1. |
- Chen, Zhe, et al.
(författare)
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Nano-scale characterization of white layer in broached Inconel 718
- 2017
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Ingår i: Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing. - Amsterdam : Elsevier BV. - 0921-5093 .- 1873-4936. ; 684, s. 373-384
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Tidskriftsartikel (refereegranskat)abstract
- The formation mechanism of white layers during broaching and their mechanical properties are not well investigated and understood to date. In the present study, multiple advanced characterization techniques with nano-scale resolution, including transmission electron microscopy (TEM), transmission Kikuchi diffraction (TKD), atom probe tomography (APT) as well as nano-indentation, have been used to systematically examine the microstructural evolution and corresponding mechanical properties of a surface white layer formed when broaching the nickel-based superalloy Inconel 718.TEM observations showed that the broached white layer consists of nano-sized grains, mostly in the range of 20–50 nm. The crystallographic texture detected by TKD further revealed that the refined microstructure is primarily caused by strong shear deformation. Co-located Al-rich and Nb-rich fine clusters have been identified by APT, which are most likely to be γ′ and γ′′ clusters in a form of co-precipitates, where the clusters showed elongated and aligned appearance associated with the severe shearing history. The microstructural characteristics and crystallography of the broached white layer suggest that it was essentially formed by adiabatic shear localization in which the dominant metallurgical process is rotational dynamic recrystallization based on mechanically-driven subgrain rotations. The grain refinement within the white layer led to an increase of the surface nano-hardness by 14% and a reduction in elastic modulus by nearly 10% compared to that of the bulk material. This is primarily due to the greatly increased volume fraction of grain boundaries, when the grain size was reduced down to the nanoscale.
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2. |
- Grolig, Jan Gustav, 1986
(författare)
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Coated Ferritic Stainless Steels as Interconnects in Solid Oxide Fuel Cells - Material Development and Electrical Properties
- 2015
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Solid oxide fuel cells (SOFCs) are attracting increasing interest as devices with potentialuses in decentralized and clean electricity and heat production. Several challengeswith respect to materials have to be overcome to achieve efficiencies and life-spansthat are sufficient for long-term applications.An important element of an SOFC stack is the interconnect component, which connectstwo adjacent fuel cell elements. Interconnects, which are commonly composedof ferritic stainless steels, have to be corrosion-resistant, mechanically stable and costoptimized.This work aimed to investigate economic solutions for interconnect materials and tounderstand the underlying mechanisms of degradation and electrical conduction ofthese materials. Mainly two substrates, a commercially available steel (AISI 441) anda ferritic stainless steel that was optimized for an SOFC application (Sandvik SanergyHT) were combined with different barrier coatings and exposed to a cathode-sideatmosphere. A method was developed that allows for the electrical characterizationof promising material systems and model alloys, thereby facilitating a fundamentalunderstanding of the dominant electrical conduction processes linked to the oxidescales that grow on interconnects. The AISI 441 steel coated with reactive elementsand cobalt showed good corrosion and chromium evaporation profiles, while AISI 441coated with cerium and cobalt also had promising electrical properties. The SanergyHT steel was examined with coatings of copper and iron and copper and manganese,respectively. The corrosion and chromium evaporation profiles of Sanergy HT wereimproved by coating with copper and iron. The copper and iron-coated Sanergy HTshowed lower area specific resistance values than cobalt-coated Sanergy HT. Chromia,which is the main constituent of oxide scales, was synthesized using differentmethods. The electrical properties of chromia were found to be sensitive to not onlyimpurities, but also heat treatment. Finally the electrical properties of cobalt- andcobalt cerium-coated Sanergy HT steels were investigated. It was revealed that theaddition of cerium improved the conductivity of the interconnect by both slowingdown chromia growth and preventing the outward diffusion of iron into the spinel.
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3. |
- Mellin, Pelle, 1985-, et al.
