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1.
  • Larsson, Carl Fredrik, 1980, et al. (författare)
  • Overcurrent Abuse of Primary Prismatic Zinc–Air Battery Cells Studying Air Supply Effects on Performance and Safety Shut-Down
  • 2017
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 3:1
  • Tidskriftsartikel (refereegranskat)abstract
    • Overcurrent abuse has been performed on commercial 48 Ah primary prismatic zinc (Zn)–Air battery cells with full air supply as well as with shut-off air supply. Compared to other battery technologies, e.g., lithium-ion batteries, metal–air batteries offer the possibility to physically stop the battery operation by stopping its air supply, thus offering an additional protection against severe battery damage in the case of, e.g., an accidental short circuit. This method may also reduce the electrical hazard in a larger battery system since, by stopping the air supply, the voltage can be brought to zero while maintaining the energy capacity of the battery. Measurements of overdischarge currents and current cut-off by suffocation have been performed to assess the safety of this type of Zn–air battery. The time to get to zero battery voltage is shown to mainly be determined by the volume of air trapped in the cell.
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2.
  • Olsson, Linda, 1980-, et al. (författare)
  • Circular Business Models for Extended EV Battery Life
  • 2018
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 4:4
  • Tidskriftsartikel (refereegranskat)abstract
    • In the near future, a large volume of electric vehicle (EV) batteries will reach their end-of-life in EVs. However, they may still retain capacity that could be used in a second life, e.g., for a second use in an EV, or for home electricity storage, thus becoming part of the circular economy instead of becoming waste. The aim of this paper is to explore second life of EV batteries to provide an understanding of how the battery value chain and related business models can become more circular. We apply qualitative research methods and draw on data from interviews and workshops with stakeholders, to identify barriers to and opportunities for second use of EV batteries. New business models are conceptualized, in which increased economic viability of second life and recycling and increased business opportunities for stakeholders may lead to reduced resource consumption. The results show that although several stakeholders see potential in second life, there are several barriers, many of which are of an organizational and cognitive nature. The paper concludes that actors along the battery value chain should set up new collaborations with other actors to be able to benefit from creating new business opportunities and developing new business models together.
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3.
  • Kerner, Manfred, 1984, et al. (författare)
  • Pyrrolidinium FSI and TFSI-Based Polymerized Ionic Liquids as Electrolytes for High-Temperature Lithium-Ion Batteries
  • 2018
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 4:1
  • Tidskriftsartikel (refereegranskat)abstract
    • Promising electrochemical and dynamical properties, as well as high thermal stability, have been the driving forces behind application of ionic liquids (ILs) and polymerized ionic liquids (PILs) as electrolytes for high-temperature lithium-ion batteries (HT-LIBs). Here, several ternary lithium-salt/IL/PIL electrolytes (PIL el ) have been investigated for synergies of having both FSI and TFSI anions present, primarily in terms of physico-chemical properties, for unique application in HT-LIBs operating at 80 ◦ C. All of the electrolytes tested have low T g and are thermally stable ≥100 ◦ C, and with TFSI as the exclusive anion the electrolytes (set A) have higher thermal stabilities ≥125 ◦ C. Ionic conductivities are in the range of 1 mS/cm at 100 ◦ C and slightly higher for set A PIL el , which, however, have lower oxidation stabilities than set B PIL el with both FSI and TFSI anions present: 3.4–3.7 V vs. 4.2 V. The evolution of the interfacial resistance increases for all PIL el during the first 40 h, but are much lower for set B PIL el and generally decrease with increasing Li-salt content. The higher interfacial resistances only influence the cycling performance at high C-rates (1 C), where set B PIL el with high Li-salt content performs better, while the discharge capacities at the 0.1 C rate are comparable. Long-term cycling at 0.5 C, however, shows stable discharge capacities for 100 cycles, with the exception of the set B PIL el with high Li-salt content. Altogether, the presence of both FSI and TFSI anions in the PIL el results in lower ionic conductivities and decreased thermal stabilities, but also higher oxidation stabilities and reduced interfacial resistances and, in total, result in an improved rate capability, but compromised long-term capacity retention. Overall, these electrolytes open for novel designs of HT-LIBs.
