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- Andersson, N., et al.
(författare)
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Impact of dissolved lignin in peroxide bleaching
- 2017
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Ingår i: PEERS Conference 2017. - : TAPPI Press. - 9781510852464 ; , s. 597-604
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Konferensbidrag (refereegranskat)abstract
- It has been demonstrated in previous studies that dissolved lignin carryover has a significant impact in oxygen delignification and chlorine dioxide stages. Specifically for chlorine dioxide stages, it has been shown that the total kappa number of the pulp, i.e. the sum of the fiber kappa number and the filtrate kappa number, corresponds very well to its bleach demand and should be used for accurate feedforward based control. Since peroxide also is commonly used for pulp bleaching, and gaining in popularity, the present study was conducted in order to investigate the basic relations and mechanisms, using laboratory peroxide bleaching experiments comparing different carryover lignin concentrations and types. The results show that in particular chlorine dioxide filtrates have significant negative impact on delignification and brightening, likely due to alkali consumption of e.g. dissolved lignin, and that compensation using a higher alkali charge will result in lower brightness at a given kappa number. The paper also touches upon the opportunities using advanced process control systems for bleach plants, and the process and economic improvements which can be made by properly accounting for disturbances such as carryover variability.
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| 5. |
- Wilke, Caroline, 1982-, et al.
(författare)
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Impact of dissolved matter in the oxygen delignification stage
- 2017
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Ingår i: TAPPI Journal. - : TAPPI Press. - 0734-1415. ; 16:5, s. 275-284
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Tidskriftsartikel (refereegranskat)abstract
- The presence of dissolved matter in the pulp suspension in an oxygen (O-2) delignification stage, consisting mainly of dissolved lignin, is normally considered to negatively affect the delignification rate due to the competing reactions between the fiber bound lignin and the lignin dissolved in the filtrate. Recirculated oxidized filtrate from the post-O-2 washing is usually considered to be less harmful to the delignification efficiency than unoxidized dissolved matter originating from the cooking stage. To develop a better understanding of the mechanisms of the dissolved matter's reactions and impact on the O-2 stage performance, laboratory oxygen delignification experiments with varying levels of unoxidized and oxidized dissolved matter were conducted. The results showed that unoxidized dissolved matter had a negative impact on the delignification in the O-2 stage, whereas oxidized dissolved matter actually had a positive effect. The delignification efficiency of the laboratory experiments thus depends on both the amount of dissolved matter and its origin. The pulp viscosity decreased with increasing dissolved matter content irrespective of its origin but at higher COD levels; however, the viscosity drop was larger for the unoxidized dissolved matter. In terms of selectivity, the oxidized filtrate had a similar impact as additional NaOH charge. Both types of filtrates consumed hydroxide and the final pH decreased with increasing dissolved matter content. The final pH was significantly lower in the unoxidized filtrate experiments at higher COD levels, indicating a high reactivity between the unoxidized dissolved matter and the oxygen in the reactor. Based on the results, further understanding is achieved about the relation between pre-O-2 washing performance and process configuration in an actual mill case, as well as the impact of dissolved matter on delignification. The importance of efficient removal of harmful unoxidized dissolved matter is verified, but the results also suggest that the oxidized dissolved matter that is recirculated from post-O-2 washing actually has a significant positive impact on the delignification and is not just a potential problem in case of carryover to the bleach plant. Subsequently, pulp washing efficiency is critical both pre- and post-O-2.
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| 6. |
- Wilke, Caroline, 1982-, et al.
(författare)
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Impact of dissolved organic matter in DO-and ADO-stages in bleaching of birch kraft pulp
- 2019
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Ingår i: Nordic Pulp & Paper Research Journal. - : Walter de Gruyter. - 0283-2631 .- 2000-0669. ; 34:4, s. 433-441
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Tidskriftsartikel (refereegranskat)abstract
- To be able to charge a correct amount of chlorine dioxide in the D-0-stage, a pulp mill needs good control of the bleaching process and good sensors to keep the variability of the bleaching result on an acceptable level. It is also important to include the bleaching agent demand from the dissolved matter in the pulp slurry. If this is done correctly, over- or undercharging of bleaching agents can be reduced, which lead to lower bleaching chemical cost, lower polluting emissions and higher pulp quality. Our previous research has shown that the dissolved organic carryover from the O-2-stage varies significantly when bleaching softwood kraft pulp. The present study investigated the corresponding impact in the case of bleaching of birch pulp. Different mill configurations and process conditions have been simulated in laboratory trials, including proceeding A-stage treatment, different degrees of washing before and between the stages, and a comparison of the effects of recycled and non-recycled wash filtrates. The results have confirmed the significant impact of the dissolved organic matter, and the knowledge which have been generated can be used to understand how measurement and control concepts can be developed to improve the pulp quality control and to decrease production cost.
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| 7. |
- Wilke, Caroline, 1982-, et al.
