| 1. |
- Andersson, Martin, et al.
(författare)
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Analysis of the competition between forbidden and hyperfine-induced transitions in Ne-like ions
- 2016
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Ingår i: Physical Review A (Atomic, Molecular and Optical Physics). - 1050-2947. ; 93:3
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Tidskriftsartikel (refereegranskat)abstract
- In this work we investigate the decay of the |2p53sP03) state in neon-like ions along the isoelectronic sequence ranging from Z=10 to Z=35. In the absence of a nuclear spin, the magnetic dipole transition to |2p53sP13) is the dominating decay channel. However, for isotopes with a nuclear spin, the interaction between the nuclear magnetic dipole moment and the electronic field introduces a mixing of |2p53sP13) and |P11) into the |P03) state, which in turn opens up a competing hyperfine-induced electric dipole decay channel to the ground state. This hyperfine-induced transition channel clearly dominates over the magnetic dipole channel for the neutral end of the isoelectronic sequence, when present. We give values for the rates of both these competing channels and discuss how the introduction of the hyperfine-induced transition channel could have a dramatic influence on the spectrum, not only because it introduces a new line, but also since it can substantially decrease the intensity of the magnetic dipole 2p53sP03→2p53sP13 line and affect the predicted ionization balance in different plasmas.
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| 2. |
- Andersson, Martin, et al.
(författare)
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HYPERFINE-DEPENDENT gf -VALUES OF Mn i LINES IN THE 1.49–1.80 μm H BAND
- 2015
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Ingår i: The Astrophysical Journal Supplement Series. - : American Astronomical Society. - 0067-0049 .- 1538-4365. ; 216:1
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Tidskriftsartikel (refereegranskat)abstract
- The three Mn I lines at 17325, 17339, and 17349 angstrom are among the 25 strongest lines (log(gf) > 0.5) in the H band. They are all heavily broadened due to hyperfine structure, and the profiles of these lines have so far not been understood. Earlier studies of these lines even suggested that they were blended. In this work, the profiles of these three infrared (IR) lines have been studied theoretically and compared to experimental spectra to assist in the complete understanding of the solar spectrum in the IR. It is shown that the structure of these lines cannot be described in the conventional way using the diagonal A and B hyperfine interaction constants. The off-diagonal hyperfine interaction not only has a large impact on the energies of the hyperfine levels, but also introduces a large intensity redistribution among the hyperfine lines, changing the line profiles dramatically. By performing large-scale calculations of the diagonal and off-diagonal hyperfine interaction and the gf-values between the upper and lower hyperfine levels and using a semi-empirical fitting procedure, we achieved agreement between our synthetic and experimental spectra. Furthermore, we compare our results with observations of stellar spectra. The spectra of the Sun and the K1.5 III red giant star Arcturus were modeled in the relevant region, 1.73-1.74 mu m, using our theoretically predicted gf-values and energies for each individual hyperfine line. Satisfactory fits were obtained and clear improvements were found using our new data compared with the old available Mn I data. A complete list of energies and gf-values for all the 3d(5)4s(S-7)4d e(6)D - 3d(5)4s(S-7)4f w(6)F hyperfine lines are available as supporting material, whereas only the stronger lines are presented and discussed in detail in this paper.
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| 3. |
- Chambers, Josephine M., et al.
(författare)
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Co-productive agility and four collaborative pathways to sustainability transformations
- 2022
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Ingår i: Global Environmental Change. - : Elsevier BV. - 0959-3780 .- 1872-9495. ; 72
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Tidskriftsartikel (refereegranskat)abstract
- Co-production, the collaborative weaving of research and practice by diverse societal actors, is argued to play an important role in sustainability transformations. Yet, there is still poor understanding of how to navigate the tensions that emerge in these processes. Through analyzing 32 initiatives worldwide that co-produced knowledge and action to foster sustainable social-ecological relations, we conceptualize 'co-productive agility' as an emergent feature vital for turning tensions into transformations. Co-productive agility refers to the willingness and ability of diverse actors to iteratively engage in reflexive dialogues to grow shared ideas and actions that would not have been possible from the outset. It relies on embedding knowledge production within processes of change to constantly recognize, reposition, and navigate tensions and opportunities. Co-productive agility opens up multiple pathways to transformation through: (1) elevating marginalized agendas in ways that maintain their integrity and broaden struggles for justice; (2) questioning dominant agendas by engaging with power in ways that challenge assumptions, (3) navigating conflicting agendas to actively transform interlinked paradigms, practices, and structures; (4) exploring diverse agendas to foster learning and mutual respect for a plurality of perspectives. We explore six process considerations that vary by these four pathways and provide a framework to enable agility in sustainability transformations. We argue that research and practice spend too much time closing down debate over different agendas for change - thereby avoiding, suppressing, or polarizing tensions, and call for more efforts to facilitate better interactions among different agendas.
