| 1. |
- Chaika, Alexander N., et al.
(författare)
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Rotated domain network in graphene on cubic-SiC(001)
- 2014
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Ingår i: Nanotechnology. - : IOP Publishing. - 0957-4484 .- 1361-6528. ; 25:13
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Tidskriftsartikel (refereegranskat)abstract
- The atomic structure of the cubic-SiC(001) surface during ultra-high vacuum graphene synthesis has been studied using scanning tunneling microscopy (STM) and low-energy electron diffraction. Atomically resolved STM studies prove the synthesis of a uniform, millimeter-scale graphene overlayer consisting of nanodomains rotated by +/- 13.5 degrees relative to the < 110 >-directed boundaries. The preferential directions of the domain boundaries coincide with the directions of carbon atomic chains on the SiC(001)-c(2 x 2) reconstruction, fabricated prior to graphene synthesis. The presented data show the correlation between the atomic structures of the SiC(001)-c(2 x 2) surface and the graphene/SiC(001) rotated domain network and pave the way for optimizing large-area graphene synthesis on low-cost cubic-SiC(001)/Si(001) wafers.
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| 2. |
- Wu, Han-Chun, et al.
(författare)
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Transport Gap Opening and High On-Off Current Ratio in Trilayer Graphene with Self-Aligned Nanodomain Boundaries.
- 2015
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Ingår i: ACS Nano. - : American Chemical Society (ACS). - 1936-086X .- 1936-0851. ; 9:9, s. 8967-8975
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Tidskriftsartikel (refereegranskat)abstract
- Trilayer graphene exhibits exceptional electronic properties that are of interest both for fundamental science and for technological applications. The ability to achieve a high on-off current ratio is the central question in this field. Here, we propose a simple method to achieve a current on-off ratio of 10(4) by opening a transport gap in Bernal-stacked trilayer graphene. We synthesized Bernal-stacked trilayer graphene with self-aligned periodic nanodomain boundaries (NBs) on the technologically relevant vicinal cubic-SiC(001) substrate and performed electrical measurements. Our low-temperature transport measurements clearly demonstrate that the self-aligned periodic NBs can induce a charge transport gap greater than 1.3 eV. More remarkably, the transport gap of ∼0.4 eV persists even at 100 K. Our results show the feasibility of creating new electronic nanostructures with high on-off current ratios using graphene on cubic-SiC.
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| 3. |
- Hugelius, Gustaf, et al.
(författare)
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High-resolution mapping of ecosystem carbon storage and potential effects of permafrost thaw in periglacial terrain, European Russian Arctic
- 2011
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Ingår i: Journal of Geophysical Research. - 0148-0227 .- 2156-2202. ; 116, s. G03024-
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Tidskriftsartikel (refereegranskat)abstract
- This study describes detailed partitioning of phytomass carbon (C) and soil organic carbon (SOC) for four study areas in discontinuous permafrost terrain, Northeast European Russia. The mean aboveground phytomass C storage is 0.7 kg C m(-2). Estimated landscape SOC storage in the four areas varies between 34.5 and 47.0 kg C m(-2) with LCC (land cover classification) upscaling and 32.5-49.0 kg C m(-2) with soil map upscaling. A nested upscaling approach using a Landsat thematic mapper land cover classification for the surrounding region provides estimates within 5 +/- 5% of the local high-resolution estimates. Permafrost peat plateaus hold the majority of total and frozen SOC, especially in the more southern study areas. Burying of SOC through cryoturbation of O- or A-horizons contributes between 1% and 16% (mean 5%) of total landscape SOC. The effect of active layer deepening and thermokarst expansion on SOC remobilization is modeled for one of the four areas. The active layer thickness dynamics from 1980 to 2099 is modeled using a transient spatially distributed permafrost model and lateral expansion of peat plateau thermokarst lakes is simulated using geographic information system analyses. Active layer deepening is expected to increase the proportion of SOC affected by seasonal thawing from 29% to 58%. A lateral expansion of 30 m would increase the amount of SOC stored in thermokarst lakes/fens from 2% to 22% of all SOC. By the end of this century, active layer deepening will likely affect more SOC than thermokarst expansion, but the SOC stores vulnerable to thermokarst are less decomposed.
