| 1. |
- Fu, Ying, 1964, et al.
(författare)
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Wave packet transmission in a ZnO nanorod under the influence of repulsive/attractive scattering center
- 2004
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Ingår i: Journal of Nanoscience and Nanotechnology. - : AMER SCIENTIFIC PUBLISHERS. - 1533-4880 .- 1533-4899 .- 0000-0000. ; 4:02-Jan, s. 91-93
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Tidskriftsartikel (refereegranskat)abstract
- We study electron wave packet propagation and scattering in ZnO nanorods. By solving the time-dependent three-dimensional Schrodinger equation, we were able to describe propagation and dynamics of the scattering process of the wave packet by ionized impurities. Scattering behavior of the wave packet by an attractive/repulsive scattering center is clearly demonstrated.
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| 2. |
- Arve, K, et al.
(författare)
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Analysis of the state and size of silver on alumina in effective removal of NOx from oxygen rich exhaust gas
- 2006
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 0000-0000. ; 6:4, s. 1076-1083
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Tidskriftsartikel (refereegranskat)abstract
- Ag/alumina catalysts with different silver contents for octane-SCR were prepared by impregnation and incipient wetness methods. Activity tests revealed that the decisive factor for high activity is not only a high dispersion of silver, but also the ability of the system to redisperse clustered silver. Determination of dispersion by TEM/HAADF and O-2-chemisorption experiments resulted in values close to each other even if the results were not directly comparable. This is suggested to be due to not complete silver reduction below 700 degrees C and the samples being very heterogeneous in terms of particle size, e.g., having a bimodal size distribution. Small charged Ag-n(delta+) clusters containing 2-8 silver atoms highly prevailed in the samples containing < 2 wt% Ag and exhibiting high octane-SCR activity In highly loaded Ag/alumina samples or those reduced and reoxidized at high temperature (> 400 degrees C), large metallic particles are stabilized, resulting in poor conversion of NOx to N-2.
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| 3. |
- Balmes, Olivier, et al.
(författare)
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Self-healing and self-organized gold nanoparticle films at a water/organic solvent interface
- 2006
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 0000-0000. ; 6:1, s. 130-134
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Tidskriftsartikel (refereegranskat)abstract
- Gold nanoparticles (5 nm and 20 nm) have been synthesized and stabilized with mercaptoundecanol. These particles, although insoluble in water or common organic solvents, spread as a thin film at the liquid-liquid interface between a water phase and an organic phase. Films of these gold nanoparticles have been observed both by conventional transmission electron microscopy of deposited samples and by cryo-transmission electron microscopy of plunge-frozen samples. The film can be monolayered and extend over centimeter-sized areas. The particle films spontaneously re-assemble and self-organize at the interface when disrupted. This self-healing capacity of the film should make it possible to build a device for continuous production and deposition of the film.
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| 4. |
- Bolton, Kim, 1964, et al.
(författare)
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Atomistic simulations of catalyzed carbon nanotube growth
- 2006
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Ingår i: JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY. - : American Scientific Publishers. - 1533-4880 .- 0000-0000. ; 6:5, s. 1211-1224
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Tidskriftsartikel (refereegranskat)abstract
- We review the advances made in understanding the mechanism of catalyzed carbon nanotube growth, with the main focus on direct dynamics and molecular dynamics studies of single-walled carbon nanotube (SWNT) growth. These studies have deepened our understanding of the catalytic SWNT nucleation and growth mechanisms, but more accurate and efficient methods are required for a complete investigation at experimental growth conditions.
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| 5. |
- Chen, W, et al.
