu terrane), separated by the Bentong-Raub Paleo-Tethyan suture that closed in the Late Triassic. The present study, however, shows that this model is oversimplified and that the direct application of Chappell and White’s (1974) I- and S-type classification cannot account for many of the characteristics shared by Malaysian granitoids. Despite being commonly hornblende bearing, as is typical for I-type granites, the roof zones of the Eastern province granites are hornblende free. In addition, the Main Range province granitoids contain insignificant primary muscovite, and are dominated by biotite granites, mineralogically similar to many of the plutons of the Eastern province. In general, the Malaysian granitoids from both provinces are more enriched in high field strength elements than typical Cordilleran I- and S-type granitoids. The mineralogy and geochemistry of the Eastern province granitoids, and their relationship with contemporaneous volcanics, confirm their I-type nature. The bulk liquid lines of descent of both granitic provinces largely overlap with one another. Sr-Nd isotopic data further demonstrate that the Malaysian granitoids, especially those of the Main Range, were hybridized melts derived from two “end-member” source regions, one of which is isotopically similar to the Kontum orthoamphibolites and the other akin to the Kontum paragneisses of the Indochina block. However, there are differences in the source rocks for the two provinces, and it is suggested in this paper that these are related to differing proportions of igneous and sedimentary protoliths. The incorporation of sedimentary-sourced melts in the Eastern province is insignificant, which allowed the granites in this belt to maintain their I-type nature. The presence of minor primary tin mineralization in the Eastern province compared to the much more significant tin endowment in the Main Range is considered to reflect the incorporation of a smaller proportion of sedimentary protolith in the melt products of the former.
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