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| 4. |
- Marchenko, Sergey, et al.
(författare)
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A plot-scale study of firn stratigraphy at Lomonosovfonna, Svalbard, using ice cores, borehole video and GPR surveys in 2012–14
- 2017
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Ingår i: Journal of Glaciology. - : Cambridge University Press (CUP). - 0022-1430 .- 1727-5652. ; 63:237, s. 67-78
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Tidskriftsartikel (refereegranskat)abstract
- Spatial heterogeneity of snow and firn properties on glaciers introduces uncertainty in interpretation of point and profile observations and complicates modelling of meltwater percolation and runoff. Here we present a study of the temporal and spatial dynamics of firn density and stratigraphy at the plot-scale (approximate to 10 m x 10 m x 10 m) repeated annually during 2012-14 at the Lomonosovfonna ice-field, Svalbard. Results from cores, video inspections in boreholes and radar grid surveys are compared. Ice layers 0.1-50 cm thick comprised approximate to 8% of the borehole length. Most of them are 1-3 cm thick and could not be traced between boreholes separated by 3 m. Large lateral variability of firn structure affects representativeness of observations in single holes and calls for repeated studies in multiple points to derive a representative stratigraphy signal. Radar reflections are poorly correlated with ice layers in individual boreholes. However, the match between the high amplitude peaks in the grid-averaged radar signal and horizons of preferential ice layer formation revealed by averaging the video surveys over multiple boreholes is higher. These horizons are interpreted as buried firn layers previously exposed to melt-freeze or wind-driven densification and several of them are consistently recovered throughout three field campaigns.
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| 5. |
- Marchenko, Sergey A., et al.
(författare)
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Water content of firn at Lomonosovfonna, Svalbard, derived from subsurface temperature measurements
- 2021
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Ingår i: Journal of Glaciology. - : Cambridge University Press. - 0022-1430 .- 1727-5652. ; 67:265, s. 921-932
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Tidskriftsartikel (refereegranskat)abstract
- The potential of capillary forces to retain water in pores is an important property of snow and firn at glaciers. Meltwater suspended in pores does not contribute to runoff and may refreeze during winter, which can affect the climatic mass balance and the subsurface density and temperature. However, measurement of firn water content is challenging and few values have been reported in the literature. Here, we use subsurface temperature and density measured at the accumulation zone of Lomonosovfonna (1200 m a.s.l.), Svalbard, to derive water content of the firn profiles after the 2014 and 2015 melt seasons. We do this by comparing measured and simulated rates of freezing front propagation. The calculated volumetric water content of firn is ~1.0–2.5 vol.% above the depth of 5 m and <0.5 vol.% below. Results derived using different thermistor strings suggest a prominent lateral variability in firn water content. Reported values are considerably lower than those commonly used in snow/firn models. This is interpreted as a result of preferential water flow in firn leaving dry volumes within wetted firn. This suggests that the implementation of irreducible water content values below 0.5 vol.% within snow/firn models should be considered at the initial phase of water infiltration.
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| 6. |
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| 7. |
- Marchenko, Sergey, et al.
