| 1. |
- Blythe, Lara S., 1984-
(författare)
-
Understanding Crustal Volatiles : Provenance, Processes and Implications
- 2012
-
Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Knowledge of the provenance of crustal volatiles and the processes by which they are released is extremely important for the dynamics of magmatic systems. Presented here are the results of multiple investigations, which aim to understand magmatic volatile contamination from contrasting but complementary perspectives. The main methodologies used include He and C isotope values and CO2/3He ratios of volcanic gases and fluids; simulation of magma-carbonate interaction using high-pressure high-temperature experimental petrology; X-ray microtomography of vesiculated xenoliths and computer modeling. Findings show that the contribution from upper crustal volatiles can be substantial, and is dependant on the upper crustal lithology on which a volcano lies, as well as the composition of the magma supplied. Carbonate dissolution in particular is strongly controlled by the viscosity of the host magma. The details of the breakdown of vesiculated xenoliths is complex but has wide reaching implications, ranging from the dissemination of crustally derived materials through a magma body to highlighting that crustal volatiles are largely unaccounted for in both individual volcano and global volatile budgets. In synthesizing the conclusions from each of the individual perspectives presented, I propose the contribution of volatiles from crustal sources to play a significant role in many geological systems. This volatile component should be taken into consideration in future research efforts.
|
|
| 2. |
- Jolis, Ester Muñoz, et al.
(författare)
-
Experimental simulation of magma-carbonate interaction beneath Mt. Vesuvius, Italy
- 2013
-
Ingår i: Contributions to Mineralogy and Petrology. - : Springer Science and Business Media LLC. - 0010-7999 .- 1432-0967. ; 166:5, s. 1335-1353
-
Tidskriftsartikel (refereegranskat)abstract
- We simulated the process of magma-carbonate interaction beneath Mt. Vesuvius in short duration piston-cylinder experiments under controlled magmatic conditions (from 0 to 300 s at 0.5 GPa and 1,200 A degrees C), using a Vesuvius shoshonite composition and upper crustal limestone and dolostone as starting materials. Backscattered electron images and chemical analysis (major and trace elements and Sr isotopes) of sequential experimental products allow us to identify the textural and chemical evolution of carbonated products during the assimilation process. We demonstrate that melt-carbonate interaction can be extremely fast (minutes), and results in dynamic contamination of the host melt with respect to Ca, Mg and Sr-87/Sr-86, coupled with intense CO2 vesiculation at the melt-carbonate interface. Binary mixing between carbonate and uncontaminated melt cannot explain the geochemical variations of the experimental charges in full and convection and diffusion likely also operated in the charges. Physical mixing and mingling driven by exsolving volatiles seems to be a key process to promote melt homogenisation. Our results reinforce hypotheses that magma-carbonate interaction is a relevant and ongoing process at Mt. Vesuvius and one that may operate not only on a geological, but on a human timescale.
|
|
| 3. |
- Troll, Valentin, et al.
(författare)
-
Floating stones off El Hierro, Canary Islands: xenoliths of pre-island sedimentary origin in the early products of the October 2011 eruption
- 2012
-
Ingår i: Solid Earth. - : Copernicus Publications. - 1869-9510 .- 1869-9529. ; 3:1, s. 97-110
-
Tidskriftsartikel (refereegranskat)abstract
- A submarine eruption started off the south coast of El Hierro, Canary Islands, on 10 October 2011 and continues at the time of this writing (February 2012). In the first days of the event, peculiar eruption products were found floating on the sea surface, drifting for long distances from the eruption site. These specimens, which have in the meantime been termed "restingolites" (after the close-by village of La Restinga), appeared as black volcanic "bombs" that exhibit cores of white and porous pumice-like material. Since their brief appearance, the nature and origin of these "floating stones" has been vigorously debated among researchers, with important implications for the interpretation of the hazard potential of the ongoing eruption. The "restingolites" have been proposed to be either (i) juvenile high-silica magma (e. g. rhyolite), (ii) remelted magmatic material (trachyte), (iii) altered volcanic rock, or (iv) reheated hyaloclastites or zeolite from the submarine slopes of El Hierro. Here, we provide evidence that supports yet a different conclusion. We have analysed the textures and compositions of representative "restingolites" and compared the results to previous work on similar rocks found in the Canary Islands. Based on their high-silica content, the lack of igneous trace element signatures, the presence of remnant quartz crystals, jasper fragments and carbonate as well as wollastonite (derived from thermal overprint of carbonate) and their relatively high oxygen isotope values, we conclude that "restingolites" are in fact xenoliths from pre-island sedimentary layers that were picked up and heated by the ascending magma, causing them to partially melt and vesiculate. As they are closely resembling pumice in appearance, but are xenolithic in origin, we refer to these rocks as "xeno-pumice". The El Hierro xeno-pumices hence represent messengers from depth that help us to understand the interaction between ascending magma and crustal lithologies beneath the Canary Islands as well as in similar Atlantic islands that rest on sediment-covered ocean crust (e. g. Cape Verdes, Azores). The occurrence of "restingolites" indicates that crustal recycling is a relevant process in ocean islands, too, but does not herald the arrival of potentially explosive high-silica magma in the active plumbing system beneath El Hierro.
|
|
| 4. |
- Troll, Valentin R., et al.
(författare)
-
Crustal CO2 liberation during the 2006 eruption and earthquake events at Merapi volcano, Indonesia
- 2012
-
Ingår i: Geophysical Research Letters. - 0094-8276 .- 1944-8007. ; 39, s. L11302-
-
Tidskriftsartikel (refereegranskat)abstract
- High-temperature volcanic gas is widely considered to originate from ascending, mantle-derived magma. In volcanic arc systems, crustal inputs to magmatic gases mainly occur via subducted sediments in the mantle source region. Our data from Merapi volcano, Indonesia imply, however, that during the April-October 2006 eruption significant quantities of CO2 were added from shallow crustal sources. We show that prior to the 2006 events, summit fumarole gas delta C-13((CO2)) is virtually constant (delta C-13(1994-2005) = -4.1 +/- 0.3 parts per thousand), but during the 2006 eruption and after the shallow Yogyakarta earthquake of late May, 2006 (M6.4; hypocentres at 10-15 km depth), carbon isotope ratios increased to -2.4 +/- 0.2 parts per thousand. This rise in delta C-13 is consistent with considerable addition of crustal CO2 and coincided with an increase in eruptive intensity by a factor of similar to 3 to 5. We postulate that this shallow crustal volatile input supplemented the mantle-derived volatile flux at Merapi, intensifying and sustaining the 2006 eruption. Late-stage volatile additions from crustal contamination may thus provide a trigger for explosive eruptions independently of conventional magmatic processes.
|
|