(författare)
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Fabrication and luminescence of ZnS : Mn2+ nanoflowers
- 2005
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 0000-0000. ; 5:9, s. 1309-1322
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Tidskriftsartikel (refereegranskat)abstract
- Visually striking nanoflowers composed of ZnS:Mn2+ nanoparticles are prepared and characterized. The configurations of these fractal structures are very sensitive to both the pH values of the particle solutions from which they are precipitated and the substrates on which they are deposited. At pH 2.2, the fractal structures resemble trees without leaves; at pH 7.7, they are tree-like with four arms and at pH 11.0 they resemble trees with six arms. High resolution transmission microscopy reveals that the nanoflowers are composed of ZnS:Mn2+ nanoparticles of 2-5 nm in size. X-ray photoelectron spectral data indicate that the sample compositions of nitrogen, chlorine, and sulfur vary gradually with pH values of the solutions. These changes may have an impact on both the fractal configuration and the luminescence properties. The emission spectra of the particle solutions at pH values of 2.2 and 11.0 are similar with the emission maximum at 475 nm. As the pH value approaches 7.7, the emission spectral maximum shifts to longer wavelengths. At a pH value of 7.7, the emission peak wavelength is the reddest, 520 nm. The emission peak of the nanoflowers at a pH value of 9.3 is 510 nm, while the emission spectrum of the nanoflowers at 5.2 has two peaks at 500 nm and 440 nm, respectively. These blue-green emissions are attributed to defects and are the dominant luminescence from the nanoflowers. The emission from Mn2+ dopant is only observed in the delayed spectra of the fractal solid samples.
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| 6. |
- Lee, DongSu, et al.
(författare)
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Fabrication of crossed junctions of semiconducting and metallic carbon nanotubes: A CNT-gated CNT-FET
- 2006
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Ingår i: Journal of nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 0000-0000. ; 6, s. 1325-1330
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Tidskriftsartikel (refereegranskat)abstract
- We have developed a method to fabricate crossed junctions between semiconducting (s) and metallic (m) carbon nanotubes (CNTs) combining electric field directed chemical vapor deposition growth and dielectrophoretic alignment. By separating the s- and m-CNTs with a thin dielectric an ultrasmall field effect transistor (FET) was fabricated. By using the m-CNT as a gate it was possible to modulate the source-drain current through the s-CNT FET channel. We have also used the m-CNT as an electrical lead. An off-state current lowering was observed when the m-CNT lead was used as a drain electrode.
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| 7. |
- Amin, Sidra, et al.
(författare)
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MoSx-Co3O4 Nanocomposite for Selective Determination of Ascorbic Acid
- 2021
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Ingår i: Journal of Nanoscience and Nanotechnology. - : AMER SCIENTIFIC PUBLISHERS. - 1533-4880 .- 1533-4899. ; 21:4, s. 2595-2603
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Tidskriftsartikel (refereegranskat)abstract
- Designing a nanocomposite with sensitive and selective determination of ascorbic acid is challenging task. It is possible through the exploitation of attractive features of nanoscience and nanotechnology for the synthesis of nanostructured materials. Herein, we report the decoration of nanoparticle of MoSx on the surface of Co3O4 nanowires by hydrothermal method. The MoSx nanoparticles shared the large surface on the Co3O4 nanowires, thus it supported in the development enzyme free ascorbic acid sensor. Non-enzymatic sensor based on MoSx-Co3O4 composite was found very selective for the determination of ascorbic acid (AA) in phosphate buffer solution of pH 7.4. The MoSx-Co3O4 nanocomposite was used to modify the glassy carbon electrode to measure AA from variety of practical samples. The MoSx-Co3O4 nanocomposite was used to modify the glassy carbon electrode and it has shown the attractive analytical features such as a low working potential +0.3 V, linear range of concentration from 100-7000 mu M, low limit of detection 14 mu M, and low limit of quantification (LOQ) of 42 mu M. The developed sensor is highly selective and stable. Importantly, it was applied successfully for the practical applications such as detection of AA from grapefruit, tomato and lemon juice. The excellent electrochemical properties of fabricated MoSx-Co3O4 nanocomposite can be attributed to the increasing electro active surface area of MoSx. The presented nanocomposite is earth abundant, environment friendly and inexpensive and it holds promising features for the selective and sensitive determination of AA from practical applications. The nanocomposite can be capitalized into the wide range of biomedical applications.
