| 1. |
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- 2019
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Tidskriftsartikel (refereegranskat)
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| 2. |
- Liu, Tao, et al.
(författare)
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16% efficiency all-polymer organic solar cells enabled by a finely tuned morphology via the design of ternary blend
- 2021
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Ingår i: Joule. - : CELL PRESS. - 2542-4351. ; 5:4, s. 914-930
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Tidskriftsartikel (refereegranskat)abstract
- A SUMMARY There is an urgent demand for all-polymer organic solar cells (AP-OSCs) to gain higher efficiency. Here, we successfully improve the performance to 16.09% by introducing a small amount of BN-T, a B <- N-type polymer acceptor, into the PM6:PY-IT blend. It has been found that BN-T makes the active layer, based on the PM6:PY-IT:BN-T ternary blend, more crystalline but meanwhile slightly reduces the phase separation, leading to enhancement of both exciton harvesting and charge transport. From a thermodynamic viewpoint, BN-T prefers to reside between PM6 and PY-IT, and the fraction of this fine-tunes the morphology. Besides, a significantly reduced nonradiative energy loss occurs in the ternary blend, along with the coexistence of energy and charge transfer between the two acceptors. The progressive performance facilitated by these improved properties demonstrates that AP-OSCs can possibly comparably efficient with those based on small molecule acceptors, further enhancing the competitiveness of this device type.
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| 3. |
- He, Chengliang, et al.
(författare)
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Asymmetric electron acceptor enables highly luminescent organic solar cells with certified efficiency over 18%
- 2022
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Ingår i: Nature Communications. - : NATURE PORTFOLIO. - 2041-1723. ; 13:1
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Tidskriftsartikel (refereegranskat)abstract
- Enhancing the luminescence property without sacrificing the charge collection is one key to high-performance organic solar cells (OSCs), while limited by the severe non-radiative charge recombination. Here, we demonstrate efficient OSCs with high luminescence via the design and synthesis of an asymmetric non-fullerene acceptor, BO-5Cl. Blending BO-5Cl with the PM6 donor leads to a record-high electroluminescence external quantum efficiency of 0.1%, which results in a low non-radiative voltage loss of 0.178 eV and a power conversion efficiency (PCE) over 15%. Importantly, incorporating BO-5Cl as the third component into a widely-studied donor:acceptor (D:A) blend, PM6:BO-4Cl, allows device displaying a high certified PCE of 18.2%. Our joint experimental and theoretical studies unveil that more diverse D:A interfacial conformations formed by asymmetric acceptor induce optimized blend interfacial energetics, which contributes to the improved device performance via balancing charge generation and recombination. High-performance organic solar cells call for novel designs of acceptor molecules. Here, He et al. design and synthesize a non-fullerene acceptor with an asymmetric structure for diverse donor:acceptor interfacial conformations and report a certificated power conversion efficiency of 18.2%.
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| 4. |
- Hu, Jutao, et al.
(författare)
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The origin of anomalous hydrogen occupation in high entropy alloys
- 2022
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Ingår i: Journal of Materials Chemistry A. - : Royal Society of Chemistry (RSC). - 2050-7488 .- 2050-7496. ; 10:13, s. 7228-7237
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Tidskriftsartikel (refereegranskat)abstract
- Metal hydrogen storage materials have been the focus of intensive research in the field of hydrogen-based economy. An outstanding question is that the number of hydrogen atoms accommodated in metal hydrides is generally much below the number of interstices, which limits their hydrogen storage capacities. Unlike traditional FCC metal hydrides where hydrogen can only occupy tetrahedral interstices, this study demonstrates that hydrogen can also occupy octahedral interstices in FCC high entropy alloy (HEA) hydrides, which leads to the violation of the Switendick criterion. For Ti25V25Nb25Ta25 and Ti25V25Nb25Zr25 HEAs, nearly 20% and 17.5% of octahedral interstices can be occupied by hydrogen, respectively. The anomalous hydrogen occupation mainly originates from the intrinsic electron delocalization between hydrogen atoms in HEA hydrides, which presents a sharp contrast to traditional metal hydrides. Such electron delocalization decreases repulsive interactions between hydrogens and promotes the electron localization at octahedral interstices. Additionally, this study reveals that hydrogen occupation at octahedral interstices enhances the structural disordering and decreases the thermal stability of HEA hydrides, which will be beneficial to reduce the dehydrogenation temperature. The presented results may provide a new strategy for the design of high-density storage materials.
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| 5. |
- Zhou, Xuming, et al.
(författare)
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Research on Gob-Side Entry Retaining Mining of Fully Mechanized Working Face in Steeply Inclined Coal Seam: A Case in Xinqiang Coal Mine
- 2022
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Ingår i: Sustainability. - : MDPI. - 2071-1050. ; 14:16
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Tidskriftsartikel (refereegranskat)abstract
- As a kind of non-coal pillar roadway support technique, gob-side entry retaining is of great significance to improve the production efficiency of a fully mechanized working face. However, the construction of the roadway is often subject to the surrounding rock conditions, the application is mainly concentrated in the nearly horizontal and gently inclined coal seam conditions, and the application in the steeply inclined coal seam conditions is relatively less. This paper is based on the gob-side entry retaining roadway construction of the 58# upper right 3# working face in the fifth district of Xinqiang Coal Mine, and describes the investigation in which we measured the advanced abutment stress, mining stress, and roof stress and analyzed the moving rule of roof. On this basis, in this work, we determined the filling parameters and process and investigated the filling effect from the perspective of the deformation of the filling body and the surrounding rock. The results show that the influence range of the advanced abutment stress in the working face is about 20~25 m, the stress in the upper part is intense, and stress in the middle and lower parts are relaxed. The setting load, the cycle-end resistance, and the time-weighted mean resistance at the upper end of working face along the direction of length are the largest, followed by the middle part, and the lower end is the minimum. When exploiting the steep inclined coal seam, the upper part of the working face is more active than the lower part, and the damaging range of overlaying strata is mainly in the upper part of the goaf. With this research, we established the filling mining process in steeply inclined coal seams and determined the relevant parameters. The gangue cement mortar filling can ensure the deformation of the filling body, the surrounding rock of the roadway is small in the process of roadway retention, and the stress of the filling body is also small, which ensure the successful retention of the roadway. This study verifies the possibility of repair-less exploitation and provides a reference for the popularization and application of the gob-side entry retaining technique in steep inclined coal seam.
