| 1. |
- Agostini, Andrea, et al.
(författare)
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Evolution, pattern, and partitioning of deformation during oblique continental rifting : Inferences from lithospheric-scale centrifuge models
- 2009
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 10, s. Q11015-
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Tidskriftsartikel (refereegranskat)abstract
- Oblique rifting is investigated through centrifuge experiments that reproduce extension of a continental lithosphere containing a preexisting weakness zone. During extension, this weakness localizes deformation, and different rift obliquity is obtained by varying its trend with respect to the stretching direction. Model results show that deformation is mostly controlled by the obliquity angle a (defined as the angle between the orthogonal to the rift trend and the extension direction). For low obliquity (alpha < 45 degrees), rifting is initially characterized by activation of large, en echelon boundary faults bordering a subsiding rift depression, with no deformation affecting the rift floor. Increasing extension results in the abandonment of the boundary faults and the development of new faults within the rift depression. These faults are orthogonal to the direction of extension and arranged in two en echelon segments linked by a complex transfer zones, characterized by strike-slip component of motion. In these models, a strong strain partitioning is observed between the rift margins, where the boundary fault systems have an oblique-slip motion, and the valley floor that away from the transfer zones is affected by a pure extension. Moderate obliquity (alpha = 45 degrees) still results in a two-phase rift evolution, although boundary fault activity is strongly reduced, and deformation is soon transferred to the rift depression. The fault pattern is similar to that of low-obliquity models, although internal faults become slightly oblique to the orthogonal to the direction of extension. Deformation partitioning between the rift margins and the valley floor is still observed but is less developed than for low-obliquity rifting. For high obliquity (alpha > 45 degrees), no boundary faults form, and the extensional deformation affects the rift depression since early stages of extension. Dominance of the strike-slip motion over extension leads to the development of oblique-slip and nearly pure strike-slip faults, oblique to both the rift trend and the orthogonal to the extension direction, with no strain partitioning between the margins and the rift floor. These results suggest that oblique reactivation of preexisting weaknesses plays a major role in controlling rift evolution, architecture, and strain partitioning, findings that have a significant relevance for natural oblique rifts.
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| 2. |
- Aiuppa, Sandro, et al.
(författare)
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Tracking formation of a lava lake from ground and space: Masaya volcano (Nicaragua), 2015-2017
- 2018
-
Ingår i: Geochemistry, Geophysics, Geosystems. - 1525-2027. ; 19:2, s. 496-515
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Tidskriftsartikel (refereegranskat)abstract
- A vigorously degassing lava lake appeared inside the Santiago pit crater of Masaya volcano (Nicaragua) in December 2015, after years of degassing with no (or minor) incandescence. Here, we present an unprecedented-long (3 years) and continuous volcanic gas record that instrumentally characterizes the (re)activation of the lava-lake. Our results show that, before appearance of the lake, the volcanic gas plume composition became unusually CO2-rich, as testified by high CO2/SO2 ratios (mean, 12.2±6.3) and low H2O/CO2 ratios (mean, 2.3±1.3). The volcanic CO2 flux also peaked in November 2015 (mean, 81.3±40.6 kg/s; maximum, 247 kg/s). Using results of magma degassing models and budgets, we interpret this elevated CO2 degassing as sourced by degassing of a volatile-rich fast-convecting (3.6-5.2 m3·s-1) magma, supplying CO2-rich gas bubbles from minimum equivalent depths of 0.36-1.4 km. We propose this elevated gas bubbles supply destabilized the shallow (<1 km) Masaya magma reservoir, leading to upward migration of vesicular (buoyant) resident magma, and ultimately to (re)formation of the lava lake. At onset of lava lake activity on 11 December 2015 (constrained by satellite-based (MODIS) thermal observations), the gas emissions transitioned to more SO2-rich composition, and the SO2 flux increased by a factor ~40 % (11.4±5.2 kg/s) relative to background degassing (8.0 kg/s), confirming faster than normal (4.4 vs. ~3 m3·s-1) shallow magma convection. Elevated shallow magma circulation is also supported by gradual increase in irradiated thermal energy, captured by MODIS, from which we calculate that 0.4-0.8 m3·s-1 of magma have been surface-emplaced since December 2015.
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| 3. |
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| 4. |
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| 5. |
- Almqvist, Bjarne, et al.
(författare)
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Seismic properties of the Kohistan oceanic arc root : insights from laboratory measurements and thermodynamic modeling
- 2013
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 14:6, s. 1819-1841
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Tidskriftsartikel (refereegranskat)abstract
- P-wave velocities (Vp) have been measured in the laboratory and calculated using thermodynamic modeling for seven representative rock samples from the lower crust to mantle section of the Kohistan paleo-island arc. Lower crustal rocks comprise plagioclase-rich gabbro, garnet-bearing gabbro, and hornblendite; mantle rocks comprise garnetite, pyroxenite, websterite, and dunite. Measurements were performed at confining pressures up to 0.5GPa and temperatures up to 1200 degrees C. Vp were also calculated using rock major element chemistry with the Perple_X software package. Calculated Vp match closely the laboratory measurements. At depths representative for the arc root, Vp of upper mantle rocks vary from 7.7-8.1km/s, whereas the lower crustal rocks have velocities between 6.9-7.5km/s. P-wave anisotropy is small, with exceptions of sheared gabbros. Measured and calculated seismic properties are consistent with, and complement a growing database of published seismic properties from the Kohistan arc. In the light of such data, we discuss seismic imaging of present-day island arcs. Intermediate Vp (7.4-7.7km/s) in arc roots can be explained by pyroxenites and garnet-bearing mafic rocks. Strong seismic reflectors may be related to garnetites (8.0-8.2km/s).
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| 6. |
- Bailey, Lydia R., et al.
(författare)
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Characteristics and Consequences of Red Bed Bleaching by Hydrocarbon Migration : A Natural Example From the Entrada Sandstone, Southern Utah
- 2022
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Ingår i: Geochemistry Geophysics Geosystems. - : John Wiley & Sons. - 1525-2027. ; 23:8
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Tidskriftsartikel (refereegranskat)abstract
- Extensive regions of yellow and white ("bleached") sandstones within the terrestrial Jurassic red bed deposits of the Colorado Plateau reflect widespread interaction with subsurface reduced fluids which resulted in the dissolution of iron-oxide grain coatings. Reduced fluids such as hydrocarbons, CO2, and organic acids have been proposed as bleaching agents. In this study, we characterize an altered section of the Slick Rock member of the Jurassic Entrada Sandstone that exposes bleached sandstone with bitumen-saturated pore spaces. We observe differences in texture, porosity, mineralogy, and geochemistry between red, pink, yellow, and gray facies. In the bleached yellow facies we observe quartz overgrowths, partially dissolved K-feldspar, calcite cement, fine-grained illite, TiO2-minerals, and pyrite concretions. Clay mineral content is highest at the margins of the bleached section. Fe2O3 concentrations are reduced up to 3x from the red to gray facies but enriched up to 50x in iron-oxide concretions. Metals such as Zn, Pb, and rare-earth elements are significantly enriched in the concretions. Supported by a batch geochemical model, we conclude the interaction of red sandstones with reduced hydrocarbon-bearing fluids caused iron-oxide and K-feldspar dissolution, and precipitation of quartz, calcite, clay, and pyrite. Localized redistribution of iron into concretions can account for most of the iron removed during bleaching. Pyrite and carbonate stable isotopic data suggest the hydrocarbons were sourced from the Pennsylvanian Paradox Formation. Bitumen in pore spaces and pyrite precipitation formed a reductant trap required to produce Cu, U, and V enrichment in all altered facies by younger, oxidized saline brines.
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| 7. |
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| 8. |
- Barker, Abigail, et al.
(författare)
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Strontium isotopic constraints on fluid flow in the sheeted dyke complex of fast spreading crust: Pervasive fluid flow at Pito Deep.
- 2008
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 9:6
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Tidskriftsartikel (refereegranskat)abstract
- Fluid flow through the axial hydrothermal system at fast spreading ridges is investigated using the Sr-isotopic composition of upper crustal samples recovered from a tectonic window at Pito Deep (NE Easter microplate). Samples from the sheeted dike complex collected away from macroscopic evidence of channelized fluid flow, such as faults and centimeter-scale hydrothermal veins, show a range of 87Sr/86Sr from 0.7025 to 0.7030 averaging 0.70276 relative to a protolith with 87Sr/86Sr of ∼0.7024. There is no systematic variation in 87Sr/86Sr with depth in the sheeted dike complex. Comparison of these new data with the two other localities that similar data sets exist for (ODP Hole 504B and the Hess Deep tectonic window) reveals that the extent of Sr-isotope exchange is similar in all of these locations. Models that assume that fluid-rock reaction occurs during one-dimensional (recharge) flow lead to significant decreases in the predicted extent of isotopic modification of the rock with depth in the crust. These model results show systematic misfits when compared with the data that can only be avoided if the fluid flow is assumed to be focused in isolated channels with very slow fluid-rock exchange. In this scenario the fluid at the base of the crust is little modified in 87Sr/86Sr from seawater and thus unlike vent fluids. Additionally, this model predicts that some rocks should show no change from the fresh-rock 87Sr/86Sr, but this is not observed. Alternatively, models in which fluid-rock reaction occurs during upflow (discharge) as well as downflow, or in which fluids are recirculated within the hydrothermal system, can reproduce the observed lack of variation in 87Sr/86Sr with depth in the crust. Minimum time-integrated fluid fluxes, calculated from mass balance, are between 1.5 and 2.6 × 106 kg m−2 for all areas studied to date. However, new evidence from both the rocks and a compilation of vent fluid compositions demonstrates that some Sr is leached from the crust. Because this leaching lowers the fluid 87Sr/86Sr without changing the rock 87Sr/86Sr, these mass balance models must underestimate the time-integrated fluid flux. Additionally, these values do not account for fluid flow that is channelized within the crust.
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| 9. |
- Bhatnagar, Guarav, et al.
