| 1. |
- Chen, Hong, et al.
(författare)
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PKU-3 : An HCI-Inclusive Aluminoborate for Strecker Reaction Solved by Combining RED and PXRD
- 2015
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Ingår i: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 0002-7863 .- 1520-5126. ; 137:22, s. 7047-7050
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Tidskriftsartikel (refereegranskat)abstract
- A novel microporous aluminoborate, denoted as PKU-3, was prepared by the boric acid flux method. The structure of PKU-3 was determined by combining the rotation electron diffraction and synchrotron powder X-ray diffraction data with well resolved ordered Cl- ions in the channel. Composition and crystal structure analysis showed that there are both proton and chlorine ions in the channels. Part of these protons and chlorine ions can be washed away by basic solutions to activate the open pores. The washed PKU-3 can be used as an efficient catalyst in the Strecker reaction with yields higher than 90%.
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| 2. |
- Li, Chunmei, et al.
(författare)
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A facile approach to ZnO/CdS nanoarrays and their photocatalytic and photoelectrochemical properties
- 2013
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Ingår i: Applied Catalysis B. - : Elsevier BV. - 0926-3373 .- 1873-3883. ; 138, s. 175-183
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Tidskriftsartikel (refereegranskat)abstract
- ZnO nanorods were successfully deposited on Transparent Conductive Oxide (TCO) glass by electrochemical deposition, during which initial pulse potential proves important for the fast nucleation and even distribution of ZnO. CdS nanoparticles were coated outside the as-prepared ZnO nanorods by chemical-bath deposition forming ZnO/CdS nanoarrays. The nanoarrays were characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), ultraviolet-visible (UV-vis) spectroscopy, and photoelectrochemistry. The short-circuit current density (J(sc)) of some ZnO/CdS sample showed over 3.3 mA/cm(2) under solar-simulated illumination. The ZnO/CdS nanoarrays showed promising photocatalytic activity with respect to the degradation of Eriochrome Black T (EBT). The relatively high photoelectrochemical properties and photocatalytic performance under visible light irradiation can be ascribed to the enhanced visible light harvest from CdS and charge separation by the coupling of the semiconductors. The combination of electrodeposition and chemical-bath deposition can provide a simple and facile approach to the fabrication of one-dimensional nanocomposites.
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| 3. |
- Li, Chunmei, et al.
(författare)
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An essential role for DYF-11/MIP-T3 in assembling functional intraflagellar transport complexes
- 2008
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Ingår i: PLOS Genetics. - : Public Library of Science (PLoS). - 1553-7390 .- 1553-7404. ; 4:3, s. e1000044-
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Tidskriftsartikel (refereegranskat)abstract
- MIP-T3 is a human protein found previously to associate with microtubules and the kinesin-interacting neuronal protein DISC1 ( Disrupted-in-Schizophrenia 1), but whose cellular function(s) remains unknown. Here we demonstrate that the C. elegans MIP-T3 ortholog DYF-11 is an intraflagellar transport (IFT) protein that plays a critical role in assembling functional kinesin motor-IFT particle complexes. We have cloned a loss of function dyf-11 mutant in which several key components of the IFT machinery, including Kinesin-II, as well as IFT subcomplex A and B proteins, fail to enter ciliary axonemes and/or mislocalize, resulting in compromised ciliary structures and sensory functions, and abnormal lipid accumulation. Analyses in different mutant backgrounds further suggest that DYF-11 functions as a novel component of IFT subcomplex B. Consistent with an evolutionarily conserved cilia-associated role, mammalian MIP-T3 localizes to basal bodies and cilia, and zebrafish mipt3 functions synergistically with the Bardet-Biedl syndrome protein Bbs4 to ensure proper gastrulation, a key cilium- and basal body-dependent developmental process. Our findings therefore implicate MIP-T3 in a previously unknown but critical role in cilium biogenesis and further highlight the emerging role of this organelle in vertebrate development.
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| 4. |
- Xia, Shaopan, et al.
(författare)
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Distribution, sources, and decomposition of soil organic matter along a salinity gradient in estuarine wetlands characterized by C:N ratio, δ13C-δ15N, and lignin biomarker
- 2021
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Ingår i: Global Change Biology. - : John Wiley & Sons. - 1354-1013 .- 1365-2486. ; 27:2, s. 417-434
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Tidskriftsartikel (refereegranskat)abstract
- Despite increasing recognition of the critical role of coastal wetlands in mitigating climate change, sea‐level rise, and salinity increase, soil organic carbon (SOC) sequestration mechanisms in estuarine wetlands remain poorly understood. Here, we present new results on the source, decomposition, and storage of SOC in estuarine wetlands with four vegetation types, including single Phragmites australis (P, habitat I), a mixture of P. australis and Suaeda salsa (P + S, habitat II), single S. salsa (S, habitat III), and tidal flat (TF, habitat IV) across a salinity gradient. Values of δ13C increased with depth in aerobic soil layers (0–40 cm) but slightly decreased in anaerobic soil layers (40–100 cm). The δ15N was significantly enriched in soil organic matter at all depths than in the living plant tissues, indicating a preferential decomposition of 14N‐enriched organic components. Thus, the kinetic isotope fractionation during microbial degradation and the preferential substrate utilization are the dominant mechanisms in regulating isotopic compositions in aerobic and anaerobic conditions, respectively. Stable isotopic (δ13C and δ15N), elemental (C and N), and lignin composition (inherited (Ad/Al)s and C/V) were not completely consistent in reflecting the differences in SOC decomposition or accumulation among four vegetation types, possibly due to differences in litter inputs, root distributions, substrate quality, water‐table level, salinity, and microbial community composition/activity. Organic C contents and storage decreased from upstream to downstream, likely due to primarily changes in autochthonous sources (e.g., decreased onsite plant biomass input) and allochthonous materials (e.g., decreased fluvially transported upland river inputs, and increased tidally induced marine algae and phytoplankton). Our results revealed that multiple indicators are essential to unravel the degree of SOC decomposition and accumulation, and a combination of C:N ratios, δ13C, δ15N, and lignin biomarker provides a robust approach to decipher the decomposition and source of sedimentary organic matter along the river‐estuary‐ocean continuum.
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| 5. |
- Zhang, Heng, et al.
(författare)
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From Solid-Solution Electrodes and the Rocking-Chair Concept to Today's Batteries
- 2020
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Ingår i: Angewandte Chemie - International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 59:2, s. 534-538
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Tidskriftsartikel (refereegranskat)abstract
- Lithium-ion batteries (LIBs) have become ubiquitous power sources for small electronic devices, electric vehicles, and stationary energy storage systems. Despite the success of LIBs which is acknowledged by their increasing commodity market, the historical evolution of the chemistry behind the LIB technologies is laden with obstacles and yet to be unambiguously documented. This Viewpoint outlines chronologically the most essential findings related to today's LIBs, including commercial electrode and electrolyte materials, but furthermore also depicts how the today popular and widely emerging solid-state batteries were instrumental at very early stages in the development of LIBs.
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