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Sökning: WFRF:(Batten S. R.)

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2.
  • Batten, S. R., et al. (författare)
  • Coordination polymers, metal-organic frameworks and the need for terminology guidelines
  • 2012
  • Ingår i: CrystEngComm. - : Royal Society of Chemistry (RSC). - 1466-8033. ; 14:9, s. 3001-3004
  • Tidskriftsartikel (refereegranskat)abstract
    • Coordination polymers (CPs) and metal–organic frameworks (MOFs) are among the most prolific research areas of inorganic chemistry and crystal engineering in the last 15 years, and yet it still seems that consensus is lacking about what they really are, or are not.
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3.
  • Batten, S. R., et al. (författare)
  • Terminology of Metal-Organic Frameworks and Coordination Polymers (IUPAC recommendations 2013)
  • 2013
  • Ingår i: Pure and Applied Chemistry. - 1365-3075 .- 0033-4545. ; 85:8, s. 1715-1724
  • Tidskriftsartikel (refereegranskat)abstract
    • A set of terms, definitions, and recommendations is provided for use in the classi- fication of coordination polymers, networks, and metal–organic frameworks (MOFs). A hier- archical terminology is recommended in which the most general term is coordination poly- mer. Coordination networks are a subset of coordination polymers and MOFs a further subset of coordination networks. One of the criteria an MOF needs to fulfill is that it contains poten- tial voids, but no physical measurements of porosity or other properties are demanded per se. The use of topology and topology descriptors to enhance the description of crystal structures of MOFs and 3D-coordination polymers is furthermore strongly recommended.
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5.
  • Bonneau, Charlotte, et al. (författare)
  • Deconstruction of Crystalline Networks into Underlying Nets: Relevance for Terminology Guidelines and Crystallographic Databases
  • 2018
  • Ingår i: Crystal Growth & Design. - : American Chemical Society (ACS). - 1528-7505 .- 1528-7483. ; 18:6, s. 3411-3418
  • Tidskriftsartikel (refereegranskat)abstract
    • This communication briefly reviews why network topology is an important tool (for understanding, comparing, communicating, designing, and solving crystal structures from powder diffraction data) and then discusses the terms of an IUPAC project dealing with various aspects of network topology. One is the ambiguity in node assignment, and this question is addressed in more detail. First, we define the most important approaches: the "all node" deconstruction considering all branch points of the linkers, the "single node" deconstruction considering only components mixed, and the ToposPro "standard representation" also considering linkers as one node but, if present, takes each metal atom as a separate node. These methods are applied to a number of metal-organic framework structures (MOFs, although this is just one example of materials this method is applicable on), and it is concluded that the "all node" method potentially yields more information on the structure in question but cannot be recommended as the only way of reporting the network topology. In addition, several terms needing definitions are discussed.
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  • Resultat 1-5 av 5

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