(författare)
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Analytical theory relating the depth of the sulfate‐methane transition to gas hydrate distribution and saturation
- 2011
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 12:3, s. 1-21
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Tidskriftsartikel (refereegranskat)abstract
- [1] We develop a theory that relates gas hydrate saturation in marine sediments to the depth of the sulfate‐ methane transition (SMT) zone below the seafloor using steady state, analytical expressions. These expres- sions are valid for systems in which all methane transported into the gas hydrate stability zone (GHSZ) comes from deeper external sources (i.e., advective systems). This advective constraint causes anaerobic oxidation of methane to be the only sulfate sink, allowing us to link SMT depth to net methane flux. We also develop analytical expressions that define the gas hydrate saturation profile based on SMT depth and site‐specific parameters such as sedimentation rate, methane solubility, and porosity. We evaluate our analytical model at four drill sites along the Cascadia Margin where methane sources from depth dominate. With our model, we calculate average gas hydrate saturations across GHSZ and the top occurrence of gas hydrate at these sites as 0.4% and 120 mbsf (Site 889), 1.9% and 70 mbsf (Site U1325), 4.7% and 40 mbsf (Site U1326), and 0% (Site U1329), mbsf being meters below seafloor. These values compare favorably with average saturations and top occurrences computed from resistivity log and chloride data. The analyt- ical expressions thus provide a fast and convenient method to calculate gas hydrate saturation and first‐ order occurrence at a given geologic setting where vertically upward advection dominates the methane flux.
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| 10. |
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| 11. |
- Bohm, Katja, et al.
(författare)
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Modern-type Paleogene Eolian Regime and Global Cooling-Modulated Dust Provenance in Late Paleogene of Central-East Asia
- 2024
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 25:2
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Tidskriftsartikel (refereegranskat)abstract
- Atmospheric mineral dust is a poorly constrained yet extremely important component of the climate system. Provenance studies from geologic dust archives are crucial to understand the drivers of the dust cycle over long time scales. Our multi-technique provenance analysis of a rare Paleogene (35–27 Ma) eolian dust sequence from Ulantatal, ∼400 km northwest of the Chinese Loess Plateau (CLP), shows that Paleogene dust transporting winds generally varied between northwesterly and westerly, the same as those in the late Neogene-Quaternary bipolar icehouse. We propose that, as today, westerly wind circulation patterns would have been modulated by an Arctic Oscillation (AO)-like situation, and that the warm Eocene favored a long-term negative phase of AO, leading to meridional westerly circulation and the dominance of a northwesterly dust transport pathway. After the Eocene-Oligocene transition (EOT), long-term positive phase of AO-like conditions initiated, leading to stronger and more zonal westerlies. The Siberian High (SH) also formed or strengthened at the EOT and started to control dust storm activity along the northwesterly transport pathway. We argue that increased Paleogene Northern Hemisphere (NH) ice volume was the ultimate driver of this modern-type dust transport regime in the Ulantatal region, possibly also controlling initial Ulantatal dust sequence formation via the development of the SH and modern-type eolian regime. The similarity between the Ulantatal and late Neogene northern CLP dust provenance signals suggests that the increased NH ice volume, via its control on the northwesterly dust transport, could have promoted increased loess formation also in the late Miocene.
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| 12. |
- Borthwick, Verity E., et al.
(författare)
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Quantification of mineral behavior in four dimensions : grain boundary and substructure dynamics in salt
- 2012
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 13, s. Q05005-
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Tidskriftsartikel (refereegranskat)abstract
- Here we present the first four dimensional (time and three dimensional space resolved) experiment on a strongly deformed geological material. Results show that even complicated microstructures with large continuous and discontinuous changes in crystallographic orientation can be resolved quantitatively. The details that can be resolved are unprecedented and therefore the presented technique promises to become influential in a wide range of geoscientific investigations. Grain and subgrain scale processes are fundamental to mineral deformation and associated Earth Dynamics, and time resolved observation of these processes is vital for establishing an in-depth understanding of the latter. However, until recently, in situ experiments were restricted to observations of two dimensional surfaces. We compared experimental results from two dynamic, in situ annealing experiments on a single halite crystal; a 2D experiment conducted inside the scanning electron microscope and a 3D X-ray diffraction experiment. This allowed us to evaluate the possible effects of the free surface on grain and subgrain processes. The extent to which surface effects cause experimental artifacts in 2D studies has long been questioned. Our study shows that, although the nature of recovery processes are the same, the area swept by subgrain boundaries is up to 5 times larger in the volume than observed on the surface. We suggest this discrepancy is due to enhanced drag force on subgrain boundaries by thermal surface grooving. Our results show that while it is problematic to derive absolute mobilities from 2D experiments, derived relative mobilities between boundaries with different misorientation angles can be used.
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| 13. |
- Brandstätter, Jennifer, et al.
(författare)
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The Origin of Carbonate Veins Within the Sedimentary Cover and Igneous Rocks of the Cocos Ridge : Results From IODP Hole U1414A
- 2018
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Ingår i: Geochemistry, Geophysics, Geosystems. - 1525-2027. ; 19:10, s. 3721-3738
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Tidskriftsartikel (refereegranskat)abstract
- Carbonate veins in the igneous basement and in the lithified sedimentary cover of the Cocos Ridge at International Ocean Discovery Program (IODP) Hole 344-U1414A reveal the hydrologic system and fluid-rock interactions. IODP Hole 344-U1414A was drilled on the northern flank of the Cocos Ridge and is situated 1 km seaward from the Middle America Trench offshore Costa Rica. Isotopic and elemental compositions were analyzed to constrain the fluid source of the carbonate veins and to reveal the thermal history of Hole 344-U1414A. The formation temperatures (oxygen isotope thermometer) of the carbonate veins in the lithified sedimentary rocks range from 70 to 92 °C and in the basalt from 32 to 82 °C. 87Sr/86Sr ratios of the veins in the altered Cocos Ridge basalt range between 0.707307 and 0.708729. The higher ratios are similar to seawater strontium ratios in the Neogene. 87Sr/86Sr ratios lower 0.7084 indicate exchange of Sr with the igneous host rock. The calcite veins hosted by the sedimentary rocks are showing more primitive 87Sr/86Sr ratios <0.706396. The isotopic compositions indicate seawater, modified into a hydrothermal fluid by subsequent heating, as the main fluid source. Low-temperature alteration and the presence of a high-temperature fluid resulted in different carbonate precipitates forming up to several cm thick veins. The geochemical data combined with age data of the sedimentary rocks suggest intraplate seamount volcanism in the area between the Galapagos hot spot and the Cocos Island as an additional heating source, after the formation of the Cocos Ridge at the Galapagos hot spot.
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| 14. |
- Budd, David, 1985-, et al.
(författare)
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Persistent multitiered magma plumbing beneath Katla volcano, Iceland
- 2016
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 17:3, s. 966-980
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Tidskriftsartikel (refereegranskat)abstract
- Recent seismic unrest and a persistent Holocene eruption record at Katla volcano, Iceland indicate that a near-future eruption is possible. Previous petrological investigations suggest that Katla is supplied by a simple plumbing system that delivers magma directly from depth, while seismic and geodetic data also point toward the existence of upper-crustal magma storage. To characterize Katla's recent plumbing system, we established mineral-melt equilibrium crystallization pressures from four age-constrained Katla tephras spanning from 8 kyr BP to 1918. The results point to persistent shallow- (≤8 km depth) as well as deep-crustal (ca. 10 – 25 km depth) magma storage beneath Katla throughout the last 8 kyr. The presence of multiple magma storage regions implies that mafic magma from the deeper reservoir system may become gas-rich during ascent and storage in the shallow crust and erupt explosively. Alternatively, it might intersect evolved magma pockets in the shallow-level storage region, and so increase the potential for explosive mixed-magma ash eruptions.
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| 15. |
- Burchardt, Steffi, 1982-, et al.
(författare)
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Three-dimensional geometry of concentric intrusive sheet swarms in the Geitafell and the Dyrfjöll Volcanoes, Eastern Iceland
- 2011
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Ingår i: Geochemistry Geophysics Geosystems. - Washington, DC : American Geophysical Union (AGU) and the Geochemical Society. - 1525-2027. ; 12:7, s. Q0AB09-
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Tidskriftsartikel (refereegranskat)abstract
- Sheet intrusions (inclined sheets and dykes) in the deeply eroded volcanoes of Geitafell and Dyrfjöll,eastern Iceland, were studied at the surface to identify the location, depth, and size of their magmaticsource(s). For this purpose, the measured orientations of inclined sheets were projected in three dimensionsto produce models of sheet swarm geometries. For the Geitafell Volcano, the majority of sheetsconverge toward a common focal area with a diameter of at least 4 to 7 km, the location of which coincideswith several gabbro bodies exposed at the surface. Assuming that these gabbros represent part of the magmachamber feeding the inclined sheets, a source depth of 2 to 4 km below the paleoland surface is derived.A second, younger swarm of steeply dipping sheets crosscuts this gabbro and members of the first swarm.The source of this second swarm is estimated to be located to the SE of the source of Swarm 1, below thepresent‐day level of exposure and deeper than the source of the first swarm. For the Dyrfjöll Volcano,we show that the sheets can be divided into seven different subsets, three of which can be interpretedas swarms. The most prominent swarm, the Njardvik Sheet Swarm, converges toward a several kilometerswide area in the Njardvik Valley at a depth of 1.5 to 4 km below the paleoland surface. Two additionalmagmatic sources are postulated to be located to the northeast and southwest of the main source. Crosscuttingrelationships indicate contemporaneous, as well as successive activity of different magma chambers,but without a resolvable spatial trend. The Dyrfjöll Volcano is thus part of a complex volcanic cluster thatextends far beyond the study area and can serve as fossil analog for nested volcanoes such as Askja, whereasin Geitafell, the sheet swarms seem to have originated from a single focus at one time, thus defining a singlecentral volcanic complex, such as Krafla Volcano.
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| 16. |
- Böttner, Christoph, et al.
