| 1. |
- Luo, Yifei, et al.
(författare)
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Technology Roadmap for Flexible Sensors
- 2023
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Ingår i: ACS Nano. - : American Chemical Society. - 1936-0851 .- 1936-086X. ; 17:6, s. 5211-5295
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Forskningsöversikt (refereegranskat)abstract
- Humans rely increasingly on sensors to address grand challenges and to improve quality of life in the era of digitalization and big data. For ubiquitous sensing, flexible sensors are developed to overcome the limitations of conventional rigid counterparts. Despite rapid advancement in bench-side research over the last decade, the market adoption of flexible sensors remains limited. To ease and to expedite their deployment, here, we identify bottlenecks hindering the maturation of flexible sensors and propose promising solutions. We first analyze challenges in achieving satisfactory sensing performance for real-world applications and then summarize issues in compatible sensor-biology interfaces, followed by brief discussions on powering and connecting sensor networks. Issues en route to commercialization and for sustainable growth of the sector are also analyzed, highlighting environmental concerns and emphasizing nontechnical issues such as business, regulatory, and ethical considerations. Additionally, we look at future intelligent flexible sensors. In proposing a comprehensive roadmap, we hope to steer research efforts towards common goals and to guide coordinated development strategies from disparate communities. Through such collaborative efforts, scientific breakthroughs can be made sooner and capitalized for the betterment of humanity.
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| 2. |
- Liao, Wenlong, et al.
(författare)
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Simple Data Augmentation Tricks for Boosting Performance on Electricity Theft Detection Tasks
- 2023
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Ingår i: IEEE transactions on industry applications. - : Institute of Electrical and Electronics Engineers (IEEE). - 0093-9994 .- 1939-9367. ; 59:4, s. 1-12
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Tidskriftsartikel (refereegranskat)abstract
- In practical engineering, electricity theft detection is usually performed on highly imbalanced datasets (i.e., the number of fraudulent samples is much smaller than the benign ones), which limits the accuracy of the classifier. To alleviate the data imbalance problem, this article proposes simple data augmentation tricks (SDAT) to boost performance on electricity theft detection tasks. SDAT includes five simple but powerful operations: adding noises to electricity consumption readings, drifting values of electricity consumption readings, quantizing electricity consumption readings to a level set, adding a fixed value to electricity consumption readings, and adding changeable values to electricity consumption readings. In addition, eight potential tricks are also mentioned. Numerical simulations are conducted on a real-world dataset. The simulation results show that SDAT can significantly boost the performance of different classifiers, especially for small datasets. Besides, specific suggestions on how to select parameters of SDAT are provided for its migration use to other datasets.
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| 3. |
- Lu, Yang, et al.
(författare)
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Precise tuning of interlayer electronic coupling in layered conductive metal-organic frameworks
- 2022
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Ingår i: Nature Communications. - : Nature Portfolio. - 2041-1723. ; 13:1
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Tidskriftsartikel (refereegranskat)abstract
- Layered metal-organic frameworks attract interests for optoelectronics and spintronics. Here, the authors report a strategy to tune interlayer charge transport and thermoelectric properties via side-chain induced control of the layer spacing. Two-dimensional conjugated metal-organic frameworks (2D c-MOFs) have attracted increasing interests for (opto)-electronics and spintronics. They generally consist of van der Waals stacked layers and exhibit layer-depended electronic properties. While considerable efforts have been made to regulate the charge transport within a layer, precise control of electronic coupling between layers has not yet been achieved. Herein, we report a strategy to precisely tune interlayer charge transport in 2D c-MOFs via side-chain induced control of the layer spacing. We design hexaiminotriindole ligands allowing programmed functionalization with tailored alkyl chains (HATI_CX, X = 1,3,4; X refers to the carbon numbers of the alkyl chains) for the synthesis of semiconducting Ni-3(HATI_CX)(2). The layer spacing of these MOFs can be precisely varied from 3.40 to 3.70 angstrom, leading to widened band gap, suppressed carrier mobilities, and significant improvement of the Seebeck coefficient. With this demonstration, we further achieve a record-high thermoelectric power factor of 68 +/- 3 nW m(-1) K-2 in Ni-3(HATI_C3)(2), superior to the reported holes-dominated MOFs.