(författare)
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Parameterizing deep water percolation improves subsurface temperature simulations by a multilayer firn model
- 2017
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Ingår i: Frontiers in Earth Science. - : Frontiers Media SA. - 2296-6463. ; 5:16
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Tidskriftsartikel (refereegranskat)abstract
- Deep preferential percolation of melt water in snow and firn brings water lower along the vertical profile than a laterally homogeneous wetting front. This widely recognized process is an important source of uncertainty in simulations of subsurface temperature, density, and water content in seasonal snow and in firn packs on glaciers and ice sheets. However, observation and quantification of preferential flow is challenging and therefore it is not accounted for by most of the contemporary snow/firn models. Here we use temperature measurements in the accumulation zone of Lomonosovfonna, Svalbard, done in April 2012-2015 using multiple thermistor strings to describe the process of water percolation in snow and firn. Effects of water flow through the snow and firn profile are further explored using a coupled surface energy balance - firn model forced by the output of the regional climate model WRF. In situ air temperature, radiation, and surface height change measurements are used to constrain the surface energy and mass fluxes. To account for the effects of preferential water flow in snow and firn we test a set of depth-dependent functions allocating a certain fraction of the melt water available at the surface to each snow/firn layer. Experiments are performed for a range of characteristic percolation depths and results indicate a reduction in root mean square difference between the modeled and measured temperature by up to a factor of two compared to the results from the default water infiltration scheme. This illustrates the significance of accounting for preferential water percolation to simulate subsurface conditions. The suggested approach to parameterization of the preferential water flow requires low additional computational cost and can be implemented in layered snow/ firn models applied both at local and regional scales, for distributed domains with multiple mesh points.
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| 8. |
- Marchenko, Sergey, 1988-
(författare)
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Subsurface fluxes of mass and energy at the accumulation zone of Lomonosovfonna ice cap, Svalbard
- 2018
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Glaciers cover ca 10% of the Earth's land and are found in the high altitudes and latitudes. They are important components of environmental systems due to the multiple feedbacks linking them with the atmosphere, hydrosphere and periglacial landscapes. The cold sloping surfaces of glaciers change the patterns of atmospheric circulation at different scales and at the same time glaciers are largely controlled by climate. They are commonly used as climatic archives for reconstruction of the past environmental changes based on evidences from the areas affected by glaciation at the moment and in the past. Glaciers are the largest fresh-water reservoirs on our planet and runoff thereof significantly affects the global sea level and life in glaciated catchments. However, melt- and rain-induced runoff from glaciers greatly depends on the subsurface conditions which thus need to be taken into account, particularly in a changing climate.This thesis focuses on the processes of subsurface mass and energy exchange in the accumulation zones of glaciers, which are largely driven by the climate at the surface. Results are largely based on empirical data from Lomonosovfonna ice cap, Svalbard, collected during field campaigns in 2012-2017. Observations of subsurface density and stratigraphy using shallow cores, video records from boreholes and radar surveys returned detailed descriptions of the snow and firn layering. The subsurface temperature data collected using multiple thermistor strings provided insights into several subsurface processes. The temperature values measured during three summer seasons were used to constrain the suggested parameterization of deep preferential water flow through snow and firn. The part of data recorded during the cold seasons was employed for an inverse modelling exercise resulting in optimized values of effective thermal conductivity of the subsurface profile. These results are then used to compute the subsurface water content by comparing the simulated and measured rates of freezing front propagation after the melt season in 2014.The field observations and quantitative estimates provide further empirical evidences of preferential water flow in snow/firn packs at glaciers. Results presented in the thesis call for implementation of description of the process in layered models simulating the subsurface fluxes of energy and mass at glaciers. This will result in a better understanding of glacier response to the past and future climatic changes and more accurate estimates of glacier runoff.
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| 9. |
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| 10. |
- Marchenko, Sergey, et al.
(författare)
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Thermal conductivity of firn at Lomonosovfonna, Svalbard, derived from subsurface temperature measurements
- 2019
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Ingår i: The Cryosphere. - : Copernicus GmbH. - 1994-0416 .- 1994-0424. ; 13, s. 1843-1859
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Tidskriftsartikel (refereegranskat)abstract
- Abstract. Accurate description of snow and firn processes is necessary for estimating the fraction of glacier surface melt that contributes to runoff. Most processes in snow and firn are to a great extent controlled by the temperature therein and in the absence of liquid water, the temperature evolution is dominated by the conductive heat exchange. The latter is controlled by the effective thermal conductivity k. Here we reconstruct the effective thermal conductivity of firn at Lomonosovfonna, Svalbard, using an optimization routine minimizing the misfit between simulated and measured subsurface temperatures and densities. The optimized k* values in the range from 0.2 to 1.6 W (m K)−1 increase downwards and over time. The results are supported by uncertainty quantification experiments, according to which k* is most sensitive to systematic errors in empirical temperature values and their estimated depths, particularly in the lower part of the vertical profile. Compared to commonly used density-based parameterizations, our k values are consistently larger, suggesting a faster conductive heat exchange in firn.