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| 4. |
- Chambers, Josephine M., et al.
(författare)
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Six modes of co-production for sustainability
- 2021
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Ingår i: Nature Sustainability. - : Springer Science and Business Media LLC. - 2398-9629. ; 4, s. 983-996
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Tidskriftsartikel (refereegranskat)abstract
- Co-production includes diverse aims, terminologies and practices. This study explores such diversity by mapping differences in how 32 initiatives from 6 continents co-produce diverse outcomes for the sustainable development of ecosystems at local to global scales. The promise of co-production to address complex sustainability challenges is compelling. Yet, co-production, the collaborative weaving of research and practice, encompasses diverse aims, terminologies and practices, with poor clarity over their implications. To explore this diversity, we systematically mapped differences in how 32 initiatives from 6 continents co-produce diverse outcomes for the sustainable development of ecosystems at local to global scales. We found variation in their purpose for utilizing co-production, understanding of power, approach to politics and pathways to impact. A cluster analysis identified six modes of co-production: (1) researching solutions; (2) empowering voices; (3) brokering power; (4) reframing power; (5) navigating differences and (6) reframing agency. No mode is ideal; each holds unique potential to achieve particular outcomes, but also poses unique challenges and risks. Our analysis provides a heuristic tool for researchers and societal actors to critically explore this diversity and effectively navigate trade-offs when co-producing sustainability.
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| 5. |
- Fei, Z., et al.
(författare)
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Experimental and theoretical study of the ground-state M1 transition in Ag-like tungsten
- 2012
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Ingår i: Physical Review A (Atomic, Molecular and Optical Physics). - 1050-2947. ; 86:6
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Tidskriftsartikel (refereegranskat)abstract
- We present an experimental and theoretical study of the F-2(5/2) -> F-2(7/2) M1 transition in Ag-like W (W27+). The experiments employed the Shanghai permanent magnet electron beam ion trap, which has been developed especially for assisting spectroscopic diagnostics of edge plasmas for magnetic fusion devices. The theoretical value was obtained using the GRASP2K set of computer codes and included a comprehensive correlation study. The experimental M1 wavelength was measured as 3377.43 +/- 0.26 angstrom (3378.43 angstrom vacuum wavelength), whereas the calculated wavelength is in good agreement at 3381.80 angstrom. This good agreement shows the importance of fully understanding the electron correlation effects to predict the energy of the fine structure even in this, for tungsten, relatively simple case.
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| 6. |
- Fei, Z., et al.
(författare)
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Forbidden-line spectroscopy of the ground-state configuration of Cd-like W
- 2014
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Ingår i: Physical Review A (Atomic, Molecular and Optical Physics). - 1050-2947. ; 90:5
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Tidskriftsartikel (refereegranskat)abstract
- only using electric-dipole forbidden emission lines, in what we label forbidden-line spectroscopy, we identified several energy levels in cadmium-like tungsten, W26+. The spectrum was recorded at the Shanghai permanentmagnet electron beam ion trap in the visible region. The identifications were supported by large-scale multiconfiguration Dirac-Hartree-Fock calculations which involved careful investigations of core-valence and core-core correlation effects, and by relativistic many-body perturbation theory calculations. With this novel method we identified in all seven lines and measured their wavelengths. From this we can determine the relative position of seven energy levels. Due to the close degeneracy of two levels, we give alternative energies for three of the levels.
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| 7. |
- Grumer, Jon, et al.
