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1.
  • Wolpher, H., et al. (författare)
  • Synthesis and properties of an iron hydrogenase active site model linked to a ruthenium tris-bipyridine photosensitizer
  • 2003
  • Ingår i: Inorganic Chemistry Communications. - 1387-7003 .- 1879-0259. ; 6:8, s. 989-991
  • Tidskriftsartikel (refereegranskat)abstract
    • A dinuclear iron complex, related to the active site of Fe hydrogenases, has been covalently linked to a redox active ruthenium tris-bipyridine type photosensitizer. Photophysics and electrochemistry of this system are studied in solution. IR spectra of this complex together with its precursor, the dinuclear iron complex, were also shown.
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2.
  • Anderlund, Magnus F., et al. (författare)
  • A new, dinuclear high spin manganese(III) complex with bridging phenoxy and methoxy groups. Structure and magnetic properties
  • 2006
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 9:12, s. 1195-1198
  • Tidskriftsartikel (refereegranskat)abstract
    • A new mu-phenoxy-mu-metoxy di-manganese(III) complex with the trisphenolic ligand, 2,6-bis[((2-hydroxybenzyl)(2-pyridylmethyl)amino)methyl]-4-methylphenol, was isolated as a perchlorate salt. The X-ray structure shows that the two manganese(III) ions are in a distorted octrahedral enviroment with approximately perpendicular Jahn-Teller axes. Investigation of the molar magnetic susceptibility reveals a ferromagnetic coupling between the two high-spin manganese(III) ions. Fitting of the data led to g = 2 and J = 12.5 cm(-1).
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3.
  • Biradar, Bhimaraya R., et al. (författare)
  • High areal capacitance polyoxotungstate-reduced graphene oxide-based supercapacitors
  • 2023
  • Ingår i: Inorganic Chemistry Communications. - : ELSEVIER. - 1387-7003 .- 1879-0259. ; 155
  • Tidskriftsartikel (refereegranskat)abstract
    • The modern lifestyle has driven the advent of high-power electronic gadgets to need high-efficiency energy storage devices. Towards that goal, reduced graphene oxide (rGO) mediated polyoxometalates (POMs) based electrode materials are increasingly showing promising performance for building efficient energy storage devices primarily due to their redox properties. In this report, the silicotungstate [K5[SiVW11O40]. nH2O (SiVW11) embedded rGO nanocomposites as electrode materials in supercapacitor applications were synthesized via chemical and hydrothermal methods. The synthesized nanocomposites were characterized by various techniques, such as Fourier-Transform-Infrared (FTIR) Spectroscopy, Powder X-ray Diffraction (XRD) and Energy Dispersive X-ray Spectroscopy (EDS), Thermogravimetric Analysis (TGA), X-ray photoelectron spectroscopy (XPS) and Brunauer-Emmett-Teller (BET) measurement. The nanocomposites electrochemical properties were examined by adopting a two-electrode setup with cyclic voltammetry (CV) and galvanostatic charge/discharge (GCD) in a 0.5 M H2SO4 electrolyte medium. The hydrothermally reduced graphene oxide (HrGO) nanocomposite exhibited a noticeable surge in areal capacitance of 377.4 mF/cm2 at a current density of 1.5 mA/cm2. The resulting composite had 52.4 & mu;Wh/cm2 and 1500 & mu;W/cm2 as energy and power density, respectively at 1.5 mA/cm2 current density. In addition, the capacitance retention is over 81% after 5000 cycles at a current density of 9 mA/ cm2. The highest specific power of 5000 & mu;W/cm2 was obtained at 5 mA/cm2 current density. On the other hand, chemically reduced graphene (CrGO) nanocomposite showed an areal capacitance of 277.2 mF/cm2 at the same current density. As a result, the SiVW11 clusters coupled with the rGO increase the areal capacitance of nanocomposites with exceptional electrical and mechanical stability. From an application standpoint, both composites were employed successfully for running a DC motor in a series cell connection.
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4.
  • Bortoluzzi, Marco, et al. (författare)
  • Green-emitting manganese (II) complexes with phosphoramide and phenylphosphonic diamide ligands
  • 2018
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier. - 1387-7003 .- 1879-0259. ; 92, s. 145-150
  • Tidskriftsartikel (refereegranskat)abstract
    • Tetrahedral manganese(II) complexes having formulae [MnX2{O = PR(NMe2)2}2] (X = Br, I; R = NMe2, Ph) were isolated and characterized, and in the case of [MnBr2{O = PPh(NMe2)2}2] the structure was ascertained by means of single crystal X-ray diffraction. All the complexes showed intense green emission assigned to the Mn(II) 4T1(4G) → 6A1(6S) transition upon excitation with UV light, with photoluminescence lifetimes in the range 100–1000 μs. Bromo-complexes maintain their luminescence features once dispersed in polycaprolactone matrix.