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4.
  • Kucinskis, Gints, et al. (författare)
  • Enhanced Electrochemical Properties of Na0.67MnO2 Cathode for Na-Ion Batteries Prepared with Novel Tetrabutylammonium Alginate Binder
  • 2022
  • Ingår i: BATTERIES-BASEL. - : MDPI AG. - 2313-0105. ; 8:1, s. 6-
  • Tidskriftsartikel (refereegranskat)abstract
    • Both the binder and solid-electrolyte interface play an important role in improving the cycling stability of electrodes for Na-ion batteries. In this study, a novel tetrabutylammonium (TBA) alginate binder is used to prepare a Na0.67MnO2 electrode for sodium-ion batteries with improved electrochemical performance. The ageing of the electrodes is characterized. TBA alginate-based electrodes are compared to polyvinylidene fluoride- (PVDF) and Na alginate-based electrodes and show favorable electrochemical performance, with gravimetric capacity values of up to 164 mAh/g, which is 6% higher than measured for the electrode prepared with PVDF binder. TBA alginate-based electrodes also display good rate capability and improved cyclability. The solid-electrolyte interface of TBA alginate-based electrodes is similar to that of PVDF-based electrodes. As the only salt of alginic acid soluble in non-aqueous solvents, TBA alginate emerges as a good alternative to PVDF binder in battery applications where the water-based processing of electrode slurries is not feasible, such as the demonstrated case with Na0.67MnO2.
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5.
  • Kurdve, Martin, 1971, et al. (författare)
  • Considerations when Modelling EV Battery Circularity Systems
  • 2019
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 5:2
  • Tidskriftsartikel (refereegranskat)abstract
    • The electric vehicle market is expected to grow substantially in the coming years, which puts new requirements on the end-of-life phase and on the recycling systems. To a larger extent, the environmental footprint from these vehicles is related to raw material extraction and production, and, consequently, a material- and energy-efficient 3R system (reuse, remanufacturing, recycling) is urgently needed. The ability to understand and model the design and development of such a system therefore becomes important. This study contributes to this by identifying factors that affect 3R system design and performance, relating these factors to the various actors and processes of the system and categorising them according to time from implementation to impact. The above is achieved by applying a PEST analysis (political, economic, social and technological factors), differentiating between political, economic, social and technological factors. Data were gathered from literature, by interviews and by a number of workshops in the automotive industry and the 3R system and observations at meetings, etc. The study confirms some previous results on how vehicle battery 3R systems work and adds knowledge about the influencing factors, especially the timeframes and dynamics of the system, necessary for modelling the system and the influencing factors. For practitioners, the results indicate how to use appropriate models and which factors are most relevant to them.
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6.
  • Larsson, Carl Fredrik, 1980, et al. (författare)
  • Lithium-Ion Battery Aspects on Fires in Electrified Vehicles on the Basis of Experimental Abuse Tests
  • 2016
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 2:2
  • Tidskriftsartikel (refereegranskat)abstract
    • Safety issues concerning the use of large lithium-ion (Li-ion) batteries in electrified vehicles are discussed based on the abuse test results of Li-ion cells together with safety devices for cells. The presented abuse tests are: overcharge, short circuit, propane fire test and external heating test (oven). It was found that in a fire, cells with higher state of charge (SOC) gave a higher heat release rate (HRR), while the total heat release (THR) had a lower correlation with SOC. One fire test resulted in a hazardous projectile from a cylindrical cell. In the fire tests, toxic gas emissions of hydrogen fluoride (HF) were measured for 100%, 50% and 0% SOC.
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7.