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| 8. |
- Andersson, Gabriella, et al.
(författare)
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Anisotropy Tuning in Tetragonal FeCo Alloys
- 2010
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 10:9, s. 6186-6189
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Tidskriftsartikel (refereegranskat)abstract
- We review our previous work on magnetocrystalline anisotropy tuning of superlattices based on tetragonally distorted FeCo-alloys. In addition we present new experimental results on the effect of changing the composition of the FeCo alloy. The discussion is based on the separation of the magnetocrystalline anisotropy into contributions from the interfaces and strain, as well as from the composition.
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| 9. |
- Andersson, Mikael, 1988
(författare)
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Nanoparticle Magnetism: Superspin Glasses
- 2019
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 19:8, s. 4903-4910
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Tidskriftsartikel (refereegranskat)abstract
- This article discusses the magnetic super-phase, which occurs in strongly interacting magnetic nanoparticle systems. The phase is a nanoparticle analog to the atomic magnetic spin glass phase and is therefore called a superspin glass. Experimental data for a dense maghemite nanoparticle compact is presented and it is shown that this system forms a superspin glass phase by undergoing a second order phase transition. Below its transition temperature the system exhibits non-equilibrium dynamical properties similar to those of atomic spin glasses. It was shown that it is possible to tune the transition temperature by choosing the size of the particles used to make the compact. By mixing two sizes of particles (9 and 11.5 nm) and making compacts of different relative concentration of these sizes it was shown that it is the average dipolar interaction which determines the transition temperature.
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| 10. |
- Anttu, Nicklas, et al.
(författare)
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Coupling of Light into Nanowire Arrays and Subsequent Absorption
- 2010
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Ingår i: Journal of Nanoscience And Nanotechnology. - : American Scientific Publishers. - 1533-4899 .- 1533-4880. ; 10:11, s. 7183-7187
-
Konferensbidrag (refereegranskat)abstract
- We present a theoretical study of the absorption of light in periodic arrays of InP nanowires. The absorption in the array depends strongly on the diameter and the length of the nanowires, as well as the period of the array. Nanowires of a length of just 2 Am are able, after an appropriate choice for the other parameters, to absorb more than 90% of the incident energy of TE and TM polarized light, with photon energies almost all the way down to the band gap energy and an incidence angle up to 50 degree. This high total absorption arises from a good coupling of the incident light into the nanowire array at the top interface between air and the array and absorption inside the array before the light reaches the interface between the nanowires and the substrate. We find that for a given photon energy there exists a critical nanowire diameter above which a dramatic increase in the absorption occurs. The critical diameter decreases for increasing photon energies, and is directly related to the dispersion of waveguiding modes in single isolated nanowires. A characterization showed that the absorption characteristics of the nanowire arrays are very promising for photovoltaic applications.
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| 11. |
- Battiston, S., et al.
(författare)
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Influence of Al and Mg Addition on Thermoelectric Properties of Higher Manganese Silicides Obtained by Reactive Sintering
- 2017
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 17:3, s. 1668-1673
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Tidskriftsartikel (refereegranskat)abstract
- Higher manganese silicides (HMS), represented by MnSix (x = 1.71-1.75), are promising p-type candidates for thermoelectric (TE) energy harvesting systems at intermediate temperature range. The materials are very attractive as they may replace lead based compounds due to their nontoxicity, low cost of starting materials, and high thermal and chemical stability. Dense pellets were obtained through fast reactive sintering by spark plasma sintering (SPS). The addition -or nanoinclusion, of Al and Mg permitted the figure of merit enhancement of the material obtained with this technique, reaching the highest value of 0.40 at 600 degrees C. Morphology, composition and crystal structure of the samples were characterized by electron microscopies, energy dispersive X-ray spectroscopy, and X-ray diffraction analyses, respectively.
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| 12. |
- Bhatti, Adeel Liaquat, et al.
