| 1. |
- Darmastuti, Zhafira
(författare)
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SiCFET gassensors : theory, developent, and applications to flue gas cleaning processes in power plants
- 2012
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Licentiatavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Environmental and health concerns lead to stricter regulations on power plant emission. Sensors play an important role, not only as part of the process control to ensure that the effluent stays under the regulated values, but also to increase the pollution removal efficiency and to decrease the reagent consumption.Previous studies, on the use of SiC based Field Effect Transistors (FET) as NH3 sensors in Tekniska Verken power plants and as CO sensors for the control of the domestic boilers, have shown promising results. Moreover, these sensors can withstand high temperature operation and are considerably cheaper than most conventional sensors used in power plants. The price of the sensors enable the installation of multiple sensors in one flue gas duct section, which lead to better monitoring of the flue gas uniformity. Based on that argument, this study is performed to determine whether it is possible to expand the possible application of SiC-FET sensors for the detection of other pollutants emitted by power plants. This thesis reports the characterization and performance testing of SiC-FET sensors towards other selected air pollutants: H2S, methanol as a product of CO2 hydrogenation, and SO2.The study is performed by I-V characterization of the sensors toward the test gas in different background gases and studies of the detection mechanism. Detection mechanism studies include DRIFT spectroscopy, mass spectroscopy, and theoretical study of the surface reaction with Density Functional Theory (DFT).Ir-gate SiC-FET sensors at 350oC show a very high sensitivity to H2S. The large response reduces the possibility of cross-sensitivity from other gases. Pt-gate sensors offer very fast response with decent response magnitude at 200oC for methanol. The presence of oxygen improves the response to methanol, which is favorable for the leak detection application. Besides oxygen, the influence of hydrogen, propene, and water vapor is also observed in the experiment with methanol. The detection mechanism and different sensing behavior of Pt and Ir gates are illustrated with model reaction mechanisms on the surface of the metals. Sensor characterization has been performed for SO2 with several catalytic metal gates: Pt, Ir, Cu, and Au. The results suggest that a single sensor with any of Pt, Ir, Cu, and Au gates is able to detect the presence of SO2 in the air or nitrogen background. However, they are unable to measure different SO2 concentration. Moreover, the response level to SO2 is so small, that it will probably disappear if there is any other gas present in the mixture.
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| 2. |
- Afzal, Adeel, et al.
(författare)
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Electrochemical deposition of gold on indium zirconate (InZrOx with In/Zr atomic ratio 1.0) for high temperature automobile exhaust gas sensors
- 2015
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Ingår i: Journal of Solid State Electrochemistry. - : SPRINGER. - 1432-8488 .- 1433-0768. ; 19:9, s. 2859-2868
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Tidskriftsartikel (refereegranskat)abstract
- Automobile exhaust gas emissions are causing serious damage to urban air quality in and around major cities of the world, which demands continuous monitoring of exhaust emissions. The chief components of automobile exhaust include carbon monoxide (CO), nitrogen oxides (NOx), and hydrocarbons. Indium zirconate (InZrOx) and gold/indium zirconate (Au/InZrOx) composite nanopowders are believed to be interesting materials to detect these substances. To this end, characterization and gas sensing properties of InZrOx and Au/InZrOx composite nanopowders are discussed. InZrOx nanoparticles with In/Zr atomic ratio of 1.00 (+/- 0.05) are synthesized via pH-controlled co-precipitation of In and Zr salts in aqueous ammonia. Gold (Au) nanoparticles are subsequently deposited on InZrOx using an in situ sacrificial Au electrolysis procedure. The products are characterized by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The gas sensing performance of Au/InZrOx composite nanopowder is studied by depositing a thick powder film on interdigitated electrode structures patterned on SiC substrate to facilitate high temperature operation. The resistivity of the Au/InZrOx layer is the sensor signal, and the sensors could be operated at 500-600 A degrees C, which is a suitable temperature range for engine exhaust measurements. The control sensing measurements reveal that Au/InZrOx composite nanopowder exhibits higher response towards 2-20 % O-2 gas as compared to pristine InZrOx nanoparticles. Further studies show that when applied to exhaust gases such as CO and nitric oxide (NO), the response of Au/InZrOx sensors is significantly higher towards NO in this temperature range. Thus, sensor performance characteristics of Au/InZrOx composite nanopowder are promising in terms of their applications in automobile exhaust emission control.
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| 3. |
- Alene Asres, Georgies, et al.
(författare)
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A novel WS2 nanowire-nanoflake hybrid material synthesized from WO3 nanowires in sulfur vapor
- 2016
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Ingår i: Scientific Reports. - : NATURE PUBLISHING GROUP. - 2045-2322. ; 6:25610
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Tidskriftsartikel (refereegranskat)abstract
- In this work, WS2 nanowire-nanoflake hybrids are synthesized by the sulfurization of hydrothermally grown WO3 nanowires. The influence of temperature on the formation of products is optimized to grow WS2 nanowires covered with nanoflakes. Current-voltage and resistance-temperature measurements carried out on random networks of the nanostructures show nonlinear characteristics and negative temperature coefficient of resistance indicating that the hybrids are of semiconducting nature. Bottom gated field effect transistor structures based on random networks of the hybrids show only minor modulation of the channel conductance upon applied gate voltage, which indicates poor electrical transport between the nanowires in the random films. On the other hand, the photo response of channel current holds promise for cost-efficient solution process fabrication of photodetector devices working in the visible spectral range.
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| 4. |
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| 5. |
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| 6. |
- Andersson, Mike, 1977-, et al.