(författare)
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Coronal lines and the importance of deep-core-valence correlation in Ag-like ions
- 2014
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Ingår i: Physical Review A (Atomic, Molecular and Optical Physics). - 1050-2947. ; 89:6
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Tidskriftsartikel (refereegranskat)abstract
- We report on large-scale and critically evaluated ab initio multiconfiguration Dirac-Hartree-Fock calculations of the wavelength and transition rate of the "coronal," M1 transition 4f F-2(5/2)o-F-2(7/2)o in Ag-like ions. The transition between these two fine-structure levels, which makes up the ground term for Z >= 62 in the isoelectronic sequence, has recently been observed in Yb23+ and W27+, where the latter could be of great importance for fusion plasma diagnostics. We present values for all members of the sequence between Z = 50 and 94, which are supported by excellent agreement with values from recent experiments. The importance of including core-valence correlation with the n = 3 shell in the theoretical model is emphasized. The results show close-to-spectroscopic accuracy for these forbidden lines.
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| 8. |
- Grumer, Jon, et al.
(författare)
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Magnetic field induced transition rates in Ne- and Be-like ions for plasma diagnostics and E1M1 two-photon decay rate determination
- 2014
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Ingår i: XXVIII International Conference on Photonic, Electronic and Atomic Collisions (ICPEAC 2013). - : IOP Publishing. - 1742-6588 .- 1742-6596. ; 488, s. 152005-152005
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- We report on theoretical results of magnetic field induced transitions (MITs) in Ne- and Be-like ions without nuclear spin for two applicalions. Firstly, MITs are promising candidates in the determination of magnetic fields in plasmas. In our work on Ne-like ions we present accurate theoretical MIT rates for 2p(6 1)S(O) - 2p(5)3s 3P(O),2 [11. Purthermore, for Be-like ions, it has been proposed to extract the rate of the BIM1 two-photon transition 2s(2 1)S(O) - 2s2p P-3(O) by measuring the lifetime of the 'Po state using a storage ring, which involves an external magnetic field. The MIT rates are carefully evaluated and shown to be of the same order as the ElMI rates [2].
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| 9. |
- Grumer, Jon, et al.
(författare)
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Magnetic-field Induced Transitions : the Search for Close Degeneracies
- 2014
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Ingår i: Ninth International Conference on Atomic and Molecular Data and Their Applications: book of abstracts. ; , s. 54-54
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- Magnetic fields play a crucial role in numerous astrophysical and experimental plasma, such as solar protuberances, tokamaks, ion traps and storage rings. It is well-known that external fields affects ions by breaking the spherical symmetry, resulting in non-degenerate magnetic sublevels (the Zeeman effect). A more intriguing consequence is that the field will introduce new decay channels through off-diagonal interactions. We call these magnetic-field induced transitions (MITs). Such exotic lines could have a significant impact on the spectrum under investigation, especially for systems containing close degeneracies or when otherwise strictly forbidden one-photon channels are opened up. These transitions have attracted new attention recently due to the development of accurate and systematic methods of calculations of their rates [1,2] and the possible application as a tool for measuring plasma magnetic fields in cases when conventional methods, such as measurements of Zeeman separation energies, are beyond reach. We are currently developing a module for general atomic systems [3] based on wave-functions and transition matrix elements calculated with the well-established multiconfiguration Dirac-Hartree-Fock program package GRASP2K [4]. The code also supports ions with non-zero nuclear spin (and therefore also pure hyperfine induced transitions) and the aim is to eventually make it available to the general public as an extension module to GRASP2K. We will give an overview and recent progress in this field and present some new results. One interesting example is our ongoing investigation of enhanced MITs appearing due to close degeneracies, and the possible application of these as probes of magnetic fields in solar flares of which no direct measurements yet exists. The origin of these eruptions is connected to regions in the Solar corona with comparatively strong magnetic fields (sunspots) and it is believed that the energy released in a flare has been stored in these fields. It is therefore of great importance to measure the magnetic field strength and we propose a method based on MIT intensities.
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| 10. |
- Grumer, Jon, et al.
(författare)
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Magnetic field induced transition rates in Ne- and Be-like ions for plasma diagnostics and E1M1 two-photon decay rate determination
- 2013
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Ingår i: Book of abstracts. - : Institute of Modern Physics, Chinese Academy of Sciences.
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- Synopsis We report on theoretical results of magnetic field induced transitions (MITs) in Ne- and Be-like ions without nuclear spin for two applications. Firstly, MITs are promising candidates in the determination of magnetic fields in plasmas. In our work on Ne-like ions we present accurate theoretical MIT rates for 2p6 1S0 − 2p53s 3P0 , 2 [1]. Furthermore, for Be-like ions, it has been proposed to extract the rate of the E1M1 two-photon transition 2s2 1S0 − 2s2p 3P0 by measuring the lifetime of the 3P0 state using a storage ring, which involves an external magnetic field. The MIT rates are carefully evaluated and shown to be of the same order as the E1M1 rates.
