| 1. |
- Brohede, Ulrika, et al.
(författare)
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A novel graded bioactive high adhesion implant coating
- 2009
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Ingår i: Applied Surface Science. - : Elsevier BV. - 0169-4332 .- 1873-5584. ; 255:17, s. 7723-7728
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Tidskriftsartikel (refereegranskat)abstract
- One method to increase the clinical success rate of metal implants is to increase their bone bonding properties, i.e. to develop a bone bioactive surface leading to reduced risks of interfacial problems. Much research has been devoted to modifying the surface of metals to make them become bioactive. Many of the proposed methods include depositing a coating on the implant. However, there is a risk of coating failure due to low substrate adhesion. This paper describes a method to obtain bioactivity combined with a high coating adhesion via a gradient structure of the coating. Gradient coatings were deposited on Ti (grade 5) using reactive magnetron sputtering with increasing oxygen content. To increase the grain size in the coating, all coatings were post annealed at 385 degrees C. The obtained coating exhibited a gradual transition over 70 nm from crystalline titanium oxide (anatase) at the surface to metallic Ti in the substrate, as shown using cross-section transmission electron microscopy and X-ray photoelectron spectroscopy depth pro. ling. Using scratch testing, it could be shown that the adhesion to the substrate was well above 1 GPa. The bioactivity of the coating was verified in vitro by the spontaneous formation of hydroxylapatite upon storage in phosphate buffer solution at 37 degrees C for one week. The described process can be applied to implants irrespective of bulk metal in the base and should introduce the possibility to create safer permanent implants like reconstructive devices, dental, or spinal implants.
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| 2. |
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| 3. |
- Försth, Michael, et al.
(författare)
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Spectrally selective and adaptive surfaces for protection against radiative heating : ITO and VO2
- 2014
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Ingår i: Fire and Materials. - : Wiley. - 0308-0501 .- 1099-1018. ; 38:1, s. 111-124
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Tidskriftsartikel (refereegranskat)abstract
- Two surface materials for reducing absorptivity of heat radiation from fires have been investigated. The first is VO2, which is a thermochromic material. When the temperature of a VO2 surface increases over a certain temperature, it switches, ideally, from infrared (IR)-absorbing to IR-reflecting. VO2 window coatings are still on a research level, yet to be commercialized. In this study, VO2 powder available on the market was investigated. The thermochromic effect could be identified but was not large enough to significantly improve the fire properties of treated surfaces. Some thoughts concerning how to improve the performance of VO2 are discussed. The second investigated material is indium tin oxide (ITO), which is a so called low-e coating, which means that it has low emissivity and absorptivity in the IR part of the spectrum. ITO is spectrally selective in the sense that it transmits visible light while reflecting a large fraction of the IR radiation, which is a rare property for surfaces in general but a typical property of thin electrically conducting non-metallic films. It is shown that the application of ITO to poly(methyl methacrylate) (PMMA) significantly improves its fire properties. ITO coating is a mature technology already in widespread use today in the electronics industry.
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| 4. |
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| 5. |
- Kubart, Tomas, et al.
(författare)
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A model of DC reactive magnetron sputtering for graded solar thermal absorbers
- 2008
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Ingår i: Journal of Physics, Conference Series. - : IOP Publishing. - 1742-6588 .- 1742-6596. ; 100:8, s. 082024-
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Tidskriftsartikel (refereegranskat)abstract
- In this work we present process modelling of reactive in-line sputtering. Although modelling of reactive sputtering is often used, most models are based on assumptions which make them insufficient for use in this case. The presented model takes into account a realistic deposition rate profile and distribution of reactive gas pressure. The model has been applied to reactive sputter deposition of graded solar thermal absorbers. It has been shown that the presented model represents a simple alternative to complex Monte Carlo simulations while still representing all important features of the process.
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| 6. |
- Ning, Yuping, et al.
(författare)
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Effects of substrates, film thickness and temperature on thermal emittance of Mo/substrate deposited by magnetron sputtering
- 2016
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Ingår i: Vacuum. - : Elsevier BV. - 0042-207X .- 1879-2715. ; 128, s. 73-79
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Tidskriftsartikel (refereegranskat)abstract
- The thermal emittance of the Mo film, as an IR-refiector in solar selective absorbing coatings, is the most important property. The effects of the substrate material, the substrate surface roughness, the film thickness and the temperature on the thermal emittance of the Mo/substrate have been investigated. A series of Mo films with increasing film thickness were deposited on two types of substrate materials (glass and stainless steel). A saturated Mo thickness of 50 nm is found to produce the lowest thermal emittance. The thermal emittance of the Mo film is reduced by decreasing the substrate surface roughness. The emittance of the optimal Mo film remains 0.05 from 25 degrees C to 400 degrees C, which can meet the optical requirements for the IR-reflector.