(författare)
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Detecting non-hydrogen containing species with field effect devices
- 2008
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Ingår i: IEEE Sensors,2008. - : IEEE. - 9781424425815 - 9781424425808 ; , s. 1320-1323
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Konferensbidrag (refereegranskat)abstract
- An investigation of the influence and role of oxygen in the detection of non-hydrogen containing substances with Pt/SiO2/SiC based MOS field effect sensors, employing new model systems, has been carried out. With the use of a novel intermediate layer, by which the direct influence of hydrogen on the sensor response can be markedly reduced, the part of the sensor response which is not directly related to hydrogen (which to a small extent is always present in any gas mixture) could be resolved. The Pt/SiO2 NO reduction/oxidation model system has also been studied from a sensor perspective and the results compared to spectroscopic and mass spectrometry studies of the surface reactions from the field of catalysis. The results support the hypothesis from earlier work that the removal of oxygen from the sensor surface (e.g. by oxidation reactions with CO or NO) to a certain extent directly is involved in the detection of non-hydrogen containing species.
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| 7. |
- Andersson, Mike, et al.
(författare)
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Field Effect Based Gas Sensors, from Basic Mechanisms to the Latest Commercial Device Designs
- 2016
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Ingår i: SENSORS AND ELECTRONIC INSTRUMENTATION ADVANCES (SEIA). - : INT FREQUENCY SENSOR ASSOC-IFSA. - 9788460899631 ; , s. 19-21
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Konferensbidrag (refereegranskat)abstract
- This contribution treats the latest developments in the understanding of basic principles regarding device design, transduction mechanisms, gas-materials-interactions, and materials processing for the tailored design and fabrication of SiC FET gas sensor devices, mainly intended as products for the automotive sector.
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| 8. |
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| 9. |
- Andersson, Mike, 1977-, et al.
(författare)
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In situ DRIFT study of the CO response mechanism of MISFET sensors using Pt/SiO2 model sensor
- 2008
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Ingår i: Proceedings of IEEE Sensors. - : IEEE. - 9781424425815 - 9781424425808 ; , s. 1309-1312
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Konferensbidrag (refereegranskat)abstract
- The temperature dependence of the sensor response towards CO of SiC-FET sensors has been studied by combining in situ DRIFT spectroscopy and sensor response measurements. The DRIFT spectroscopy studies have been performed on a model sensor representing the top layer of a SiC-FET sensor with porous Pt gate. Adsorbates on the model sensor have been studied at varying temperatures and gas concentrations, and correlated to sensor response measurements at similar experimental conditions. The results show that the temperature dependence partly can be correlated to the CO coverage of the surface. The switching point of the sensor response, observed at different temperatures depending on the CO and oxygen concentrations is well in accordance with the kinetics of the CO oxidation reaction.
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| 10. |
- Andersson, Mike, et al.
(författare)
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Investigations on the possibilities of a MISiCFET sensor system for OBD and combustion control utilizing different catalytic gate materials
- 2004
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Ingår i: Topics in catalysis. - 1022-5528 .- 1572-9028. ; 30-31:1, s. 365-368
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Tidskriftsartikel (refereegranskat)abstract
- Different catalytic materials, like Pt and Ir, applied as gate contacts on metal insulator silicon carbide field effect transistors — MISiCFET—facilitate the manufacture of gas sensor devices with differences in selectivity, devices which due to the chemical stability and wide band gap of SiC are suitable for high temperature applications. The combination of such devices in a sensor system, utilizing multivariate analysis/modeling, have been tested and some promising results in respect of monitoring a few typical exhaust and flue gas constituents, in the future aiming at on board diagnostics (OBD) and combustion control, have been obtained.
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| 11. |
- Andersson, Mike, et al.
(författare)
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New generation SiC based field effect transistor gas sensors
- 2013
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Ingår i: Sensors and actuators. B, Chemical. - : Elsevier. - 0925-4005 .- 1873-3077. ; 179:SI, s. 95-106
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Tidskriftsartikel (refereegranskat)abstract
- With the advances in SiC processing and high temperature packaging technology over the past few years as well as the accumulation of knowledge regarding the sensing characteristics of different gate metal/insulator material combinations for different gaseous substances SiC based field effect high temperature sensors are moving towards commercial maturity. The route towards commercialization has, however, also led to the necessity of making new considerations regarding the basic transducer design and operation. The focus of this paper is thus the investigation of some basic transducer related parameters influence on sensor device performance, e.g. sensitivity and long-term stability, and characteristics to exemplify the importance of taking design, processing and operation parameters into account when developing field effect sensor devices for commercial applications. less thanbrgreater than less thanbrgreater thanTwo different types of devices, enhancement and depletion type MISFET sensors, with different gate dimensions and two different gate metallisations, Pt and Ir, have been processed. I/V-characteristics have been obtained under exposure to various concentrations of H-2, NH3, CO and O-2 and different bias conditions and the influence of gate dimensions and bias conditions on the sensitivity and dynamic range investigated. The long-term stability has also been studied and compared between different devices and bias conditions for conceptually different gas compositions. The results show that the type of basic transducer device, its design and mode of operation has a large influence on sensor performance. Depletion type devices offer better possibilities for tuning of sensitivity and dynamic range as well as improved longterm stability properties, whereas enhancement type devices require much less control of the processing to ensure good repeatability and yield. Some results have also been verified for two possible applications of SiC based field effect sensors, ammonia slip monitoring for the control of SCR/SNCR and combustion control in domestic/district heating facilities.
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| 12. |
- Andersson, Mike, et al.
(författare)
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On the applicability of MISiCFET gas sensors regarding ammonia slip monitoring in small-scale boilers running SNCR
- 2007
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Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- Gas sensitive Metal Insulator Silicon Carbide Field Effect Transistor – MISiCFET – devices have shown good possibilities of realizing sensors for high temperature applications. One such application could be the monitoring of ammonia slip from boilers running SNCR – Selective Non-Catalytic Reduction of nitrogen oxides (NOx) with ammonia (NH3). In this study a number of MISiCFET gas sensors operated at different temperatures and with both platinum (Pt) and iridium (Ir) as the gate contact have been tested for their ability to detect and quantify ammonia slip in flue gases from a 5.6 MW wood fired boiler during a test of a new SNCR-system. The individual sensors have been evaluated and compared to each other for the sensitivity towards NH3 and possible cross-sensitivities to other flue gas species through the comparison of the sensor signals with the signals from analytical instruments like FTIR – Fourier Transform Infrared spectroscopy – for nitrogen oxides (NO + NO2), NH3, and carbon monoxide (CO) and an FID – Flame Ionization Detector – for the Total Hydrocarbon Concentration (THC). The ability of a combination of sensors to provide extra or more accurate information about the NH3 concentration was also evaluated through the construction and validation of a Partial Least Squares – PLS – regression model based on all the sensor signals. Under the assumption that the sensors’ responses follow a logarithmic dependence on NH3 concentration the results regarding ammonia slip quantification were promising both for a single Ir sensor and for the system based on all sensors. There is still a question mark for the long-term stability of the devices in real flue gases, however.