(författare)
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An Efficient and Functional Fe3O4/Co3O4 Composite for Oxygen Evolution Reaction
- 2021
-
Ingår i: Journal of Nanoscience and Nanotechnology. - : AMER SCIENTIFIC PUBLISHERS. - 1533-4880 .- 1533-4899. ; 21:4, s. 2675-2680
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Tidskriftsartikel (refereegranskat)abstract
- The design of efficient, stable, durable and noble metal free electro catalysts for oxygen evolution reaction (OER) are of immediate need, but very challenging task. In this study, iron induction into cobalt oxide (Co3O4) has resulted composite structure by wet chemical method. The iron impurity has brought an electronic disorder into Fe3O4/cobalt oxide composite thereby efficient oxygen evolution reaction is demonstrated. An addition of iron content into composite resulted the alternation of morphology from Nano rods to clusters of nanoparticles. The successive addition of iron into composite system reduced the onset potential of OER as compared to the pristine cobalt oxide. A Tafel slope of 80 mVdec(-1) indicates the favorable oxygen evolution reaction kinetics on the sample 4. An over-potential of 370 mV is required to reach a 10 mAcm(-2) current density which is acceptable for a nonprecious catalyst. The catalyst is highly durable and stable for 30 hours. Electrochemical impedance spectroscopy further provided a deeper insight on charge transfer resistance and sample 4 has low charge transfer resistance that supported the OER polarization curves. The sample 4 has more electrochemical active surface area of 393.5 cm(2). These obtained results are exciting and highlighting the importance of composite structure and leave a huge space for the future investigations on composite materials for energy related applications.
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| 13. |
- Bhatti, Muhammad Ali, et al.
(författare)
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TiO2/ZnO Nanocomposite Material for Efficient Degradation of Methylene Blue
- 2021
-
Ingår i: Journal of Nanoscience and Nanotechnology. - : AMER SCIENTIFIC PUBLISHERS. - 1533-4880 .- 1533-4899. ; 21:4, s. 2511-2519
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Tidskriftsartikel (refereegranskat)abstract
- In this research work, we have produced a composite material consisting titanium dioxide (TiO2) and zinc oxide (ZnO) nanostructures via precipitation method. Scanning electron microscopy (SEM) study has shown the mixture of nanostructures consisting nanorods and nano flower. Energy dispersive spectroscopy (EDS) study has confirmed the presence of Ti, Zn and O as main elements in the composite. X-ray diffraction (XID) study has revealed that the successful presence of TiO2 and ZnO in the composite. The composite material exhibits small optical energy band gap which led to reduction of the charge recombination rate of electron-hole pairs. The band gap for the composite TiO2/ZnO samples namely 1, 2, 3 and 4 is 3.18, 3.00, 2.97 and 2.83 eV respectively. Small optical bandgap gives less relaxation time for the recombination of electron and hole pairs, thus favorable photodegradation is found. The degradation efficiency for the TiO2/ZnO samples for methylene blue in order of 55.03%, 75.7%, 85.14% and 90.08% is found for the samples 1, 2, 3 and 4 respectively. The proposed study of titanium dioxide addition into ZnO is facile and inexpensive for the development of efficient photocatalysts. This can be capitalized at large scale for the energy and environmental applications.
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| 14. |
- Bora, Tanujjal, et al.
(författare)
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Applications of nanotechnology in wastewater treatment-A review
- 2014
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 14:1, s. 613-626
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Tidskriftsartikel (refereegranskat)abstract
- Water on Earth is a precious and finite resource, which is endlessly recycled in the water cycle. Water, whose physical, chemical, or biological properties have been altered due to the addition of contaminants such as organic/inorganic materials, pathogens, heavy metals or other toxins making it unsafe for the ecosystem, can be termed as wastewater. Various schemes have been adopted by industries across the world to treat wastewater prior to its release to the ecosystem, and several new concepts and technologies are fast replacing the traditional methods. This article briefly reviews the recent advances and application of nanotechnology for wastewater treatment. Nanomaterials typically have high reactivity and a high degree of functionalization, large specific surface area, size-dependent properties etc., which makes them suitable for applications in wastewater treatment and for water purification. In this article, the application of various nanomaterials such as metal nanoparticles, metal oxides, carbon compounds, zeolite, filtration membranes, etc., in the field of wastewater treatment is discussed.