(författare)
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Nano-sized by-products from metal 3D printing, composite manufacturing and fabric production
- 2016
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Ingår i: Journal of Cleaner Production. - Sweden : Elsevier. - 0959-6526 .- 1879-1786. ; 139, s. 1224-1233
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Tidskriftsartikel (refereegranskat)abstract
- Recently, the health and environmental perspective of nano-materials has gained attention. Most previous work focused on Engineered Nanoparticles (ENP). This paper examines some recently introduced production routes in terms of generated nano-sized by-products. A discussion on the hazards of emitting such particles and fibers is included. Fine by-products were found in recycled metal powder after 3D printing by Selective Laser Melting (SLM). The process somehow generated small round metal particles (~1e2 mm) that are possibly carcinogenic and respirable, but not small enough to enter by skin-absorption. With preventive measures like closed handling and masks, any health related effects can be prevented. The composite manufacturing in particular generated ceramic and carbonaceous particles that are very small and respirable but do not appear to be intrinsically toxic. The smallest features in agglomerates were about 30 nm. Small particles and fibers that were not attached in agglomerates were found in a wide range of sizes, from 1 μm and upwards. Preventive measures like closed handling and masks are strongly recommended. In contrast, the more traditional production route of fabric production is investigated. Here, brushing residue and recycled wool from fabric production contained few nano-sized by-products.
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4. |
- Vilardell, A. M., et al.
(författare)
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B2-structured Fe3Al alloy manufactured by laser powder bed fusion : Processing, microstructure and mechanical performance
- 2023
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Ingår i: Intermetallics (Barking). - : Elsevier. - 0966-9795 .- 1879-0216. ; 156
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Tidskriftsartikel (refereegranskat)abstract
- Prealloyed Fe3Al was successfully manufactured by laser powder bed fusion. The best set of process parameters led to parts with a relative density of 99.5 %, a surface roughness, Sa, of 31.5 ± 5.6 μm and a hardness of 319 ± 14 HV0.1. Its microstructure as well as its mechanical properties at room and high temperatures were analyzed. The results of the chemical composition showed minor variations in aluminum content oscillating between 21 and 28 at.% along the melt pool. Additionally, elongated grains were observed to grow parallel to the building direction, as well as the development of a weak 001 texture along the building direction. The mechanical properties were influenced by the temperature. Compression tests showed a loss in strength with the increase in temperature, from a yield strength of 621 ± 40 MPa at room temperature to 89 ± 20 MPa at 650 °C. Reciprocating sliding wear tests showed that fragmentation of the intermetallic at room temperature occurs, whereas plastic deformation dominated at higher temperatures. For all temperatures, tribochemical wear was also present due to the oxidation of wear debris.
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5. |
- Skagestad, Ragnhild, 1978, et al.
(författare)
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GCCSI Webinar: Cutting Cost of CO2 Capture in Process Industry (CO2stCap) Project overview & first results for partial CO2 capture at integrated steelworks
- 2017
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Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- GCCSI Webinar: Cutting Cost of CO2 Capture in Process Industry (CO2stCap) Project overview & first results for partial CO2 capture at integrated steelworks This publication has the format of a webinar: The CO2StCap project is a four year initiative carried out by industry and academic partners with the aim of reducing capture costs from CO2 intensive industries (more information here). The project, led by Tel-Tek, is based on the idea that cost reduction is possible by capturing only a share of the CO2 emissions from a given facility, instead of striving for maximized capture rates. This can be done in multiple ways, for instance by capturing only from the largest CO2 sources at individual multi-stack sites utilising cheap waste heat or adapting the capture volumes to seasonal changes in operations. The main focus of this research is to perform techno-economic analyses for multiple partial CO2 capture concepts in order to identify economic optimums between cost and volumes captured. In total for four different case studies are developed for cement, iron & steel, pulp & paper and ferroalloys industries. The first part of the webinar gave an overview of the project with insights into the cost estimation method used. The second part presented the iron & steel industry case study based on the Lulea site in Sweden, for which waste-heat mapping methodology has been used to assess the potential for partial capture via MEA-absorption. Capture costs for different CO2 sources were discussed, demonstrating the viability of partial capture in an integrated steelworks.
