| 1. |
- Boostani, Sareh, et al.
(författare)
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Development and characterization of medium and high internal phase novel multiple Pickering emulsions stabilized by hordein nanoparticles
- 2022
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Ingår i: Food Chemistry. - : Elsevier BV. - 0308-8146. ; 372
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Tidskriftsartikel (refereegranskat)abstract
- Medium and high internal phase W1/O/W2 multiple Pickering emulsions (MPEs) were fabricated by physically-modified hordein nanoparticles. A triphasic system was developed at dispersed phase volume fraction (Φ) of 0.5 with an overrun value of ∼40%. No overrun was detected in high internal phase MPEs (Φ 0.8). Optical and confocal laser scanning microscopy confirmed the formation of MPEs. Monomodal droplet size distribution with a mean diameter of 32.90 and 21.48 μm was observed for MPEs at Φ 0.5 and Φ 0.8, respectively. Static multiple light scattering confirmed that creaming was the main mechanism behind the instability of MPEs. Both MPEs revealed pseudo-plastic behavior and predominant storage modulus (G′) over the applied frequency range. The encapsulation efficiency of vitamin B12 in MPEs was 98.3% and remained relatively constant during 28 d. These results suggested the excellent potential of hordein nanoparticles as appropriate candidate for designing multi-structural colloidal systems using plant proteins.
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| 2. |
- Boostani, Sareh, et al.
(författare)
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The influence of emulsion parameters on physical stability and rheological properties of Pickering emulsions stabilized by hordein nanoparticles
- 2020
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Ingår i: Food Hydrocolloids. - : Elsevier BV. - 0268-005X. ; 101
-
Tidskriftsartikel (refereegranskat)abstract
- In this study, the effect of pH (3–8), ionic strength (I, 0.01–1 M), protein particle concentration (C, 0.5%–2%), and dispersed phase volume fraction (Φ, 0.25–0.8) on the efficacy of hordein-based colloidal nanoparticles in the stabilization of Pickering structures was investigated. Colloidal particles were synthesized via anti-solvent method. Depending on pH and I, the average size and zeta-potential of hordein particles ranged from 425 to around 4000 nm, and +27.5 to −15.63 mV, respectively. The intense aggregation of particles at pH close to isoelectric point and also at high I led to poor formation and stability of Pickering emulsions. The overrun value was influenced by various emulsion parameters. At pH 3, triphasic (with the overrun value of 75%) and high internal phase (HIP) emulsions with an average droplet size of 15.6–86.7 μm were formed at Φ 0.25 and 0.8, respectively. At Φ 0.5 and 0.8, an elastic gel-like behavior (i.e., storage modulus (G′) > loss modulus (G″)) was observed over the applied frequency range. At Φ 0.25, a predominant viscous character (G">G′) was observed at low frequencies; while, at higher frequencies, G′ exceeded G″ due to the foam collapse. The morphology was studied by optical microscopy and confocal laser scanning microscopy (CLSM). Monitoring the physical stability using static multiple light scattering (MLS) revealed three destabilization profiles of foam-like, emulsion-foam and gel-like structures. The results of this study might help in designing triphasic Pickering systems (using plant-based proteins) and developing solid-like structured vegetable oils from the gel-like HIP emulsions.
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| 3. |
- Hadi, Nabilah Abdul, et al.
(författare)
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Comparison of three methods to determine the degree of substitution of quinoa and rice starch acetates, propionates, and butyrates : Direct stoichiometry, FTIR, and 1H-NMR
- 2020
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Ingår i: Foods. - : MDPI AG. - 2304-8158. ; 9:1
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Tidskriftsartikel (refereegranskat)abstract
- Rice and quinoa starch esters were prepared by acylation using short-chain fatty acid anhydrides with different chain lengths (acetic, propionic, and butyric anhydride). A direct stoichiometric method based on the acylation reaction was used to determine the degree of substitution (DS) and acyl content (AC). In addition, Fourier-transform infrared spectroscopy (FTIR) was used to validate the conformational changes of acylated starch and 1H-NMR was used as a DS reference method. DS by stoichiometric calculation was shown to be in agreement with FTIR and was comparable with DS obtained from Proton nuclear magnetic resonance (1H-NMR). Based on this study, stoichiometric calculation allows rapid and direct determination of substitution levels and acyl content without the loss of samples, which provides efficiency and optimization of manufacturing procedures in producing the desired level of esterified starches.
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| 4. |
- Helstad, Amanda, et al.