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| 13. |
- Andersson, Mike, et al.
(författare)
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On the CO response mechanism of SiC based field effect gas sensors
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Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- The response characteristics of Metal Insulator Silicon Carbide (MISiC) field effect sensor devices, with platinum (Pt) as the metal contact, towards carbon monoxide (CO) at varying oxygen (O2) concentrations and over a wide range of temperatures have been investigated in detail at atmospheric pressure. The influence of hydrogen (H2) on the CO response was also studied. Sensor devices with thin, porous as well as dense, homogeneous Pt films on top of both silicon dioxide (SiO2) and magnesium oxide (MgO) as insulator materials were investigated in this study. The reaction products generated on the sensor surfaces were also monitored with a mass spectrometer connected to the gas flow just downstream of the sensor location and the results compared to CO oxidation characteristics over Pt/SiO2 and to some extent Pt/MgO catalysts as reported in literature. By correlating the response characteristics of these devices with CO2 formation and hydrogen consumption on the sensor surfaces, strong indications for a CO response mechanism involving a CO induced increased sensitivity to background hydrogen have been obtained, this mechanism being hypothesized to be the only one behind the CO sensitivity of devices with dense Pt metal contacts. The results also give further support to the idea that also other processes than an increased sensitivity to background hydrogen contribute to the CO response of sensor devices with a porous platinum film as the metal contact, one candidate being the removal of oxygen anions from the surface of exposed oxide areas through the oxidation reaction with CO.
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| 14. |
- Andersson, Mike, et al.
(författare)
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On the response mechanism of SiC based field effect gas sensors towards non-hydrogen containing species and specifically NO
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Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- The response characteristics of Metal Insulator Silicon Carbide (MISiC) field effect sensor devices, with platinum (Pt) as the metal contact, towards nitrogen oxide (NO) for both low as well as relatively high background oxygen (O2) concentrations and different temperatures have been investigated at atmospheric pressure. Devices with both porous and dense Pt metal gate contacts have been investigated and the results seem to confirm the theories and results from earlier measurements regarding the requirement of porous metal films for the existence of a response to NO for this kind of sensor device. The results also suggest that no NO induced increased sensitivity to background hydrogen exists, at least it does not play any role in the observed NO sensitivity, as opposed to what has been suggested in the case of CO. The obtained results are also discussed in relation to some of the proposed sensing mechanisms for non-hydrogen containing substances and in comparison to NO reduction characteristics on Pt/SiO2 catalysts, as reported in literature. The results further give some indications about also some other process/ processes being important for the response of SiC based field effect sensors towards NO than just adsorption/desorption.
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| 15. |
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| 16. |
- Andersson, Mike, 1977-, et al.
(författare)
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Recent progress in silicon carbide field effect gas sensors
- 2020. - 2
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Ingår i: Semiconductor gas sensors. - Oxford : Woodhead Publishing Limited. - 9780081025598 ; , s. 309-346
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Bokkapitel (refereegranskat)abstract
- The introduction of silicon carbide as the semiconductor in gas-sensitive field effect devices has disruptively improved this sensor platform extending the operation temperature to more than 600 °C with an increased number of detectable gases. Here, we review recent progress in research and applications, starting with transducer and detection mechanisms, presenting new material combinations as sensing layers for improved selectivity and detection limits down to subparts per billion. We describe how temperature cycled operation combined with advanced data evaluation enables one sensor to act as a sensor array thereby vastly improving selectivity. Field tests require advanced packaging, which is described, and examples of possible applications like selective detection of ammonia for urea injection control in diesel exhausts and toxic volatile organic compounds for indoor air quality monitoring and control are given.
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| 17. |
- Andersson, Mike, et al.
(författare)
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Recent trends in Silicon Carbide (SiC) and Graphene based gas sensors
- 2013
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Ingår i: Semiconductor Gas Sensors. - : Woodhead Publishing Limited. - 9780857092366 - 9780857098665 ; , s. 117-158
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Bokkapitel (refereegranskat)abstract
- The introduction of silicon carbide (SiC) as the semiconductorin gas sensitive field effect devices has tremendously improved this sensor platform extending the temperature range and number of detectable gases. Here we review the recent trends in research, starting with transducer mechanisms, latest findings regarding the detection mechanism, and present new material combinations as sensing layers and smart operation of the field effect sensors enabling one sensor to act as a sensor array. Introducing epitaxially-grown graphene on SiC as gas sensing layer shows the potential of ppb detection of NO2 .