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| 4. |
- Yang, Hao, et al.
(författare)
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Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites
- 2022
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Ingår i: Nature Catalysis. - : Springer Nature. - 2520-1158. ; 5:5, s. 414-429
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Tidskriftsartikel (refereegranskat)abstract
- Exploration of efficient water oxidation catalysts (WOCs) is the primary challenge in conversion of renewable energy into fuels. Here we report a molecularly well-defined heterogeneous WOC with Aza-fused, pi-conjugated, microporous polymer (Aza-CMP) coordinated single cobalt sites (Aza-CMP-Co). The single cobalt sites in Aza-CMP-Co exhibited superior activity under alkaline and near-neutral conditions. Moreover, the molecular nature of the isolated catalytic sites makes Aza-CMP-Co a reliable model for studying the heterogeneous water oxidation mechanism. By a combination of experimental and theoretical results, a pH-dependent nucleophilic attack pathway for O-O bond formation was proposed. Under alkaline conditions, the intramolecular hydroxyl nucleophilic attack (IHNA) process with which the adjacent -OH group nucleophilically attacks Co4+=O was identified as the rate-determining step. This process leads to lower activation energy and accelerated kinetics than those of the intermolecular water nucleophilic attack (WNA) pathway. This study provides significant insights into the crucial function of electrolyte pH in water oxidation catalysis and enhancement of water oxidation activity by regulation of the IHNA pathway.
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| 5. |
- Yang, Wenlong, et al.
(författare)
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Performance improvement and thermomechanical analysis of a novel asymmetrical annular thermoelectric generator
- 2024
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Ingår i: Applied Thermal Engineering. - 1359-4311. ; 237
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Tidskriftsartikel (refereegranskat)abstract
- Enhancing thermoelectric performance hinges on optimizing the geometry of thermoelectric legs. In this study, we present a novel asymmetrical annular thermoelectric generator (ATEG) in which the proportions of P-type and N-type legs are meticulously balanced. We construct a one-dimensional analytical model tailored to this ATEG. Utilizing this model, we derive the relationship governing thermal-electrical impedance matching in an asymmetrical ATEG and formulate a general expression for optimizing the asymmetry coefficient. We explore the influence of various thermal boundary conditions on optimal impedance matching, ideal annular leg parameters, and the optimal asymmetry coefficient. Our findings reveal that thermal boundary conditions significantly affect the optimal load ratio. Furthermore, in comparison to traditional ATEGs, our proposed asymmetrical ATEG with the optimized structure exhibits a remarkable 16.2 % increase in output power while maintaining the same material volume. Additionally, we perform a three-dimensional numerical analysis of the asymmetrical ATEG using Comsol. Our research findings indicate that introducing the asymmetric structure leads to higher maximum thermal stress on the legs. Interestingly, the study of asymmetric thermal boundary conditions highlights that improving heat transfer between the ATEG and the cooler yields higher mechanical reliability compared to enhancing heat transfer between the ATEG and the heat source.
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| 6. |
- Yang, Wenlong, et al.