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| 11. |
- McGuire, A. David, et al.
(författare)
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Variability in the sensitivity among model simulations of permafrost and carbon dynamics in the permafrost region between 1960 and 2009
- 2016
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Ingår i: Global Biogeochemical Cycles. - 0886-6236 .- 1944-9224. ; 30:7, s. 1015-1037
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Tidskriftsartikel (refereegranskat)abstract
- A significant portion of the large amount of carbon (C) currently stored in soils of the permafrost region in the Northern Hemisphere has the potential to be emitted as the greenhouse gases CO2 and CH4 under a warmer climate. In this study we evaluated the variability in the sensitivity of permafrost and C in recent decades among land surface model simulations over the permafrost region between 1960 and 2009. The 15 model simulations all predict a loss of near-surface permafrost (within 3m) area over the region, but there are large differences in the magnitude of the simulated rates of loss among the models (0.2 to 58.8x10(3)km(2)yr(-1)). Sensitivity simulations indicated that changes in air temperature largely explained changes in permafrost area, although interactions among changes in other environmental variables also played a role. All of the models indicate that both vegetation and soil C storage together have increased by 156 to 954TgCyr(-1) between 1960 and 2009 over the permafrost region even though model analyses indicate that warming alone would decrease soil C storage. Increases in gross primary production (GPP) largely explain the simulated increases in vegetation and soil C. The sensitivity of GPP to increases in atmospheric CO2 was the dominant cause of increases in GPP across the models, but comparison of simulated GPP trends across the 1982-2009 period with that of a global GPP data set indicates that all of the models overestimate the trend in GPP. Disturbance also appears to be an important factor affecting C storage, as models that consider disturbance had lower increases in C storage than models that did not consider disturbance. To improve the modeling of C in the permafrost region, there is the need for the modeling community to standardize structural representation of permafrost and carbon dynamics among models that are used to evaluate the permafrost C feedback and for the modeling and observational communities to jointly develop data sets and methodologies to more effectively benchmark models.
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| 12. |
- Van Pelt, Ward, et al.
(författare)
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A long-term dataset of climatic mass balance, snow conditions, and runoff in Svalbard (1957–2018)
- 2019
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Ingår i: The Cryosphere. - : Copernicus GmbH. - 1994-0416 .- 1994-0424. ; 13, s. 2259-2280
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Tidskriftsartikel (refereegranskat)abstract
- The climate in Svalbard is undergoing amplified change compared to the global mean. This has major implications for runoff from glaciers and seasonal snow on land. We use a coupled energy balance–subsurface model, forced with downscaled regional climate model fields, and apply it to both glacier-covered and land areas in Svalbard. This generates a long-term (1957–2018) distributed dataset of climatic mass balance (CMB) for the glaciers, snow conditions, and runoff with a 1 km×1 km spatial and 3-hourly temporal resolution. Observational data including stake measurements, automatic weather station data, and subsurface data across Svalbard are used for model calibration and validation. We find a weakly positive mean net CMB (+0.09 m w.e. a−1) over the simulation period, which only fractionally compensates for mass loss through calving. Pronounced warming and a small precipitation increase lead to a spatial-mean negative net CMB trend (−0.06 m w.e. a−1 decade−1), and an increase in the equilibrium line altitude (ELA) by 17 m decade−1, with the largest changes in southern and central Svalbard. The retreating ELA in turn causes firn air volume to decrease by 4 % decade−1, which in combination with winter warming induces a substantial reduction of refreezing in both glacier-covered and land areas (average −4 % decade−1). A combination of increased melt and reduced refreezing causes glacier runoff (average 34.3 Gt a−1) to double over the simulation period, while discharge from land (average 10.6 Gt a−1) remains nearly unchanged. As a result, the relative contribution of land runoff to total runoff drops from 30 % to 20 % during 1957–2018. Seasonal snow on land and in glacier ablation zones is found to arrive later in autumn (+1.4 d decade−1), while no significant changes occurred on the date of snow disappearance in spring–summer. Altogether, the output of the simulation provides an extensive dataset that may be of use in a wide range of applications ranging from runoff modelling to ecosystem studies.