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| 18. |
- Andersson, Mike, 1977-
(författare)
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SiC based field effect sensors and sensor systems for combustion control applications
- 2007
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Increasing oil prices and concerns about global warming have reinforced the interest in biofuels for domestic and district heating, most commonly through combustion of solid biomass like wood logs, hog fuel and pellets. Combustion at non-optimal conditions can, however, lead to substantial emissions of noxious compounds like unburned hydrocarbons, carbon monoxide, and nitrogen oxides as well as the generation of soot.Depending on the rate of combustion more or less air is needed per unit time to completely oxidize the fuel; deficiency of air leading to emissions of unburned matter and too much of excess air to slow combustion kinetics and emissions of mainly carbon monoxide. The rate of combustion is influenced by parameters like fuel quality – moisture and ash content etc. – and in what phase the combustion takes place (in the gas phase through combustion of evaporated substances or on the surface of char coal particles), none of which is constant over time.The key to boiler operation, both from an environmental as well as a power to fuel economy point of view, is thus the careful adjustment of the air supply throughout the combustion process. So far, no control schemes have been applied to small-scale combustors, though, mainly due to the lack of cheap and simple means to measure basic flue gas parameters like oxygen, total hydrocarbon, and carbon monoxide concentrations.This thesis reports about investigations on and characterization of silicon carbide (SiC) based Metal Insulator Semiconductor (MIS) field effect gas sensors regarding their utility in emissions monitoring and combustion control applications as well as the final development of a sensor based control system for wood fired domestic heating systems.From the main sensitivity profiles of such sensor devices, with platinum (Pt) and iridium (Ir) as the catalytic metal contacts (providing the gas sensing ability), towards some typical flue gas constituents as well as ammonia (NH3), a system comprising four individual sensors operated at different temperatures was developed, which through the application of Partial Least Squares (PLS) regression, showed good performance regarding simultaneous monitoring of propene (a model hydrocarbon) and ammonia concentrations in synthetic flue gases of varying content. The sensitivity to CO was, however, negligible. The sensor system also performed well regarding ammonia slip monitoring when tested in real flue gases in a 5.6 MW boiler running SNCR (Selective Non-Catalytic reduction of nitrogen oxides with ammonia).When applied to a 200 kW wood pellet fuelled boiler a similar sensor system was, however, not able to follow the flue gas hydrocarbon concentration in all encountered situations. A PCA (Principal Components Analysis) based scheme for the manipulation of sensor and flue gas temperature data, enabling monitoring of the state of combustion (deficiency or too much of excess air), was however possible to develop. The discrepancy between laboratory and field test results was suspected and later on shown to depend on the larger variation in CO and oxygen concentrations in the flue gases as compared to the laboratory tests.Detailed studies of the CO response characteristics for Pt gate MISiC sensors revealed a highly non-linear sensitivity towards CO, a large response only encountered at high CO/O2 ratios or low temperatures. The response exhibits a sharp switch between a small and a large value when crossing a certain CO/O2 ratio at constant operating temperature, correlated to the transition from an oxygen dominated to an almost fully CO covered Pt surface, originating from the difference in adsorption kinetics between CO and O2. Indications were also given pointing towards an increased sensitivity to background hydrogen as being the mediator of at least part of the CO response. Some general characteristics regarding the response mechanism of field effect sensors with differently structured metal contacts were also indicated.The CO response mechanism of Pt metal MISiC sensors could also be utilized in developing a combustion control system based on two sensors and a thermocouple, which when tested in a 40 kW wood fired boiler exhibited a good performance for fuels with extremely low to normal moisture content, substantially decreasing emissions of unburned matter.
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| 19. |
- Andersson, Mike, et al.
(författare)
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SiC-FE gas sensor based combustion control in domestic heating systems, characteristics and utility
- 2007
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Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- SiC based field effect gas sensors have been evaluated for future possible use in combustion control schemes for domestic heating systems. Emphasis has been on the possibility to monitor the state of combustion and follow the development of the combustion process from an emissions point of view and to determine its cause. The sensor signals have been compared to true emissions data – CO and total hydrocarbon concentration – as obtained by an IR spectrometer and a flame ionization detector (FID) as well as flue gas concentration of oxygen as obtained by a paramagnetic cell. The sensor characteristics have been evaluated using multivariate statistics and the results suggest that, by using the signals from one or more SiC-based field effect sensors and a thermocouple, it seems possible to provide a rough picture of the state of combustion applicable to a control scheme in order to reduce emissions and increase the power to fuel economy.
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| 20. |
- Andersson, Mike, et al.
(författare)
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SiC-FET sensors for selective and quantitative detection of VOCs down to ppb level
- 2016
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Ingår i: Procedia Engineering. - : Elsevier. - 1877-7058. ; 168, s. 216-220
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Tidskriftsartikel (refereegranskat)abstract
- With the increased interest in development of cheap, simple means for indoor air quality monitoring, and specifically in relation to certain well-known pollutant substances with adverse health effects even at very low concentrations, such as different Volatile Organic Compounds (VOCs), this contribution aims at providing an overview of the development status of the silicon carbide field effect transistor (SiC FET) based sensor platform for ppb level detection of VOCs. Optimizing the transducer design, the gas-sensitive material(s) composition, structure and processing, its mode of operation - applying temperature cycled operation in conjunction with multivariate data evaluation - and long-term performance it has been possible to demonstrate promising resultsregarding the sensor technology’s ability to achieve both single-digit ppb sensitivity towards e.g. naphthalene as well as selective detection of individual substances in a mixture of different VOCs.
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| 21. |
- Andersson, Mike, et al.
(författare)
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Tailoring of field effect gas sensors for sensing of non-hydrogen containing substances from mechanistic studies on model systems
- 2009
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Konferensbidrag (refereegranskat)abstract
- To gain knowledge about the transduction mechanisms involved in the sensitivity of field effect gas sensors towards non-hydrogen containing substances, such as O-2, NO and CO, the sensor signal characteristics during exposure of some conceptually different model sensors to these as well as hydrogen containing gases have been investigated. The MOS capacitor based model sensors employ different combinations of insulator and contact materials, such as MgO, LaF3, IrO2 etc. The gas composition downstream of the sensor during test gas exposure at various conditions has also been studied by mass spectrometry (MS) and compared for the different model systems. The results have been compared to the characteristics of ordinary SiC/SiO2/Pt structures and from the information obtained a tailor made field effect sensor structure for oxygen sensing, to our knowledge for the first time with minimal interference from H-2, CO, and hydrocarbons, has been tested with promising results.
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| 22. |
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| 23. |
- Andersson, Mike, et al.