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| 6. |
- Hu, Jutao, et al.
(författare)
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Effects of NH4+ doping on the hydrogen storage properties of metal hydrides
- 2023
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Ingår i: International journal of hydrogen energy. - : Elsevier Ltd. - 0360-3199 .- 1879-3487. ; 48:50, s. 19153-19159
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Tidskriftsartikel (refereegranskat)abstract
- Doping can modify the properties of metal hydrogen storage materials significantly. Currently, the metal doping is a frequent strategy, while the non-metal cation doping has not been examined extensively so far. In this study, the effects of NH4+ doping on the hydrogen storage properties of different metal hydrides, including TiH2, Ti0·25V0·25Nb0·25Zr0·25H2, Ti0·5V0·5H2 and VH2, are investigated by first-principles calculations. It is found that the NH4+ presents a good affinity for metal hydrides and the NH4+ incorporation leads to charge redistribution and formation of dihydrogen bond. Furthermore, the NH4+ doping in metal hydrides is favorable for enhancing the hydrogen storage capacity and decreasing the thermal stability simultaneously. The possible reason for the NH4+ doping induced destabilization in metal hydrides is the relatively weak interaction between NH4+ and hydrogen atoms.
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| 7. |
- Qi, Zhenyu, et al.
(författare)
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Blueshifting the Absorption of a Small -Molecule Donor and Using it as the Third Component to Achieve High-Efficiency Ternary Organic Solar Cells
- 2022
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Ingår i: Solar RRL. - : WILEY-V C H VERLAG GMBH. - 2367-198X. ; 6:9
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Tidskriftsartikel (refereegranskat)abstract
- Adding a small-molecule donor (SMD) to state-of-the-art nonfullerene organic solar cells (OSCs) is demonstrated as a useful strategy to construct ternary organic solar cells, as SMDs typically have high crystallinity and can tune charge transport properties of OSCs. However, the absorption of most SMDs overlaps with typical donor polymers (e.g., PM6), which is against the general guidelines of adopting materials with complementary absorption in ternary OSCs. Herein, the absorption of state-of-art SMDs (BTR-CI) by linking the beta position of the outer thiophene to the alpha position of the inner thiophene unit is intentionally blueshifted. The resulting molecule beta-S1 shows a maximum absorption peak at 505 nm in the film state, which exhibits wider bandgap and shows complementary absorption with the host system (PM6:Y6). The corresponding ternary OSCs with 20%wt beta-S1 show significantly enhanced efficiency from 16.2% to 17.1% due to the increased short-circuit current (J(sc)) and improved fill factor (FF). Herein, an effective strategy to design SMDs with both wider bandgaps and higher crystallinity for high-performance ternary OSCs is presented.
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| 8. |
- Sun, Xiaoyu, et al.
(författare)
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Revealing microstructural degradation mechanism induced by interdiffusion between Amdry365 coating and IN792 superalloy
- 2024
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Ingår i: Materials and Design. - : ELSEVIER SCI LTD. - 1873-4197 .- 0264-1275. ; 241
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Tidskriftsartikel (refereegranskat)abstract
- Metallic coatings are widely employed to improve the oxidation resistance of superalloys. However, the interdiffusion between the metallic coatings and the superalloys leads to microstructural degradation in both. Some of the underlying degradation mechanisms are still elusive, e.g., the γ′ (Ni3Al) phase depletion in superalloys, where a large amount of γ′ precipitates are dissolved in the γ matrix even though the incoming Al from coatings indeed increases the Al content. Here, we investigated the interdiffusion behavior between the Amdry365 coating and the IN792 superalloy at 1100 °C, using multiple microscopic techniques and thermodynamics calculations. Our results showed an excellent agreement between experiments and thermodynamics simulations, indicating the dominant role of Al on the initial diffusion-induced phase transitions. We proposed the Al-Cr interference effect to account for the pile-up behavior of Cr and the reduced Al content near the coating/superalloy interface. The local phase equilibrium calculations revealed that the γ′ depletion in the superalloy is primarily attributed to the loss of γ′-forming elements, such as Ta and Ti. Our findings opened up an avenue for studies on the superalloy/coating interdiffusion, contributing to reducing this damaging impact.
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| 9. |
- Wei, Zhongbao, et al.
(författare)
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Multi-stage state of health estimation of lithium-ion battery with high tolerance to heavily-partial charging
- 2022
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Ingår i: IEEE Transactions on Power Electronics. - 0885-8993 .- 1941-0107. ; 37:6, s. 7432-7442
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Tidskriftsartikel (refereegranskat)abstract
- State of health (SOH) is critical to the management of lithium-ion battery (LIB) due to its deep insight into the health diagnostic and protection. However, the absence of complete charging data, which is common in practice, risks impairing the charging-based SOH estimators. This paper proposes a multi-stage SOH estimation method with a broad scope of applications, including the unfavorable but practical scenarios of heavily-partial charging. In particular, different sets of health indicators (HIs), covering both the morphological IC features and the voltage entropy information, are extracted from the partial CC charging data with different initial charging voltage to characterize the aging status. Following this endeavor, artificial neural network (ANN)-based HI fusion is proposed to estimate the SOH of LIB precisely in real time. The proposed method is evaluated with long-term aging experiments performed on different types of LIBs. Results validate several superior merits of the proposed method, including high estimation accuracy, high tolerance to partial charging, strong robustness to cell inconsistency, and wide generality to different battery types.
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| 10. |
- Amer, Ramses, 1961-, et al.
