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- Deksnys, T., et al.
(författare)
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Synthesis and characterisation of a carbazole-based bipolar exciplex-forming compound for efficient and color-tunable OLEDs
- 2017
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Ingår i: New Journal of Chemistry. - : RSC Publishing. - 1144-0546 .- 1369-9261. ; 41:2, s. 559-568
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Tidskriftsartikel (refereegranskat)abstract
- A new ambipolar fluorophore, 3,6-di(4,4′-dimethoxydiphenylaminyl)-9-(1-naphthyl)carbazole, was synthesized and its physical properties were studied by differential scanning calorimetry, thermogravimetric analysis, UV-vis absorption, luminescence and photoelectron emission spectroscopy, cyclic voltammetry and a time of flight method. The latter technique indicates that the compound demonstrates bipolar semiconducting properties. Using the synthesized compound as an emissive material, a single-layer OLED with an electroluminescence spectrum containing a voltage-dependent electroplex emission band in the region of 550-650 nm was fabricated. Another OLED was fabricated with an additional electron transporting bathophenanthroline layer that forms a direct interface with the layer of 3,6-di(4,4′-dimethoxydiphenylaminyl)-9-(1-naphthyl)carbazole. A strong exciplex-type band in the electroluminescence spectrum of this OLED with an emission maximum at ca. 540 nm was observed. The electroluminescence spectra of both devices were found to be clearly dependent on the applied bias. This effect can be useful for the development of efficient and colour-tunable OLEDs.
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| 3. |
- Gudeika, D., et al.
(författare)
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Flexible diphenylsulfone versus rigid dibenzothiophene-dioxide as acceptor moieties in donor-acceptor-donor TADF emitters for highly efficient OLEDs
- 2020
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Ingår i: Organic electronics. - : Elsevier. - 1566-1199 .- 1878-5530. ; 83
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Tidskriftsartikel (refereegranskat)abstract
- Flexible versus rigid molecular structures of donor-acceptor-donor type compounds are investigated with respect to efficiency of thermally activated delayed fluorescence (TADF) by theoretical and experimental approaches. Three highly efficient TADF emitters based on flexible diphenylsulfone and rigid dibenzothiophene-dioxide as acceptor units and di-tert-butyldimethyldihydroacridine as donor moiety were designed and synthesized. Despite they showed similar singlet-triplet splitting (0.01–0.02 eV) and high photoluminescence quantum yields in appropriate hosts, maximum external quantum efficiencies as different as 24.1 and 15.9/19.4% were obtained for organic light emitting devices based on these emitters with, respectively, flexible and rigid molecular structures. The high efficiency of the light-emitting compounds with the flexible molecular structure could be traced to the bi-configurational nature of the lowest singlet and triplet states resulting in higher spin-orbit coupling than for molecules with rigid structures. All derivatives showed bipolar charge transport character. High device efficiency with electron mobility of 3 × 10−5 cm2V−1s−1 and hole mobility of 1.3 × 10−4 cm2V−1s−1 at the electric field of 5 × 105 Vcm−1 was recorded for the layer of para-disubstituted diphenylsulfone with flexible molecular structure. This TADF emitter showed an excellent performance in the organic light emitting device, exhibiting a maximum current efficiency, power efficiency, and external quantum efficiency of 61.1 cdA-1, 64.0 lmW−1, and 24.1%, respectively.
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