  • Lu, Huiran, et al. (författare)
  • Flexible and Lightweight Lithium-Ion Batteries Based on Cellulose Nanofibrils and Carbon Fibers
  • 2018
  • Ingår i: BATTERIES-BASEL. - : MDPI. - 2313-0105. ; 4:2
  • Tidskriftsartikel (refereegranskat)abstract
    • Flexible, low-weight electrodes with integrated current collectors based on chopped polyacrylonitrile carbon fibers (CF) were produced using an easy, aqueous fabrication process, where only 4 wt% of TEMPO-oxidized cellulose nanofibrils (CNF) were used as the binder. A flexible full cell was assembled based on a LiFePO4 (LFP) positive electrode with a CF current collector and a current collector-free CF negative electrode. The cell exhibited a stable specific capacity of 121 mAh g(-1) based on the LFP weight. The CF in the negative electrode acted simultaneously as active material and current collector, which has a significant positive impact on energy density. Stable specific capacities of the CF/CNF negative electrode of 267 mAh g(-1) at 0.1 C and 150 mAh g(-1) at 1 C are demonstrated. The LFP/CNF with CF/CNF, as the current collector positive electrode (LFP-CF), exhibited a good rate performance with a capacity of -150 mAh g(-1) at 0.1 C and 133 mAh g(-1) at 1 C. The polarization of the LFP-CF electrode was similar to that of a commercial Quallion LFP electrode, while much lower compared to a flexible LFP/CNF electrode with Al foil as the current collector. This is ascribed to good contact between the CF and the active material.
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8.
  • Nasser, Olimpia A., et al. (författare)
  • Review of achieved purities after li-ion batteries hydrometallurgical treatment and impurities effects on the cathode performance
  • 2021
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 7:3
  • Forskningsöversikt (refereegranskat)abstract
    • This paper is a product purity study of recycled Li-ion batteries with a focus on hydromet-allurgical recycling processes. Firstly, a brief description of the current recycling status was presented based on the research data. Moreover, this work presented the influence of impurities such as Cu, Fe and Mg on recovered cathode materials performance. The impact of the impurities was described depending on their form (metallic or ionic) and concentration. This work also reviewed hydromet-allurgical recycling processes depending on the recovered material, obtained purity and recovery methods. This purity data were obtained from both research and battery industry actors. Finally, the purity study was completed by collecting data regarding commercial battery-grade chemical compounds and active lithium cathode materials, including required purity levels and allowed impurity limitations.
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9.
  • Nordelöf, Anders, 1975, et al. (författare)
  • Methodological Approaches to End-Of-Life Modelling in Life Cycle Assessments of Lithium-Ion Batteries
  • 2019
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 5:51, s. 1-15
  • Forskningsöversikt (refereegranskat)abstract
    • This study presents a review of how the end-of-life (EOL) stage is modelled in life cycle assessment (LCA) studies of lithium-ion batteries (LIBs). Twenty-five peer-reviewed journal and conference papers that consider the whole LIB life cycle and describe their EOL modelling approach sufficiently were analyzed. The studies were categorized based on two archetypal EOL modelling approaches in LCA: The cutoff (no material recovery, possibly secondary material input) and EOL recycling (material recovery, only primary material input) approaches. It was found that 19 of the studies followed the EOL recycling approach and 6 the cutoff approach. In addition, almost a third of the studies deviated from the expected setup of the two methods by including both material recovery and secondary material input. Such hybrid approaches may lead to double counting of recycling benefits by both including secondary input (as in the cutoff approach) and substituting primary materials (as in the EOL recycling approach). If the archetypal EOL modelling approaches are not followed, it is imperative that the modelling choices are well-documented and motivated to avoid double counting that leads to over- or underestimations of the environmental impacts of LIBs. Also, 21 studies model hydrometallurgical treatment, and 17 completely omit waste collection.
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10.
  • Oltean, Gabriel, et al. (författare)
  • Towards Li-ion batteries operating at 80 °C: Ionic liquid versus conventional liquid electrolytes
  • 2018
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 4, s. 2-6
  • Tidskriftsartikel (refereegranskat)abstract
    • Li-ion battery (LIB) full cells comprised of TiO2-nanotube (TiO2-nt) and LiFePO4 (LFP)electrodes and either a conventional organic solvent based liquid electrolyte or an ionic liquid basedelectrolyte have been cycled at 80 °C. While the cell containing the ionic liquid based electrolyteexhibited good capacity retention and rate capability during 100 cycles, rapid capacity fading was found for the corresponding cell with the organic electrolyte. Results obtained for TiO2-nt and LFP half-cells indicate an oxidative degradation of the organic electrolyte at 80 °C. In all, ionic liquidbased electrolytes can be used to significantly improve the performance of LIBs operating at 80 °C.