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| 11. |
- Grumer, Jon, et al.
(författare)
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The effect of an external magnetic field on the determination of E1M1 two-photon decay rates in Be-like ions
- 2013
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - : American Physical Society. - 1050-2947 .- 1094-1622. ; 88
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Tidskriftsartikel (refereegranskat)abstract
- In this work we report on ab initio theoretical results for the magnetic-field-induced 2s 2p 3P0 → 2s2 1S0 E1 transition for ions in the beryllium isoelectronic sequence between Z = 5 and 92. It has been proposed that the rate of the E1M1 two-photon transition 2s 2p 3P0 → 2s2 1S0 can be extracted from the lifetime of the 3P0 state in Be-like ions with zero nuclear spin by employing resonant recombination in a storage ring. This experimental approach involves a perturbing external magnetic field. The effect of this field needs to be evaluated in order to properly extract the two-photon rate from the measured decay curves. The magnetic-field-induced transition rates are carefully evaluated, and it is shown that, with a typical storage-ring field strength, it is dominant or of the same order as the E1M1 rate for low- and mid-Z ions. Results for several field strengths and ions are presented, and we also give a simple Z-dependent formula for the rate. We estimate the uncertainties of our model to be within 5% for low- and mid-Z ions and slightly larger for more highly charged ions. Furthermore we evaluate the importance of including both perturber states, 3P1 and 1P1, and it is s
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| 12. |
- Grumer, Jon, et al.
(författare)
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Unexpected transitions induced by spin-dependent, hyperfine and external magnetic-field interactions
- 2014
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Ingår i: Physica Scripta. - : IOP Publishing. - 0031-8949 .- 1402-4896. ; 89:11
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Tidskriftsartikel (refereegranskat)abstract
- Unexpected transitions are induced by weaker interactions not included in the gross structure model of the ion under investigation. We discuss different examples of such decay channels, starting with relativistic spin-induced transitions. These represented an important field of study a few decades ago, and we illustrate how some challenging cases can be treated very accurately with today's computational techniques, while close degeneracy sometimes still prevents ab initio methods from obtaining accurate results. For hyperfine induced transitions we review some recent results and discuss remaining challenges for experiment and theory. Finally, we discuss the newly opened field of accurate calculations for transitions induced by an external magnetic field and point to some examples of where these are accessible for experimental tests.
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| 13. |
- Guo, Xueling, et al.
(författare)
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Energy levels and radiative data for Kr-like W38+ from MCDHF and RMBPT calculations
- 2016
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Ingår i: Journal of Physics B: Atomic, Molecular and Optical Physics. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 49:13
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Tidskriftsartikel (refereegranskat)abstract
- Energies, transition rates, line strengths and lifetimes have been computed for all levels of the 4p 6 and 4p 54d configurations of W38+ by using the multi-configuration Dirac-Hartree-Fock (MCDHF) method as well as relativistic many-body perturbation theory. We investigate systematically correlation, relativistic and quantum electro-dynamical (QED) effects of different properties, including excitation energies and transition rates. We demonstrate that it is important to include the core-valence correlation of rather deep subshells (including 3d and 3p) to reach close to spectroscopic accuracy for the transition energies. We also show that high-multipole transitions (E3, M2) are important for the lifetime of some metastable levels of 4p 54d (). The present results are in good agreement with experiments and of considerably higher accuracy than those achieved in previous theoretical works.
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| 14. |
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| 15. |
- Li, Jiguang, et al.