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5.
  • Bortoluzzi, Marco, et al. (författare)
  • Luminescent copper(I) coordination polymer with 1-methyl-1H-benzotriazole, iodide and acetonitrile as ligands
  • 2019
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier. - 1387-7003 .- 1879-0259. ; 102, s. 141-146
  • Tidskriftsartikel (refereegranskat)abstract
    • The Cu(I) coordination polymer [Cu3(μ3-I)3(μ-btzMe)(NCCH3)]n (btzMe = 1-methyl-1H-benzotriazole) was prepared and characterized by X-Ray diffraction. The compound showed strong green emission upon excitation with wavelengths below 475 nm, with lifetime of 47 μs. The emission was attributed to 3(X,M)LCT transition on the basis of experimental data and DFT calculations.
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6.
  • Buvailo, Halyna, et al. (författare)
  • Facile one-pot synthesis of hybrid compounds based on decavanadate showing water oxidation activity
  • 2020
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 119
  • Tidskriftsartikel (refereegranskat)abstract
    • Herein, we report the synthesis of two hybrid compounds based on decavanadate anion, namely, [Cu(dien)(Hdien)]2[V10O28]·2H2O (1) and (H3dien)2[V10O28]·4H2O (2), where dien = diethylenetriamine, obtained under mild conditions. Both compounds were characterized by elemental, TG/DTA, single crystal and powder X-ray diffraction analyses, IR and EPR spectroscopies. The compound 1 was found to be active as homogeneous photochemical oxidation catalyst of water to dioxygen.
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7.
  • Chen, Y. G., et al. (författare)
  • Synthesis and property of a chiral salen Mn(III) complex covalently linked to an Ru(II) tris(bipyridyl) photosensitizer
  • 2005
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 8:7, s. 606-609
  • Tidskriftsartikel (refereegranskat)abstract
    • A catalyst-photo sensitizer binuclear Mn(III)Ru(II) complex was prepared, in which the catalyst moiety of the Mn(III) unit with a chiral pyrrolidine salen ligand was covalently linked to a photosensitizer of the Ru(II) tris(bipyridyl) fragment. The electrochemical and photophysical properties of the Mn(III)Ru(II) complex were studied.
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8.
  • Ferraro, Valentina, et al. (författare)
  • Luminescent Cu(I) complex with bis(indazol-1-yl)phenylmethane as chelating ligand
  • 2020
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier. - 1387-7003 .- 1879-0259. ; 116
  • Tidskriftsartikel (refereegranskat)abstract
    • The cationic Cu(I) complex [Cu(N^N)2]+, where N^N is bis(indazol-1-yl)phenylmethane, was synthesized as chloride or tetrafluoroborate salt by reacting CuCl or [Cu(NCCH3)4][BF4] with bis(indazol-1-yl)phenylmethane under mild conditions. The structure of [Cu(N^N)2]Cl was ascertained by single-crystal X-ray diffraction. The complex exhibited bright yellow emission upon excitation with near UV and violet light, attributed to triplet LLCT/MLCT transitions on the basis of experimental data and computational outcomes.
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9.
  • Figgemeier, Egbert, et al. (författare)
  • Modification of electron transfer properties in photoelectrochemical solar cells by substituting {Ru(terpy)(2)}(2+) dyes with thiophene
  • 2004
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 7:1, s. 117-121
  • Tidskriftsartikel (refereegranskat)abstract
    • A comparison of the properties of the 2-thienyl-substituted carboxyphenyl {RuII(terpy)2} dyes with their non-substituted analogues has enabled us to gain insight into the electronic properties that are prerequisite for efficient electron injection into the TiO2 conduction band in photoelectrochemical solar cells. Introducing the thienyl group has a profound effect upon the efficiency of photoinduced electron injection. This effect can be explained by a significant shift in the LUMO position from the terpy ligand anchored on the TiO2 surface towards the 2-thienyl substituted ligand, which is shown by means of electrochemistry and semiempirical calculations.
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10.