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11.
  • Rastabi, Shahrzad Arshadi, et al. (författare)
  • Synthesis of a NiMoO4/3D-rGO nanocomposite via starch medium precipitation method for supercapacitor performance
  • 2020
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 6:1
  • Tidskriftsartikel (refereegranskat)abstract
    • This paper presents research on the synergistic effects of nickel molybdate and reduced graphene oxide as a nanocomposite for further development of energy storage systems. An enhancement in the electrochemical performance of supercapacitor electrodes occurs by synthesizing highly porous structures and achieving more surface area. In this work, a chemical precipitation technique was used to synthesize the NiMoO4/3D-rGO nanocomposite in a starch media. Starch was used to develop the porosities of the nanostructure. A temperature of 350◦C was applied to transform graphene oxide sheets to reduced graphene oxide and remove the starch to obtain the NiMoO4/3D-rGO nanocomposite with porous structure. The X-ray diffraction pattern of the NiMoO4 nano particles indicated a monoclinic structure. Also, the scanning electron microscope observation showed that the NiMoO4 NPs were dispersed across the rGO sheets. The electrochemical results of the NiMoO4/3D-rGO electrode revealed that the incorporation of rGO sheets with NiMoO4 NPs increased the capacity of the nanocomposite. Therefore, a significant increase in the specific capacity of the electrode was observed with the NiMoO4/3D-rGO nanocomposite (450 Cg−1 or 900 Fg−1) when compared with bare NiMoO4 nanoparticles (350 Cg−1 or 700 Fg−1) at the current density of 1 A g−1. Our findings show that the incorporation of rGO and NiMoO4 NP redox reactions with a porous structure can benefit the future development of supercapacitors. 
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12.
  • Sturk, David, et al. (författare)
  • Analysis of li-ion battery gases vented in an inert atmosphere thermal test chamber
  • 2019
  • Ingår i: Batteries. - : MDPI Multidisciplinary Digital Publishing Institute. - 2313-0105. ; 5:3
  • Tidskriftsartikel (refereegranskat)abstract
    • One way to support the development of new safety practices in testing and field failure situations of electric vehicles and their lithium-ion (Li-ion) traction batteries is to conduct studies simulating plausible incident scenarios. This paper focuses on risks and hazards associated with venting of gaseous species formed by thermal decomposition reactions of the electrolyte and electrode materials during thermal runaway of the cell. A test set-up for qualitative and quantitative measurements of both major and minor gas species in the vented emissions from Li-ion batteries is described. The objective of the study is to measure gas emissions in the absence of flames, since gassing can occur without subsequent fire. Test results regarding gas emission rates, total gas emission volumes, and amounts of hydrogen fluoride (HF) and CO2 formed in inert atmosphere when heating lithium iron phosphate (LFP) and lithium nickel-manganese-cobalt (NMC) dioxide/lithium manganese oxide (LMO) spinel cell stacks are presented and discussed. Important test findings include the large difference in total gas emissions from NMC/LMO cells compared to LFP, 780 L kg−1 battery cells, and 42 L kg−1 battery cells, respectively. However, there was no significant difference in the total amount of HF formed for both cell types, suggesting that LFP releases higher concentrations of HF than NMC/LMO cells. © 2019 by the authors.
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13.
  • Thiringer, Torbjörn, 1966, et al. (författare)
  • Power Quality Issues of a Battery Fast Charging Station for a Fully-Electric Public Transport System in Gothenburg City
  • 2015
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 1:1, s. 22-33
  • Tidskriftsartikel (refereegranskat)abstract
    • An automatic fast charger station with a power level of 120 kW is developed for city Bus Line 60 in Gothenburg, Sweden. There are some power quality issues towards the utility grid during the charger operation. The aim of this paper is to explain the project and to present the measurement results with respect to power quality issues. The main specifications of the battery, charger, charging infrastructure and bus route are explained. The measurement results show that the harmonic emission is within the prescribed limit despite the high amount of low-frequency harmonics because of a passive diode rectification. It is suggested to replace the passive diode rectifier with an active front-end converter to eliminate low order current harmonics and to obtain a unity power factor operation. The main contribution of this work is to demonstrate a practical example of an electric charging system for an electric public transport system in Gothenburg.