(författare)
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High-Pressure Pasteurization of Oat Okara
- 2023
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Ingår i: Foods. - 2304-8158. ; 12:22
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Tidskriftsartikel (refereegranskat)abstract
- The issue of the short microbiological shelf life of residues from the plant-based beverage industry creates a large food waste problem. Today, the oat beverage residue, in this study referred to as oat okara, is generally converted to energy or used as animal feed. High-pressure pasteurization (200 MPa, 400 MPa, and 600 MPa) was applied to oat okara to investigate the effect on shelf life and microbiological activity. A 4-week microbiological storage study was performed and thermal properties, viscosity, and water and oil holding capacities were analyzed. The total aerobic count, including yeast and mold, was significantly reduced (p < 0.05) by 600 MPa after four weeks of storage at 4 °C. The content of lactic acid bacteria after four weeks of storage was low for untreated oat okara (3.2 log CFU/g) but, for 600 MPa, the content remained at the detection limit (2.3 log CFU/g). Conversely, the treatments of 200 MPa and 400 MPa increased the microbial content of the total aerobic count significantly (p < 0.05) after two weeks in comparison to untreated oat okara. The thermal properties of untreated and high-pressure-treated oat okara demonstrated an increase in protein denaturation of the 12S globulin, avenalin, when higher pressure was applied (400–600 MPa). This was also confirmed in the viscosity measurements where a viscosity peak for avenalin was only present for untreated and 200 MPa treated oat okara. The water holding capacity did not change as a function of high-pressure treatment (3.5–3.8 mL/g) except for the treatment at 200 MPa, which was reduced (2.7 mL/g). The oil holding capacity was constant (1.2–1.3 mL/g) after all treatments. High-pressure pasteurization of 600 MPa reduced the microbial content in oat okara resulting in a shelf life of 2–4 weeks. However, more research is required to identify the microorganisms in oat okara to achieve a microbiologically safe product that can be used for food applications.
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| 5. |
- Helstad, Amanda, et al.
(författare)
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High-Pressure Pasteurization of Soy Okara
- 2023
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Ingår i: Foods. - 2304-8158. ; 12:20, s. 1-15
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Tidskriftsartikel (refereegranskat)abstract
- Okara is a by-product from the production of soy beverages, which has a high content of protein and fiber. Even though it has a high nutritional value, it is generally discarded or used as animal feed or compost. The problem is its short shelf life due to its high water content and high water activity. The aim of this study was to investigate the effect of high-pressure pasteurization at 200 MPa, 400 MPa, and 600 MPa on the shelf life of soy okara. Microbiological growth, as well as thermal properties, viscosity, water holding capacity, and oil holding capacity, was evaluated after the pressure treatments. Treatment at 600 MPa significantly reduced (p < 0.05) the growth of total aerobic count, yeast and mold, and lactic acid bacteria for up to four weeks of storage at 4 °C. The pasting properties were increased while the water and oil holding capacities of the soy okara did not significantly change (p > 0.05) after high-pressure pasteurization at 400 MPa and 600 MPa. High-pressure pasteurization is therefore a potential application technique for soy okara to produce a microbiologically safe product with maintained functional properties. However, more research is needed to optimize the process and to further investigate the microbiological species present in untreated soy okara to exclude any potential food safety risks.
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| 6. |
- Marefati, Ali, et al.
(författare)
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Encapsulation of Lactobacillus reuteri in W1/O/W2 double emulsions : Formulation, storage and in vitro gastro-intestinal digestion stability
- 2021
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Ingår i: LWT. - : Elsevier BV. - 0023-6438. ; 146
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Tidskriftsartikel (refereegranskat)abstract
- Encapsulation of Lactobacillus reuteri in the internal aqueous phase of W1/O/W2 emulsions was investigated. Microstructure of the emulsions was evaluated using a particle size analyzer and light microscopy. The encapsulation properties were evaluated in terms of encapsulation efficiency (EE) for freshly prepared samples and encapsulation stability (ES) during storage and in vitro digestion and the results were compared to control. Particle size analysis showed that encapsulation of the bacteria increased the droplet sizes of W1/O emulsions significantly (P < 0.05) from 3.5 ± 0.2 to 4.8 ± 0.4 μm which was verified by microscopy. Neither encapsulation nor storage changed (P > 0.05) the droplet sizes for double emulsions (14.9 ± 0.3 μm) compared to control (15.5 ± 0.4 μm) which remained stable through storage period. The EE was 7.23 ± 0.07 Log CFU/mL. During cold storage, the ES decreased with a higher pace for control (from 6.18 ± 0.03 to <1 Log CFU/mL) compared to formulations with encapsulated bacteria (from 7.23 ± 0.07 to 2.82 ± 0.10 Log CFU/mL). Finally, during in vitro digestion, the ES decreased with a higher rate for control (from 6.25 ± 0.36 to 2.69 ± 0.06 Log CFU/mL) compared to encapsulated samples (from 6.69 ± 0.07 to 4.64 ± 0.06 Log CFU/mL). The results showed that encapsulation of Lactobacillus reuteri using double emulsions can protect the probiotics during storage and in vitro gastro-intestinal digestion.
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| 7. |
- Marefati, Ali, et al.