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| 15. |
- Bora, Tanujjal, et al.
(författare)
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Plasmonic Photocatalyst Design : Metal-Semiconductor Junction Affecting Photocatalytic Efficiency
- 2019
-
Ingår i: Journal of Nanoscience and Nanotechnology. - : AMER SCIENTIFIC PUBLISHERS. - 1533-4880 .- 1533-4899. ; 19:1, s. 383-388
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Tidskriftsartikel (refereegranskat)abstract
- Silver-zinc oxide nanorods (Ag-ZnO NRs) and gold-zinc oxide nanorods (Au-ZnO NRs) plasmonic photocatalysts were fabricated by the deposition of Ag and Au nanoparticles on ZnO NRs. The photocatalysts were studied with electron microscopy, energy dispersive spectroscopy (EDS), UV-vis optical absorption and photoluminescence spectroscopy. The effect of type of metals on the ZnO surface on its photocatalytic activity under ultra violet (UV) as well as visible light excitation are investigated and their contribution towards enhanced photo-generated charge separation in terms of the type of junction (Ohmic or Schottky) the metal forms with the semiconductor are explained.
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| 16. |
- Carvalho, Alexandra T.G., et al.
(författare)
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Electronic and optical properties of chlorinated silicon nanoparticles
- 2013
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 13:2, s. 1039-1042
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Tidskriftsartikel (refereegranskat)abstract
- First-principles calculations are used to investigate the structure, electronic and optical properties of silicon nanocystals with chlorine-passivated surface. The nanocrystals considered were approximately spherical, with diameters between 1.5 and 3.0 nm. We show that the nanocrystals with chlorinated surface have a smaller bandgap, lower optical absorption threshold, and greater ionization energy and electron affinity than hydrogenated silicon nanocrystals of the same size
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| 17. |
- Carvalho, Alexandra T.G., et al.
(författare)
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Increased electronic coupling in silicon nanocrystal networks doped with F4-TCNQ
- 2013
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 13:2, s. 1035-1038
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Tidskriftsartikel (refereegranskat)abstract
- The modification of the electronic structure of silicon nanocrystals using an organic dopant, 2,3,5,6- tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F 4-TCNQ), is investigated using first-principles calculations. It is shown that physisorbed F4-TCNQ molecules have the effect of oxidizing the nanocrystal, attracting the charge density towards the F 4-TCNQ-nanocrystal interface, and decreasing the excitation energy of the system. In periodic F4-TCNQ/nanocrystal superlattices, F 4-TCNQ is suggested to enhance exciton separation, and in the presence of free holes, to serve as a bridge for electron/hole transfer between adjacent nanocrystals.
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| 18. |
- Coelho, Margarida, et al.
(författare)
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Nanotechnology in automotive industry : research strategy and trends for the future – small objects, big impacts
- 2012
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 12:8, s. 6621-6630
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Tidskriftsartikel (refereegranskat)abstract
- The goal of this paper is to emphasize and present briefly the nanotechnology science and its potential impact on the automotive industry in order to improve the production of recent models with an optimization of the safety performance and a reduction in the environmental impacts. Nanomaterials can be applied in car bodies as light weight constructions without compromising the stiffness and crashwortiness, which means less material and less fuel consumption. This paper outlines the progress of nanotechnology applications into the safety features of more recent vehicle models and fuel efficiency, but also emphasis the importance of sustainable development on the application of these technologies and life cycle analysis of the considered materials, in order to meet the society trends and customers demands to improve ecology, safety and comfort.
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| 19. |
- Ding, Zong-Ling, et al.
