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| 2. |
- Geng, Longlong, et al.
(författare)
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Valence-mixed CuOx-nanoparticles anchored biomass-based carbon nanofiber for boosting toxic nitroarenes reduction : Synthesis, kinetics, and mechanisms
- 2022
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Ingår i: Journal of Environmental Chemical Engineering. - : Elsevier. - 2213-3437. ; 10:6
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Tidskriftsartikel (refereegranskat)abstract
- The rational modulation of metal catalysts with tailorable valence and redox properties is a promising strategy for further improving their catalytic performance. Herein, an environment-friendly grafting and thermal strategy was adopted to immobilize copper oxides nanoparticles on carbon nanofiber (CuOx/CF). Benefiting from the defect-rich surface and valence-mixed composition of the CuOx species, the optimized sample CuOx/CF-3 exhibits superb activity for the catalytic reduction of toxic nitrophenols. The complete conversion took only 1 min and an outstanding rate constant (k) of 112.7 × 10-3 s-1 was achieved under mild conditions (25 °C and 1 atm). Kinetic and recycle experiments demonstrated that the whole catalytic process obeys a pseudo-order kinetic, and the catalyst could maintain high conversion even after 13 successive recycles. These results demonstrate that CuOx/CF-3 is an alternative catalyst to noble metals, providing superb catalytic efficiency and stability in the reduction of toxic nitrophenols, and it can be expanded to develop other noble-metal-free catalysts for various applications.
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| 3. |
- Li, Sirui, et al.
(författare)
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Glioma grading, molecular feature classification, and microstructural characterization using MR diffusional variance decomposition (DIVIDE) imaging
- 2021
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Ingår i: European Radiology. - : Springer Science and Business Media LLC. - 0938-7994 .- 1432-1084. ; 31:11, s. 8197-8207
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Tidskriftsartikel (refereegranskat)abstract
- Objective: To evaluate the potential of diffusional variance decomposition (DIVIDE) for grading, molecular feature classification, and microstructural characterization of gliomas. Materials and methods: Participants with suspected gliomas underwent DIVIDE imaging, yielding parameter maps of fractional anisotropy (FA), mean diffusivity (MD), anisotropic mean kurtosis (MKA), isotropic mean kurtosis (MKI), total mean kurtosis (MKT), MKA/MKT, and microscopic fractional anisotropy (μFA). Tumor type and grade, isocitrate dehydrogenase (IDH) 1/2 mutant status, and the Ki-67 labeling index (Ki-67 LI) were determined after surgery. Statistical analysis included 33 high-grade gliomas (HGG) and 17 low-grade gliomas (LGG). Tumor diffusion metrics were compared between HGG and LGG, among grades, and between wild and mutated IDH types using appropriate tests according to normality assessment results. Receiver operating characteristic and Spearman correlation analysis were also used for statistical evaluations. Results: FA, MD, MKA, MKI, MKT, μFA, and MKA/MKT differed between HGG and LGG (FA: p = 0.047; MD: p = 0.037, others p < 0.001), and among glioma grade II, III, and IV (FA: p = 0.048; MD: p = 0.038, others p < 0.001). All diffusion metrics differed between wild-type and mutated IDH tumors (MKI: p = 0.003; others: p < 0.001). The metrics that best discriminated between HGG and LGGs and between wild-type and mutated IDH tumors were MKT and FA respectively (area under the curve 0.866 and 0.881). All diffusion metrics except FA showed significant correlation with Ki-67 LI, and MKI had the highest correlation coefficient (rs = 0.618). Conclusion: DIVIDE is a promising technique for glioma characterization and diagnosis. Key Points: • DIVIDE metrics MKIis related to cell density heterogeneity while MKAand μFA are related to cell eccentricity. • DIVIDE metrics can effectively differentiate LGG from HGG and IDH mutation from wild-type tumor, and showed significant correlation with the Ki-67 labeling index. • MKIwas larger than MKAwhich indicates predominant cell density heterogeneity in gliomas. • MKAand MKIincreased with grade or degree of malignancy, however with a relatively larger increase in the cell eccentricity metric MKAin relation to the cell density heterogeneity metric MKI.