(författare)
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Pockmarks in the Witch Ground Basin, Central North Sea
- 2019
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 20:4, s. 1698-1719
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Tidskriftsartikel (refereegranskat)abstract
- Marine sediments host large amounts of methane (CH4), which is a potent greenhouse gas. Quantitative estimates for methane release from marine sediments are scarce, and a poorly constrained temporal variability leads to large uncertainties in methane emission scenarios. Here, we use 2-D and 3-D seismic reflection, multibeam bathymetric, geochemical, and sedimentological data to (I) map and describe pockmarks in the Witch Ground Basin (central North Sea), (II) characterize associated sedimentological and fluid migration structures, and (III) analyze the related methane release. More than 1,500 pockmarks of two distinct morphological classes spread over an area of 225 km(2). The two classes form independently from another and are corresponding to at least two different sources of fluids. Class 1 pockmarks are large in size (> 6 m deep, > 250 m long, and > 75 m wide), show active venting, and are located above vertical fluid conduits that hydraulically connect the seafloor with deep methane sources. Class 2 pockmarks, which comprise 99.5% of all pockmarks, are smaller (0.9-3.1 m deep, 26-140 m long, and 14-57 m wide) and are limited to the soft, fine-grained sediments of the Witch Ground Formation and possibly sourced by compaction-related dewatering. Buried pockmarks within the Witch Ground Formation document distinct phases of pockmark formation, likely triggered by external forces related to environmental changes after deglaciation. Thus, greenhouse gas emissions from pockmark fields cannot be based on pockmark numbers and present-day fluxes but require an analysis of the pockmark forming processes through geological time. Plain Language Summary Marine sediments host large amounts of methane (CH4), which is a potent greenhouse gas. The amount of methane released into the atmosphere is, however, largely unknown making it difficult to implement this methane source in climate models. Here we use geophysical, geochemical, and sedimentological data to map the distribution of fluid escape structures in the central North Sea. More than 1,500 pockmarks, which are circular to semicircular depressions of the seafloor, indicate fluid flow from the subsurface. There are two distinct morphological classes of pockmarks corresponding to at least two different fluid sources. Class 1 pockmarks are large, show active venting, and are located above vertical fluid conduits in the subsurface, which feed fluids from deeper strata. Class 2 pockmarks, which comprise 99.5% of all pockmarks, are smaller and limited to the soft sediments directly below the seafloor. Older pockmarks in the subsurface document distinct phases of pockmark formation, likely triggered by external forces after the retreat of ice in the North Sea. The amount of methane released from natural geological sources based on pockmark numbers may be wrong as these do not take into account the origin and composition of released fluids.
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| 17. |
- Böttner, Christoph, et al.
(författare)
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Pockmarks in the Witch Ground Basin, Central North Sea
- 2019
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 20:4, s. 1698-1719
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Tidskriftsartikel (refereegranskat)abstract
- Marine sediments host large amounts of methane (CH4), which is a potent greenhouse gas. Quantitative estimates for methane release from marine sediments are scarce, and a poorly constrained temporal variability leads to large uncertainties in methane emission scenarios. Here, we use 2-D and 3-D seismic reflection, multibeam bathymetric, geochemical, and sedimentological data to (I) map and describe pockmarks in the Witch Ground Basin (central North Sea), (II) characterize associated sedimentological and fluid migration structures, and (III) analyze the related methane release. More than 1,500 pockmarks of two distinct morphological classes spread over an area of 225 km2. The two classes form independently from another and are corresponding to at least two different sources of fluids. Class 1 pockmarks are large in size (>6 m deep, >250 m long, and >75 m wide), show active venting, and are located above vertical fluid conduits that hydraulically connect the seafloor with deep methane sources. Class 2 pockmarks, which comprise 99.5% of all pockmarks, are smaller (0.9–3.1 m deep, 26–140 m long, and 14–57 m wide) and are limited to the soft, fine-grained sediments of the Witch Ground Formation and possibly sourced by compaction-related dewatering. Buried pockmarks within the Witch Ground Formation document distinct phases of pockmark formation, likely triggered by external forces related to environmental changes after deglaciation. Thus, greenhouse gas emissions from pockmark fields cannot be based on pockmark numbers and present-day fluxes but require an analysis of the pockmark forming processes through geological time.
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| 18. |
- Cabral, R.A., et al.
(författare)
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Volatile cycling of H2O, CO2, F, and Cl in the HIMU mantle: A new window provided by melt inclusions from oceanic hotspot lavas at Mangaia, Cook Islands.
- 2014
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 15, s. 4445-4467
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Tidskriftsartikel (refereegranskat)abstract
- Mangaia hosts the most radiogenic Pb-isotopic compositions observed in ocean island basalts and represents the HIMU (high µ = 238U/204Pb) mantle end-member, thought to result from recycled oceanic crust. Complete geochemical characterization of the HIMU mantle end-member has been inhibited due to a lack of deep submarine glass samples from HIMU localities. We homogenized olivine-hosted melt inclusions separated from Mangaia lavas and the resulting glassy inclusions made possible the first volatile abundances to be obtained from the HIMU mantle end-member. We also report major and trace element abundances and Pb-isotopic ratios on the inclusions, which have HIMU isotopic fingerprints. We evaluate the samples for processes that could modify the volatile and trace element abundances postmantle melting, including diffusive Fe and H2O loss, degassing, and assimilation. H2O/Ce ratios vary from 119 to 245 in the most pristine Mangaia inclusions; excluding an inclusion that shows evidence for assimilation, the primary magmatic H2O/Ce ratios vary up to ∼200, and are consistent with significant dehydration of oceanic crust during subduction and long-term storage in the mantle. CO2 concentrations range up to 2346 ppm CO2 in the inclusions. Relatively high CO2 in the inclusions, combined with previous observations of carbonate blebs in other Mangaia melt inclusions, highlight the importance of CO2 for the generation of the HIMU mantle. F/Nd ratios in the inclusions (30 ± 9; 2σ standard deviation) are higher than the canonical ratio observed in oceanic lavas, and Cl/K ratios (0.079 ± 0.028) fall in the range of pristine mantle (0.02–0.08).
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| 19. |
- Cohen, A. L., et al.
(författare)
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Compositional variability in a cold-water scleractinian, Lophelia pertusa: New insights into "vital effects"
- 2006
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 7
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Tidskriftsartikel (refereegranskat)abstract
- We analyzed Sr/Ca and Mg/Ca ratios in the thecal wall of Lophelia pertusa, a cold-water coral, using SIMS ion microprobe techniques. The wall grows by simultaneous upward extension and outward thickening. Compositional variability displays similar trends along the upward and outward growth axes. Sr/Ca and Mg/Ca ratios oscillate systematically and inversely. The sensitivity of Lophelia Sr/Ca ratios to the annual temperature cycle (-0.18 mmol.mol(-1)/degrees C) is twice as strong as that exhibited by tropical reef corals, and four times as strong as the temperature dependence of Sr/Ca ratios of abiogenic aragonites precipitated experimentally from seawater. A comparison of the skeletal composition of Lophelia with results from precipitation calculations carried out using experimentally determined partition coefficients suggests that both temperature-dependent element partitioning and seasonal changes in the mass fraction of aragonite precipitated from the calcifying fluid influence the composition of Lophelia skeleton. Results from calculations that combine these effects reproduce both the exaggerated amplitude of the Sr/Ca and Mg/Ca oscillations and the inverse relationship between Sr/Ca and Mg/Ca ratios.
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| 20. |
- Dayton, K., et al.
(författare)
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Magmatic Storage and Volatile Fluxes of the 2021 La Palma Eruption
- 2024
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 25:6
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Tidskriftsartikel (refereegranskat)abstract
- The 2021 La Palma eruption (Tajogaite) was unprecedented in magnitude, duration, and degree of monitoring compared to historical volcanism on La Palma. Here, we provide data on melt inclusions in samples from the beginning and end of the eruption to compare the utility of both melt and fluid inclusions as recorders of magma storage. We also investigated compositional heterogeneities within the magmatic plumbing system. We found two populations of olivine crystals: a low Mg# (78–82) population present at the beginning and end of eruption, recording the maximum volatile contents (2.5 wt % H2O, 1,800 ppm F, 700 ppm Cl, 3,800 ppm S) and a higher Mg# (83–86) population sampled toward the end of the eruption, with lower volatile contents. Despite their host composition, melt inclusions share the same maximum range of CO2 concentrations (1.2–1.4 wt %), indicating olivine growth and inclusion capture at similar depths. Overall, both melt and fluid inclusions record similar pressures (450–850 MPa, ∼15–30 km), and when hosted in the same olivine crystal pressures are indistinguishable within error. At these mantle pressures, CO2 is expected to be an exsolved phase explaining the similar range of CO2 between the two samples, but other volatile species (F, Cl, S) behave incompatibly, and thus, the increase between the two olivine populations can be explained by fractional crystallization prior to eruption. Finally, based on our new data, we provide estimates on the total volatile emission of the eruption.
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| 21. |
- Deegan, Frances, et al.
(författare)
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Age and Geochemistry of High Arctic Large Igneous Province Tholeiitic Magmatism in NW Axel Heiberg Island, Canada
- 2023
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 24:11
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Tidskriftsartikel (refereegranskat)abstract
- The Cretaceous High Arctic Large Igneous Province (HALIP) in Canada involved extrusion of continental flood basalts (CFBs) at 130-120 Ma and 100-95 Ma and emplacement of an extensive sill and dike network that intersected the Carboniferous to Paleogene Sverdrup Basin. In this paper, we present new Ar-40/Ar-39 ages, major and trace elements, and Sr-Nd-Pb isotope ratios for HALIP lava, dikes, and sills from Bukken Fiord, NW Axel Heiberg Island, Canadian Arctic Islands. Our best constrained Ar-40/(39) ages yield a weighted average of 124.1 +/- 1 (2 sigma) Ma, coincident with the first pulse of tholeiitic CFB magmatism in the Arctic-wide HALIP as exemplified by Isachsen Formation flood basalts on Axel Heiberg Island. The Bukken Fiord samples are plagioclase and clinopyroxene-phyric tholeiitic basalts, are relatively evolved (3.2-6.5 wt% MgO), and share similar major and trace element compositions to typical HALIP tholeiites. Initial Nd-143/Nd-144 ranges from 0.51260 to 0.51291 and initial Sr-87/Sr-86 ranges from 0.70362 to 0.70776, while measured Pb-206/Pb-204, Pb-207/Pb-204, and Pb-208/Pb-204 range from 18.614 to 19.199, 15.534 to 15.630, and 38.404 to 39.054, respectively. The most primitive sample in this study has Sr-Nd-Pb isotope signatures that suggest an enriched plume-derived mantle source for HALIP tholeiites. Most samples, however, possess relatively radiogenic isotope signatures that can be explained by moderate degrees of assimilation of Sverdrup Basin sedimentary rocks. Magma-crust interaction in the HALIP plumbing system was likely widespread and may have increased the environmental impact of the HALIP, particularly if crustal carbon was volatilized.