(författare)
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Impact of dissolved organic matter in hydrogen peroxide reinforced alkaline extraction stages
- 2019
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Ingår i: Appita journal. - : Appita. - 1038-6807. ; 72:1, s. 4-14
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Tidskriftsartikel (refereegranskat)abstract
- It has been demonstrated in previous studies that carryover of dissolved organic matter to a following bleaching stage has a significant impact on the reactions in oxygen delignification and chlorine dioxide stages. Since hydrogen peroxide is commonly used in the bleach plant in various positions, the present study was conducted to investigate the impact of dissolved matter on the performance of a hydrogen peroxide reinforced alkaline extraction stage. The results of a study using an OD(EP) bleaching sequence showed that chlorine dioxide filtrates have a negative impact on delignification and brightening. In the case studied, the kappa number after the laboratory (EP)-stage was up to 26% higher and the brightness was up to 10% ISO lower when carryover of dissolved matter from a chlorine dioxide stage was present. Compensating for these reductions by increasing the sodium hydroxide charge improved the brightness significantly less than the delignification.
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| 8. |
- Wilke, Caroline, 1982-, et al.
(författare)
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Integrated Forest Biorefinery : A Proposed Pulp Mill of 2040
- 2021
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Rapport (refereegranskat)abstract
- Negative environmental impact from greenhouse gas emissions and a dwindling oil supply have resulted in an interest in biorefineries based on renewable resources. The objective of a biorefinery is to upgrade the biomass to more valuable products such as biofuels, electricity, materials, and chemicals. Wood biomass is a suitable raw material for a biorefinery since it is abundant, renewable and can be harvested all year round.In the kraft pulping process, only half of the wood biomass is converted into pulp while the remaining part is turned into energy. A conventional kraft pulp mill could be transformed into an integrated forest biorefinery, and thus produce for example biofuels and chemicals in addition to the traditional pulp and paper products, by implementing several new processes that could utilize the byproducts. Utilization of the byproducts for other purposes than energy would obviously affect the energy balance but also the important sodium/sulfur balance.The processes that are discussed in this report have the potential to be included in a BAT pulp mill built in 2040. The processes are black liquor gasification, on-site production of sulfuric acid, production of tall oil diesel, and lignin and hemicellulose extraction. The possibility to produce a cleaner green liquor through a new membrane filter is also discussed.
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| 9. |
- Wilke, Caroline, 1982-, et al.
(författare)
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Oxygen delignification : Laboratory evaluation of the impact of dissolved organic matter, sodium carbonate and sodium thiosulfate
- 2019
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Ingår i: Holzforschung. - : Walter de Gruyter. - 0018-3830 .- 1437-434X. ; 73:7, s. 645-652
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Tidskriftsartikel (refereegranskat)abstract
- Dissolved matter (DM) in the oxygen delignification (O2Del) stage affects the lignin and carbohydrate degradation. To understand this topic better, laboratory O2Del experiments were conducted with controlled addition of either unoxidized dissolved matter (UnoxDM) originating from the cooking stage or oxidized dissolved matter (OxDM) recycled from the post-O2Del washing. The presence of UnoxDM decreased the delignification, while the presence of OxDM showed the opposite effect, both compared to a well-washed pulp and at the same alkali charge level. However, both types of DM had a negative impact on the carbohydrate degradation. The distribution between these DMs will affect the resulting lignin degradation, because the filtrate accompanying the fibers into the O2Del stage is a mixture of UnoxDM and OxDM. It is proposed that the positive impact on the delignification by OxDM is due to the high carbonate ion concentration in the filtrate. Further, the high content of thiosulfate ions in the UnoxDM was one of the reasons for the lower delignification in its presence.
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| 10. |
- Wilke, Caroline, 1982-
(författare)
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The Impact of Dissolved Matter on Fiberline Processes
- 2018
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- The impact of dissolved matter on the performance of four fiberline process stages was investigated: oxygen delignification, hot acid treatment, chlorine dioxide bleaching, and hydrogen peroxide reinforced alkaline extraction. In particular the impact on delignification due to dissolved lignin was studied.The impact of unoxidized and oxidized dissolved matter on lignin and carbohydrate degradation was investigated in a laboratory oxygen delignification stage. It was concluded that the delignification was decreased by the presence of unoxidized dissolved matter but increased in the case of oxidized dissolved matter. Both types of dissolved matter comparably increased the carbohydrate degradation. Thus, the presence of unoxidized dissolved matter impaired the selectivity. In the case of oxidized dissolved matter, the selectivity was affected in the same way as when using a higher sodium hydroxide charge.The presence of dissolved matter reduced the efficiency of a laboratory hot acid stage, and subsequently further affected the chemical demand in a following chlorine dioxide stage. In a laboratory chlorine dioxide stage, the presence of dissolved matter reduced the delignification. The additional chemical demand required to compensate for this reduction was proportional to the content of dissolved matter. Moreover, the total chemical demand was found proportional to the total kappa number of the pulp, that is the sum of the fiber and filtrate kappa numbers. Finally, the presence of dissolved matter in a laboratory hydrogen peroxide reinforced alkaline extraction stage reduced both the delignification and the brightness.Furthermore, mill studies showed that the content of dissolved lignin varied significantly, and often more than the fiber-bound lignin, in a bleaching stage. For chlorine dioxide stages, it was proposed that the chemical consumption could be reduced by controlling the chemical charge based on the sum of the fiber-bound lignin and the dissolved lignin.
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