(författare)
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Theoretical investigation of magnetic-field-induced 2p(5)3s 3P(0,2)-2p(6) S-1(0) transitions in Ne-like ions without nuclear spin
- 2013
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Ingår i: Physical Review A (Atomic, Molecular and Optical Physics). - 1050-2947. ; 88:1
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Tidskriftsartikel (refereegranskat)abstract
- We report theoretical results for magnetic-field-induced 2p(5)3s 3P(0,2)-2p(6) S-1(0) E1 transitions in Ne-like ions with zero nuclear spin (I = 0) between Mg III and Zn XXI as well as in Ne I. We demonstrate that it is important to include both "perturber" states 2p(5)3s P-1(1) and 2p(5)3s P-3(1) in order to produce reliable transition rates. Furthermore, we investigate the trends of the rates along the isoelectronic sequence of the 2p(5)3s 3P(0,2)-2p(6) S-1(0) transitions and their competition with the 2p(5)3s P-3(0)-2p(5)3s P-3(1) M1 and the 2p(5)3s P-3(2)-2p(6) S-1(0) M2 decays. For the 2p(5)3s P-3(0) state the magnetic-field-induced transition becomes the dominant decay channel for the light elements even in a relatively weak magnetic field, and it will therefore prove useful in diagnostics of the strength of magnetic fields in different plasmas. The influence of an external magnetic field on the lifetime of the 2p(5)3s P-3(2) state is much smaller but still observable for the ions near the neutral end of the sequence. As a special case, the magnetic field effect on the lifetimes of 2p(5)3s P-3(0,2) states of neutral Ne-20 is discussed. It is found that the lifetimes are drastically reduced by a magnetic field, which may be an underlying reason for the discrepancies in the lifetime of the 2p(5)3s P-3(2) state between experiment [14.73(14) s] and theory (17.63 s).
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| 16. |
- Li, Jiguang, et al.
(författare)
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Theoretical investigation of magnetic-field-induced 2p53s 3P0 - 2p6 1S0 transitions in Ne-like ions without nuclear spin
- 2013
-
Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - : American Physical Society. - 1050-2947 .- 1094-1622. ; 88:1
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Tidskriftsartikel (refereegranskat)abstract
- We report theoretical results for magnetic-field-induced 2p53s 3P0,2 − 2p6 1S0 E1 transitions in Ne-like ions with zero nuclear spin (I = 0) between Mg III and Zn XXI as well as in Ne I.We demonstrate that it is important to include both “perturber” states 2p53s 1P1 and 2p53s 3P1 in order to produce reliable transition rates. Furthermore, we investigate the trends of the rates along the isoelectronic sequence of the 2p53s 3P0,2 − 2p6 1S0 transitions and their competition with the 2p53s 3P0 − 2p53s 3P1 M1 and the 2p53s 3P2 − 2p6 1S0 M2 decays. For the 2p53s 3P0 state the magnetic-field-induced transition becomes the dominant decay channel for the light elements even in a relatively weak magnetic field, and it will therefore prove useful in diagnostics of the strength of magnetic fields in different plasmas. The influence of an external magnetic field on the lifetime of the 2p53s 3P2 state is much smaller but still observable for the ions near the neutral end of the sequence. As a special case, the magnetic field effect on the lifetimes of 2p53s 3P0,2 states of neutral 20Ne is discussed. It is found that the lifetimes are drastically reduced by a magnetic field, which may be an underlying reason for the discrepancies in the lifetime of the 2p53s 3P2 state between experiment [14.73(14) s] and theory (17.63 s).
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| 17. |
- Li, Wenxian, et al.
(författare)
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A Novel Method to Determine Magnetic Fields in Low-density Plasma Facilitated Through Accidental Degeneracy of Quantum States in Fe9
- 2015
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Ingår i: Astrophysical Journal. - 0004-637X. ; 807:1
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Tidskriftsartikel (refereegranskat)abstract
- We propose a new method to determine magnetic fields, by using the magnetic-field-induced electric dipole transition 3p(4) 3d D-4(7/2) -> 3p(5) P-3/2 in Fe9+ ions. This ion has a high abundance in astrophysical plasma and is therefore well suited for direct measurements of even rather weak fields in, e.g., solar flares. This transition is induced by an external magnetic field and its rate is proportional to the square of the magnetic field strength. We present theoretical values for what we will label the reduced rate and propose that the critical energy difference between the upper level in this transition and the close-to-degenerate 3p(4) 3d D-4(5/2) should be measured experimentally since it is required to determine the relative intensity of this magnetic line for different magnetic fields.
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| 18. |
- Li, Wenxian, et al.