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| 22. |
- Drake, Henrik, Docent, 1979-, et al.
(författare)
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In Situ Rb/Sr Geochronology and Stable Isotope Geochemistry Evidence for Neoproterozoic and Paleozoic Fracture-Hosted Fluid Flow and Microbial Activity in Paleoproterozoic Basement, SW Sweden
- 2023
-
Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 24:5
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Tidskriftsartikel (refereegranskat)abstract
- Recent studies have shown that biosignatures of ancient microbial life exist in mineral coatings in deep bedrock fractures of Precambrian cratons, but such surveys have been few and far between. Here, we report results from southwestern Sweden in an area of 1.6-1.5 Ga Paleoproterozoic rocks heavily reworked by the 1.14-0.96 Ga Sveconorwegian orogeny, a terrane previously scarcely explored for ancient microbial biosignatures. Calcite-pyrite-adularia-illite-coated fractures were analyzed for stable isotopes via Secondary Ion Mass Spectrometry (delta C-13, delta O-18, delta S-34) and in situ Rb/Sr geochronology via Laser-ablation inductively coupled plasma mass spectrometry. The Rb/Sr ages for calcite-adularia and calcite-illite show that several fluid flow events can be discerned (797 +/- 18-769 +/- 7, 391 +/- 5-387 +/- 6, 356 +/- 5-347 +/- 4, and 301 +/- 7 Ma). The delta C-13, delta O-18 and Sr-87/Sr-86 values of different calcite growth zones further confirmed episodic fluid flow. Pyrite delta S-34 values down to -49.9% V-CDT, together with systematically increased delta S-34 from crystal core to rim, suggest formation following microbial sulfate reduction under semi-closed conditions. Assemblages involving MSR-related pyrite generally have Devonian to Permian Rb/Sr ages, indicating an association to extension-related fracturing and fluid mixing during foreland-basin formation linked to Caledonian orogeny in the northwest. An assemblage with an age of 301 +/- 7 Ma is potentially related to Oslo Rift extension, whereas the Neo-Proterozoic ages relate to post-Sveconorwegian extensional tectonics. Remnants of short-chained fatty acids in the youngest calcite coatings further indicate a biogenic origin, while the absence of organic molecules in older calcite is in line with thermal degradation, potentially related to heating during Caledonian foreland basin burial. Plain Language Summary This study investigates mineral coatings in Proterozoic basement fractures of Southwestern Sweden, within the Precambrian Fennoscandian shield, to gain insights into ancient microbial life and paleo-fluid flow. Isotopic signatures of these mineral coatings suggest that microbial sulfate reducers have been present in the system as also indicated by preserved organic molecules. Microanalytical geochronology determinations reveal that the fracture system has been activated several times in the Neoproterozoic, Devonian-Early Carboniferous, and Late Carboniferous/Early Permian. These activations are associated with extension events following the Sveconorwegian and Caledonian orogenies as well as formation of the Oslo Rift. The signs of microbial activity are related to the youngest of these events, post-dating burial in the Caledonian foreland basin, when bedrock temperatures became habitable.
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| 23. |
- Døssing, Arne, et al.
(författare)
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New aero-gravity results from the Arctic : Linking the latest Cretaceous-early Cenozoic plate kinematics of the North Atlantic and Arctic Ocean
- 2013
-
Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 14:10, s. 4044-4065
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Tidskriftsartikel (refereegranskat)abstract
- The tectonic history of the Arctic Ocean remains poorly resolved and highly controversial. Details regarding break up of the Lomonosov Ridge from the Barents-Kara shelf margins and the establishment of seafloor spreading in the Cenozoic Eurasia Basin are unresolved. Significantly, the plate tectonic evolution of the Mesozoic Amerasia Basin is essentially unknown. The Arctic Ocean north of Greenland is at a critical juncture that formed at the locus of a Mesozoic three-plate setting between the Lomonosov Ridge, Greenland, and North America. In addition, the area is close to the European plate, resulting in complicated interactions between all these areas that are difficult to resolve. In 2009, the 550,000 km2 LOMGRAV aero-geophysical survey produced the first collocated gravity and magnetic measurements over the area, significantly increasing the data coverage. We present an interpretation of a new free-air gravity compilation, which reveals a regionally consistent structural grain across the Lomonosov Ridge, the Ellesmere and Lincoln Sea shelves, and the Alpha Ridge. We interpret the grain as evidence of latest Cretaceous (∼80 Ma) regional extension in response to the northward propagation of Atlantic and Labrador Sea opening into the Arctic, west of Greenland. This interpretation is consistent with coincident alkaline volcanic activity evident in the borderlands of the Lincoln Sea. We further suggest that Eurekan crustal shortening contributed to the formation of the distinct Lomonosov Ridge plateau against an important fault zone north of Greenland. Our results provide new constraints for Cretaceous-Cenozoic plate reconstructions of the Arctic. Key Points Presentation of the largest aero-gravity survey acquired over the Arctic Ocean Plate tectonic link between Atlantic and Arctic spreading west of Greenland New plate reconstruction models are presented for the area north of Greenland
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| 24. |
- Elger, Judith, et al.
(författare)
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Core‐log‐seismic integration in metamorphic rocks and its implication for the regional geology : A case study for the ICDP drilling project COSC‐1, Sweden
- 2021
-
Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 22:3
-
Tidskriftsartikel (refereegranskat)abstract
- Continental collision causes deformation in the crust along shear zones. However, the physical and chemical conditions at which these zones operate and the deformation processes that enable up to hundreds of km of tectonic transport are still unclear because of the depth at which they occur and the challenges in imaging them. Ancient exhumed collision zones allow us to investigate these processes much better, for example at the COSC‐1 borehole in the central Scandinavian Caledonides. This study combines data from the COSC‐1 borehole with different seismic measurements to provide constraints on the spatial lithological and textural configuration of the Seve Nappe Complex. This is one of the few studies that shows that core‐log‐seismic integration in metamorphic rocks allows to identify the spatial distribution of major lithological units. Especially gamma ray logs in combination with density data are powerful tools to distinguish between mafic and felsic lithologies in log‐core correlation. Our results indicate that reflections along the borehole are primarily caused by compositional rather than textural changes. Reflections in the Seve Nappe Complex are not as distinct as in greater depths but continuous and several of them can be linked to magmatic intrusions, which have been metamorphically overprinted. Their setting indicates that the Seve Nappe Complex consists of the remnants of a volcanic continental margin. Our results suggest that ductile‐deformed middle crustal reflectivity is primarily a function of pre‐orogenic lithological variations which has to be considered when deciphering mountain building processes.Plain Language SummaryAreas where continents collide experience different kind of deformation. However, these processes and the conditions at which they take place are difficult to study because of the great depth at which they occur. Former collision zones that are closer to the surface these days allow the investigation of these processes much better, for example at the COSC‐1 borehole in the central Scandinavian Caledonides. The challenge remains to image the remnant of these processes in high detail but at the same time over a large area. This study combines data from the COSC‐1 borehole with different geophysical measurements to better understand the lithology and structure of the Seve Nappe Complex. We show that the combination of these data allows us to distinguish between rocks from mafic and sedimentary origin. Our results indicate that the geophysical data along the borehole image the change of the composition of the rocks which probably originates from magmatic intrusions and have been overprinted by geological processes, rather than from fracture zones.
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| 25. |
- Gaspard, François, et al.
(författare)
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Quantifying Non-Thermal Silicate Weathering Using Ge/Si and Si Isotopes in Rivers Draining the Yellowstone Plateau Volcanic Field, USA
- 2021
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Ingår i: Geochemistry, Geophysics, Geosystems. - 1525-2027. ; 22:11
-
Tidskriftsartikel (refereegranskat)abstract
- In active volcanic regions, high-temperature chemical reactions in the hydrothermal system consume CO2 sourced from magma or from the deep crust, whereas reactions with silicates at shallow depths mainly consume atmospheric CO2. Numerous studies have quantified the load of dissolved solids in rivers that drain volcanic regions to determine chemical weathering rates and atmospheric CO2 consumption rates. However, the balance between thermal and non-thermal components to riverine fluxes in these areas remains poorly constrained, hindering accurate estimates of atmospheric CO2 consumption rates. Here we use the Ge/Si ratio and the stable silicon isotopes (δ30Si) as tracers for quantifying non-thermal silicon contributions in rivers draining the Yellowstone Plateau Volcanic Field, USA. The Ge/Si ratio (µmol.mol−1) was determined for seven thermal water samples (183 ± 22), eight rivers (35 ± 23) and six creeks flowing into Yellowstone Lake (5 ± 3) during base flow and during peak water discharge following snowmelt. The δ30Si value (‰) was determined for thermal waters (−0.09 ± 0.04), Yellowstone River at Yellowstone Lake outlet (1.91 ± 0.23) and creek samples (0.82 ± 0.29). The calculated atmospheric CO2 consumption associated with non-thermal waters flowing through Yellowstone's rivers during peak discharge is ∼3.03 ton.km−2.yr−1, which is ∼2% of the annual mean atmospheric CO2 consumption in other volcanic regions. This study highlights the significance of quantifying seasonal variations in chemical weathering rates for improving estimates of atmospheric CO2 consumption rates in active volcanic regions.
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| 26. |
- Geiger, Harri, et al.
(författare)
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Magma plumbing for the 2014-2015 Holuhraun eruption, Iceland
- 2016
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 17:8, s. 2953-2968
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Tidskriftsartikel (refereegranskat)abstract
- The 2014-2015 Holuhraun eruption on Iceland was located within the Askja fissure swarm but was accompanied by caldera subsidence in the Baroarbunga central volcano 45 km to the southwest. Geophysical monitoring of the eruption identified a seismic swarm that migrated from Baroarbunga to the Holuhraun eruption site over the course of two weeks. In order to better understand this lateral connection between Baroarbunga and Holuhraun, we present mineral textures and compositions, mineral-melt-equilibrium calculations, whole rock and trace element data, and oxygen isotope ratios for selected Holuhraun samples. The Holuhraun lavas are compositionally similar to recorded historical eruptions from the Baroarbunga volcanic system but are distinct from the historical eruption products of the nearby Askja system. Thermobarometry calculations indicate a polybaric magma plumbing system for the Holuhraun eruption, wherein clinopyroxene and plagioclase crystallized at average depths of approximate to 17 km and approximate to 5 km, respectively. Crystal resorption textures and oxygen isotope variations imply that this multilevel plumbing system facilitated magma mixing and assimilation of low-O-18 Icelandic crust prior to eruption. In conjunction with the existing geophysical evidence for lateral migration, our results support a model of initial vertical magma ascent within the Baroarbunga plumbing system followed by lateral transport of aggregated magma batches within the upper crust to the Holuhraun eruption site.
