| 1. |
- Dagar, Janardan, et al.
(författare)
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Alkali Salts as Interface Modifiers in n-i-p Hybrid Perovskite Solar Cells
- 2019
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Ingår i: Solar RRL. - : Wiley. - 2367-198X. ; 3:9
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Tidskriftsartikel (refereegranskat)abstract
- After demonstration of a 23% power conversion efficiency, a high operational stability is the next most important scientific and technological challenge in perovskite solar cells (PSCs). A potential failure mechanism is tied to a bias-induced ion migration, which causes current–voltage hysteresis and a decay in the device performance over time. Herein, alkali salts are shown to mitigate hysteresis and stabilize device performance in n-i-p hybrid planar PSCs. Different alkali salts of potassium chloride, iodide, and nitrate as well as sodium chloride and iodide are deposited from aqueous solution onto the n-type contact, based on SnO2, prior to deposition of the perovskite absorber Cs0.05(FA0.83MA0.17)0.95Pb(I0.83Br0.17)3. Introduction of potassium-based alkali salts suppresses the current–voltage hysteresis and stabilizes the operational device stability at the maximum power point. This is attributed to the suppression of hole trapping at the n-type selective transport layer (SnO2)/perovskite interface observed by surface photovoltage spectroscopy, which is interpreted to reduce interfacial recombination and improve charge carrier extraction. The best and most stable performance of 19% is achieved using potassium nitrate as the interface modifier. Devices with higher and more stable performance exhibit substantially lower current transients, analyzed during maximum power point tracking.
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| 2. |
- Wolff, Christian M., et al.
(författare)
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Perfluorinated Self-Assembled Monolayers Enhance the Stability and Efficiency of Inverted Perovskite Solar Cells
- 2020
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Ingår i: ACS Nano. - : American Chemical Society (ACS). - 1936-0851 .- 1936-086X. ; 14:2, s. 1445-1456
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Tidskriftsartikel (refereegranskat)abstract
- Perovskite solar cells are among the most exciting photovoltaic systems as they combine low recombination losses, ease of fabrication, and high spectral tunability. The Achilles heel of this technology is the device stability due to the ionic nature of the perovskite crystal, rendering it highly hygroscopic, and the extensive diffusion of ions especially at increased temperatures. Herein, we demonstrate the application of a simple solution-processed perfluorinated self-assembled monolayer (p-SAM) that not only enhances the solar cell efficiency, but also improves the stability of the perovskite absorber and, in turn, the solar cell under increased temperature or humid conditions. The p-i-n-type perovskite devices employing these SAMs exhibited power conversion efficiencies surpassing 21%. Notably, the best performing devices are stable under standardized maximum power point operation at 85 °C in inert atmosphere (ISOS-L-2) for more than 250 h and exhibit superior humidity resilience, maintaining ∼95% device performance even if stored in humid air in ambient conditions over months (∼3000 h, ISOS-D-1). Our work, therefore, demonstrates a strategy towards efficient and stable perovskite solar cells with easily deposited functional interlayers.
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