(författare)
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Simulation and experimental study of thermoelectric generators with an axial gradient metal foam heat exchanger
- 2024
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Ingår i: Renewable Energy. - 0960-1481 .- 1879-0682. ; 232
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Tidskriftsartikel (refereegranskat)abstract
- The utilization of metal foam for heat transfer augmentation is regarded as a highly efficient technique, albeit associated with significant pressure losses. To enhance the feasibility of employing metal foam in thermoelectric generators and mitigate the high-pressure drop, we propose an enhancement strategy involving the partial axial filling of gradient metal foam. Both analytical modeling and experimental investigation were employed to evaluate the effects of porosity, pore density, and gradient structure at various filling rates on the overall performance of thermoelectric generators. The results show that arranging metal foam with increasingly high frame density in the direction of fluid flow, rather than adopting increasingly sparse or constant structures, leads to improved voltage uniformity and reduced pressure drop. A positive gradient configuration with a pore density distribution of 5-10-20 PPI yielded the highest net power at 118.3 W, which is 12.5 % higher than that of metal foam with constant 20 PPI. Ultimately, empirical verification substantiates the comprehensive performance advantages of positive gradient configuration. For filling rates of 30 %, 60 %, and 100 %, pressure drop is reduced by 35.9 %, 33.4 %, and 29.2 %, respectively, in comparison to constant 20 PPI metal foam, despite a modest reduction in output power, which remains less than 3 %.
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| 7. |
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| 8. |
- Zhao, Li-Chen, et al.
(författare)
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Spin soliton with a negative-positive mass transition
- 2020
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Ingår i: Physical Review A: covering atomic, molecular, and optical physics and quantum information. - : AMER PHYSICAL SOC. - 2469-9926 .- 2469-9934. ; 101:4
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Tidskriftsartikel (refereegranskat)abstract
- We obtain a striking spin soliton in a two-component Bose-Einstein condensate and investigate its motions in the presence of a constant force. The initially static spin soliton first moves in a direction opposite to the force and then changes direction, showing an extraordinary ac oscillation. The underlying mechanism is uncovered: the spin soliton can exhibit a periodic transition between negative and positive inertial mass because of a particular relation between its energy and moving velocity. We then develop a quasiparticle model that can account for this extraordinary oscillation. Important implications and possible applications are discussed.
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| 9. |
- Li, Fusheng, et al.
(författare)
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Device Fabrication for Water Oxidation, Hydrogen Generation, and CO2 Reduction via Molecular Engineering
- 2018
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Ingår i: Joule. - : CELL PRESS. - 2542-4351. ; 2:1, s. 36-60
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Tidskriftsartikel (refereegranskat)abstract
- Research on the storage of solar energy in terms of hydrogen or carbon-based fuels by using sunlight to split water or to reduce CO2, respectively, has gained significant attention in recent years. Among reported water-splitting systems, one approach has focused on hybrid systems with molecular catalysts or molecular light-harvesting systems that are combined with nanostructured materials. In this perspective we summarize recent developments in operation and fabrication strategies for various water-splitting devices constructed from electrodes (electrochemical cells) or photoelectrodes (photoelectrochemical cells) using molecular engineering. We also provide insights into the factors that influence device efficiency and stability, and provide guidelines for future fabrication strategies for more advanced devices.
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| 10. |
- Li, Gang, et al.
(författare)
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Selective Electrochemical Alkaline Seawater Oxidation Catalyzed by Cobalt Carbonate Hydroxide Nanorod Arrays with Sequential Proton-Electron Transfer Properties
- 2021
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Ingår i: ACS Sustainable Chemistry and Engineering. - : American Chemical Society (ACS). - 2168-0485. ; 9:2, s. 905-913
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Tidskriftsartikel (refereegranskat)abstract
- Seawater oxygen evolution is one of the promising energy conversion technologies for large-scale renewable energy storage. It requires efficient catalysts to accelerate the oxygen evolution reaction (OER) for sustained water oxidation, avoiding chlorine evolution under acidic conditions or hypochlorite formation in alkaline solutions. Conventional metal oxide-based OER catalysts follow the adsorbate evolution mechanism that involves concerted proton-electron transfer steps at the active sites. Thus, on the scale of reversible hydrogen electrode, their catalytic activity is independent of the pH of electrolytes. In the present study, nanostructured cobalt carbonate hydroxide (CoCH) with sequential proton-electron transfer properties was tested as a catalyst for seawater oxygen evolution. CoCH exhibited pH-dependent water oxidation activities, thereby providing larger potential and current operating windows for selective water oxidation compared to the catalysts with pH-independent OER activities. The operating window can be further expanded by increasing the pH of the electrolyte.
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