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| 4. |
- Pott, Christian, et al.
(författare)
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Wielandiella villosa comb. nov. from the Middle Jurassic of Daohugou, China: More evidence for divaricate plant architecture in Williamsoniaceae
- 2015
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Ingår i: Botanica Pacifica. - Vladivostok. - 2226-4701. ; 4:2, s. 137-148
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Tidskriftsartikel (refereegranskat)abstract
- Recently discovered fossils yielding branched axes with attached foliage are described from the Middle Jurassic Daohugou beds, Inner Mongolia, China. The leaves of the plant were earlier described as isolated and disarticulated foliage and assigned to Anomozamites villosus; the plant architecture, however, necessitates the re-assignment of the fossils under study to Wielandiella, a bennettitalean whole-plant fossil taxon that includes stems, leaves and unisexual ovuliferous repro-ductive structures. Wielandiella villosa is the second known species attributable to Wielandiella and extends the taxon’s range from the Rhaetian into the Middle Jurassic. Wielandiella villosa is interpreted to encompass specialised shrubs that are regarded to have thrived in swampy settings but also potentially extended to other lowland habitats, especially where conditions of physiological drought prevailed; conditions that, in modern vegetation, are considered to favour the development of divaricate plant growth forms. The foliage and reproductive organs of these medium-sized shrubs would have been of suitable size for ground-based animals to browse, potentially also stimulating a divaricate growth form in Wielandiella villosa. The ecological pressures promoting indumentum development and the protruding hairs on the leaves of Wielandiella villosa are interpreted as predominant-ly an adaptation for passive defence against herbivores rather than xeromorphic features. The latter add to ongoing investigations of the depositional setting of the fossils in order to unravel the plant’s habitat and micro-climate at Daohugou.
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| 5. |
- Qi, Xingmei, et al.
(författare)
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Spider silk protein forms amyloid-like nanofibrils through a non-nucleation-dependent polymerization mechanism
- 2023
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Ingår i: Small. - : John Wiley & Sons. - 1613-6810 .- 1613-6829. ; 18:46
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Tidskriftsartikel (refereegranskat)abstract
- Amyloid fibrils—nanoscale fibrillar aggregates with high levels of order—are pathogenic in some today incurable human diseases; however, there are also many physiologically functioning amyloids in nature. The process of amyloid formation is typically nucleation-elongation-dependent, as exemplified by the pathogenic amyloid-β peptide (Aβ) that is associated with Alzheimer's disease. Spider silk, one of the toughest biomaterials, shares characteristics with amyloid. In this study, it is shown that forming amyloid-like nanofibrils is an inherent property preserved by various spider silk proteins (spidroins). Both spidroins and Aβ capped by spidroin N- and C-terminal domains, can assemble into macroscopic spider silk-like fibers that consist of straight nanofibrils parallel to the fiber axis as observed in native spider silk. While Aβ forms amyloid nanofibrils through a nucleation-dependent pathway and exhibits strong cytotoxicity and seeding effects, spidroins spontaneously and rapidly form amyloid-like nanofibrils via a non-nucleation-dependent polymerization pathway that involves lateral packing of fibrils. Spidroin nanofibrils share amyloid-like properties but lack strong cytotoxicity and the ability to self-seed or cross-seed human amyloidogenic peptides. These results suggest that spidroins' unique primary structures have evolved to allow functional properties of amyloid, and at the same time direct their fibrillization pathways to avoid formation of cytotoxic intermediates.
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| 6. |
- Qi, Xingmei, et al.