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14.
  • Gupta, Priyank, 1991-, et al. (författare)
  • Layer-Resolved Mechanical Degradation of a Ni-Rich Positive Electrode
  • 2023
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 9:12, s. 575-
  • Tidskriftsartikel (refereegranskat)abstract
    • The effects of electrochemical aging on the mechanical properties of electrodes in lithium-ion batteries are challenging to measure and are largely unknown. Mechanochemical degradation processes occur at different scales within an electrode and understanding the correlation between the degradation of mechanical properties, electrochemical aging, and morphological changes is crucial for mitigating battery performance degradation. This paper explores the evolution of mechanical and electrochemical properties at the layer level in a Ni-rich positive electrode during the initial stages of electrochemical cycling. The investigation involves complementary cross-section analyses aimed at unraveling the connection between observed changes on both macroscopic and microscopic scales. The macroscopic constitutive properties were assessed using a U-shaped bending test method that had been previously developed. The compressive modulus exhibited substantial dependency on both the porous structure and binder properties. It experienced a notable reduction with electrolyte wetting but demonstrated an increase with cycling and aging. During the initial stages of aging, electrochemical impedance spectra revealed increased local resistance near the particle–electrolyte interface. This is likely attributable to factors such as secondary particle grain separation and the redistribution of carbon black. The swelling of particles, compression of the binder phase, and enhanced particle contact were identified as probable factors adding to the elevation of the elastic modulus within the porous layer as a result of cycling.
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15.
  • Martínez-López, Joseba, et al. (författare)
  • Voltage and Overpotential Prediction of Vanadium Redox Flow Batteries with Artificial Neural Networks
  • 2024
  • Ingår i: Batteries. - 2313-0105. ; 10:1
  • Tidskriftsartikel (refereegranskat)abstract
    • This article explores the novel application of a trained artificial neural network (ANN) in the prediction of vanadium redox flow battery behaviour and compares its performance with that of a two-dimensional numerical model. The aim is to evaluate the capability of two ANNs, one for predicting the cell potential and one for the overpotential under various operating conditions. The two-dimensional model, previously validated with experimental data, was used to generate data to train and test the ANNs. The results show that the first ANN precisely predicts the cell voltage under different states of charge and current density conditions in both the charge and discharge modes. The second ANN, which is responsible for the overpotential calculation, can accurately predict the overpotential across the cell domains, with the lowest confidence near high-gradient areas such as the electrode membrane and domain boundaries. Furthermore, the computational time is substantially reduced, making ANNs a suitable option for the fast understanding and optimisation of VRFBs.
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16.
  • Paulraj, Alagar Raj, et al. (författare)
  • Electrochemical Performance and in Operando Charge Efficiency Measurements of Cu/Sn-Doped Nano Iron Electrodes
  • 2019
  • Ingår i: Batteries. - : MDPI. - 2313-0105. ; :1
  • Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
    • Fe-air or Ni-Fe cells can offer low-cost and large-scale sustainable energy storage. At present, they are limited by low coulombic efficiency, low active material use, and poor rate capability. To overcome these challenges, two types of nanostructured doped iron materials were investigated: (1) copper and tin doped iron (CuSn); and (2) tin doped iron (Sn). Single-wall carbon nanotube (SWCNT) was added to the electrode and LiOH to the electrolyte. In the 2 wt. % Cu + 2 wt. % Sn sample, the addition of SWCNT increased the discharge capacity from 430 to 475 mAh g−1, and charge efficiency increased from 83% to 93.5%. With the addition of both SWCNT and LiOH, the charge efficiency and discharge capacity improved to 91% and 603 mAh g−1, respectively. Meanwhile, the 4 wt. % Sn substituted sample performance is not on par with the 2 wt. % Cu + 2 wt. % Sn sample. The dopant elements (Cu and Sn) and additives (SWCNT and LiOH) have a major impact on the electrode performance. To understand the relation between hydrogen evolution and charge current density, we have used in operando charging measurements combined with mass spectrometry to quantify the evolved hydrogen. The electrodes that were subjected to prolonged overcharge upon hydrogen evolution failed rapidly. This insight could help in the development of better charging schemes for the iron electrodes.
