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  • Elding, Lars Ivar, et al. (author)
  • Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters
  • 1998
  • In: Chemical Communications. - : Royal Society of Chemistry (RSC). - 1364-548X .- 1359-7345. ; 1998:24, s. 2721-2722
  • Journal article (peer-reviewed)abstract
    • Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.
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