(författare)
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ASEAN, China and the South China Sea Dispute Management
- 2012
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Annan publikation (populärvet., debatt m.m.)abstract
- Managing the situation in the South China Sea has proven to be difficult. In this context the role that the Association of Southeast Asian Nations (ASEAN) can play is of particular interest. Some of the complexities involved were displayed at the recent ASEAN meetings held in Cambodia.
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| 11. |
- Amer, Ramses, 1961-, et al.
(författare)
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Dispute Settlement in Practice – Assessing Progress and Challenges in the South China Sea Region
- 2012
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- The paper examines dispute settlement in practice through an overview of developments in the South China Sea region. It first studies dispute settlement arrangements from the international legal perspectives by examining the Charter of the United Nations and the 1982 United Nations Convention on the Law of the Sea. As a case study, the South China Sea region is assessed in regard to progress made and challenges persisted in dispute settlement and conflict management. The progress made is outlined through an overview of settled and managed territorial disputes in the South China Sea and adjacent area, followed by an analysis of settlement and management approaches. The challenge of the unsettled disputes is analysed and assessed by highlighting both the nature of the disputes and the efforts in managing them. The paper is concluded by a broader assessment of the progress made in terms of dispute settlement as well as of the remaining challenges in the South China Sea region from the perspectives of dispute settlement, in light of the international legal mechanisms.
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| 12. |
- Amer, Ramses, 1961-, et al.
(författare)
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Enhancing Maritime Peace in East Asia Through the Charter of the United Nations : Non-Use of Force and Peaceful Settlement of Dispute
- 2012
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- The paper investigates how maritime peace in East Asia can be enhanced through the Charter of the United Nations. This is done through an examination of two key norms of the Charter, the prohibition of the use of force in inter-state relations and the peaceful settlement of disputes. The empirical application of these principles and their possible impact on maritime peace in the East Asia region is studied through the foreign policy of China and through the principles governing the Association of Southeast Asian Nations (ASEAN). This is motivated by the fact that both China and ASEAN put strong emphasis on non-use of force in inter-state relations and peaceful settlement of inter-state disputes. The paper examines the possible impact of the policies of the major external actor, i.e. the United States of America (USA). The paper is concluded by a broader discussion on the linkage between non-use of force and peaceful settlement of disputes and the promotion of maritime peace in East Asia.
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| 13. |
- Amer, Ramses, 1961-, et al.
(författare)
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Recent Developments in the South China Sea : An Assessment of the Core Bilateral Relationship Between China and Vietnam
- 2012
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Ingår i: Maritime Security Issues in the South China Sea and the Arctic. - Beijing : China Democracy and Legal System Publishing House. - 9787516200360 ; , s. 41-75
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Bokkapitel (refereegranskat)abstract
- This study examines recent developments in the South China Sea through a case study of the China-Vietnam relationship. The study outlines and examines how China and Vietnam deal with tensions relating to their territorial disputes in the South China Sea. It looks specifically at the tension caused by incidents in late May and early June 2011 and how the tension was brought under control by the two countries. These developments are examined in the broader context of the Sino-Vietnamese approach to managing border disputes since full normalisation of relations in late 1991. The implications and lessons drawn from the developments in May-June 2011 as well as from the broader period since late 1991 are outlined. Furthermore, the challenges for China and Vietnam to properly manage their disputes and related tension in the South China Sea are discussed.
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| 14. |
- Amer, Ramses, 1961-, et al.
(författare)
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Recent Developments in the South China Sea – Assessing the China-Vietnam and China-Philippines Relationships
- 2012
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- The paper examines recent developments in the South China Sea through two bilateral relationships – China-Vietnam and China-Philippines – respectively. The paper first outlines recent developments in both bilateral relations relating to the South China Sea. The nature of the events causing tension is identified and the way in which the events have been managed is examined. Particular attention is devoted to the management or lack of management mechanisms in the two bilateral relationships. Possible differences between the two relationships will be explored with the aim of assessing whether relevant variations in management mechanisms can be explained by such differences. The paper is concluded by a summary of the main findings and some observations.
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| 15. |
- Chang, Keke, et al.
(författare)
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Considerations on Circuit Design and Data Acquisition of a Portable Surface Plasmon Resonance Biosensing System
- 2015
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Ingår i: Sensors. - : MDPI AG. - 1424-8220. ; 15:8, s. 20511-20523
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Tidskriftsartikel (refereegranskat)abstract
- The aim of this study was to develop a circuit for an inexpensive portable biosensing system based on surface plasmon resonance spectroscopy. This portable biosensing system designed for field use is characterized by a special structure which consists of a microfluidic cell incorporating a right angle prism functionalized with a biomolecular identification membrane, a laser line generator and a data acquisition circuit board. The data structure, data memory capacity and a line charge-coupled device (CCD) array with a driving circuit for collecting the photoelectric signals are intensively focused on and the high performance analog-to-digital (A/D) converter is comprehensively evaluated. The interface circuit and the photoelectric signal amplifier circuit are first studied to obtain the weak signals from the line CCD array in this experiment. Quantitative measurements for validating the sensitivity of the biosensing system were implemented using ethanol solutions of various concentrations indicated by volume fractions of 5%, 8%, 15%, 20%, 25%, and 30%, respectively, without a biomembrane immobilized on the surface of the SPR sensor. The experiments demonstrated that it is possible to detect a change in the refractive index of an ethanol solution with a sensitivity of 4.99838 × 10(5) ΔRU/RI in terms of the changes in delta response unit with refractive index using this SPR biosensing system, whereby the theoretical limit of detection of 3.3537 × 10(-5) refractive index unit (RIU) and a high linearity at the correlation coefficient of 0.98065. The results obtained from a series of tests confirmed the practicality of this cost-effective portable SPR biosensing system.
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| 16. |
- Chen, Cheng, et al.