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| 7. |
- Ning, Yuping, et al.
(författare)
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Investigation on low thermal emittance of Al films deposited by magnetron sputtering
- 2016
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Ingår i: Infrared physics & technology. - : Elsevier BV. - 1350-4495 .- 1879-0275. ; 75, s. 133-138
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Tidskriftsartikel (refereegranskat)abstract
- A series of Al films with different thicknesses were deposited on polished stainless steel by direct current (DC) magnetron sputtering as a metal IR-reflector layer in solar selective absorbing coating (SSAC). The effects of the film thickness and the temperature on the thermal emittance of the Al films are studied. An optimal thickness 78 nm of the Al film for the lowest total thermal emittance is obtained. The thermal emittance of the optimal Al film keeps close to 0.02 from 25 degrees C to 400 degrees C, which are low enough to satisfy the optical requirements in SSAC. The optical constants of the AI film are deduced by fitting the reflectance and transmission spectra using SCOUT software.
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| 8. |
- Ning, Yuping, et al.
(författare)
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Optical simulation and preparation of novel Mo/ZrSiN/ZrSiON/SiO2 solar selective absorbing coating
- 2017
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Ingår i: Solar Energy Materials and Solar Cells. - : Elsevier BV. - 0927-0248 .- 1879-3398. ; 167, s. 178-183
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Tidskriftsartikel (refereegranskat)abstract
- A novel Mo/ZrSiN/ZrSiON/SiO2 solar selective absorbing coating has been investigated, which was prepared by magnetron sputtering on stainless steel substrate. A high solar absorptance of 0.94 and a low thermal emittance of 0.06 at 25 degrees C were achieved. By proportionally decreasing the thicknesses of the ZrSiN, ZrSiON and SiO2 layers, the thermal emittance at 500 degrees C was decreased significantly from 0.19 to 0.12 (Delta epsilon = 0.07) while keeping the solar absorptance unchanged. The coating also showed high thermal stability at 500 degrees C in vacuum, implying that it is a promising candidate for high temperature concentrated solar power (CSP) applications.
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| 9. |
- Ning, Yuping, et al.
(författare)
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Tuning of reflectance transition position of Al-AlN cermet solar selective absorbing coating by simulating
- 2017
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Ingår i: Infrared physics & technology. - : Elsevier BV. - 1350-4495 .- 1879-0275. ; 80, s. 65-70
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Tidskriftsartikel (refereegranskat)abstract
- The reflectance spectra of the AI/double cermet Al-AIN/AIO(x)N(y) solar selective absorbing coating are simulated. Two methods have been found to effectively tune the position of reflectance transition of the Al-MN cermet solar selective absorbing coating, which is crucial to obtain a low emittance at elevated temperature. The position of reflectance transition is mainly determined by the high metal volume fraction (HMVF) cermet layer. It is effectively tuned to shift to lower wavelength by reducing the metal volume fraction or the thickness of the HMVF layer. This provides easy ways to tune the position of reflectance transition.
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| 10. |
- Wu, Yongxin, et al.
(författare)
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Optical simulation and experimental optimization of Al/NbMoN/NbMoON/SiO2 solar selective absorbing coatings
- 2015
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Ingår i: Solar Energy Materials and Solar Cells. - : Elsevier BV. - 0927-0248 .- 1879-3398. ; 134, s. 373-380
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Tidskriftsartikel (refereegranskat)abstract
- For the applications in solar thermal power, the preparation and optimization of an Al/NbMoN/NbMoON/SiO2 multilayer solar selective absorbing coating are carried out by combining experiments with optical simulation. A series of NbMoN and NbMoON single layers are deposited by magnetron reactive sputtering method with different N-2/O-2 gas flowing rates. And then their optical constants are obtained by fitting their reflection (R) and transmission (T) spectra in the wavelength range of 300-2500 nm using SCOUT software. These optical constants are used to design the Al/NbMoN/NbMoON/SiO2 solar selective absorbing coating so as to get the ideal spectral selectivity, i.e. high alpha/epsilon ratio. According to the optical design of the coating structure, we prepared the all-layer coating, and the thickness of each layer was optimized until the best spectral selective properties are obtained. The experimental reflectance spectrum fits very well with the simulated result. The optimized solar absorbing coating deposited on stainless steel substrate exhibited high absorptance (alpha=0.948) and low emittance (epsilon=0.050) at 80 degrees C. It offers a good method to quickly reach the ideal spectral selectivity through optical simulation. The thermal stability of the coating is evaluated, and it exhibits a good thermal stability in vacuum at 400 degrees C.
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