(författare)
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ATOMIC-LEVEL PSEUDO-DEGENERACY of ATOMIC LEVELS GIVING TRANSITIONS INDUCED by MAGNETIC FIELDS, of IMPORTANCE for DETERMINING the FIELD STRENGTHS in the SOLAR CORONA
- 2016
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Ingår i: Astrophysical Journal. - 0004-637X. ; 826:2
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Tidskriftsartikel (refereegranskat)abstract
- We present a measured value for the degree of pseudo-degeneracy between two fine-structure levels in Fe9+ from line intensity ratios involving a transition induced by an external magnetic field. The extracted fine-structure energy difference between 3p4 3d 4D7/2 the and 4D7/2 levels, where the latter is the upper state for the magnetic-field induced line, is needed in our recently proposed method to measure magnetic-field strengths in the solar corona. The intensity of the 3p4 3d 4D7/2 → 3p5 2 P3/2 line at 257.262 Å is sensitive to the magnetic field external to the ion. This sensitivity is in turn strongly dependent on the energy separation in the pseudo-degeneracy through the mixing induced by the external magnetic field. Our measurement, which uses an Electron Beam Ion Trap with a known magnetic-field strength, indicates that this energy difference is 3.5 cm-1. The high abundance of Fe9+ and the sensitivity of the line's transition probability to field strengths below 0.1 T opens up the possibility of diagnosing coronal magnetic fields. We propose a new method to measure the magnetic field in the solar corona, from similar intensity ratios in Fe9+. In addition, the proposed method to use the line ratio of the blended line 3p4 3d 4D7/2.5/2 → 3p5 2P3/2 with another line from Fe x as the density diagnostic should evaluate the effect of the magnetic-field-induced transition line.
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| 19. |
- Si, Ran, et al.
(författare)
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A First Spectroscopic Measurement of the Magnetic-field Strength for an Active Region of the Solar Corona
- 2020
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Ingår i: Astrophysical Journal Letters. - : Institute of Physics (IOP). - 2041-8205 .- 2041-8213. ; 898:2
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Tidskriftsartikel (refereegranskat)abstract
- For all involved in astronomy, the importance of monitoring and determining astrophysical magnetic-field strengths is clear. It is also a well-known fact that the corona magnetic fields play an important part in the origin of solar flares and the variations of space weather. However, after many years of solar corona studies, there is still no direct and continuous way to measure and monitor the solar magnetic-field strength. We present here a scheme that allows such a measurement, based on a careful study of an exotic class of atomic transitions, known as magnetic induced transitions, in Fe9+. In this contribution we present a first application of this methodology and determine a value of the coronal field strength using the spectroscopic data from Hinode.
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| 20. |
- Wenxian, Li, et al.
(författare)
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A Novel Method to Determine Magnetic Fields in low-density Plasma eg Solar Flares Facilitated Through Accidental Degeneracy of Quantum States in Fe 9
- 2015
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Ingår i: Astrophysical Journal. - : Bibliopolis, Edizioni di Filosofia e Scienze. - 0004-637X .- 1538-4357. ; 807:1
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Tidskriftsartikel (refereegranskat)abstract
- We propose a new method to determine magnetic fields, by using the magnetic-field-induced electric dipole transition 3p4 3d 4D 7 2 3p P 5 2 3 2 in Fe9+ ions. This ion has a high abundance in astrophysical plasma and is therefore well suited for direct measurements of even rather weak fields in, e.g., solar flares. This transition is induced by an external magnetic field and its rate is proportional to the square of the magnetic field strength. We present theoretical values for what we will label the reduced rate and propose that the critical energy difference between the upper level in this transition and the close-to-degenerate 3p4 3d 4D 5 2 should be measured experimentally since it is required to determine the relative intensity of this magnetic line for different magnetic fields.
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| 21. |
- Zhao, R., et al.
(författare)
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The M1 ground state fine structure transition in Ag-like Yb
- 2014
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Ingår i: Journal of Physics B: Atomic, Molecular and Optical Physics. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 47:18
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Tidskriftsartikel (refereegranskat)abstract
- In our previous work, the agreement between the theoretical and measured wavelength for the 4f-M1 transition of Ag-like W shed light on the importance of a careful treatment of all core-valence correlation effects to obtain a reliable value of this fine structure energy separation. To confirm these results and extend the analysis isoelectronically, we have undertaken an experimental and theoretical study of the same M1 transition in Ag-like Yb. The measured wavelength for this M1 transition is 515.77 +/- 0.10 nm (515.91 nm in vacuum) which agrees well with our ab initio theoretical value of 515.48 nm.
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