(författare)
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A novel multi-source data fusion method based on Bayesian inference for accurate estimation of chlorophyll-a concentration over eutrophic lakes
- 2021
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Ingår i: Environmental Modelling and Software. - : Elsevier BV. - 1364-8152. ; 141
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Tidskriftsartikel (refereegranskat)abstract
- A novel multi-source data fusion method based on Bayesian inference (BIF) was proposed in this study to blend the advantages of in-situ observations and remote sensing estimations for obtaining accurate chlorophyll-a (Chla) concentration in Lake Taihu (China). Two error models (additive and multiplicative) were adopted to construct the likelihood function in BIF; the BIF method was also compared with three commonly used data fusion algorithms, including linear and nonlinear regression data fusion (LRF and NLRF) and cumulative distribution function matching data fusion (CDFF). The results showed the multiplicative error model had small normalized residual errors and was a more suitable choice. The BIF method largely outperformed the data fusion algorithms of CDFF, NLRF and LRF, with the largest correlation coefficients and smallest root mean square error. Moreover, the BIF results can capture the high Chla concentrations in the northwest and the low Chla concentrations in the east of Lake Taihu.
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| 17. |
- Fan, Qunping, 1989, et al.
(författare)
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High-performance all-polymer solar cells enabled by a novel low bandgap non-fully conjugated polymer acceptor
- 2021
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Ingår i: Science in China Series B. - : Springer Nature. - 1674-7291 .- 1869-1870. ; 64, s. 1380-1388
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Tidskriftsartikel (refereegranskat)abstract
- Anon-fully conjugated polymer as a new class of acceptor materials has shown some advantages over its small molecular counterpart when used in photoactive layers for all-polymer solar cells (all-PSCs), despite a low power conversion efficiency (PCE) caused by its narrow absorption spectra. Herein, a novel non-fully conjugated polymer acceptor PFY-2TS with a low bandgap of similar to 1.40 eV was developed, via polymerizing a large pi-fused small molecule acceptor (SMA) building block (namely YBO) with a non-conjugated thioalkyl linkage. Compared with its precursor YBO, PFY-2TS retains a similar low bandgap but a higher LUMO level. Moreover, compared with the structural analog of YBO-based fully conjugated polymer acceptor PFY-DTC, PFY-2TS shows similar absorption spectrum and electron mobility, but significantly different molecular crystallinity and aggregation properties, which results in optimal blend morphology with a polymer donor PBDB-T and better device physical processes in all-PSCs. As a result, PFY-2TS-based all-PSCs achieved a PCE of 12.31% with a small energy loss of 0.56 eV enabled by the reduced non-radiative energy loss (0.24 eV), which is better than that of 11.08% for the PFY-DTC-based ones. Our work clearly demonstrated that non-fully conjugated polymers as a new class of acceptor materials are very promising for the development of high-performance all-PSCs.
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| 18. |
- Fu, Huiting, et al.
(författare)
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High Efficiency (15.8%) All-Polymer Solar Cells Enabled by a Regioregular Narrow Bandgap Polymer Acceptor
- 2021
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Ingår i: Journal of the American Chemical Society. - : AMER CHEMICAL SOC. - 0002-7863 .- 1520-5126. ; 143:7, s. 2665-2670
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Tidskriftsartikel (refereegranskat)abstract
- Y Despite the significant progresses made in all-polymer solar cells (all-PSCs) recently, the relatively low short-circuit current density (J(sc)) and large energy loss are still quite difficult to overcome for further development. To address these challenges, we developed a new class of narrow-bandgap polymer acceptors incorporating a benzotriazole (BTz)-core fused-ring segment, named the PZT series. Compared to the commonly used benzothiadiazole (BT)-containing polymer PYT, the less electron-deficient BTz renders PZT derivatives with significantly red-shifted optical absorption and up-shifted energy levels, leading to simultaneously improved J(sc) and open-circuit voltage in the resultant all-PSCs. More importantly, a regioregular PZT (PZT-gamma) has been developed to achieve higher regiospecificity for avoiding the formation of isomers during polymerization. Benefiting from the more extended absorption, better backbone ordering, and more optimal blend morphology with donor component, PZT-gamma-based all-PSCs exhibit a record-high power conversion efficiency of 15.8% with a greatly enhanced J(sc) of 24.7 mA/cm(2) and a low energy loss of 0.51 eV.
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| 19. |
- Hou, Yandong, et al.
(författare)
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Numerical simulation study of boiling critical heat flux characteristics of graphene nanofluids
- 2024
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Ingår i: Progress in nuclear energy (New series). - : Elsevier BV. - 0149-1970 .- 1878-4224. ; 172
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Tidskriftsartikel (refereegranskat)abstract
- IVR-ERVC (In-Vessel Retention – External Reactor Vessel Cooling) is a critical accident management method for ensuring the integrity of the reactor pressure vessel (RPV) lower head. One of the most crucial aspects within this method is to enhance the CHF (Critical Heat Flux) on the outer surface of the reactor pressure vessel (RPV) lower head. This paper explores the application of graphene nanofluids in IVR-ERVC. This paper uses computational fluid dynamics to numerically simulate the CHF characteristics of graphene nanofluids under different undercooling, mass flow rate, concentration, tilt angle, and gap size conditions and analyzes the impact of different factors on CHF and the coupling effects between different factors. The undercooling range is 5 K–100 K, the mass flow rate range is 150 kg/(m2∙s) to 3000 kg/(m2∙s), the concentration range is 0–1%, the inclination angle range is 0°–90°, and the gap sizes are 10 mm and 20 mm. The results show that the CHF can be effectively improved by adding nano-graphene into the base solution, and the CHF increases with the increase of subcooling degree, mass flow rate, concentration, dip Angle and gap size. Within the simulation range, the strengthening effect on CHF weakens when raising the undercooling and mass flow rate. And the larger the concentration and inclination angle within the simulation range, the better the enhancement effect on CHF. The maximum increase was 290%, while the average increase was 75.6%. This article studies the coupling effects between different parameters through numerical simulation. It can be concluded that increasing the mass flow rate weakens the enhancement of subcooling and concentration on CHF, increasing the subcooling weakens the enhancement effect of mass flow rate and concentration on CHF, and increasing the concentration enhances the enhancement effect of subcooling and mass flow rate on CHF. Enhance the mass flow rate will weaken tilt angle effect, while increasing the concentration will enhance the strengthening effect of tilt angle on CHF.