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| 27. |
- Hahn, A., et al.
(författare)
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Comparative study of infrared techniques for fast biogeochemical sediment analyses
- 2011
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Ingår i: Geochemistry Geophysics Geosystems. - Washington, DC : AGU and the Geochemical Society. - 1525-2027. ; 12, s. Q10003-
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Tidskriftsartikel (refereegranskat)abstract
- Analysis of sediment samples in the visible to mid infrared (IR) region requires small amounts of sample material and enables rapid and cost efficient geochemical analysis of mineral and organic sediment components. Here we use geochemical properties (total organic and inorganic carbon, biogenic silica, total nitrogen) from the ICDP deep drilling project PASADO to compare three different IR spectroscopy techniques: Diffuse Reflectance Fourier Transform IR Spectrometry (DRIFTS), Attenuated Total Reflectance Fourier Transform IR Spectroscopy (ATR-FTIRS) and Visible Near IR Spectroscopy (VNIRS). ATR-FTIRS and VNIRS are more rapid techniques compared to DRIFTS. Results show that calibration models developed using DRIFTS are most robust (correlation coefficient: R = 0.92 for TIC, R = 0.84 for BSi, R = 0.97 for TOC, R = 0.95 for TN). However, good statistical performance was also obtained by using ATR-FTIRS and VNIRS. When time and costs are limiting factors, these tools may be given preference for rapid biogeochemical screening.
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| 28. |
- Hidalgo, Silvana, et al.
(författare)
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Evolution of the 2015 Cotopaxi Eruption Revealed by Combined Geochemical & Seismic Observations
- 2018
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Ingår i: Geochemistry, Geophysics, Geosystems. - 1525-2027. ; 19:7, s. 2087-2108
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Tidskriftsartikel (refereegranskat)abstract
- Through integration of multiple data streams to monitor volcanic unrest scientists are able to make more robust eruption forecast and to obtain a more holistic interpretation of volcanic systems. We examined gas emission and gas geochemistry and seismic and petrologic data recorded during the 2015 unrest of Cotopaxi (Ecuador) in order to decipher the origin and temporal evolution of this eruption. Identification of families of similar seismic events and the use of seismic amplitude ratios reveals temporal changes in volcanic processes. SO2 (300 to 24,000 t/d), BrO/SO2 (5–10 × 10−5), SO2/HCl (5.8 ± 4.8 and 6.6 ± 3.0), and CO2/SO2 (0.6 to 2.1) measured throughout the eruption indicate a shallow magmatic source. Bulk ash and glass chemistry indicate a homogenous andesitic (SiO2 wt % = 56.94 ± 0.25) magma having undergone extensive S-exsolution and degassing during ascent. These data lead us to interpret this eruption as a magma intrusion and ascend to shallow levels. The intrusion progressively interacted with the hydrothermal system, boiled off water, and produced hydromagmatic explosions. A small volume of this intrusion continued to fragment and produced episodic ash emissions until it was sufficiently degassed and rheologically stiff. Based on the 470 kt of measured SO2 we estimate that ~65.3 × 106 m3 of magma were required to supply the emitted gases. This volume exceeds the volume of erupted juvenile material by a factor of 50. This result emphasizes the importance of careful monitoring of Cotopaxi to identify the intrusion of a new batch of magma, which could rejuvenate the nonerupted material.
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| 29. |
- Hillier, Stephen
(författare)
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Holocene evolution in weathering and erosion patterns in the Pearl River delta
- 2013
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Ingår i: Geochemistry, Geophysics, Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 14, s. 2349-2368
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Tidskriftsartikel (refereegranskat)abstract
- Sediments in the Pearl River delta have the potential to record the weathering response of this river basin to climate change since 9.5 ka, most notably weakening of the Asian monsoon since the Early Holocene (approximate to 8 ka). Cores from the Pearl River delta show a clear temporal evolution of weathering intensity, as measured by K/Al, K/Rb, and clay mineralogy, that shows deposition of less weathered sediment at a time of weakening monsoon rainfall in the Early-Mid Holocene (6.0-2.5 ka). This may reflect an immediate response to a less humid climate, or more likely reduced reworking of older deposits from river terraces as the monsoon weakened. Human settlement of the Pearl River basin may have had a major impact on landscape and erosion as a result of the establishment of widespread agriculture. After around 2.5 ka weathering intensity sharply increased, despite limited change in the monsoon, but at a time when anthropogenic pollutants (e.g., Cu, Zn, and Pb) increased and when the flora of the basin changed. Sr-87/Sr-86 covaries with these other proxies but is also partly influenced by the presence of carbonate. The sediments in the modern Pearl River are even more weathered than the youngest material from the delta cores. We infer that the spread of farming into the Pearl River basin around 2.7 ka was followed by a widespread reworking of old, weathered soils after 2.5 ka, and large-scale disruption of the river system that was advanced by 2.0 ka.
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| 30. |
- Jackson, Marie, et al.
(författare)
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Authigenic mineral textures in submarine 1979 basalt drill core, Surtsey volcano, Iceland
- 2019
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Ingår i: Geochemistry Geophysics Geosystems. - New York : American Geophysical Union (AGU). - 1525-2027. ; 20:7, s. 3751-3773
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Tidskriftsartikel (refereegranskat)abstract
- Micrometer‐scale maps of authigenic microstructures in submarine basaltic tuff from a 1979 Surtsey volcano, Iceland, drill core acquired 15 years after eruptions terminated describe the initial alteration of oceanic basalt in a low‐temperature hydrothermal system. An integrative investigative approach uses synchrotron source X‐ray microdiffraction, microfluoresence, micro‐computed tomography, and scanning transmission electron microscopy coupled with Raman spectroscopy to create finely resolved spatial frameworks that record a continuum of alteration in glass and olivine. Microanalytical maps of vesicular and fractured lapilli in specimens from 157.1‐, 137.9‐, and 102.6‐m depths and borehole temperatures of 83, 93.9, and 141.3 °C measured in 1980, respectively, describe the production of nanocrystalline clay mineral, zeolites, and Al‐tobermorite in diverse microenvironments. Irregular alteration fronts at 157.1‐m depth resemble microchannels associated with biological activity in older basalts. By contrast, linear microstructures with little resemblance to previously described alteration features have nanocrystalline clay mineral (nontronite) and zeolite (amicite) texture. The crystallographic preferred orientation rotates around an axis parallel to the linear feature. Raman spectra indicating degraded and poorly ordered carbonaceous matter of possible biological origin are associated with nanocrystalline clay mineral in a crystallographically oriented linear microstructure in altered olivine at 102.6 m and with subcircular nanoscale cavities in altered glass at 137.9‐m depth. Although evidence for biotic processes is inconclusive, the integrated analyses describe the complex organization of previously unrecognized mineral texture in very young basalt. They provide a foundational mineralogical reference for longitudinal, time‐lapse characterizations of palagonitized basalt in oceanic environments.
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| 31. |
- Jiang, Qiang, et al.
(författare)
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Timing of Seafloor Spreading Cessation at the Macquarie Ridge Complex (SW Pacific) and Implications for Upper Mantle Heterogeneity
- 2021
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 22:1
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Tidskriftsartikel (refereegranskat)abstract
- The Macquarie Ridge Complex (MRC) on the Australia‐Pacific plate boundary south of New Zealand is an extinct mid‐ocean ridge that has experienced a complex tectonic history and produced highly heterogeneous mid‐ocean ridge basalts (MORBs). When and how seafloor spreading ceased along the proto‐Macquarie mid‐ocean ridge remain elusive, and it is unclear how the mantle source of MORBs is affected by the gradual cessation of seafloor spreading at mid‐ocean ridges. To constrain the tectonic evolution of the MRC, the mantle source variations for MORBs at dying mid‐ocean ridges, and the mechanisms of mantle enrichment and asthenospheric heterogeneities, we report 11 pyroxene, plagioclase, basaltic glass, groundmass, and sericite 40Ar/39Ar and one zircon U‐Pb ages for the MRC MORBs. Our data reveal that basalts from the MRC seamounts were erupted between 25.9 and 1.6 Ma and Macquarie Island at ∼10 Ma. Combined age and plate reconstruction results reveal that the cessation of seafloor spreading at the MRC generally propagated from south to north along the ridge. Basalts produced by the then dying Macquarie mid‐ocean ridge at different times on different seamounts/island show a large variation in isotopic compositions and there is no clear correlation between ages and isotopic ratios. The heterogeneity of mantle source for MORBs from the proto‐Macquarie mid‐ocean ridge suggests that the upper asthenospheric mantle is heterogeneous, and such heterogeneity becomes most obvious at dying mid‐ocean ridges where the degrees of partial melting are low and a large range of melt compositions are produced.
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| 32. |
- Jochum, K. P., et al.
(författare)
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MPI-DING reference glasses for in situ microanalysis: New reference values for element concentrations and isotope ratios
- 2006
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 7:15 Febr
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Tidskriftsartikel (refereegranskat)abstract
- [1] We present new analytical data of major and trace elements for the geological MPI-DING glasses KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, BM90/21-G, T1-G, and ATHO-G. Different analytical methods were used to obtain a large spectrum of major and trace element data, in particular, EPMA, SIMS, LA-ICPMS, and isotope dilution by TIMS and ICPMS. Altogether, more than 60 qualified geochemical laboratories worldwide contributed to the analyses, allowing us to present new reference and information values and their uncertainties ( at 95% confidence level) for up to 74 elements. We complied with the recommendations for the certification of geological reference materials by the International Association of Geoanalysts (IAG). The reference values were derived from the results of 16 independent techniques, including definitive ( isotope dilution) and comparative bulk ( e. g., INAA, ICPMS, SSMS) and microanalytical ( e. g., LA-ICPMS, SIMS, EPMA) methods. Agreement between two or more independent methods and the use of definitive methods provided traceability to the fullest extent possible. We also present new and recently published data for the isotopic compositions of H, B, Li, O, Ca, Sr, Nd, Hf, and Pb. The results were mainly obtained by high-precision bulk techniques, such as TIMS and MC-ICPMS. In addition, LA-ICPMS and SIMS isotope data of B, Li, and Pb are presented.
