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Enumeration	Reference	Cover	Find
1.	Aad, G., et al. (author) 2012 swepub:Mat__t (peer-reviewed)
2.	Stokes, F.A., et al. (author) Structure and Bonding of the Manganese(II) Phosphide Complex (t-BuPH(2))(eta(5)-Cp)Mn{mu-(t-BuPH)}(2)Mn(Cp)(t-BuPH(2)) 2012 In: Organometallics. - : American Chemical Society (ACS). - 0276-7333 .- 1520-6041. ; 31:1, s. 23-26 Journal article (peer-reviewed)abstract Rather than achieving bis-deprotonation of the phosphine, reaction of Cp2Mn (Cp = cyclopentadienyl) with t-BuPH2 at room temperature yields monodeprotonation of half of the available phosphine in the product (t-BuPH2)(η5-Cp)Mn{μ-(t-BuPH)}2Mn(Cp)(t-BuPH2) (1). This complex comprises a Mn(II) phosphide and is a dimer in the solid state, containing a Mn2P2 diamond core. Consistent with the observation of a relatively short intermetal distance of 2.8717(4) Å in 1, DFT analysis of the full structure points to a singlet ground state stabilized by a direct Mn–Mn single bond. This is in line with the diamagnetic character of 1 and an 18-electron count at Mn.

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Author/Editor: Aad, G (1); Abbott, B. (1); Abdallah, J (1); Abdinov, O (1); Zwalinski, L. (1); Gregersen, K. (1); show more...; Abi, B. (1); Abramowicz, H. (1); Abreu, H. (1); Adams, D. L. (1); Adelman, J. (1); Adomeit, S. (1); Adye, T. (1); Aielli, G. (1); Akimoto, G. (1); Akimov, A. V. (1); Albert, J. (1); Albrand, S. (1); Aleksa, M. (1); Aleksandrov, I. N. (1); Alexander, G. (1); Alexandre, G. (1); Alexopoulos, T. (1); Alhroob, M. (1); Alimonti, G. (1); Alison, J. (1); Allport, P. P. (1); Almond, J. (1); Aloisio, A. (1); Gonzalez, B. Alvarez (1); Alviggi, M. G. (1); Amako, K. (1); Amelung, C. (1); Amorim, A. (1); Amram, N. (1); Anastopoulos, C. (1); Ancu, L. S. (1); Andari, N. (1); Andeen, T. (1); Anders, G. (1); Anderson, K. J. (1); Andreazza, A. (1); Andrei, V. (1); Angerami, A. (1); Anghinolfi, F. (1); Anjos, N. (1); Annovi, A. (1); Antonaki, A. (1); Antonelli, M. (1); Antonov, A. (1); show less...

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