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| 20. |
- Hu, Jian, et al.
(författare)
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Residual Statistics-Based Current Sensor Fault Diagnosis for Smart Battery Management
- 2022
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Ingår i: IEEE Journal of Emerging and Selected Topics in Power Electronics. - : Institute of Electrical and Electronics Engineers (IEEE). - 2168-6777 .- 2168-6785. ; 10:2, s. 2435-2444
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Tidskriftsartikel (refereegranskat)abstract
- Current sensor fault diagnostic is critical to the safety of lithium-ion batteries (LIBs) to prevent over-charging and over-discharging. Motivated by this, this article proposes a novel residual statistics-based diagnostic method to detect two typical types of sensor faults, leveraging only the 50 current-voltage samples at the startup phase of the LIB system. In particular, the load current is estimated by using particle swarm optimization (PSO)-based model matching with measurable initial system states. The estimation residuals are analyzed statistically with Monte-Carlo simulation, from which an empirical residual threshold is generated and used for accurate current sensor fault diagnostic. The residual evaluation process is well proved with high robustness to the measurement noises and modeling uncertainties. The proposed method is validated experimentally to be effective in current sensor fault diagnosis with low miss alarm rate (MAR) and false alarm rate (FAR).
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| 21. |
- Jiang, Kui, et al.
(författare)
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Suppressed recombination loss in organic photovoltaics adopting a planar-mixed heterojunction architecture
- 2022
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Ingår i: Nature Energy. - : NATURE PORTFOLIO. - 2058-7546. ; 7:11, s. 1076-1086
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Tidskriftsartikel (refereegranskat)abstract
- At present, high-performance organic photovoltaics mostly adopt a bulk-heterojunction architecture, in which exciton dissociation is facilitated by charge-transfer states formed at numerous donor-acceptor (D-A) heterojunctions. However, the spin character of charge-transfer states originated from recombination of photocarriers allows relaxation to the lowest-energy triplet exciton (T-1) at these heterojunctions, causing photocurrent loss. Here we find that this loss pathway can be alleviated in sequentially processed planar-mixed heterojunction (PMHJ) devices, employing donor and acceptor with intrinsically weaker exciton binding strengths. The reduced D-A intermixing in PMHJ alleviates non-geminate recombination at D-A contacts, limiting the chance of relaxation, thus suppressing T-1 formation without sacrificing exciton dissociation efficiency. This resulted in devices with high power conversion efficiencies of >19%. We elucidate the working mechanisms for PMHJs and discuss the implications for material design, device engineering and photophysics, thus providing a comprehensive grounding for future organic photovoltaics to reach their full promise. Organic solar cells with a bulk-heterojunction architecture suffer from photocurrent loss driven by triplet states. Now, Jiang et al. show that sequentially deposited donor-acceptor planar-mixed heterojunctions suppress triplet formation, enabling efficiencies over 19%.
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| 22. |
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| 23. |
- Li, Jianwei, et al.
(författare)
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Freedom of Navigation: UNCLOS, Chinese Perspectives and Personal Thoughts
- 2011
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- Freedom of navigation has played a vital role for economic prosperity in East Asia by promoting seaborne trade. As activities at the sea increase, the global concerns for navigational safety and security are growing. Under the United Nations Convention on the Law of the Sea (UNCLOS), vessels are endowed with different rights and obligations when they navigate through different maritime zones, e.g. internal waters, territorial sea, exclusive economic zone and high seas. Hence freedom of navigation seems to be limited to different extents. Due to environmental and national security concerns, coastal states enact domestic laws to regulate navigation in the waters under their jurisdiction. After spelling out different navigational regimes under the UNCLOS, this paper intends to examine China’s relevant legal arrangements and some cases of practice in relation to navigation. Personal thoughts will be provided on reflections of China’s perspectives in relation to UNCLOS and beyond.
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| 24. |
- Li, Jianwei, et al.
(författare)
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Recent Practice in Dispute Settlement in the South China Sea
- 2010
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Konferensbidrag (refereegranskat)abstract
- This paper 1) traces the history of both settled and unsettled maritime disputes in the South China Sea and surrounding regions; 2) studies the potential advantages and disadvantages of various approaches to dispute management utilized in the South China Sea; and 3) examines China’s territorial claims, dispute management policy, and history of confidence-building and dispute resolution.
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| 25. |
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| 26. |
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| 27. |
- Li, Xiane, et al.
(författare)
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Mapping the energy level alignment at donor/acceptor interfaces in non-fullerene organic solar cells
- 2022
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Ingår i: Nature Communications. - : Nature Portfolio. - 2041-1723. ; 13:1
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Tidskriftsartikel (refereegranskat)abstract
- Energy level alignment (ELA) at donor-acceptor heterojunctions is of vital importance yet largely undetermined in organic solar cells. Here, authors determine the heterojunction ELA with (mono) layer-by-layer precision to understand the co-existence of efficient charge. Energy level alignment (ELA) at donor (D) -acceptor (A) heterojunctions is essential for understanding the charge generation and recombination process in organic photovoltaic devices. However, the ELA at the D-A interfaces is largely underdetermined, resulting in debates on the fundamental operating mechanisms of high-efficiency non-fullerene organic solar cells. Here, we systematically investigate ELA and its depth-dependent variation of a range of donor/non-fullerene-acceptor interfaces by fabricating and characterizing D-A quasi bilayers and planar bilayers. In contrast to previous assumptions, we observe significant vacuum level (VL) shifts existing at the D-A interfaces, which are demonstrated to be abrupt, extending over only 1-2 layers at the heterojunctions, and are attributed to interface dipoles induced by D-A electrostatic potential differences. The VL shifts result in reduced interfacial energetic offsets and increased charge transfer (CT) state energies which reconcile the conflicting observations of large energy level offsets inferred from neat films and large CT energies of donor - non-fullerene-acceptor systems.