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6. |
- Wärmefjord, Kristina, 1976, et al.
(författare)
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Welding of non-nominal geometries : physical tests
- 2016
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Ingår i: Procedia CIRP. - : Elsevier BV. - 2212-8271 .- 2212-8271. ; 43, s. 136-141
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Tidskriftsartikel (refereegranskat)abstract
- The geometrical quality of a welded assembly is to some extent depending part positions before welding. Here, a design of experiment is set up in order to investigate this relation using physical tests in a controlled environment. Based on the experimental results it can be concluded that the influence of part position before welding is significant for geometrical deviation after welding. Furthermore, a working procedure for a completely virtual geometry assurance process for welded assemblies is outlined. In this process, part variations, assembly fixture variations and welding induced variations are important inputs when predicting the capability of the final assembly.
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7. |
- Hosseini, Seyedehsan, 1994
(författare)
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Additive-Driven Improvements in Interfacial Properties and Processing of TMP-Polymer Composites
- 2023
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Efforts to address environmental concerns have resulted in new regulations designed to plan the reduction of plastic and synthetic polymer usage, necessitating the search for sustainable natural alternatives with comparable cost-effectiveness and mechanical performance. Thermomechanical pulp (TMP) fibres are one of the most affordable natural fibres that have no chemical refining in production, production have a high yield of 90-98% and TMP fibres have been demonstrated to improve the mechanical characteristics (strength, stiffness and toughness) of wood-polymer composites (WPCs) compared to the pure polymer. The integration of TMP fibres with non-polar synthetic polymers remains a challenge due to surface polarity differences. This PhD thesis aims to ease the processing of TMP fibre composites through the incorporation of additives. The hypothesis posits that incorporating magnesium stearate (MgSt), molybdenum disulfide (MoS2) and alkyl ketene dimer (AKD) as additives in TMP composites will enhance interfacial properties, resulting in improved processability and flow behaviour at high temperatures. MoS2 is known for its interaction with lignin, which exists in TMP and MgSt is recognised for its ability to improve flow in pharmaceutical processing when combined with cellulose, also a component of TMP. AKD modifies the hydrophilic properties of lignocellulosic surfaces. The experimental work explores the effect of these additives on the properties of TMP composites of ethylene acrylic acid copolymer (EAA) and polypropylene (PP) matrices. The dynamic mechanical analysis (DMA) and mechanical analysis results reveal that MoS2 exhibits superior interaction with TMP fibres, yielding enhanced interfacial properties compared to MgSt in between EAA and TMP fibres. Rheological studies elucidate the transition from a fluid-like state to a network-like structure upon the incorporation of TMP into the PP matrix. The incorporation of AKD with C18 reduces the viscosity of TMP-PP composites and PP itself, and, as determined through theoretical Hansen solubility parameter (HSP) calculations, increases compatibility between cellulose in TMP fibres and PP. The addition of AKD influences both the colour (lighter) and shape (smoother surface) of the extrudate filaments in the TMP-PP composites, indicative of improved processing. In addition, frictional analysis demonstrates the reduction of the coefficient of friction (COF) between metal and TMP fibre by MgSt and AKD treatments.
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8. |
- Goel, Sneha, 1993-, et al.