(författare)
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Technology and application opportunities for SiC-FET gas sensors
- 2012
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Ingår i: Solid State Gas Sensors - Industrial Application. - Berlin, Heidelberg : Springer Berlin/Heidelberg. - 9783642280924 ; , s. 189-214
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Bokkapitel (refereegranskat)abstract
- The development of SiC-FET gas sensors has proceeded for about fifteen years. The maturity of the SiC material and a deeper understanding of the transduction mechanisms and sensor surface processes behind the sensitivity to a number of target substances have recently allowed the development of market-ready sensors for certain applications. Some examples presented below are a sensor system for domestic boiler control, an ammonia sensor for control of the SCR (selective catalytic reduction) and SNCR (Selective Non-Catalytic Reduction) NOx abatement processes as well as other more or less market-ready applications. In parallel, the basic research continues in order to reach more demanding markets/new applications and also to possibly lower the production costs of the sensors. Therefore, current research and future challenges are also treated, such as the development of new types of conducting ceramics for ohmic contacts to SiC in order to increase the operation temperature beyond the present state of the art.
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| 24. |
- Andersson, Mike, et al.
(författare)
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The characteristics and utility of SiC-FE gas sensors for control of combustion in domestic heating systems [MISFET sensors]
- 2004
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Ingår i: Proceedings of IEEE Sensors, 2004.. - 0780386922 ; , s. 1157-1160
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Konferensbidrag (refereegranskat)abstract
- The possible utility of MISiCFET gas sensors in the application of combustion control in small-scale boilers has been tested and compared to commercially available resistive-type MOS sensors. The results suggest that by using the signals from one or more MISiCFET sensors, together with the measured temperature of the furnace, it seems possible to provide a rough picture of the state of combustion applicable to a control scheme in order to reduce emissions and increase the power to fuel economy.
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| 25. |
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| 26. |
- Asres, Georgies Alene, et al.
(författare)
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High photoresponse of individual WS2 nanowire-nanoflake hybrid materials
- 2018
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Ingår i: Applied Physics Letters. - : AMER INST PHYSICS. - 0003-6951 .- 1077-3118. ; 112:23
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Tidskriftsartikel (refereegranskat)abstract
- van der Waals solids have been recognized as highly photosensitive materials that compete conventional Si and compound semiconductor based devices. While 2-dimensional nanosheets of single and multiple layers and 1-dimensional nanowires of molybdenum and tungsten chalcogenides have been studied, their nanostructured derivatives with complex morphologies are not explored yet. Here, we report on the electrical and photosensitive properties of WS2 nanowire-nanoflake hybrid materials we developed lately. We probe individual hybrid nanostructured particles along the structure using focused ion beam deposited Pt contacts. Further, we use conductive atomic force microscopy to analyze electrical behavior across the nanostructure in the transverse direction. The electrical measurements are complemented by in situ laser beam illumination to explore the photoresponse of the nanohybrids in the visible optical spectrum. Photodetectors with responsivity up to similar to 0.4 AW(-1) are demonstrated outperforming graphene as well as most of the other transition metal dichalcogenide based devices. Published by AIP Publishing.
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| 27. |
- Asres, Georgies Alene, et al.
(författare)
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Ultrasensitive H2S gas sensors based on p-type WS2 hybrid materials
- 2018
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Ingår i: Nano Reseach. - : Springer. - 1998-0124 .- 1998-0000. ; 11:8, s. 4215-4224
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Tidskriftsartikel (refereegranskat)abstract
- Owing to their higher intrinsic electrical conductivity and chemical stability with respect to their oxide counterparts, nanostructured metal sulfides are expected to revive materials for resistive chemical sensor applications. Herein, we explore the gas sensing behavior of WS2 nanowire-nanoflake hybrid materials and demonstrate their excellent sensitivity (0.043 ppm-1) as well as high selectivity towards H2S relative to CO, NH3, H2, and NO (with corresponding sensitivities of 0.002, 0.0074, 0.0002, and 0.0046 ppm-1, respectively). Gas response measurements, complemented with the results of X-ray photoelectron spectroscopy analysis and first-principles calculations based on density functional theory, suggest that the intrinsic electronic properties of pristine WS2 alone are not sufficient to explain the observed high sensitivity towards H2S. A major role in this behavior is also played by O doping in the S sites of the WS2 lattice. The results of the present study open up new avenues for the use of transition metal disulfide nanomaterials as effective alternatives to metal oxides in future applications for industrial process control, security, and health and environmental safety.
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| 28. |
- Baranzahi, Amir, et al.
(författare)
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Chemical sensors with catalytic metal gates - Switching behavior and kinetic phase transitions
- 1998
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Ingår i: Journal of the Electrochemical Society. - : Electrochemical Society. - 0013-4651 .- 1945-7111. ; 145:10, s. 3401-3406
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Tidskriftsartikel (refereegranskat)abstract
- Rapid transitions in the response of platinum-based chemical sensors occurring at given hydrogen-oxygen concentration ratios are explained by kinetic phase transitions or switching phenomena on the catalytic metal surface. Below the transition point the response of platinum-insulator silicon carbide devices is small and above the transition it is large. It is found that the critical ratio depends on the operation temperature and the properties of the device. Three different cases are identified, namely, injection-, diffusion-, and reaction-rate-determined transitions. At sufficiently large temperatures the transition is injection limited and occurs at the stoichiometric ratio of hydrogen and oxygen in the gas mixture. The implications of the experimental observations on the applications of chemical sensors with catalytic sensing layers are discussed.
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| 29. |
- Baranzahi, Amir, et al.
(författare)
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Gas sensitive field effect devices for high temperature
- 1995
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Ingår i: Sensors and actuators. B, Chemical. - : Elsevier. - 0925-4005 .- 1873-3077. ; 26:1-3, s. 165-169
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Tidskriftsartikel (refereegranskat)abstract
- Field effect sensors based on metal-oxide-silicon carbide (MOSiC) devices are used as high temperature gas sensors. They are sensitive to, for example, saturated hydrocarbons and hydrogen and can be operated up to at least 800 degrees C, which make them suitable for several types of combustion control. A metal gate with two layer platinum and a buffer layer of tantalum silicide in between gave a large increase in the long term stability of the sensors. At temperatures below 600 degrees C, the response to ethane in oxygen was shown to have a threshold at a ratio of about 0.38 for the ethane-to-oxygen concentrations. Below this ratio, the surface can be considered as mainly oxygen covered and the response is small. Above this ratio the metal surface is probably mainly hydrogen covered and the response is considerably larger.