  • Ghazzali, Mohamed I D M, 1974, et al. (författare)
  • Synthesis, EPR and DFT calculations of rare Ag(II)porphyrins and the crystal structure of [Zn(II)tetrakis(4-bromo-2-thiophene)porphyrin]
  • 2008
  • Ingår i: Inorganic Chemistry Communication. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 11:9, s. 1019-1022
  • Tidskriftsartikel (refereegranskat)abstract
    • Meso-tetrakis (4-bromo-2-thiophene) and (5-bromo-2-thiophene) porphyrins were synthesized in 18% yield from freshly distilled pyrrole and the corresponding aldehydes in refluxing propionic acid. Reaction of both porphyrins with either Zn(OAc) 2 · 2H 2 O or Ag(OAc) afforded the corresponding metal complexes in 20% yield. The free bases and metal complexes were characterized by IR, NMR, EPR, MS and XPS. The crystal structure of 5,10,15,20(4-bromo-2-thiophene)porphyrinato Zn(II) was determined by X-ray diffraction and shows a 'zigzag-like' packing pattern due to S···S intermolecular interaction. Structural features of these molecules are discussed by DFT quantum chemical calculations. © 2008 Elsevier B.V. All rights reserved.
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11.
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12.
  • Jarenmark, Martin, et al. (författare)
  • Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases
  • 2010
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1879-0259 .- 1387-7003. ; 13:3, s. 334-337
  • Tidskriftsartikel (refereegranskat)abstract
    • The heterodinuclear complexes [FeZn(L)(CH3CO2)(2)](+) (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases (C) 2009 Elsevier B V All rights reserved
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13.
  • Jiang, S., et al. (författare)
  • A furan-containing diiron azadithiolate hexacarbonyl complex with unusual lower catalytic proton reduction potential
  • 2006
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 9:3, s. 290-292
  • Tidskriftsartikel (refereegranskat)abstract
    • A new biomimetic model of the active site of Fe-only hydrogenase [{(mu-SCH2)(2)N(2-C4H3O)} Fe-2(CO)(6)] (6) was synthesized and characterized by IR, H-1, C-13 NMR spectroscopy. The butterfly based core structure was also confirmed by X-ray diffraction. The electrochemistry data indicated that the reductive potential at -1.13 V versus Fc/Fc(+) by HClO4 is the lowest of that reported.
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14.
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15.
  • Kostakis, George, et al. (författare)
  • Two 3D supramolecular architectures from zinc hydrogen aconitate 1D polymers
  • 2006
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1879-0259 .- 1387-7003. ; 9:9, s. 915-919
  • Tidskriftsartikel (refereegranskat)abstract
    • The reaction of Zn(NO3)(2)center dot 3(H2O) with trans-aconitic acid, in presence of chelating Lewis bases, leads to the formation of the 1D polymers [Zn(N-N)(LH)] center dot nH(2)O, where LH3 = trans-aconitic acid, 1 : N-N = 1,10-phenanthroline (phen), n = 1, 2 : N-N = 2,2'-bipyridine (bpy), n = 2. 3D supramolecular assemblies are constructed through H-bonding and stacking interactions. (C) 2006 Elsevier B.V. All rights reserved.
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16.
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17.
  • Otto, Stefanus, et al. (författare)
  • Bridge-splitting of trans-[PtCl2(eta(2)-CH2=CH2)](2) by weak nucleophiles: Crystal and molecular structure of trans-[PtCl2(eta(2)-CH2=CH2)(MeCN)]
  • 2009
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1879-0259 .- 1387-7003. ; 12:8, s. 766-768
  • Tidskriftsartikel (refereegranskat)abstract
    • Bridge-splitting of trans-[PtCl2(eta(2)-CH2=CH2)](2), 1, by L in dichloromethane yields trans-[PtCl2(eta(2)-CH2=CH2)(L)] (L = THF, 2, or MeCN, 3) with bridge-splitting equilibrium constants of 0.0289 +/- 0.0007 and 3601 +/- 215 mol(-1) dm(3), respectively, as determined by UV/Vis measurements. The reaction of 3 in MeCN with Cl- is essentially quantitative. The crystal structure of trans-[PtCl2(eta(2)-CH2=CH2)(CH3CN)] is reported. (C) 2009 Elsevier B.V. All rights reserved.
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18.
  • Sharma, Manish Kumar, et al. (författare)
  • Comprehensive investigations of the synergistic effect of chalcone on the anti-corrosion activity of environmentally benign triazole hybrid
  • 2023
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier B.V.. - 1387-7003 .- 1879-0259. ; 158
  • Tidskriftsartikel (refereegranskat)abstract
    • This research article presents a comprehensive investigation into the corrosion inhibition performance of a 1,2,3-triazole-based hybrid (TCA) with incorporated triazole, chalcone, and amide moieties. The amalgamation of these pharmacologically active moieties synergistically enhances the ability of the TCA hybrid to form protective films on metal surfaces. The study employs a combination of experimental and theoretical methods to assess the corrosion inhibition properties. Multiple sophisticated techniques like weight loss, EIS, PDP, SEM, EDX, and UV–Vis spectroscopy reveals TCA's exceptional inhibitory efficiency (∼99 % at 200 ppm) for mild steel (MS). PDP analysis suggests a mixed-type inhibition mechanism. The experimental findings are further supported by the DFT calculations by exploring the interactions between the inhibitor and mild steel (MS). The remarkable corrosion inhibition efficacy of TCA along with its eco-friendly behavior aligns the present work with the growing global emphasis on sustainability.
