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1.	Huang, Xiaofeng, et al. (författare) Solvent racing crystallization : Low-solvation dispersion cosolvents for high-quality halide perovskites in photovoltaics 2023 Ingår i: Joule. - : Elsevier. - 2542-4351. ; 7:7, s. 1556-1573 Tidskriftsartikel (refereegranskat)abstract The solvation capacity of dispersion solvents plays a crucial role in the solution processing of metal halide perovskites. For instance, N,N-dimethylformamide (DMF), a widely used dispersion solvent, possesses high solvation capacity but often generates suboptimal film quality due to slow crystallization kinetics. We propose using low-solvation binary cosolvents (nitrile-and ether-type solvents) to achieve a balance between solvation (i.e., sufficient solubility of precursors) and desolvation (i.e., rapid crystallization of films) pro-cesses during perovskite synthesis. The polarity and hydrogen -bonding property of these cosolvents synergistically enhance their solvation capacity, facilitating perovskite precursor dissolution. Moreover, the low-solvation cosolvents accelerate the crystalliza-tion of well-defined intermediate films, yielding higher-quality pe-rovskites than those synthesized with DMF. The optimized modules achieved an active-area efficiency of 22.27%, with a certified aper-ture-area efficiency of 16.10% and corresponding active-area effi-ciency of 20.75%. This research on solvation regulation provides universal guidelines for innovatively preparing high-quality halide perovskites.

Huang, Xiaofeng, et al. (författare)
Solvent racing crystallization : Low-solvation dispersion cosolvents for high-quality halide perovskites in photovoltaics
2023
Ingår i: Joule. - : Elsevier. - 2542-4351. ; 7:7, s. 1556-1573
Tidskriftsartikel (refereegranskat)abstract
- The solvation capacity of dispersion solvents plays a crucial role in the solution processing of metal halide perovskites. For instance, N,N-dimethylformamide (DMF), a widely used dispersion solvent, possesses high solvation capacity but often generates suboptimal film quality due to slow crystallization kinetics. We propose using low-solvation binary cosolvents (nitrile-and ether-type solvents) to achieve a balance between solvation (i.e., sufficient solubility of precursors) and desolvation (i.e., rapid crystallization of films) pro-cesses during perovskite synthesis. The polarity and hydrogen -bonding property of these cosolvents synergistically enhance their solvation capacity, facilitating perovskite precursor dissolution. Moreover, the low-solvation cosolvents accelerate the crystalliza-tion of well-defined intermediate films, yielding higher-quality pe-rovskites than those synthesized with DMF. The optimized modules achieved an active-area efficiency of 22.27%, with a certified aper-ture-area efficiency of 16.10% and corresponding active-area effi-ciency of 20.75%. This research on solvation regulation provides universal guidelines for innovatively preparing high-quality halide perovskites.

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