(författare)
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Spider Silk Protein Forms Amyloid-Like Nanofibrils through a Non-Nucleation-Dependent Polymerization Mechanism (Small 46/2023)
- 2023
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Ingår i: Small. - : Wiley. - 1613-6810 .- 1613-6829. ; 19:46
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Tidskriftsartikel (refereegranskat)abstract
- Amyloid fibrils—nanoscale fibrillar aggregates with high levels of order—are pathogenic in some today incurable human diseases; however, there are also many physiologically functioning amyloids in nature. The process of amyloid formation is typically nucleation-elongation-dependent, as exemplified by the pathogenic amyloid-β peptide (Aβ) that is associated with Alzheimer's disease. Spider silk, one of the toughest biomaterials, shares characteristics with amyloid. In this study, it is shown that forming amyloid-like nanofibrils is an inherent property preserved by various spider silk proteins (spidroins). Both spidroins and Aβ capped by spidroin N- and C-terminal domains, can assemble into macroscopic spider silk-like fibers that consist of straight nanofibrils parallel to the fiber axis as observed in native spider silk. While Aβ forms amyloid nanofibrils through a nucleation-dependent pathway and exhibits strong cytotoxicity and seeding effects, spidroins spontaneously and rapidly form amyloid-like nanofibrils via a non-nucleation-dependent polymerization pathway that involves lateral packing of fibrils. Spidroin nanofibrils share amyloid-like properties but lack strong cytotoxicity and the ability to self-seed or cross-seed human amyloidogenic peptides. These results suggest that spidroins´ unique primary structures have evolved to allow functional properties of amyloid, and at the same time direct their fibrillization pathways to avoid formation of cytotoxic intermediates.
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| 7. |
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| 8. |
- Wei, Linyong, et al.
(författare)
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An Extended Triple Collocation Method With Maximized Correlation for Near Global-Land Precipitation Fusion
- 2023
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Ingår i: Geophysical Research Letters. - 0094-8276. ; 50:24
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Tidskriftsartikel (refereegranskat)abstract
- An Extended Triple Collocation for maximized Correlation (ETCC) method was proposed with a unique correlation function, the purpose of which is to maximize the correlation between the merged product and unknown truth. The method was tested over quasi-global land by combining three independent precipitation products. The performance of the ETCC-merged product was then evaluated against three reference data sets and compared with the existing Triple Collocation (TC) merging. The merged product was found to be generally superior to each contributor. Moreover, the ETCC method is better able to improve the correlation of merged product compared with the TC approach. Other improvements are also shown in the absolute difference of the ETCC-merged product, such as regional validation for central North America and mainland China. These demonstrate the effectiveness of the ETCC method, and accordingly, it can provide a promising solution for maximizing the correlation of merged product without the truth.
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| 9. |
- Wei, Linyong, et al.
(författare)
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Spatiotemporal changes of terrestrial water storage and possible causes in the closed Qaidam Basin, China using GRACE and GRACE Follow-On data
- 2021
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Ingår i: Journal of Hydrology. - : Elsevier BV. - 0022-1694. ; 598
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Tidskriftsartikel (refereegranskat)abstract
- Terrestrial water storage (TWS) is a crucial indicator of regional water balance and water resources changes. Due to limited hydrological observations, we combined the Gravity Recovery and Climate Experiment (GRACE) and GRACE Follow-On (GRACE-FO) products using the Long Short-Term Memory (LSTM) neural network to monitor the TWS changes from April 2002 to March 2020 over the closed Qaidam Basin in northwest China and examined the impacts of climate and meteorological changes on TWS variations. The results indicated that the LSTM model, driven by the cumulative precipitation, temperature, and Global Land Data Assimilation System datasets, was reliable for use in reconstruction of the GRACE products in the closed basin. The TWS variations featured seasonal variation characteristics and a significant upward trend at internal-annual scales, which were tested via linear statistics and a modified Mann–Kendall method. The increasing trend is likely to remain strongly sustainable in the near future with a Hurst index over 0.75 in most regions. Moreover, the TWS oscillation has a periodicity and nonlinearity increase trend of 0.43 mm/month as observed using ensemble empirical mode decomposition analysis, and the TWS components (including snow water equivalent, soil moisture, and groundwater) demonstrate discordant increasing trends in the basin. Under climate change conditions, teleconnection factors have strong impacts on TWS variability, particularly for the Pacific Decadal Oscillation index with a significant negative correlation by cross wavelet transform technology. Nonetheless, the increase in TWS is primarily influenced by precipitation increases and is more sensitive to the accumulated precipitation in this region. In this study, the GRACE products in combination with GRACE-FO data may help us to better understand the spatiotemporal characterization of TWS in Qaidam Basin, which will provide an important support for the water resource management and ecological environment protection in such data-scarce regions.
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