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| 33. |
- Kim, Ji-Hoon, et al.
(författare)
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A Pulse of Meteoric Subsurface Fluid Discharging Into the Chukchi Sea During the Early Holocene Thermal Maximum (EHTM)
- 2021
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 22:8
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Tidskriftsartikel (refereegranskat)abstract
- The response of Arctic Ocean biogeochemistry to subsurface flow driven by permafrost thaw is poorly understood. We present dissolved chloride and water isotopic data from the Chukchi Sea Shelf sediments that reveal the presence of a meteoric subsurface flow enriched in cations with a radiogenic Sr fingerprint. This subsurface fluid is also enriched in dissolved inorganic carbon and methane that bear isotopic compositions indicative of a carbon reservoir modified by reactions in a closed system. Such fluid characteristics are in stark contrast with those from other sites in the Chukchi Sea where the pore water composition shows no sign of meteoric input, but reflect typical biogeochemical reactions associated with early diagenetic sequences in marine sediment. The most likely source of the observed subsurface flow at the Chukchi Sea Shelf is from the degradation of permafrost that had extended to the shelf region during the Last Glacial Maximum. Our data suggest that the permafrost-driven subsurface flow most likely took place during the 2-3 degrees C warming in the Early Holocene Thermal Maximum. This time scale is supported by numerical simulation of pore water profiles, which indicate that a minimum of several thousand years must have passed since the cessation of the subsurface methane-bearing fluid flow.
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| 34. |
- Kind, R., et al.
(författare)
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Scandinavia : A former Tibet?
- 2013
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 14:10, s. 4479-4487
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Tidskriftsartikel (refereegranskat)abstract
- The Himalaya and the Tibetan Plateau are uplifted by the ongoing northward underthrusting of the Indian continental lithosphere below Tibet resulting in lithospheric stacking. The layered structure of the Tibetan upper mantle is imaged by seismic methods, most detailed with the receiver function method. Tibet is considered as a place where the development of a future craton is currently under way. Here we study the upper mantle from Germany to northern Sweden with seismic S receiver functions and compare the structure below Scandinavia with that below Tibet. Below Proterozoic Scandinavia, we found two low-velocity zones on top of each other, separated by a high-velocity zone. The top of the upper low-velocity zone at about 100 km depth extends from Germany to Archaean northern Sweden. It agrees with the lithosphere-asthenosphere boundary (LAB) below Germany and Denmark. Below Sweden it is known as the 8 degrees discontinuity, or as a mid-lithospheric discontinuity (MLD), similar to observations in North America. Seismic tomography places the LAB near 200 km in Scandinavia, which is close to the top of our deeper low-velocity zone. We also observed the bottom of the asthenosphere (the Lehmann discontinuity) deepening from 180 km in Germany to 260 km below Sweden. Remnants of old subduction in the upper about 100 km below Scandinavia and Finland are known from controlled source seismic experiments and local earthquake studies. Recent tomographic studies indicate delamination of the lithosphere below southern Scandinavia and northern Germany. We are suggesting that the large-scale layered structure in the Scandinavian upper mantle may be caused by processes similar to the ongoing lithospheric stacking in Tibet.
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| 35. |
- Konrad-Schmolke, Matthias, 1970, et al.
(författare)
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Slab mantle dehydrates beneath Kamchatka: yet recycles water into the deep mantle.
- 2016
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 17:8, s. 2987-3007
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Tidskriftsartikel (refereegranskat)abstract
- The subduction of hydrated slab mantle is the most important and yet weakly constrained factor in the quantification of the Earth's deep geologic water cycle. The most critical unknowns are the initial hydration state and the dehydration behavior of the subducted oceanic mantle. Here we present a combined thermomechanical, thermodynamic, and geochemical model of the Kamchatka subduction zone that indicates significant dehydration of subducted slab mantle beneath Kamchatka. Evidence for the subduction of hydrated oceanic mantle comes from across-arc trends of boron concentrations and isotopic compositions in arc volcanic rocks. Our thermodynamic-geochemical models successfully predict the complex geochemical patterns and the spatial distribution of arc volcanoes in Kamchatka assuming the subduction of hydrated oceanic mantle. Our results show that water content and dehydration behavior of the slab mantle beneath Kamchatka can be directly linked to compositional features in arc volcanic rocks. Depending on hydration depth of the slab mantle, our models yield water recycling rates between 1.1 × 103 and 7.4 × 103 Tg/Ma/km corresponding to values between 0.75 × 106 and 5.2 × 106 Tg/Ma for the entire Kamchatkan subduction zone. These values are up to one order of magnitude lower than previous estimates for Kamchatka, but clearly show that subducted hydrated slab mantle significantly contributes to the water budget in the Kamchatkan subduction zone.
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| 36. |
- Kovács, Zsófia, et al.
(författare)
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The Calcium Isotope (δ44/40Ca) Record Through Environmental Changes : Insights From the Late Triassic
- 2022
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Ingår i: Geochemistry, Geophysics, Geosystems. - 1525-2027. ; 23:12
-
Tidskriftsartikel (refereegranskat)abstract
- Calcium isotopes (δ44/40Ca) are particularly useful in palaeo-environmental studies due to the key role of carbonate minerals in continental weathering and their formation in seawater. The calcium isotope ratio can provide hints on past changes in the calcium fluxes, environmental shifts, ecological factors and alternatively diagenesis of carbonate rocks. The investigation of the Late Triassic calcium isotope record offers a great opportunity to evaluate such factors in a time interval that witnessed important environmental and ecological turnovers, such as the first appearance of calcareous nannoplankton, ocean acidification and periods of elevated extinction rates. In this study, we present a δ44/40Ca data set from the upper Norian (Upper Triassic) through the lower Hettangian (Lower Jurassic) interval. The isotope records reveal two globally significant signals: a ∼ 0.20‰ decrease through the early Rhaetian (Upper Triassic) and a small, negative (∼0.14‰) excursion corresponding to the emplacement of the Central Atlantic Magmatic Province, at the end of the Triassic. The possible explanations for these signals are changes in the isotopic ratio of the continental calcium influx to the ocean due to the high chemical weathering rate of carbonates and possibly ocean acidification, respectively. The considerable (∼0.15–0.30‰) offset in δ44/40Ca between study areas is likely the combined result of local differences in lithology and early marine diagenesis. The major evolutionary step represented by the first occurrence of calcareous nannoplankton did not have at this time a determining role on the calcium isotopic signature of the marine carbonates.
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| 37. |
- Kumari, Monika, et al.
(författare)
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Experimental mixtures of superparamagnetic single domain magnetite with respect to Day-Dunlop plots
- 2015
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 16:6, s. 1739-1752
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Tidskriftsartikel (refereegranskat)abstract
- Day‐Dunlop plots are widely used in paleomagnetic and environmental studies as a tool to determine the magnetic domain state of magnetite, i.e., superparamagnetic (SP), stable single‐domain (SD), pseudosingle‐domain (PSD), multidomain (MD), and their mixtures. The few experimental studies that have examined hysteresis properties of SD‐SP mixtures of magnetite found that the ratios of saturation remanent magnetization to saturation magnetization and the coercivity of remanence to coercivity are low, when compared to expected theoretical mixing trends based on Langevin theory. This study reexamines Day‐Dunlop plots using experimentally controlled mixtures of SD and SP magnetite grains. End‐members include magnetotactic bacteria (MSR‐1) as the SD source, and a commercial ferrofluid or magnetotactic bacteria (ΔA12) as the SP source. Each SP‐component was added incrementally to a SD sample. Experimental results from these mixing series show that the magnetization and coercivity ratios are lower than the theoretical prediction for bulk SP magnetic size. Although steric repulsion was present between the particles, we cannot rule out interaction in the ferrofluid for higher concentrations. The SP bacteria are noninteracting as the magnetite was enclosed by an organic bilipid membrane. Our results demonstrate that the magnetization and coercivity ratios of SD‐SP mixtures can lie in the PSD range, and that an unambiguous interpretation of particle size can only be made with information about the magnetic properties of the end‐members.
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| 38. |
- Lages, J., et al.
(författare)
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Volcanic Gas Emissions Along the Colombian Arc Segment of the Northern Volcanic Zone (CAS-NVZ): Implications for volcano monitoring and volatile budget of the Andean Volcanic Belt
- 2019
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Ingår i: Geochemistry, Geophysics, Geosystems. - 1525-2027. ; 20:11, s. 5057-5081
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Tidskriftsartikel (refereegranskat)abstract
- Studying spatial and temporal trends in volcanic gas compositions and fluxes is crucial both to volcano monitoring and to constrain the origin and recycling efficiency of volatiles at active convergent margins. New volcanic gas compositions and volatile fluxes are here reported for Nevado del Ruiz, Galeras, and Purace, three of the most persistently degassing volcanoes located in the Colombian Arc Segment of the Northern Volcanic Zone. At Nevado del Ruiz, from 2014 to 2017, plume emissions showed an average molar CO2/S-T ratio of 3.9 +/- 1.6 (S-T is total sulfur, S). Contemporary, fumarolic chemistry at Galeras progressively shifted toward low-temperature, S-depleted fumarolic gas discharges with an average CO2/S-T ratio in excess of 10 (6.0-46.0, 2014-2017). This shift in volcanic gas compositions was accompanied by a concurrent decrease in SO2 emissions, confirmed on 21 March 2017 by high-resolution ultraviolet camera-based SO2 fluxes of similar to 2.5 kg/s (similar to 213 t/day). For comparison, SO2 emissions remained high at Nevado del Ruiz (weighted average of 8 kg/s) between 2014 and 2017, while Purace maintained rather low emission levels (<1 kg/s of SO2, CO2/SO2 approximate to 14). We here estimate carbon dioxide fluxes for Nevado del Ruiz, Galeras, and Purace of similar to 23, 30, and 1 kg/s, respectively. These, combined with recent CO2 flux estimates for Nevado del Huila of similar to 10 kg/s (similar to 860 t/day), imply that this arc segment contributes about 50% to the total subaerial CO2 budget of the Andean Volcanic Belt. Furthermore, our work highlights the northward increase in carbon-rich sediment input into the mantle wedge via slab fluids and melts that is reflected in magmatic CO2/S-T values far higher than those reported for Southern Volcanic Zone and Central Volcanic Zone volcanoes. We estimate that about 20% (similar to 1.3 Mt C/year) of the C being subducted (similar to 6.19 Mt C/year) gets resurfaced through subaerial volcanic gas emissions in Colombia (Nevado del Ruiz similar to 0.7 Mt C/year). As global volcanic volatile fluxes continue to be quantified and refined, the contribution from this arc segment should not be underestimated.