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| 28. |
- Liu, Xin, et al.
(författare)
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Evolutionary Neural Architecture Search and Its Applications in Healthcare
- 2024
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Ingår i: CMES - Computer Modeling in Engineering & Sciences. - : Tech Science Press. - 1526-1492 .- 1526-1506. ; 139:1, s. 143-185
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Forskningsöversikt (refereegranskat)abstract
- Most of the neural network architectures are based on human experience, which requires a long and tedious trial-and-error process. Neural architecture search (NAS) attempts to detect effective architectures without human intervention. Evolutionary algorithms (EAs) for NAS can find better solutions than human-designed architectures by exploring a large search space for possible architectures. Using multiobjective EAs for NAS, optimal neural architectures that meet various performance criteria can be explored and discovered efficiently. Furthermore, hardware-accelerated NAS methods can improve the efficiency of the NAS. While existing reviews have mainly focused on different strategies to complete NAS, a few studies have explored the use of EAs for NAS. In this paper, we summarize and explore the use of EAs for NAS, as well as large-scale multiobjective optimization strategies and hardware-accelerated NAS methods. NAS performs well in healthcare applications, such as medical image analysis, classification of disease diagnosis, and health monitoring. EAs for NAS can automate the search process and optimize multiple objectives simultaneously in a given healthcare task. Deep neural network has been successfully used in healthcare, but it lacks interpretability. Medical data is highly sensitive, and privacy leaks are frequently reported in the healthcare industry. To solve these problems, in healthcare, we propose an interpretable neuroevolution framework based on federated learning to address search efficiency and privacy protection. Moreover, we also point out future research directions for evolutionary NAS. Overall, for researchers who want to use EAs to optimize NNs in healthcare, we analyze the advantages and disadvantages of doing so to provide detailed guidance, and propose an interpretable privacy-preserving framework for healthcare applications.
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| 29. |
- Liu, Xin, et al.
(författare)
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Federated Neural Architecture Search for Medical Data Security
- 2022
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Ingår i: IEEE Transactions on Industrial Informatics. - : Institute of Electrical and Electronics Engineers (IEEE). - 1551-3203 .- 1941-0050. ; 18:8, s. 5628-5636
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Tidskriftsartikel (refereegranskat)abstract
- Medical data widely exist in the hospital and personal life, usually across institutions and regions. They have essential diagnostic value and therapeutic significance. The disclosure of patient information causes people's panic, therefore, medical data security solution is very crucial for intelligent health care. The emergence of federated learning (FL) provides an effective solution, which only transmits model parameters, breaking through the bottleneck of medical data sharing, protecting data security, and avoiding economic losses. Meanwhile, the neural architecture search (NAS) has become a popular method to automatically search the optimal neural architecture for solving complex practical problems. However, few papers have combined the FL and NAS for simultaneous privacy protection and model architecture selection. Convolutional neural network (CNN) has outstanding performance in the image recognition field. Combining CNN and fuzzy rough sets can effectively improve the interpretability of deep neural networks. This article aims to develop a multiobjective convolutional interval type-2 fuzzy rough FL model based on NAS (CIT2FR-FL-NAS) for medical data security with an improved multiobjective evolutionary algorithm. We test the proposed framework on the LC25000 lung and colon histopathological image dataset. Experimental verification demonstrates that the designed multiobjective CIT2FR-FL-NAS framework can achieve high accuracy superior to state-of-the-art models and reduce network complexity under the condition of protecting medical data security.
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| 30. |
- Ma, Ruijie, et al.
(författare)
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All-polymer solar cells with over 16% efficiency and enhanced stability enabled by compatible solvent and polymer additives
- 2022
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Ingår i: Aggregate. - : Wiley. - 2692-4560 .- 2766-8541. ; 3:3
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Tidskriftsartikel (refereegranskat)abstract
- Considering the robust and stable nature of the active layers, advancing the power conversion efficiency (PCE) has long been the priority for all-polymer solar cells (all-PSCs). Despite the recent surge of PCE, the photovoltaic parameters of the state-of-the-art all-PSC still lag those of the polymer:small molecule-based devices. To compete with the counterparts, judicious modulation of the morphology and thus the device electrical properties are needed. It is difficult to improve all the parameters concurrently for the all-PSCs with advanced efficiency, and one increase is typically accompanied by the drop of the other(s). In this work, with the aids of the solvent additive (1-chloronaphthalene) and the n-type polymer additive (N2200), we can fine-tune the morphology of the active layer and demonstrate a 16.04% efficient all-PSC based on the PM6:PY-IT active layer. The grazing incidence wide-angle X-ray scattering measurements show that the shape of the crystallites can be altered, and the reshaped crystallites lead to enhanced and more balanced charge transport, reduced recombination, and suppressed energy loss, which lead to concurrently improved and device efficiency and stability.
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| 31. |
- Qin, Linqing, et al.
(författare)
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Triplet Acceptors with a D-A Structure and Twisted Conformation for Efficient Organic Solar Cells
- 2020
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Ingår i: Angewandte Chemie International Edition. - : WILEY-V C H VERLAG GMBH. - 1433-7851 .- 1521-3773. ; 59:35, s. 15043-15049
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Tidskriftsartikel (refereegranskat)abstract
- Triplet acceptors have been developed to construct high-performance organic solar cells (OSCs) as the long lifetime and diffusion range of triplet excitons may dissociate into free charges instead of net recombination when the energy levels of the lowest triplet state (T-1) are close to those of charge-transfer states ((CT)-C-3). The current triplet acceptors were designed by introducing heavy atoms to enhance the intersystem crossing, limiting their applications. Herein, two twisted acceptors without heavy atoms, analogues of Y6, constructed with large pi-conjugated core and D-A structure, were confirmed to be triplet materials, leading to high-performance OSCs. The mechanism of triplet excitons were investigated to show that the twisted and D-A structures result in large spin-orbit coupling (SOC) and small energy gap between the singlet and triplet states, and thus efficient intersystem crossing. Moreover, the energy level of T-1 is close to (CT)-C-3, facilitating the split of triplet exciton to free charges.