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17.
  • Rossini, Matteo, et al. (författare)
  • Nanostructured Lead Electrodes with Reduced Graphene Oxide for High-Performance Lead-Acid Batteries
  • 2022
  • Ingår i: BATTERIES-BASEL. - : MDPI AG. - 2313-0105. ; 8:11
  • Tidskriftsartikel (refereegranskat)abstract
    • Nanostructured Pb electrodes consisting of nanowire arrays were obtained by electrodeposition, to be used as negative electrodes for lead-acid batteries. Reduced graphene oxide was added to improve their performances. This was achieved via the electrochemical reduction of graphene oxide directly on the surface of nanowire arrays. The electrodes with and without reduced graphene oxide were tested in a 5 M sulfuric acid solution using a commercial pasted positive plate and an absorbed glass mat separator in a zero-gap configuration. The electrodes were tested in deep cycling conditions with a very low cut-off potential. Charge-discharge tests were performed at 5C. The electrode with reduced graphene oxide outperformed the electrode without reduced graphene oxide, as it was able to work with a very high utilization of active mass and efficiency. A specific capacity of 258 mAhg(-1)-very close to the theoretical one-was achieved, and the electrode lasted for more than 1000 cycles. On the other hand, the electrode without reduced graphene oxide achieved a capacity close to 230 mAhg(-1), which corresponds to a 90% of utilization of active mass.
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18.
  • Simões Dos Reis, Glaydson (författare)
  • Recent Progress in Biomass-Derived Carbon Materials for Li-Ion and Na-Ion Batteries-A Review
  • 2023
  • Ingår i: Batteries. - : MDPI AG. - 2313-0105. ; 9
  • Forskningsöversikt (refereegranskat)abstract
    • Batteries are the backbones of the sustainable energy transition for stationary off-grid, portable electronic devices, and plug-in electric vehicle applications. Both lithium-ion batteries (LIBs) and sodium-ion batteries (NIBs), most commonly rely on carbon-based anode materials and are usually derived from non-renewable sources such as fossil deposits. Biomass-derived carbon materials are extensively researched as efficient and sustainable anode candidates for LIBs and NIBs. The main purpose of this perspective is to brief the use of biomass residues for the preparation of carbon anodes for LIBs and NIBs annexed to the biomass-derived carbon physicochemical structures and their aligned electrochemical properties. In addition, an outlook and some challenges faced in this promising area of research is presented. This review enlightens the readers with valuable insights and a reasonable understanding of issues and challenges faced in the preparation, physicochemical properties, and application of biomass-derived carbon materials as anode candidates for LIBs and NIBs.
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19.
  • Singh, Veena, et al. (författare)
  • Electrode Fabrication Techniques for Li Ion Based Energy Storage System : A Review
  • 2023
  • Ingår i: BATTERIES-BASEL. - : MDPI AG. - 2313-0105. ; 9:3
  • Forskningsöversikt (refereegranskat)abstract
    • Development of reliable energy storage technologies is the key for the consistent energy supply based on alternate energy sources. Among energy storage systems, the electrochemical storage devices are the most robust. Consistent energy storage systems such as lithium ion (Li ion) based energy storage has become an ultimate system utilized for both domestic and industrial scales due to its advantages over the other energy storage systems. Considering the factors related to Li ion-based energy storage system, in the present review, we discuss various electrode fabrication techniques including electrodeposition, chemical vapor deposition (CVD), stereolithography, pressing, roll to roll, dip coating, doctor blade, drop casting, nanorod growing, brush coating, stamping, inkjet printing (IJP), fused deposition modelling (FDM) and direct ink writing (DIW). Additionally, we analyze the statistics of publications on these fabrication techniques and outline challenges and future prospects for the Li ion battery market.
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20.