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| 39. |
- Lenz, Conny, et al.
(författare)
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Hypoxia-driven variations in iron and manganese shuttling in the Baltic Sea over the past 8 kyr
- 2015
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 16:10, s. 3754-3766
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Tidskriftsartikel (refereegranskat)abstract
- The Baltic Sea has experienced three major intervals of bottom water hypoxia following the intrusion of seawater circa 8 kyr ago. These intervals occurred during the Holocene Thermal Maximum (HTM), Medieval Climate Anomaly (MCA), and during recent decades. Here we show that sequestration of both Fe and Mn in Baltic Sea sediments generally increases with water depth, and we attribute this to shelf-to-basin transfer (shuttling) of Fe and Mn. Burial of Mn in slope and basin sediments was enhanced following the lake-brackish/marine transition at the beginning of the hypoxic interval during the HTM. During hypoxic intervals, shelf-to-basin transfer of Fe was generally enhanced but that of Mn was reduced. However, intensification of hypoxia within hypoxic intervals led to decreased burial of both Mn and Fe in deep basin sediments. This implies a nonlinearity in shelf Fe release upon expanding hypoxia with initial enhanced Fe release relative to oxic conditions followed by increased retention in shelf sediments, likely in the form of iron sulfide minerals. For Mn, extended hypoxia leads to more limited sequestration as Mn carbonate in deep basin sediments, presumably because of more rapid reduction of Mn oxides formed after inflows and subsequent escape of dissolved Mn to the overlying water. Our Fe records suggest that modern Baltic Sea hypoxia is more widespread than in the past. Furthermore, hypoxia-driven variations in shelf-to-basin transfer of Fe may have impacted the dynamics of P and sulfide in the Baltic Sea thus providing potential feedbacks on the further development of hypoxia.
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| 40. |
- Longpré, Marc-Antoine, et al.
(författare)
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Volcanic and geochemical evolution of the Teno massif, Tenerife, Canary Islands : Some repercussions of giant landslides on ocean island magmatism
- 2009
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 10:12, s. 31-
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Tidskriftsartikel (refereegranskat)abstract
- Large-scale, catastrophic mass wasting is a major process contributing to the dismantling of oceanic intraplate volcanoes. Recent studies, however, have highlighted a possible feedback relationship between flank collapse, or incipient instability, and subsequent episodes of structural rearrangement and/or renewed volcano growth. The Teno massif, located in northwestern Tenerife (Canary Islands), is a deeply eroded Miocene shield volcano that was built in four major eruptive phases punctuated by two lateral collapses, each removing >20–25 km3 of the volcano's north flank. In this paper, we use detailed field observations and petrological and geochemical data to evaluate possible links between large-scale landslides and subsequent volcanism/magmatism during Teno's evolution. Inspection of key stratigraphic sequences reveals that steep angular unconformities, relics of paleolandslide scars, are marked by polymict breccias. Near their base, these deposits typically include abundant juvenile pyroclastic material, otherwise scarce in the region. While some of Teno's most evolved, low-density magmas were produced just before flank collapses, early postlandslide lava sequences are characterized by anomalously high proportions of dense ankaramite flows, extremely rich in clinopyroxene and olivine crystals. A detailed sampling profile shows transitions from low-Mg # lavas relatively rich in SiO2 to lavas with low silica content and comparatively high Mg # after both landslides. Long-term variations in Zr/Nb, normative nepheline, and La/Lu are coupled but do not show a systematic correlation with stratigraphic boundaries. We propose that whereas loading of the growing precollapse volcano promoted magma stagnation and differentiation, the successive giant landslides modified the shallow volcano-tectonic stress field at Teno, resulting in widespread pyroclastic eruptions and shallow magma reservoir drainage. This rapid unloading of several tens of km3 of near-surface rocks appears to have upset magma differentiation processes, while facilitating the remobilization and tapping of denser ankaramite magmas that were stored in the uppermost mantle. Degrees of mantle melting coincidently reached a maximum in the short time interval between the two landslides and declined shortly after, probably reflecting intrinsic plume processes rather than a collapse-induced influence on mantle melting. Our study of Teno volcano bears implications for other oceanic volcanoes where short-term compositional variations may also directly relate to major flank collapse events.
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| 41. |
- Mattesini, Maurizio, et al.
(författare)
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Polymorphic Nature of Iron and Degree of Lattice Preferred Orientation Beneath the Earth's Inner Core Boundary
- 2018
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Ingår i: Geochemistry Geophysics Geosystems. - : AMER GEOPHYSICAL UNION. - 1525-2027. ; 19:1, s. 292-304
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Tidskriftsartikel (refereegranskat)abstract
- Deciphering the polymorphic nature and the degree of iron lattice-preferred orientation in the Earth's inner core holds a key to understanding the present status and evolution of the inner core. A multiphase lattice-preferred orientation pattern is obtained for the top 350 km of the inner core by means of the ab initio based Candy Wrapper Velocity Model coupled to a Monte Carlo phase discrimination scheme. The achieved geographic distribution of lattice alignment is characterized by two regions of freezing, namely within South America and the Western Central Pacific, that exhibit an uncommon high degree of lattice orientation. In contrast, widespread regions of melting of relatively weak lattice ordering permeate the rest of the inner core. The obtained multiphase lattice-preferred orientation pattern is in line with mantle-constrained geodynamo simulations and allows to setup an ad hoc mineral physics scenario for the complex Earth's inner core. It is found that the cubic phase of iron is the dominating iron polymorph in the outermost part of the inner core.
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| 42. |
- Mattsson, Tobias, et al.
(författare)
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Transport of Magma in Granitic Mush Systems; an Example From the Götemar Pluton, Sweden
- 2024
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 25:1
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Tidskriftsartikel (refereegranskat)abstract
- Granitic magma bodies form in the ephemeral part of magma mush systems and are emplaced by a variety of mechanisms in different tectonic settings. This study investigates how granitic magma emplacement processes and tectonomagmatic interactions assert control over the architecture of mush state pluton-scale magma transport pathways. The 1.45 Ga shallow-crustal Gotemar pluton is a 4.5 km diameter circular pluton that consists of three granite units: a coarse-grained red granite, a medium-grained pale to red granite, and fine-grained pale microgranite sheets. We employed geological mapping supported by Anisotropy of Magnetic Susceptibility (AMS) to examine the magmatic and regional tectonic controls on late-stage magma transport in the Gotemar granitic magma mush system. Multiple parallel arcuate subhorizontal microgranite and medium-grained granite sheets (from 0.1 to 10s of meters thick) were mapped within the pluton. The arcuate sheets pinch out from the northern part of the pluton toward the SE inferring magma propagation direction. A dominant set of vertical granitic sheets within the granite body strikes NW-SE. The AMS fabrics are contact-parallel in the main medium-grained granite body and indicate inflation. Within the microgranite sheets, the AMS fabrics are parallel to the sheet strike and support a sheet propagation direction to the SE. The Gotemar pluton displays a clear link between arcuate (concentric) magma-transporting sheets and concentric strain-partitioning related to the intrusion of medium-grained granite magma. The vertical magma sheet orientations are consistent with an NE-SW extensional stress field that is associated with the extensional back-arc stress regime of the contemporary Hallandian Orogen. The eruptive products of volcanoes are thought to be stored in pockets of melt in crystal-dominated magmatic systems called crystal mushes prior to volcanic eruptions. An understanding of where magma is stored and how it is transported in mush systems is important in order to predict the eruptive behavior of the volcanic system. This contribution investigates the magma transport pathways in the Gotemar granite in Sweden and its relationship to local magmatic deformation and regional deformation related to the Hallandian mountain building event. We show that magma is transported in vertical sheets parallel to the front of the Hallandian Orogen and laterally in sub-horizontal arcuate sheets that reflect the circular shape of the granite pluton. Our study highlights the importance of understanding the shape and the formation of the magmatic granite body for deciphering the melt transport in the magma mush system under volcanoes. Subhorizontal magma transport in a granitic magma mush controlled by magma emplacement structuresVertical magma sheets in granitic magma mush controlled by the regional stress fieldMagma transported in concentric magma fingers in the circular Gotemar granite pluton
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| 43. |
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| 44. |
- McIntosh, Jennifer, et al.
(författare)
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Burial and Denudation Alter Microbial Life at the Bottom of the Hypo‐Critical Zone
- 2023
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 24:6
-
Tidskriftsartikel (refereegranskat)abstract
- How subsurface microbial life changed at the bottom of the kilometers-deep (hypo) Critical Zone in response to evolving surface conditions over geologic time is an open question. This study investigates the burial and exhumation, biodegradation, and fluid circulation history of hydrocarbon reservoirs across the Colorado Plateau as a window into the hypo-Critical Zone. Hydrocarbon reservoirs, in the Paradox and Uinta basins, were deeply buried starting ca. 100 to 60 Ma, reaching temperatures >80–140°C, likely sterilizing microbial communities present since the deposition of sediments. High salinities associated with evaporites may have further limited microbial activity. Upward migration of hydrocarbons from shale source rocks into shallower reservoirs during maximum burial set the stage for microbial re-introduction by creating organic-rich “hot spots.” Denudation related to the incision of the Colorado River over the past few million years brought reservoirs closer to the surface under cooler temperatures, enhanced deep meteoric water circulation and flushing of saline fluids, and likely re-inoculated more permeable sediments up to several km depth. Modern- to paleo-hydrocarbon reservoirs show molecular and isotopic evidence of anaerobic oxidation of hydrocarbons coupled to bacterial sulfate reduction in areas with relatively high SO4-fluxes. Anaerobic oil biodegradation rates are high enough to explain the removal of at least some portion of postulated “supergiant oil fields” across the Colorado Plateau by microbial activity over the past several million years. Results from this study help constrain the lower limits of the hypo-Critical Zone and how it evolved over geologic time, in response to changing geologic, hydrologic, and biologic forcings.