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| 30. |
- Baranzahi, Amir, et al.
(författare)
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Kinectic phase transitions and chemical sensors with catalytic metal gates
- 1997
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Ingår i: Chemical & Biological Sensors & Analytical Electrochemical Methods, 1997. - : Electrochemical Society. - 9781566771474 - 1566771471 ; , s. 1-15
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- Rapid transitions in the response of platinum based chemical sensors occurring at given hydrogen-oxygen concentration ratios are explained by kinetic phase transitions or switching phenomena on the catalytic metal surface. Below the transition point the response of platinum-insulator silicon carbide devices is small and above the transition large and almost saturated. It is found that the critical ratio depends on the operation temperature and the properties of the device. Three different cases are identified, namely injection-, diffusion- and reaction rate determined transitions. At sufficiently large temperatures the transition is injection limited and occurs at the stoichiometric ratio of hydrogen and oxygen in the gas mixture. The implications of the experimental observations on the applications of chemical sensors with catalytic sensing layers are discussed.
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| 31. |
- Baranzahi, Amir, et al.
(författare)
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Response of metal-oxide-silicon carbide sensors to simulated and real exhaust gases
- 1997
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Ingår i: Sensors and actuators. B, Chemical. - : Elsevier. - 0925-4005 .- 1873-3077. ; 43:1-3, s. 52-59
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Tidskriftsartikel (refereegranskat)abstract
- Field effect devices based on catalytic metal-oxide-silicon carbide (MOSiC) structures can be used as high temperature gas sensors. The devices are sensitive to hydrocarbons and hydrogen and can be operated up to at least 900 degrees C, which make them suitable for several combustion applications, Simulated and real exhaust gases from a car engine have been studied at sensor temperatures from 200 to 650 degrees C, and it was round that the sensor signal is high for excess hydrocarbon and low for excess oxygen. The response time is less than 100 ms and only a small degradation of the devices was observed after several days of operation. The devices also react to changes of the gas composition In the fuel-rich and fuel-lean region. The devices show an interesting temperature dependence in the fuel rich region.
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| 32. |
- Baranzahi, Amir, et al.
(författare)
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Reversible hydrogen annealing of metal‐oxide‐silicon carbide devices at high temperatures
- 1995
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Ingår i: Applied Physics Letters. - : American Institute of Physics (AIP). - 0003-6951 .- 1077-3118. ; 67:21, s. 3203-3205
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Tidskriftsartikel (refereegranskat)abstract
- We report on a reversible hydrogen annealing effect observed in platinum-silicon dioxide-silicon carbide structures at temperatures above about 650 degrees C. It appears as a decrease of the inversion capacitance in the presence of hydrogen. This phenomenon is shown to depend on hydrogen atoms, created on the catalytic metal, that pass through the oxide and interact with charge generation sites at the oxide-silicon carbide interface. The consequence of the observation for chemical sensors based on silicon carbide is discussed. The results are phenomenological, since no details of the annealing chemistry could be developed from the present experiments. We find, however, that the annealing process and its reversal have activation energies of about 0.9 eV and 2.9 eV/site,respectively.
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| 33. |
- Bastuck, Manuel, et al.
(författare)
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Characterizing the Influence of Gate Bias on Electrical and Catalytical Properties of a Porous Platinum Gate on Field Effect Gas Sensors
- 2016
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Ingår i: 2016 IEEE SENSORS. - : IEEE. - 9781479982875
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Konferensbidrag (refereegranskat)abstract
- In this work, we exposed an MIS capacitor with porous platinum as gate material to different concentrations of CO and NH3. Its capacitance and typical reaction products (water, CO2 and NO) were monitored at high and low oxygen concentration and different gate bias voltages. We found that the gate bias influences the switch-point of the binary CO response usually seen when either changing the temperature at constant gas concentrations or the CO/O-2 ratio at constant temperature. For NH3, the sensor response as well as product reaction rates increase with bias voltages up to 6 V. A capacitance overshoot is observed when switching on or off either gas at low gate bias, suggesting increasing oxygen surface coverage with decreasing gate bias.
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| 34. |
- Bastuck, Manuel, et al.
(författare)
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Exploring the selectivity of WO3 with iridium catalyst in an ethanol/naphthalene mixture using multivariate statistics
- 2016
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Ingår i: Thin Solid Films. - : ELSEVIER SCIENCE SA. - 0040-6090 .- 1879-2731. ; 618, s. 263-270
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Tidskriftsartikel (refereegranskat)abstract
- Temperature cycled operation and multivariate statistics have been used to compare the selectivity of two gate (i.e. sensitive) materials for gas-sensitive, silicon carbide based field effect transistors towards naphthalene and ethanol in different mixtures of the two substances. Both gates have a silicon dioxide (SiO2) insulation layer and a porous iridium (Ir) electrode. One of it has also a dense tungsten trioxide (WO3) interlayer between Ir and SiO2. Both static and transient characteristics play an important role and can contribute to improve the sensitivity and selectivity of the gas sensor. The Ir/SiO2 is strongly influenced by changes in ethanol concentration, and is, thus, able to quantify ethanol in a range between 0 and 5 ppm with a precision of 500 ppb, independently of the naphthalene concentrations applied in this investigation. On the other hand, this sensitivity to ethanol reduces its selectivity towards naphthalene, whereas Ir/WO3/SiO2 shows an almost binary response to ethanol. Hence, the latter has a better selectivity towards naphthalene and can quantify legally relevant concentrations down to 5 ppb with a precision of 2.5 ppb, independently of a changing ethanol background between 0 and 5 ppm. (C) 2016 Elsevier B.V. All rights reserved.
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| 35. |
- Bastuck, Manuel, et al.