(författare)
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Effect of Electrodes on Geometric and Transport Properties of the Graphene-Based Nanomolecular Devices
- 2011
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 11:12, s. 10778-10781
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Tidskriftsartikel (refereegranskat)abstract
- Graphene-based nanomolecular devices are formed by connecting one of the prototype molecular materials of graphene nanoribbons to two Au electrodes. The geometric structure and electronic properties are calculated by using density functional theory. Basing on the optimized structure and the electronic distributions, we obtain the transport properties of the devices by using the Green's functional method. It is found that that the geometry structures of the molecule and the transport properties are sensitive to the distance between source and drain electrodes. With increasing the distances, the curvature radius of the atomic plane is increased, and the deformation energy is decreased. The current versus voltage curves have almost same threshold voltage with different distances between the electrodes. The transmission probability, the density of states and the external bias voltage play important role in determining the transport properties of the molecular devices.
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| 20. |
- Dispenza, Clelia, et al.
(författare)
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Radiation-Engineered Functional Nanoparticles in Aqueous Systems
- 2015
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 15:5, s. 3445-3467
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Forskningsöversikt (refereegranskat)abstract
- Controlled synthesis of nanoscalar and nanostructured materials enables the development of novel functional materials with fine-tuned optical, mechanical, electronic, magnetic, conductive and catalytic properties that are of use in numerous applications. These materials have also found their potential use in medicine as vehicles for drug delivery, in diagnostics or in combinations thereof. In principle, nanoparticles can be divided into two broad categories, organic and inorganic nanoparticles. For both types of nanoparticles there are numerous possible synthetic routes. Considering the large difference in nature of these materials and the elementary reactions involved in the synthetic routes, most manufacturing techniques are complex and only suitable for one type of particle. Interestingly, radiation chemistry, i.e., the use of ionizing radiation from radioisotopes and accelerators to induce nanomaterials or chemical changes in materials, has proven to be a versatile tool for controlled manufacturing of both organic and inorganic nanoparticles. The advantages of using radiation chemistry for this purpose are many, such as low energy consumption, minimal use of potentially harmful chemicals and simple production schemes. For medical applications one more advantage is that the material can be sterile as manufactured. Radiation-induced synthesis can be carried out in aqueous systems, which minimizes the use of organic solvents and the need for separation and purification of the final product. The radiation chemistry of water is well known, as are the various ways of fine-tuning the reactivity of the system towards a desired target by adding different solutes. This, in combination with the controllable and adjustable irradiation process parameters, makes the technique superior to most other chemical methods. In this review, we discuss the fundamentals of radiation chemistry and radiation-induced synthesis of nanoparticles in aqueous solutions. The impact of dose and dose rate as well as of controlled addition of various solutes on the final particle composition, size and size distribution are described in detail and discussed in terms of reaction mechanism and kinetics.
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| 21. |
- Duan, Haiming, et al.
(författare)
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Computational studies of small carbon and iron-carbon systems relevant to carbon nanotube growth
- 2008
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 8:11, s. 6170-6177
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Tidskriftsartikel (refereegranskat)abstract
- Density functional theory (DFT) calculations show that dimers and longer carbon strings are more stable than individual atoms on Fe(111) surfaces. It is therefore necessary to consider the formation of these species on the metal surfaces and their effect on the mechanism of single-walled nanotube (SWNT) growth. The good agreement between the trends (energies and structures) obtained using DFT and those based on the Brenner and AIREBO models indicate that these analytic models provide adequate descriptions of the supported carbon systems needed for valid molecular dynamics simulations of SWNT growth. In contrast, the AIREBO model provides a better description of the relative energies for isolated carbon species, and this model is preferred over the Brenner potential when simulating SWNT growth in the absence of metal particles. However, the PM3 semiempirical model appears to provide an even better description for these systems and, given sufficient computer resources, direct dynamics methods based on this model may be preferred.
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| 22. |
- Fan, Liangdong, 1985-, et al.