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| 32. |
- Sun, Huiliang, et al.
(författare)
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A Narrow-Bandgap n-Type Polymer with an Acceptor-Acceptor Backbone Enabling Efficient All-Polymer Solar Cells
- 2020
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Ingår i: Advanced Materials. - : WILEY-V C H VERLAG GMBH. - 0935-9648 .- 1521-4095. ; 32
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Tidskriftsartikel (refereegranskat)abstract
- Narrow-bandgap polymer semiconductors are essential for advancing the development of organic solar cells. Here, a new narrow-bandgap polymer acceptor L14, featuring an acceptor-acceptor (A-A) type backbone, is synthesized by copolymerizing a dibrominated fused-ring electron acceptor (FREA) with distannylated bithiophene imide. Combining the advantages of both the FREA and the A-A polymer, L14 not only shows a narrow bandgap and high absorption coefficient, but also low-lying frontier molecular orbital (FMO) levels. Such FMO levels yield improved electron transfer character, but unexpectedly, without sacrificing open-circuit voltage (V-oc), which is attributed to a small nonradiative recombination loss (E-loss,E-nr) of 0.22 eV. Benefiting from the improved photocurrent along with the high fill factor andV(oc), an excellent efficiency of 14.3% is achieved, which is among the highest values for all-polymer solar cells (all-PSCs). The results demonstrate the superiority of narrow-bandgap A-A type polymers for improving all-PSC performance and pave a way toward developing high-performance polymer acceptors for all-PSCs.
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| 33. |
- Tang, Yumin, et al.
(författare)
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Two Compatible Polymer Donors Enabling Ternary Organic Solar Cells with a Small Nonradiative Energy Loss and Broad Composition Tolerance
- 2020
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Ingår i: Solar RRL. - : Wiley-VCH Verlagsgesellschaft. - 2367-198X. ; 4:11
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Tidskriftsartikel (refereegranskat)abstract
- High-performance nonfullerene ternary organic solar cells (OSCs) with two polymer donors are less frequently reported because of the limited numbers of efficient polymer donors with good compatibility. Herein, a wide-bandgap polymer P1 with a deep-lying highest occupied molecular orbital (HOMO) level is incorporated as the third component into the benchmark PM6:Y6 binary system to fabricate ternary OSCs. The introduction of P1 not only leads to extended absorption coverage and forms a cascade-like energy level alignment but also shows excellent compatibility with PM6, resulting in a favorable morphology in the ternary blend. More importantly, P1 possesses a deeper HOMO level (-5.6 eV) than most well-known donor polymers, which enables resulting ternary OSCs with an improved open-circuit voltage. As a result, the optimized ternary OSCs with 40 wt% P1 in donors achieve a power conversion efficiency (PCE) of 16.2% with a small nonradiative recombination loss of 0.23 eV, which is among the highest values of ternary OSCs based on two polymer donors. In addition, the ternary OSCs show a broad composition tolerance with a high PCE of over 14% throughout the whole blend ratios. These results provide an effective approach to fabricate efficient ternary OSCs by synergizing two wide-bandgap polymer donors.
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| 34. |
- Xu, Xiaoxiang, et al.
(författare)
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Nanocarriers for Inner Ear Disease Therapy
- 2021
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Ingår i: Frontiers in Cellular Neuroscience. - : Frontiers Media SA. - 1662-5102. ; 15
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Forskningsöversikt (refereegranskat)abstract
- Hearing loss is a common disease due to sensory loss caused by the diseases in the inner ear. The development of delivery systems for inner ear disease therapy is important to achieve high efficiency and reduce side effects. Currently, traditional drug delivery systems exhibit the potential to be used for inner ear disease therapy, but there are still some drawbacks. As nanotechnology is developing these years, one of the solutions is to develop nanoparticle-based delivery systems for inner ear disease therapy. Various nanoparticles, such as soft material and inorganic-based nanoparticles, have been designed, tested, and showed controlled delivery of drugs, improved targeting property to specific cells, and reduced systemic side effects. In this review, we summarized recent progress in nanocarriers for inner ear disease therapy. This review provides useful information on developing promising nanocarriers for the efficient treatment of inner ear diseases and for further clinical applications for inner ear disease therapy.
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| 35. |
- Yazawa, Aki, et al.
(författare)
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The Effects of Season of Birth on the Inflammatory Response to Psychological Stress in Hainan Island, China.
- 2015
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Ingår i: PLOS ONE. - : Public Library of Science (PLoS). - 1932-6203. ; 10:10
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Tidskriftsartikel (refereegranskat)abstract
- Season of birth (SOB) has been investigated as one of the environmental factors that might epigenetically determine the physiology of individuals. This study investigated the role of SOB in the association between Quality of Life (QOL), a proxy of psychological stress status, and C-reactive protein (CRP) concentration (i.e., inflammatory status) among 1,085 adults (aged 20-57 years old) in Hainan Island, China. High sensitivity CRP concentration was measured in dried blood spot samples, while the abbreviated version of the World Health Organization's QOL questionnaire was used to gather information on six QOL domains. Analysis stratified by three historically distinct age groups revealed a significant association between CRP concentration, SOB, QOL and an interaction between SOB and QOL among the youngest and oldest groups. In the oldest group, those born in the dry season had a higher CRP concentration with worse QOL whereas in the youngest group, there was a higher CRP concentration with better QOL. Annual per capita rice production, a proxy of population nutritional status in the year of birth, was found to predict CRP concentration only among the second oldest group. These findings suggest that the early environment might affect the immune response to psychological stress in adulthood and that its effect may differ by the time period in which people were born.