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| 45. |
- Morris, A. M., et al.
(författare)
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Evidence for low‐pressure crustal anatexis during the northeast atlantic break‐up
- 2024
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 25:7
-
Tidskriftsartikel (refereegranskat)abstract
- While basaltic volcanism is dominant during rifting and continental breakup, felsic magmatism may be a significant component of some rift margins. During International Ocean Discovery Program (IODP) Expedition 396 on the continental margin of Norway, a graphite-garnet-cordierite bearing dacitic unit (the Mimir dacite) was recovered in two holes within early Eocene sediments on Mimir High (Site U1570), a marginal high on the Vøring Transform Margin. Here, we present a comprehensive textural, petrological, and geochemical study of the Mimir dacite in order to assess its origin and discuss the geodynamic implications. The major mineral phases (garnet, cordierite, quartz, plagioclase, alkali feldspar) are hosted in a fresh rhyolitic, vesicular, glassy matrix that is locally mingled with sediments. The major element chemistry of garnet and cordierite, the presence of zircon inclusions with inherited cores, and thermobarometric calculations all support an upper crustal metapelitic origin. While most magma-rich margin models favor crustal anatexis in the lower crust, thermobarometric calculations performed here show that the Mimir dacite was produced at upper-crustal depths (<5 kbar, 18 km depth) and high temperature (750–800°C) with up to 3 wt% water content. In situ U-Pb analyses on zircon inclusions give a magmatic crystallization age of 54.6 ± 1.1 Ma, consistent with emplacement that post-dates the Paleocene-Eocene Thermal Maximum. Our results suggest that the opening of the Northeast Atlantic was associated with a phase of low-pressure, high-temperature crustal anatexis preceding the main phase of magmatism.
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| 46. |
- Nilsson, Andreas, et al.
(författare)
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Holocene geocentric dipole tilt model constrained by sedimentary paleomagnetic data
- 2010
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 11, s. 08018-08018
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Tidskriftsartikel (refereegranskat)abstract
- Paleomagnetic data, although undeniably limited, have been used to constrain complex time-varying geomagnetic field models. Here we present four different versions of a time varying geocentric dipole model for the past approximately 9000 years based on a limited selection of sedimentary paleomagnetic data with good spatial coverage. The robustness of the modeling approach is evaluated using modern magnetic observation station data provided by the World Data Centre for Geomagnetism in Edinburgh and we discuss the magnitude of the error introduced by insufficient data coverage. The prediction in terms of directional variations is tested against paleomagnetic data from 63 different sedimentary sites and compared to results from recently published spherical harmonic geomagnetic field models. We find that the dipole estimate can explain the paleomagnetic data almost as well as the more complicated spherical harmonic models. Specific areas and records are identified where there are significant differences between the performance of the dipole estimate and the spherical harmonic models. Our results suggest that many of the differences between the dipole model predictions and the paleomagnetic data can be related to poor paleomagnetic quality and/or the lack of accurate and precise time control inherent to some of the records. These results agree with Valet et al. ( 2008) who suggested that the CALS7K. 2 model probably underestimates the dipole contribution in order to reduce the misfit between the inversion and the data. We conclude that better paleomagnetic data and associated time control are needed to improve global geomagnetic field models.
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| 47. |
- Obrochta, S. P., et al.
(författare)
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The undatables : Quantifying uncertainty in a highly expanded Late Glacial-Holocene sediment sequence recovered from the deepest Baltic Sea basin—IODP Site M0063
- 2017
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 18:3, s. 858-871
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Tidskriftsartikel (refereegranskat)abstract
- Laminated, organic-rich silts and clays with high dissolved gas content characterize sediments at IODP Site M0063 in the Landsort Deep, which at 459 m is the deepest basin in the Baltic Sea. Cores recovered from Hole M0063A experienced significant expansion as gas was released during the recovery process, resulting in high sediment loss. Therefore, during operations at subsequent holes, penetration was reduced to 2 m per 3.3 m core, permitting expansion into 1.3 m of initially empty liner. Fully filled liners were recovered from Holes B through E, indicating that the length of recovered intervals exceeded the penetrated distance by a factor of >1.5. A typical down-core logarithmic trend in gamma density profiles, with anomalously low-density values within the upper ∼1 m of each core, suggests that expansion primarily occurred in this upper interval. Thus, we suggest that a simple linear correction is inappropriate. This interpretation is supported by anisotropy of magnetic susceptibility data that indicate vertical stretching in the upper ∼1.5 m of expanded cores. Based on the mean gamma density profiles of cores from Holes M0063C and D, we obtain an expansion function that is used to adjust the depth of each core to conform to its known penetration. The variance in these profiles allows for quantification of uncertainty in the adjusted depth scale. Using a number of bulk 14C dates, we explore how the presence of multiple carbon source pathways leads to poorly constrained radiocarbon reservoir age variability that significantly affects age and sedimentation rate calculations.
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| 48. |
- O'Regan, Matt, et al.
(författare)
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Surface heat flow measurements from the East Siberian continental slope and southern Lomonosov Ridge, Arctic Ocean
- 2016
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 17:5, s. 1608-1622
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Tidskriftsartikel (refereegranskat)abstract
- Surface heat flow data in the Arctic Ocean are needed to assess hydrocarbon and methane hydrate distributions, and provide constraints into the tectonic origins and nature of underlying crust. However, across broad areas of the Arctic, few published measurements exist. This is true for the outer continental shelf and slope of the East Siberian Sea, and the adjoining deep water ridges and basins. Here we present 21 new surface heat flow measurements from this region of the Arctic Ocean. On the Southern Lomonosov Ridge, the average measured heat flow, uncorrected for effects of sedimentation and topography, is 574 mW/m(2) (n=4). On the outer continental shelf and slope of the East Siberian Sea (ESS), the average is 5710 mW/m(2) (n=16). An anomalously high heat flow of 20328 mW/m(2) was measured at a single station in the Herald Canyon. With the exception of this high heat flow, the new data from the ESS are consistent with predictions for thermally equilibrated lithosphere of continental origin that was last affected by thermotectonic processes in the Cretaceous to early Cenozoic. Variability within the data likely arises from differences in radiogenic heat production within the continental crust and overlying sediments. This can be further explored by comparing the data with geophysical constraints on sediment and crustal thicknesses.
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| 49. |
- Pontbriand, Claire W., et al.
(författare)
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Effusive and explosive volcanism on the ultraslow-spreading Gakkel Ridge, 85 degrees E
- 2012
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Ingår i: Geochemistry Geophysics Geosystems. - 1525-2027. ; 13, s. Q10005-
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Tidskriftsartikel (refereegranskat)abstract
- We use high-definition seafloor digital imagery and multibeam bathymetric data acquired during the 2007 Arctic Gakkel Vents Expedition (AGAVE) to evaluate the volcanic characteristics of the 85 degrees E segment of the ultraslow spreading Gakkel Ridge (9 mm yr(-1) full rate). Our seafloor imagery reveals that the axial valley is covered by numerous, small-volume (order similar to 1000 m(3)) lava flows displaying a range of ages and morphologies as well as unconsolidated volcaniclastic deposits with thicknesses up to 10 cm. The valley floor contains two prominent volcanic lineaments made up of axis-parallel ridges and small, cratered volcanic cones. The lava flows appear to have erupted from a number of distinct source vents within the similar to 12-15 km-wide axial valley. Only a few of these flows are fresh enough to have potentially erupted during the 1999 seismic swarm at this site, and these are associated with the Oden and Loke volcanic cones. We model the widespread volcaniclastic deposits we observed on the seafloor as having been generated by the explosive discharge of CO2 that accumulated in (possibly deep) crustal melt reservoirs. The energy released during explosive discharge, combined with the buoyant rise of hot fluid, lofted fragmented clasts of rapidly cooling magma into the water column, and they subsequently settled onto the seafloor as fall deposits surrounding the source vent.
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| 50. |
- Rhodes, Emma, 1990-, et al.
(författare)
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Rapid Assembly and Eruption of a Shallow Silicic Magma Reservoir, Reyðarártindur Pluton, Southeast Iceland
- 2021
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Ingår i: Geochemistry Geophysics Geosystems. - : American Geophysical Union (AGU). - 1525-2027. ; 22:11
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Tidskriftsartikel (refereegranskat)abstract
- Although it is widely accepted that shallow silicic magma reservoirs exist, and can feed eruptions, their dynamics and longevity are a topic of debate. Here, we use field mapping, geochemistry, 3D pluton reconstruction and a thermal model to investigate the assembly and eruptive history of the shallow Reyoarartindur Pluton, southeast Iceland. Primarily, the exposed pluton is constructed of a single rock unit, the Main Granite (69.9-77.7 wt.% SiO2). Two further units are locally exposed as enclaves at the base of the exposure, the Granite Enclaves (67.4-70.2 wt.% SiO2), and the Quartz Monzonite Enclaves (61.8-67.3 wt.% SiO2). Geochemically, the units are related and were likely derived from the same source reservoir. In 3D, the pluton has a shape characterized by flat roof segments that are vertically offset and a volume of >2.5 km(3). The pluton roof is intruded by dikes from the pluton, and in two locations displays depressions associated with large dikes. Within these particular dikes the rock is partially to wholly tuffisitic, and rock compositions range from quartz monzonite to granite. We interpret these zones as eruption-feeding conduits from the pluton. A lack of cooling contacts throughout the pluton indicates rapid magma emplacement and a thermal model calculates the top 75 m would have rheologically locked up within 1,000 years. Hence, we argue that the Reyoarartindur Pluton was an ephemeral part of the wider plumbing system that feeds a volcano, and that timeframes from emplacement to eruption were rapid.
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