(författare)
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Low-cost chemical gas sensors for selective formaldehyde quantification at ppb-level in field tests
- 2017
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Konferensbidrag (refereegranskat)abstract
- Data from a silicon carbide based field-effect transistor were recorded over a period of nine days in a ventilated school room. For enhanced sensitivity and selectivity especially to formaldehyde, porous iridium on pulsed laser deposited tungsten trioxide was used as sensitive layer, in combination with temperature cycled operation and subsequent multivariate data processing techniques. The sensor signal was compared to reference measurements for formaldehyde concentration, CO2 concentration, temperature, and relative humidity. The results show a distinct pattern for the reference formaldehyde concentration, arising from the day/night cycle. Taking this into account, the projections of both principal component analysis and partial least squares regression lead to almost the same result concerning correlation to the reference. The sensor shows cross-sensitivity to an unidentified component of human activity, presumably breath, and, possibly, to other compounds appearing together with formaldehyde in indoor air. Nevertheless, the sensor is able to detect and partially quantify formaldehyde below 40 ppb with a correlation to the reference of 0.48 and negligible interference from ambient temperature or relative humidity.
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| 36. |
- Bastuck, Manuel, et al.
(författare)
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UV-assisted gate bias cycling in gas-sensitive field-effect transistors
- 2018
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Ingår i: Proceedings. - Basel Switzerland : MDPI. - 2504-3900. ; 2:13
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Tidskriftsartikel (refereegranskat)abstract
- Static and dynamic responses of a silicon carbide field-effect transistor gas sensor have been investigated at two different gate biases in several test gases. Especially the dynamic effects are gas dependent and can be used for gas identification. The addition of ultraviolet light reduces internal electrical relaxation effects, but also introduces new, temperature-dependent effects.
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| 37. |
- Bastuk, Emanuel, et al.
(författare)
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Identification of ammonia and carbon monoxide based on the hysteresis of a gas sensitive silicon carbide field effect transistor
- 2013
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Ingår i: Transducers 2013 & Eurosensors XXVII. - : IEEE. - 9781467359832 ; , s. 250-253
-
Konferensbidrag (refereegranskat)abstract
- In this work gate bias cycled operation (GBCO) is used on a gas-sensitive SiC field effect transistor(“GasFET”) to increase the sensitivity and selectivity. Gate bias ramps introduce strong hysteresis in the sensor signal. The shape of this hysteresis is shown to be an appropriate feature both for the discrimination of various gases (NH3, CO, NO, CH4) and also different gas concentrations (250 and 500 ppm). The shape is very sensitive to ambient conditions. Thus, the influence of oxygen concentration and relative humidity as well as sensor temperature is investigated and reasons for the observed signal changes are discussed.
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| 38. |
- Bastuk, Manuel, et al.
(författare)
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Gas identification based on bias induced hysteresis of a gas-sensitive SiC field effect transistor
- 2014
-
Ingår i: Journal of Sensors and Sensor Systems. - : Copernicus GmbH. - 2194-8771 .- 2194-878X. ; 3, s. 9-19
-
Tidskriftsartikel (refereegranskat)abstract
- In this work dynamic variation of gate bias is used on a gas-sensitive SiC field effect transistor ("GasFET") to optimize its sensitivity and increase its selectivity. Gate bias ramps introduce strong hysteresis in the sensor signal. The shape of this hysteresis is shown to be an appropriate feature both for the discrimination of various gases (ammonia, carbon monoxide, nitrogen monoxide and methane) as well as for different gas concentrations (250 and 500 ppm). The shape is very sensitive to ambient conditions as well as to the bias sweep rate. Thus, the influences of oxygen concentration, relative humidity, sensor temperature and cycle duration, i.e., sweep rate, are investigated and reasons for the observed signal changes, most importantly the existence of at least two different and competing processes taking place simultaneously, are discussed. Furthermore, it is shown that even for very fast cycles, in the range of seconds, the gas-induced shape change in the signal is strong enough to achieve a reliable separation of gases using gate bias cycled operation and linear discriminant analysis (LDA) making this approach suitable for practical application.
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| 39. |
- Basu, P. K., et al.
(författare)
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Schottky Junction Methane Sensors using Electrochmically Grown Nanocrystalline-Nanoporous ZnO Thin Films
- 2009
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Ingår i: Journal of Sensors. - : Hindawi Publishing Corporation. - 1687-725X .- 1687-7268. ; 2009:790476, s. 1-9
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- Nanocrystalline-nanoporous ZnO thin films were prepared by an electrochemical anodization method, and the films were tested as methane sensors. It was found that Pd-Ag catalytic contacts showed better sensing performance compared to other noble metal contacts like Pt and Rh. The methane sensing temperature could be reduced to as low as 100°C by sensitizing nanocrystalline ZnO thin films with Pd, deposited by chemical method. The sensing mechanism has been discussed briefly.
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| 40. |
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| 41. |
- Becker, Elin, 1981, et al.
(författare)
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In situ DRIFT study of hydrogen and CO adsorption on Pt/SiO2 model sensors
- 2007
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Ingår i: 2007 IEEE Sensors. - 1930-0395. - 9781424412617 ; 1-3, s. 1028-1031
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Konferensbidrag (refereegranskat)abstract
- The sensing mechanism towards carbon monoxide of Metal Insulator Silicon Carbide (MISiC) Field Effect devices used as sensors, has been studied by in situ FTIR spectroscopy in diffuse reflectance mode (DRIFT). The infrared studies were performed using a model sensor, where adsorption of CO in presence of oxygen and hydrogen has been studied. The results show that the CO adsorption on Pt varies with varying oxygen concentration, CO concentration, hydrogen exposure and temperature. When correlating the DRIFT spectroscopy with sensor signal measurements, the CO response or MISiC field effect devices appears to be connected to the CO coverage of the sensor surface.
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| 42. |
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| 43. |
- Becker, Elin, et al.