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19.
  • Shevchenko, Denys V., et al. (författare)
  • Direct template synthesis of a heterometallic Co-III/Zn-II complex : The advantage of using a metal powder as a starting material
  • 2008
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 11:10, s. 1209-1211
  • Tidskriftsartikel (refereegranskat)abstract
    • The heterometallic complex [Co(L-1)Cl-2][ZnCl3(DMF)] (L-1 = 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-ene) has been obtained by direct template synthesis from cobalt powder, zinc oxide, zinc chloride, ethylenediamine dihydrochloride and acetone in dimethylformamide and characterized by X-ray crystallographic analysis. The mechanism of the complex formation is suggested.
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20.
  • Thapper, Anders, et al. (författare)
  • Reversible -coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster
  • 2004
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1879-0259 .- 1387-7003. ; 7:3, s. 443-446
  • Tidskriftsartikel (refereegranskat)abstract
    • The triallylphosphine-substituted clusters [Ru3(CO)11{P(CH2CH=CH2)3}], [Ru3(CO)10{P(CH2CH=CH2)3}2] and [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] have been prepared; reaction of [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] with phosphines/phosphites leads to cleavage of the Ru–allyl -bond and formation of [Ru3(CO)11{P(CH2CH=CH2)3}(PR3)].
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21.
  • Viotti, Olle, et al. (författare)
  • Straightforward synthesis and structural characterization of the first alkoxy-zircono-silsesquioxanes - Potential models for zirconia-silica epoxidation catalysts Molecular hybrid materials mimicking solution exchange in MOFs
  • 2010
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 13:6, s. 774-777
  • Tidskriftsartikel (refereegranskat)abstract
    • The first representatives of alkoxy-zircono-silsesquioxane compounds, dinuclear [Cy7Si7O12]Zr(ROH)(mu-OR)(2)Zr(ROH)[O12Si7Cy7], where R = Pr-n, Bu-n, Bu-t: Cy = c-C6H11, and [Cy*7Si7O12]Zr(mu-ROH)(mu-OR)(2)Zr [O12Si7Cy*(7)], R = Bu-t; Cy* = c-C5H9, have been prepared with quantitative yield by interaction of the corresponding zirconium alkoxides with the cycloalkyl-substituted cage silsesquioxanes in hexane. The Xray single crystal study of the n-butoxide derivative revealed that zirconium atoms are hexacoordinated with the 3 oxygen atoms of the cage ligand, 2 from the bridging alkoxide groups and one from the solvating alcohol molecule in the coordination sphere. The molecule is additionally supported by a hydrogen bond between the solvating alcohol and an oxygen atom belonging to the cage ligand coordinated by the other zirconium atom. The structures of produced silsesquioxanes display behavior typical for metal-organic frameworks as they crystallize initially as hexane clathrates, but lose the solvent on storage in inert atmosphere. This results in formation of empty channels situated along the c-axis. (C) 2010 Elsevier B.V. All rights reserved.
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22.
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23.
  • Xu, Wei-Xia, et al. (författare)
  • A novel 3D metal-organic framework with silver iodide anion cluster [Ag14I16](2-) as node : Synthesis, structure, and fluorescence property
  • 2014
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003 .- 1879-0259. ; 40, s. 220-222
  • Tidskriftsartikel (refereegranskat)abstract
    • A novel 3D silver iodide metal-organic framework {[Ag14I16(HDABCO)(2)]center dot(DABCO)}(n) (DABCO = 1,4-diazabicyclo[2.2.2]octane) (1) has been synthesized solvothermally. In this compound, a [Ag14I16](2-) anion cluster was formed by twelve AgI4 tetrahedra and two AgI3 triangles by sharing their edges, in which its charge is compensated by two mono-protoned HDABCO(+). Each [Ag14I16](2-) cluster connects to six neighboring clusters by sharing corner I- ions between the AgI4 tetrahedra, resulting in a 3D framework. The compound 1 displays intense fluorescence emission with maximum at 400 nm and 465 nm upon 310 nm excitation at room temperature.