(författare)
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Study of Ceria-Carbonate Nanocomposite Electrolytes for Low-Temperature Solid Oxide Fuel Cells
- 2012
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 12:6, s. 4941-4945
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Tidskriftsartikel (refereegranskat)abstract
- Composite and nanocomposite samarium doped ceria-carbonates powders were prepared by solidstatereaction, citric acid-nitrate combustion and modified nanocomposite approaches and used aselectrolytes for low temperature solid oxide fuel cells. X-ray Diffraction, Scanning Electron Microscope,low-temperature Nitrogen Adsorption/desorption Experiments, Electrochemical ImpedanceSpectroscopy and fuel cell performance test were employed in characterization of these materials.All powders are nano-size particles with slight aggregation and carbonates are amorphous incomposites. Nanocomposite electrolyte exhibits much lower impedance resistance and higher ionicconductivity than those of the other electrolytes at lower temperature. Fuel cell using the electrolyteprepared by modified nanocomposite approach exhibits the best performance in the whole operationtemperature range and achieves a maximum power density of 839 mW cm−2 at 600 C withH2 as fuel. The excellent physical and electrochemical performances of nanocomposite electrolytemake it a promising candidate for low-temperature solid oxide fuel cells.
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| 23. |
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| 24. |
- Ferraz, Natalia, et al.
(författare)
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Role of Alumina Nanoporosity in Acute Cell Response
- 2011
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 11:8, s. 6698-6704
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Tidskriftsartikel (refereegranskat)abstract
- This work studied the effect of nanoporous alumina in acute cellular response in an in vivo model. Nanoporous alumina membranes, with pore size diameters of 20 and 200 nm, were fabricated by anodic oxidation of aluminium. The membranes were thereafter characterized in terms of pore size distribution and chemical composition. To evaluate acute inflammatory response, the membranes were implanted in the peritoneal cavity of mice. Cell recruitment to the implant site was determined by fluorescence activated cell sorting (FACS) analysis. Cell adhesion to material surfaces was studied in terms of cell number, type, and morphology using scanning electron microscopy (SEM) and immunocytochemical staining followed by fluorescence microscopy. The fabricated nanoporous alumina membranes were found to have narrow pore size distribution. The in vivo study showed that 200 nm alumina membranes induced stronger inflammatory response than 20 nm membranes. This was reflected by the number of implant-associated phagocytes and the number of cells recruited to the implantation site. Since both pore-size membranes possess similar chemical composition, we believe that the observed difference in cell recruitment and adhesion is an effect of the material nanotopography. Our results suggest that nanotopography can be used to subtly control the recruitment and adherence of phagocytic cells during the acute inflammatory response to alumina membranes.
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| 25. |
- Fu, T., et al.
(författare)
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Aqueous Synthesis and Fluorescence-Imaging Application of CdTe/ZnSe Core/Shell Quantum Dots with High Stability and Low Cytotoxicity
- 2010
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Ingår i: Journal of Nanoscience and Nanotechnology. - : American Scientific Publishers. - 1533-4880 .- 1533-4899. ; 10:3, s. 1741-1746
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Tidskriftsartikel (refereegranskat)abstract
- CdTe/ZnSe core/shell quantum dots were directly synthesized in an aqueous condition by heating a mixed solution of ZnCl2, NaHSe and CdTe QDs in the presence of mercaptosuccinic acid as a stabilizer. By controlling the size and composition, the CdTe/ZnSe QDs with emission wavelength ranging from 540 to 630 nm, high quantum yield (44%) and narrow full width at half maximum (FWHM) could be obtained. Characterization results with HRTEM, XRD and EDX have shown that the synthesized CdTe/ZnSe ON have good monodispersity and a nice crystal structure, and exhibited better stability and less cytotoxicity as compared with CdTe QDs. Furthermore, luminescent QD-IgG bioprobes were produced to detect the breast cancer marker Her2 on the surface of fixed MCF-7 cancer cells for their optical imaging.
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