(författare)
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Study of the Sensing Mechanism Towards Carbon Monoxide of Platinum-Based Field Effect Sensors
- 2011
-
Ingår i: IEEE SENSORS JOURNAL. - : IEEE. - 1530-437X. ; 11:7, s. 1527-1534
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Tidskriftsartikel (refereegranskat)abstract
- We have investigated the temperature dependence and the effect of hydrogen on the CO response of MISiC field effect device sensors. The evolution of adsorbates on a model sensor was studied by in situ DRIFT spectroscopy and correlated to sensor response measurements at similar conditions. A strong correlation between the CO coverage of the sensor surface and the sensor response was found. The temperature dependence and hydrogen sensitivity are partly in agreement with these observations, however at low temperatures it is difficult to explain the observed increase in sensor response with increasing temperature. This may be explained by the reduction of a surface oxide or removal of oxygen from the Pt/SiO2 interface at increasing temperatures. The sensing mechanism of MISiC field effect sensors is likely complex, involving several of the factors discussed in this paper.
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| 44. |
- Belov, Ilja, et al.
(författare)
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CFD analysis of packaging and mounting solutions for SiC-based gas sensors in automotive applications
- 2006
-
Ingår i: Sensor Letters. - 1546-198X. ; 4:1, s. 29-37
-
Tidskriftsartikel (refereegranskat)abstract
- Simulation-based guidelines were developed for designing tube-mounted gas sensors in the exhaust pipes of diesel and petrol engines, taking into account thermal constraints and gas flow conditions. Different block and tube mounting alternatives for SiC-based gas sensors were studied by means of temperature measurements and simulation of steady state heat transfer and gas flow. Design variables included the number of fins in the heat sink mounted on the inlet tube, the inlet construction, the mounting tube orientation, and the micro-heater substrate placement inside the mounting tube. The most preferable tube mounting design was determined with respect to the thermal performance of the sensor structure and with respect to the gas flow parameters, which are important for the sensor's selectivity, sensitivity and response time.
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| 45. |
- Belov, Ilja, et al.
(författare)
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Thermal and flow analysis of SiC-based gas sensors for automotive applications
- 2004
-
Ingår i: Proceedings of the 5th International Conference on Thermal and Mechanical Simulation and Experiments in Microelectronics and Microsystems, 2004. - : IEEE. - 0780384202 ; , s. 475-482
-
Konferensbidrag (refereegranskat)abstract
- Different block and tube mounting alternatives for SiC-based gas sensors were studied by means of temperature measurements and simulation of heat transfer and gas flow for steady state conditions. The most preferable tube mounting design was determined. Simulation-based guidelines were developed for designing tube-mounted gas sensors in the exhaust pipes of diesel and petrol engines, taking into account thermal constraints and flow conditions.
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| 46. |
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| 47. |
- Bounechada, Djamela, et al.
(författare)
-
Vibrational analysis of SO2 on Pt / SiO2 system
-
Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- In situ diffuse reflectance infrared Fourier transformed spectroscopy was used to study the interactions of SOx species with Pt/SiO2 between 200 and 400°C, and for SO2 concentrations between 10 and 50 ppm, which represents a concentration range where MISFET sensors exhibit good responses. In parallel, first-principles calculations have been carried out to support the experimental interpretations. It was found that sulfate species were formed on the silica surface, accompanied with removal/rearrangement of silanol groups upon exposure to SO2. Both experimental and theoretical calculations also suggest that the surface species were only formed after SO2 oxidation to SO3 on the metal surface. These evidences support the idea of SO2 oxidation to SO3 as the first step in the process of sulfate formation, followed by spillover of SO3 to the oxide, and finally the formation of sulfate species on the hydroxyl positions on the oxide. The results also indicate that the sulfate formation on silica depends both on the temperature and the SO2 concentration. Furthermore, hydrogen exposure was shown to be efficient for sulfur removal from the silica surface.
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| 48. |
- Bounechada, Djamela, 1984, et al.
(författare)
-
Vibrational Study of SOx Adsorption on Pt/SiO2
- 2014
-
Ingår i: Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 118:51, s. 29713-29723
-
Tidskriftsartikel (refereegranskat)abstract
- The formation of ad-SOx species on Pt/SiO2 upon exposure to SO2 in concentrations rang- ing from 10 to 50 ppm at between 200 and 400◦C has been studied by in situ diffuse reflectance infrared Fourier transformed spectroscopy. In parallel, first-principles calculations have been carried out to consolidate the experimental interpretations. It was found that sulfate species form on the silica surface with a concomitant removal/ rearrangement of silanol groups. For- mation of ad-SOx species occurs only after SO2 oxidation to SO3 on the platinum surface. Thus SO2 oxidation to SO3 is the first step in the SOx adsorption process, followed by spillover of SO3 to the oxide and, finally, the formation of sulfate species on the hydroxyl positions on the oxide. The sulfate formation is influenced by both temperature and SO2 concentration. Furthermore, exposure to hydrogen is shown to be sufficiently efficient as to remove ad-SOx species from the silica surface.
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| 49. |
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| 50. |
- Buchholt, Kristina, 1978-, et al.
(författare)
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Electrochemically Synthesised Pd- and Au-nanoparticles as sensing layers in NOx-sensitive field effect devices
- 2008
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Ingår i: Smart Sensors and Sensing Technology. - Berlin, Heidelberg : Springer. - 9783540795896 - 9783540795902 ; , s. 63-75
-
Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- An environmental pollutant of great concern is NOx (nitrogen monoxide and nitrogen dioxide). Here we report the utilisation of electrochemically synthesised gold and palladium nanoparticles as catalytically active gate material on gas sensitive field effect sensor devices. The synthesised nanoparticles have been characterised by TEM and XPS, and the morphology of the thermally treated nanostructured sensing layers has been investigated using SEM and XPS. Measurements on the gas response of the palladium as well as the gold nanoparticle sensors towards a number of analytes found in automotive gas exhausts were performed and their response patterns were compared. The initial gas response measurements show interesting sensing properties for both the gold and the palladium nanoparticle sensors towards NOx detection.
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