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24.
  • Zhang, Xuanjun, et al. (författare)
  • Uncoordinated inorganic salt in 1D chain structure : formation of a novel supermolecule [HgBr2(ptz)]2 ·HgBr2 (ptz = phenothiazine)
  • 2003
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier. - 1387-7003 .- 1879-0259. ; 6:10, s. 1338-1340
  • Tidskriftsartikel (refereegranskat)abstract
    • A novel supermolecule [HgBr2(ptz)]2 · HgBr2 (ptz=phenothiazine) with uncoordinated inorganic salt HgBr2 presented in a 1D chain was prepared. The bulky ligand phenothiazine has unusual coordination mode with large steric inhibition perpendicular to the chain direction. The uncoordinated HgBr2 molecule was stabilized by multiple weak Hg⋯Br interactions and the whole structure was also stabilized by strong π–π interactions and N–H⋯Br hydrogen bonds to form 2D network.
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25.
  • Borel, Cédric, 1979, et al. (författare)
  • Network analysis of barium oxalates Ba(C2O4)m(HC2O4)n(H2C2O4)p(H2O)q, including the new, uniform, five-connected loh net
  • 2009
  • Ingår i: Inorganic Chemistry Communication. - : Elsevier BV. - 1387-7003. ; 12:2, s. 105-108
  • Tidskriftsartikel (refereegranskat)abstract
    • The structures of three compounds from the system Ba(C2O4)m(HC2O4)n(H2C2O4)p(H2O)q have been structurally reinvestigated by low-temperature X-ray diffraction. Ba(C2O4)(H2O)2, 1, Ba(C2O4)(H2C2O4)(H2O)2, 2, and Ba(C2O4)0.5(HC2O4)(H2O), 3. The compounds are composed of three-dimensional coordination network structures with bridging oxalates and water molecules. Compound 1 is binodal, four and five connected with topology (4462)(4466)-tcs; 2 contains the common 66-dia net and 3 displays the new uniform network topology 610-loh. Together with the recently reported 610-ghw and 610-rld-z nets, and the 610-fnu net, the loh net forms a subclass of five-connected 610-nets based on the distorted trigonal bipyramidal coordination.
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26.
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27.
  • Hossain, Md Kamal, et al. (författare)
  • An experimental and theoretical study of a heptacoordinated tungsten(VI) complex of a noninnocent phenylenediamine bis(phenolate) ligand
  • 2018
  • Ingår i: Inorganic Chemistry Communications. - : Elsevier BV. - 1387-7003. ; 93, s. 149-152
  • Tidskriftsartikel (refereegranskat)abstract
    • [W(N2O2)(HN2O2)] (H4N2O2 = N,N′-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1,2-phenylenediamine) with a noninnocent ligand was formed by reaction of the alkoxide precursor [W(eg)3] (eg = the 1,2-ethanediolate dianion) with two equivalents of ligand. The phenol groups on one of the ligands are completely deprotonated and the ligand coordinates in a tetradentate fashion, whereas the other ligand is tridentate with one phenol having an intact OH group. The molecular structure, magnetic measurements, EPR spectroscopy, and density functional theory calculations indicate that the complex is a stable radical with the odd electron situated on the tridentate amidophenoxide ligand. The formal oxidation state of the metal center is W(VI), with the paramagnetic properties being due to the unpaired electron on the ligand.
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28.
  • Massoud, Al-Shimaà A A, 1980, et al. (författare)
  • 2D Bipyrimidine silver(I) nitrate: Synthesis, X-ray structure, solution chemistry and anti-microbial activit
  • 2011
  • Ingår i: Inorganic Chemistry Communication. - : Elsevier BV. - 1387-7003. ; 14:4, s. 550-553
  • Tidskriftsartikel (refereegranskat)abstract
    • Synthesis and X-ray single crystal structure analysis of the compound {[Ag2(μ2-bpym)(μ-O-NO3)2]}n, (1), (where bpym = 2,2′-bipyrimidine) are presented. Compound (1) has a (6,3)-2D honeycomb structure with a tetrahedral coordination geometry around the Ag(I) ion. In contrary to the solid state structural investigation, ESI-MS for (1) in solution shows a strong peak at m/z 423.0269 which indicates that the [Ag(bpym)2]+ cation is dominating instead of [Ag2(bpym)]2+. The anti-microbial activity of (1) was screened against 15 multi-drug resistant bacteria in comparison to silver(I) sulphadiazine and it showed a high activity against Burkholderia mallei which causes glanders; with a MIC value of 4 μg/ml.
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