  • Soares, Rudi, et al. (författare)
  • An Experimental Setup with Alternating Current Capability for Evaluating Large Lithium-Ion Battery Cells
  • 2018
  • Ingår i: Batteries-Basel. - : MDPI. - 2313-0105. ; 4:3
  • Tidskriftsartikel (refereegranskat)abstract
    • In the majority of applications using lithium-ion batteries, batteries are exposed to some harmonic content apart from the main charging/discharging current. The understanding of the effects that alternating currents have on batteries requires specific characterization methods and accurate measurement equipment. The lack of commercial battery testers with high alternating current capability simultaneously to the ability of operating at frequencies above 200 Hz, led to the design of the presented experimental setup. Additionally, the experimental setup expands the state-of-the-art of lithium-ion batteries testers by incorporating relevant lithium-ion battery cell characterization routines, namely hybrid pulse power current, incremental capacity analysis and galvanic intermittent titration technique. In this paper the hardware and the measurement capabilities of the experimental setup are presented. Moreover, the measurements errors due to the setup’s instruments were analysed to ensure lithium-ion batteries cell characterization quality. Finally, this paper presents preliminary results of capacity fade tests where 28 Ah cells were cycled with and without the injection of 21 A alternating at 1 kHz. Up to 300 cycles, no significant fade in cell capacity may be measured, meaning that alternating currents may not be as harmful for lithium-ion batteries as considered so far.
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21.
  • Xu, Yu, 1996, et al. (författare)
  • Maximizing Efficiency in Smart Adjustable DC Link Powertrains with IGBTs and SiC MOSFETs via Optimized DC-Link Voltage Control
  • 2023
  • Ingår i: Batteries. - 2313-0105. ; 9:6
  • Tidskriftsartikel (refereegranskat)abstract
    • In recent years, the push towards electrifying transportation has gained significant traction, with battery-electric vehicles (BEVs) emerging as a viable alternative. However, the widespread adoption of BEVs faces multiple challenges, such as limited driving range, making powertrain efficiency improvements crucial. One approach to improve powertrain energy efficiency is to adjust the DC-link voltage using a DC-DC converter between the battery and inverter. Here, it is necessary to address the losses introduced by the DC-DC converter. This paper presents a dynamic programming approach to optimize the DC-link voltage, taking into account the battery terminal voltage variation and its impact on the overall powertrain losses. We also examine the energy efficiency gains of IGBT-based and silicon carbide (SiC) MOSFET-based adjustable DC-link voltage powertrains during WLTC driving cycles through PLECS and Matlab/Simulink simulations. The findings indicate that both IGBT and MOSFET-based adjustable DC-link voltage powertrains can enhance the WLTC drive-cycle efficiency up to 2.51%2.51% and 3.25%3.25% compared to conventional IGBT and MOSFET-based powertrains, respectively.
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22.
  • Zali, Amir, et al. (författare)
  • Fabrication of TiFe-Based Electrodes Using High-Energy Ball Mill with Mn Additive for NiMH Batteries
  • 2022
  • Ingår i: BATTERIES-BASEL. - : MDPI AG. - 2313-0105. ; 8:10, s. 182-
  • Tidskriftsartikel (refereegranskat)abstract
    • Binary and ternary (with the addition of Mn) TiFe-based intermetallic compound powders were fabricated by high energy ball milling, and their electrochemical behavior as negative electrodes was investigated in 6M-KOH. X-ray diffraction exhibited the single phase of nanostructured binary and ternary TiFe-based crystallites after 20 h of milling followed the amorphous phase formation. Addition of Mn increased peak broadening and in turn decreased the nanocrystallite size of TiFe. Electrode properties of 20, 40, 60, and 70 h binary milled products showed that the discharge capacity of the 60 h one offered a maximum discharge capacity of similar to 169 mAhg(-1). Although substitution of Mn for Ti (TixFeMnx,( )x = 0.1, 0.2) caused a decrease in initial discharge capacity, the periodic stability increased compared to the binary TiFe and ternary TiFe1-xMnx (x = 0.1, 0.2). The ternary Ti0.9FeMn0.1 electrode maintained similar to 53% of its initial discharge capacity after five cycles of charge-discharge; this was just 28% in the case of binary TiFe electrode.
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