| 1. |
- Gao, Sanshuang, et al.
(författare)
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Sensitive and Selective Differential Pulse Voltammetry Detection of Cd(II) and Pb(II) Using Nitrogen-Doped Porous Carbon Nanofiber Film Electrode
- 2017
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Ingår i: Journal of the Electrochemical Society. - : Electrochemical Society. - 0013-4651 .- 1945-7111. ; 164:13, s. H967-H974
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Tidskriftsartikel (refereegranskat)abstract
- Carbon matrix materials are regarded as one of the most important electrode materials for heavy metal detection. But even so, optimization procedures of carbon nanofibers (CNFs) for tracing Cd(II) and Pb(II) remains challenging. Here, zeolitic imidazolate framework (ZIF-8)/polyacrylonitrile (PAN)-derived nitrogen-doped porous carbon nanofibers (N-PCNFs) were investigated as a new electrode material for determining the concentration of Cd(II) and Pb(II). By optimizing electrochemical conditions such as deposition potential, deposition time, pH of buffer solution, and quantity of N-PCNFs loaded on a glassy carbon electrode (GCE), the linear response curves of Cd(II) and Pb(II) could be obtained. Due to the unique structural feature and N content, the N-PCNFs possess excellent detection limits of 0.8 mu g L-1 for Cd(II) and 0.3 mu g L-1 for Pb(II) (S/N = 3). To manifest the practical use of the sensor platform the concentration of Cd(II) and Pb(II) in normal tap and waste water were monitored. According to the ICP-MS results, the calculated recovery (97.0-107%) indicates that N-PCNFs have potential as a candidate material to monitor the concentration of Cd(II) and Pb(II) in practical samples.
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| 2. |
- Qin, Danfeng, et al.
(författare)
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Protic salt-based nitrogen-doped mesoporous carbon for simultaneous electrochemical detection of Cd(II) and Pb(II)
- 2017
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Ingår i: RSC Advances. - : Royal Society of Chemistry. - 2046-2069. ; 7:59, s. 36929-36934
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Tidskriftsartikel (refereegranskat)abstract
- Nitrogen-doped mesoporous carbon (NMC) derived from a single small-molecule protic salt (p-phenylenediamine bisulfate) is used for sensing toxic heavy metal ions. Using Nafion, bismuth and NMC to anchor the glassy carbon electrode surface, the fabricate electrode shows high sensitivity for detecting Cd(II) and Pb(II). The limits of detection (S/N = 3) are estimated to be 0.3 mu g L-1 for Cd(II) and 0.4 mu g L-1 for Pb(II), respectively, which are 10 and 25 times lower than the maximum acceptable content for drinking water recommended by the WHO. Furthermore, the sensor is successfully used to analyze Cd(II) and Pb(II) in tap-water with high anti-interference capability and good recovery.
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| 3. |
- Qin, Danfeng, et al.
(författare)
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Three-dimensional carbon nanofiber derived from bacterial cellulose for use in a Nafion matrix on a glassy carbon electrode for simultaneous voltammetric determination of trace levels of Cd(II) and Pb(II)
- 2017
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Ingår i: Microchimica Acta. - : SPRINGER WIEN. - 0026-3672 .- 1436-5073. ; 184:8, s. 2759-2766
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Tidskriftsartikel (refereegranskat)abstract
- The authors describe the preparation of carbon nanofibers (CNFs) with a three-dimensional network structure by one-step carbonization of bacterial cellulose at 800 degrees C. The 3D CNFs wrapped with Nafion polymer were cast on a glassy carbon electrode (GCE) which then enables sensitive detection of Cd(II) and Pb(II). Under optimized conditions and at typical stripping peaks of around -0.80 and -0.55 V (vs Ag/AgCl), the electrode exhibits high sensitivity and a wide analytical range of 2-100 mu g.L-1 for both Cd(II) and Pb(II). The detection limits are 0.38 mu g.L-1 for Cd(II) and 0.33 mu g.L-1 for Pb(II), respectively. The modified GCE was successfully employed to the determination of trace amounts of Cd(II) and Pb(II) in both tap water and waste water.
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| 4. |
- Yalikun, Nuerbiya, et al.
(författare)
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Bacterial cellulose-based three-dimensional carbon nanofibers for the sensitive and selective determination of uric acid
- 2018
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Ingår i: Science of Advanced Materials. - : American Scientific Publishers. - 1947-2935 .- 1947-2943. ; 10:11, s. 1623-1629
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Tidskriftsartikel (refereegranskat)abstract
- In recent years, the interest in the optimization of novel nanomaterials for electrodes preparation has received tremendous attention. This article describe about develop an electrochemical sensor for to detect the uric acid (UA). Firstly, the sensing materials of carbon nanofibers (CNFs) were prepared through an economical approach under freeze-dried, mainly for CNFs were successfully synthesized through carbonized biomass green bacterial cellulose (BC) at 800 degrees C. The obtained CNFs were used to modify the glassy carbon electrode (GCE), and have an excellent electrochemical response towards the UA. Under the optimized condition, the current response of UA at the CNFs/GCE increased also the peak current linearly with the UA concentration, the limitation of detection (LOD) calculated as 0.29 mu M (S/N = 3), revealing the a high sensitivity and an broader analytical range of the as-prepared CNFs/GCE. Finally, the proposed electrochemical sensor can be used for detection of UA in human urine with the satisfactory result.
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| 5. |
- Yalikun, Nuerbiya, et al.
(författare)
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Synthesis of an iron-nitrogen co-doped ordered mesoporous carbon-silicon nanocomposite as an enhanced electrochemical sensor for sensitive and selective determination of chloramphenicol
- 2018
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Ingår i: Colloids and Surfaces B. - : Elsevier. - 0927-7765 .- 1873-4367. ; 172, s. 98-104
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Tidskriftsartikel (refereegranskat)abstract
- In this study, we developed a sensitive electrochemical sensor for the detection of chloramphenicol (CAP). An iron-nitrogen co-doped ordered mesoporous carbon-silicon nanocomposite (Si-Fe/NOMC) was prepared as follows. First, an SBA-15 surface was treated with an iron and nitrogen co-doped carbon framework obtained from the polymerization of ethylenediamine and carbon tetrachloride via the hard templating method. The mixture was then carbonized at a high temperature (900 degrees C). Finally, the Si-Fe/NOMC modified electrode was fabricated, and employed as a high-performance electrochemical sensor to trace the CAP in drug samples using the large surface area of the hetero-atoms iron, nitrogen and silicon co-doped in the porous structure. Cyclic voltammetry and differential pulse voltammetry tests were determine to assess the efficiency of the sensor. Under optimized conditions, the sensor exhibited rapid current response for CAP in a phosphate buffer solution PBS with pH 7.5. The linear concentration of CAP ranged from 1 mu M to 500 mu M, with a limit of detection of 0.03 mu M (S/N = 3). Furthermore, the electrochemical sensor was used to detect CAP in eye drop samples with satisfactory results.
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