(författare)
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The Effect of Location and Post-treatment on the Microstructure of EBM-Built Alloy 718
- 2018
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Ingår i: Proceedings of the 9th International Symposium on Superalloy 718 & Derivatives. - Cham : Springer. - 2367-1696 .- 2367-1181. - 9783319894799 - 9783319894805 ; , s. 115-129
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Konferensbidrag (refereegranskat)abstract
- Additive manufacturing (AM) of Ni-based superalloys such as Alloy 718 may obviate the need for difficult machining and welding operations associated with geometrically intricate parts, thus potentially expanding design possibilities and facilitating cost-effective manufacture of complex components. However, processing AM builds completely free from defects, which may impair mechanical properties such as fatigue and ductility, is challenging. Anisotropic properties, microstructural heterogeneities and local formation of undesired phases are additional concerns that have motivated post-treatment of AM builds. This work investigates the microstructural changes associated with post-treatment of Alloy 718 specimens produced by Electron Beam Melting (EBM) for as-built microstructures at 3 build heights: near base plate, in the middle of build and near the top of the build. Two different post-treatment conditions, hot isostatic pressing (HIP) alone and a combined HIP with solutionising and two-step aging were examined and compared to the results for the as-built condition. The influence of various post-treatments on minor phase distributions (δ, γ″, carbides), overall porosity, longitudinal grain widths and Vickers microhardness was considered. The HIP treatment led to significant reduction in overall porosity and dissolution of δ phase, which led to appreciable grain growth for both post-treatment conditions. The variation in hardness noted as a function of build height for the as-built specimens was eliminated after post-treatment. Overall, the hardness was found to decrease after HIP and increase after the full HIP, solutionising and aging treatment, which was attributed to dissolution of γ″ during HIP and its re-precipitation in subsequent heat treatment steps.
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9. |
- Karimi Neghlani, Paria, 1986-, et al.
(författare)
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Influence of successive thermal cycling on microstructure evolution of EBM-manufactured alloy 718 in track-by-track and layer-by-layer design
- 2018
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Ingår i: Materials & design. - : Elsevier BV. - 0264-1275 .- 1873-4197. ; 160, s. 427-441
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Tidskriftsartikel (refereegranskat)abstract
- Successive thermal cycling (STC) during multi-track and multi-layer manufacturing of Alloy 718 using electron beam melting (EBM) process leads to a microstructure with a high degree of complexity. In the present study, a detailed microstructural study of EBM-manufactured Alloy 718 was conducted by producing samples in shapes from one single track and single wall to 3D samples with maximum 10 longitudinal tracks and 50 vertical layers. The relationship between STC, solidification microstructure, interdendritic segregation, phase precipitation (MC, δ-phase), and hardness was investigated. Cooling rates (liquid-to-solid and solid-to-solid state) was estimated by measuring primary dendrite arm spacing (PDAS) and showed an increased cooling rate at the bottom compared to the top of the multi-layer samples. Thus, microstructure gradient was identified along the build direction. Moreover, extensive formation of solidification micro-constituents including MC-type carbides, induced by micro-segregation, was observed in all the samples. The electron backscatter diffraction (EBSD) technique showed a high textured structure in 〈001〉 direction with a few grains misoriented at the surface of all samples. Finer microstructure and possibility of more γ″ phase precipitation at the bottom of the samples resulted in slightly higher (~11%) hardness values compared to top of the samples.
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10. |
- Hedström, Peter, et al.
(författare)
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Load partitioning between single bulk grains in a two-phase duplex stainless steel during tensile loading
- 2010
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Ingår i: Acta Materialia. - : Elsevier BV. - 1359-6454 .- 1873-2453. ; 58:2, s. 734-744
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Tidskriftsartikel (refereegranskat)abstract
- The lattice strain tensor evolution for single bulk grains of austenite and ferrite in a duplex stainless steel during tensile loading to 0.02 applied strain has been investigated using in situ high-energy X-ray measurements and finite-element modeling. Single-grain X-ray diffraction lattice strain data for the eight austenite and seven ferrite grains measured show a large variation of residual lattice strains, which evolves upon deformation to the point where some grains with comparable crystallographic orientations have lattice strains different by 1.5 x 10(-3), corresponding to a stress of similar to 300 MPa. The finite-element simulations of the 15 measured grains in three different spatial arrangements confirmed the complex deformation constraint and importance of local grain environment.
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