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| 36. |
- Zhang, Xin, et al.
(författare)
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High-Performance All-Small-Molecule Organic Solar Cells Enabled by Regio-Isomerization of Noncovalently Conformational Locks
- 2022
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Ingår i: Advanced Functional Materials. - : WILEY-V C H VERLAG GMBH. - 1616-301X .- 1616-3028. ; 32:19
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Tidskriftsartikel (refereegranskat)abstract
- The power conversion efficiencies (PCEs) of organic solar cells (OSCs) have surpassed 19% thanks to the innovation of polymer donors and molecular acceptors. However, the batch-to-batch variations in polymer materials are detrimental to the reproducibility of the device performance. In comparison, small-molecule donors (SMDs) possess some unique advantages, such as well-defined molecular weights, easy purification, and excellent batch-to-batch repeatability. Herein, a pair of regioisomeric SMDs (BT-O1 and BT-O2) has been synthesized with alkoxy groups as S center dot center dot center dot O noncovalently conformational locks (NoCLs) at the inner and outer position, respectively. Theoretical and experimental results reveal that the regioisomeric effect has a significant influence on the light-harvest ability, energy levels, molecular geometries, internal reorganization energy, and packing behaviors for the two SMDs. As a result, BT-O2-based binary device shows an impressive PCE of 13.99%, much higher than that of BT-O1 based one (4.07%), due to the better-aligned energy level, more balanced charge transport, less charge recombination, lower energy loss, and more favorable phase separation. Furthermore, the fullerene derivative PC71BM is introduced into BT-O2:H3 as the third component to achieve a notable PCE of 15.34% (certified 14.6%). Overall, this work reveals that NoCLs is a promising strategy to achieve high-performance SMDs for all-small-molecule OSCs.
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| 37. |
- Zhang, Xin, et al.
(författare)
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High-Performance Noncovalently Fused-Ring Electron Acceptors for Organic Solar Cells Enabled by Noncovalent Intramolecular Interactions and End-Group Engineering
- 2021
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Ingår i: Angewandte Chemie International Edition. - : WILEY-V C H VERLAG GMBH. - 1433-7851 .- 1521-3773. ; 60:22, s. 12475-12481
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Tidskriftsartikel (refereegranskat)abstract
- Noncovalently fused-ring electron acceptors (NFREAs) have attracted much attention in recent years owing to their advantages of simple synthetic routes, high yields and low costs. However, the efficiencies of NFREAs based organic solar cells (OSCs) are still far behind those of fused-ring electron acceptors (FREAs). Herein, a series of NFREAs with S...O noncovalent intramolecular interactions were designed and synthesized with a two-step synthetic route. Upon introducing pi-extended end-groups into the backbones, the electronic properties, charge transport, film morphology, and energy loss were precisely tuned by fine-tuning the degree of multi-fluorination. As a result, a record PCE of 14.53 % in labs and a certified PCE of 13.8 % for NFREAs based devices were obtained. This contribution demonstrated that combining the strategies of noncovalent conformational locks and pi-extended end-group engineering is a simple and effective way to explore high-performance NFREAs.
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| 38. |
- Zhang, Xin, et al.
(författare)
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Side-Chain Engineering for Enhancing the Molecular Rigidity and Photovoltaic Performance of Noncovalently Fused-Ring Electron Acceptors
- 2021
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Ingår i: Angewandte Chemie International Edition. - : WILEY-V C H VERLAG GMBH. - 1433-7851 .- 1521-3773. ; 60:32, s. 17720-17725
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Tidskriftsartikel (refereegranskat)abstract
- Side-chain engineering is an effective strategy to regulate the solubility and packing behavior of organic materials. Recently, a unique strategy, so-called terminal side-chain (T-SC) engineering, has attracted much attention in the field of organic solar cells (OSCs), but there is a lack of deep understanding of the mechanism. Herein, a new noncovalently fused-ring electron acceptor (NFREA) containing two T-SCs (NoCA-5) was designed and synthesized. Introduction of T-SCs can enhance molecular rigidity and intermolecular pi-pi stacking, which is confirmed by the smaller Stokes shift value, lower reorganization free energy, and shorter pi-pi stacking distance in comparison to NoCA-1. Hence, the NoCA-5-based device exhibits a record power conversion efficiency (PCE) of 14.82 % in labs and a certified PCE of 14.5 %, resulting from a high electron mobility, a short charge-extraction time, a small Urbach energy (E-u), and a favorable phase separation.
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| 39. |
- Zhou, Hongxu, et al.
(författare)
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Model optimization of a high-power commercial PEMFC system via an improved grey wolf optimization method
- 2024
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Ingår i: Fuel. - 0016-2361. ; 357:Part A
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Tidskriftsartikel (refereegranskat)abstract
- Proton exchange membrane fuel cell (PEMFC) models are conventionally established with a set of parameters identified under steady-state operating conditions. However, such an approach is insufficient to accurately capture the dynamic characteristics of multi-parameter changes in real-world scenarios. This paper develops a semi-empirical model for a 110-kW commercial PEMFC system based on its dynamic operation data to remedy the defects. To improve the fitting accuracy of the semi-empirical PEMFC model, an improved grey wolf optimization (IGWO) algorithm is proposed for model parameter identification. The IGWO algorithm adopts chaotic mapping to optimize the initial population distribution, and a random walk strategy is incorporated to boost the local search ability of the traditional grey wolf optimization (GWO) algorithm. The effectiveness of this IGWO algorithm in optimizing the semi-empirical model is experimentally verified on the 110-kW PEMFC system under highly dynamic operating conditions. Results show that the proposed IGWO algorithm can effectively identify the semi-empirical model’s parameters, establishing a stable and robust model that outperforms those based on traditional metaheuristic algorithms such as GWO, particle swarm optimization, and genetic algorithm. The demonstrated improvement renders it as better suited for optimizing PEMFC semi-empirical models under real-world operating conditions.
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