| 1. |
- Kukk, E., et al.
(författare)
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Dissociation of deuteromethane following carbon 1s core ionization
- 2002
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - 1050-2947 .- 1094-1622. ; 66:1
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Tidskriftsartikel (refereegranskat)abstract
- Energy-resolved electron-ion coincidence spectra of the deuteromethane molecule were measured following ionization by narrow-band synchrotron radiation. The ion mass spectra were recorded in coincidence with the outer and inner valence photoelectrons and with the normal Auger electrons from the decay of the carbon 1s core hole. Complementary noncoincidence ion mass spectra were measured below and above the C 1s threshold. The fragmentation patterns of the singly and doubly ionized deuteromethane under different ionization conditions are examined. Carbon core ionization is shown to open new photodissociation pathways not available in the valence ionization photon energy regime. With the aid of ab initio quantum chemistry calculations, a two-step model of the dissociation following core ionization is proposed, showing a good agreement with the experimental findings.
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| 2. |
- Frasinski, L. J, et al.
(författare)
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Multielectron Dissociative Ionization of Co2 In Intense Laser Fields
- 1994
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Ingår i: Journal of Physics B: Atomic, Molecular and Optical Physics. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 27:6, s. 97-109
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Tidskriftsartikel (refereegranskat)abstract
- The multiphoton ionization of CO2 has been studied using a laser of 794 nm WaVelength and focused intensities in the region of 10(16) W cm-2. The kinetic energy distributions and ion yields obtained using time-of-flight spectroscopy coupled with covariance mapping can be interpreted most simply in terms of charge-symmetric fragmentation, the strongest channel being O2+ + C2+ + O2+. These results are compared with two recent experiments on CO2, one using an intense laser at 248 nm, the other using Si8+ ion projectiles of 3 MeV u-1 energy.
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| 3. |
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| 4. |
- Stankiewicz, M., et al.
(författare)
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Relaxation dynamics of SF6 studied by energy-resolved electron ion coincidence technique
- 2004
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Ingår i: Journal of Electron Spectroscopy and Related Phenomena. - : Elsevier BV. - 0368-2048 .- 1873-2526. ; 137-40, s. 369-375
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Tidskriftsartikel (refereegranskat)abstract
- The mass spectra from the SF6 molecule acquired by energy-resolved electron ion coincidence (EREICO) technique using (1t(1g) + [5t(1u),1t(2u)]), (3e(g) + 1t(2g)), 4t(1u), and 5a(1g) electrons after both valence and S 2p(-1) 6a(1g) core excitation reveal a strong selectivity in the dissociation from these states. From the comparison of the obtained spectra, the influence of the core-excited state in the relaxation pathway of the molecule is studied. The S 2p --> 6a(1g) core excitation does not affect the relaxation dynamics after participator Auger decay to the (1t(1g) + [5t(1u),1t(2u)])(-1) and (4t(1u))(-l) states, but it alters the relaxation dynamics after participator Auger decay to the (3e(g) + 1t(2g))(-1) and (5a(1g))(-1) states with respect to the decay processes after direct excitation of the same orbitals. These observations point to core excitation induced dissociation in the SF6 molecule.
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