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| 13. |
- van Pelt, Ward, et al.
(författare)
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Inverse estimation of snow accumulation along a radar transect on Nordenskioldbreen, Svalbard
- 2014
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Ingår i: Journal of Geophysical Research - Earth Surface. - 2169-9003 .- 2169-9011. ; 119:4, s. 816-835
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Tidskriftsartikel (refereegranskat)abstract
- We present an inverse modeling approach to reconstruct annual accumulation patterns from ground-penetrating radar (GPR) data. A coupled surface energy balance-snow model simulates surface melt and the evolution of subsurface density, temperature, and water content. The inverse problem consists of iteratively calibrating accumulation, serving as input for the model, by finding a match between modeled and observed radar travel times. The inverse method is applied to a 16km GPR transect on Nordenskioldbreen, Svalbard, yielding annual accumulation patterns for 2007-2012. Accumulation patterns with a mean of 0.75meter water equivalent (mwe)a(-1)contain substantial spatial variability, with a mean annual standard deviation of 0.17mwea(-1), and show only partial consistency from year to year. In contrast to traditional methods, accounting for melt water percolation, refreezing, and runoff facilitates accurate accumulation reconstruction in areas with substantial melt. Additionally, accounting for horizontal density variability along the transect is shown to reduce spatial variability in reconstructed accumulation, whereas incorporating irreducible water storage lowers accumulation estimates. Correlating accumulation to terrain characteristics in the dominant wind direction indicates a strong preference of snow deposition on leeward slopes, whereas weaker correlations are found with terrain curvature. Sensitivity experiments reveal a nonlinear response of the mass balance to accumulation changes. The related negative impact of small-scale accumulation variability on the mean net mass balance is quantified, yielding a negligible impact in the accumulation zone and a negative impact of -0.09mwea(-1)in the ablation area.
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| 14. |
- Vandecrux, Baptiste, et al.
(författare)
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The firn meltwater Retention Model Intercomparison Project (RetMIP) : evaluation of nine firn models at four weather station sites on the Greenland ice sheet
- 2020
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Ingår i: The Cryosphere. - : Copernicus GmbH. - 1994-0416 .- 1994-0424. ; 14:11, s. 3785-3810
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Tidskriftsartikel (refereegranskat)abstract
- Perennial snow, or firn, covers 80 % of the Greenland ice sheet and has the capacity to retain surface meltwater, influencing the ice sheet mass balance and contribution to sea-level rise. Multilayer firn models are traditionally used to simulate firn processes and estimate meltwater retention. We present, intercompare and evaluate outputs from nine firn models at four sites that represent the ice sheet's dry snow, percolation, ice slab and firn aquifer areas. The models are forced by mass and energy fluxes derived from automatic weather stations and compared to firn density, temperature and meltwater percolation depth observations. Models agree relatively well at the dry-snow site while elsewhere their meltwater infiltration schemes lead to marked differences in simulated firn characteristics. Models accounting for deep meltwater percolation overestimate percolation depth and firn temperature at the percolation and ice slab sites but accurately simulate recharge of the firn aquifer. Models using Darcy's law and bucket schemes compare favorably to observed firn temperature and meltwater percolation depth at the percolation site, but only the Darcy models accurately simulate firn temperature and percolation at the ice slab site. Despite good performance at certain locations, no single model currently simulates meltwater infiltration adequately at all sites. The model spread in estimated meltwater retention and runoff increases with increasing meltwater input. The highest runoff was calculated at the KAN_U site in 2012, when average total runoff across models (+/- 2 sigma) was 353 +/- 610 mm w. e. (water equivalent), about 27 +/- 48 % of the surface meltwater input. We identify potential causes for the model spread and the mismatch with observations and provide recommendations for future model development and firn investigation.
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