(författare)
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Fabrication of encapsulated oil powders from starch granule stabilized W/O/W Pickering emulsions by freeze-drying
- 2015
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Ingår i: Food Hydrocolloids. - : Elsevier BV. - 0268-005X. ; 51, s. 261-271
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Tidskriftsartikel (refereegranskat)abstract
- The process stability of water-in-oil-in-water (W/O/W) double emulsions stabilized with food-grade OSA modified quinoa starch granules was investigated. The effect of oils with differing melting points, as well as the effect of in situ partial gelatinization of the granules, on stability of emulsions was also investigated. The physical stability and release of a tracer (carmine) from the internal aqueous phase of double emulsions were characterized after each process stage using particle size analysis, light microscopy and spectrophotometry. When liquid shea oil was used the particle sizes varied in mode of D[4,3] from 28 +/- 2 mu m for initial fresh double emulsions to 90 +/- 7 mu m for heat treated and 210 +/- 11 mu m for heat treated, freeze-dried and reconstituted emulsions. Non-heat treated emulsions collapsed on freeze-drying due to high susceptibility of liquid oil droplets towards destabilization, when the external aqueous phase is crystalized. When solid shea oil was used the mode of D[4,3] varied from 48 +/- 0 mu m in initial emulsions to 118 +/- 3 mu m for heat treated emulsions and the freeze-dried and reconstituted emulsions showed 62 +/- 3 mu m or 85 +/- 11 mu m for non-heat treated and heat treated samples respectively. Reconstituted freeze-dried emulsion retained the encapsulated marker to over 97%. Overall, application of oil phase solid at room temperature and in situ heat treatment had a positive impact on process stability towards freezing and freeze drying. The result of this study revealed the feasibility to develop food-grade oil filled powders from OSA modified starch Pickering emulsions with approximately 70 wt% oil content by freeze-drying. (C) 2015 Elsevier Ltd. All rights reserved.
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| 8. |
- Marefati, Ali, et al.
(författare)
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Freezing and freeze-drying of Pickering emulsions stabilized by starch granules
- 2013
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Ingår i: Colloids and Surfaces A: Physicochemical and Engineering Aspects. - : Elsevier BV. - 0927-7757. ; 436, s. 512-520
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Tidskriftsartikel (refereegranskat)abstract
- The aim of this study was to investigate the possibility to produce novel powder materials based on chemically modified starch granule stabilized Pickering oil-in-water (O/W) emulsions. This study also investigated the effect of partial starch gelatinization in situ, dispersed phase type (two oil types with different melting points), freezing method and thawing, and freeze-drying and rehydrating on the overall properties of the emulsions. The emulsions showed high freeze thaw stability. The results of this study demonstrated the feasibility of the production of oil containing hydrocolloid-based powders, through combination of heat treated or even non-heat treated starch Pickering emulsions and freeze-drying. The final powders comprised high weight percentage of oil (over 80%, w/w). Upon rehydration of powders, the starch stabilized oil drops were found to be only moderately affected by the process with some aggregation observed. (C) 2013 Elsevier B.V. All rights reserved.
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| 9. |
- Marefati, Ali, et al.
(författare)
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In vitro intestinal lipolysis of emulsions based on starch granule Pickering stabilization
- 2019
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Ingår i: Food Hydrocolloids. - : Elsevier BV. - 0268-005X. ; 95, s. 468-475
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Tidskriftsartikel (refereegranskat)abstract
- The effect of barrier properties on in vitro intestinal lipolysis of three different types of emulsions based on oil-in-water starch granule Pickering stabilization has been investigated including non-heat treated, heat treated (gelatinized) and heat treated and stored (retrograded) emulsions. The stability of starch covered oil-water interfaces towards in vitro intestinal lipolysis was correlated to the rate of lipid hydrolysis using a pH-stat method. The results were compared with a sodium caseinate stabilized emulsion. The shape and size of the starch granules were characterized by scanning electron microscopy and light scattering. The physical properties of the emulsions were characterized by a light scattering particle size analyzer and light microscopy. In all cases, Pickering emulsions showed lower extents of lipolysis compared to the protein stabilized emulsion. In addition, heat treated starch Pickering emulsions were more susceptible to lipolysis compared to freshly prepared emulsions with no heat treatment. This was thought to be due to the gelatinized starch barrier being more susceptible to amylase present in the pancreatin. The results of this study demonstrate the interfacial layer properties can affect the rate and extent of lipolysis.
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| 10. |
- Marefati, Ali, et al.
(författare)
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Quinoa Starch Granules as Emulsion Stabilizers
- 2022
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Ingår i: Biology and Biotechnology of Quinoa : Super Grain for Food Security - Super Grain for Food Security. - Singapore : Springer Singapore. - 9789811638329 - 9789811638312 ; , s. 283-324
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Bokkapitel (refereegranskat)abstract
- Quinoa (Chenopodium quinoa Willd.) has gained recent popularity mainly due to its attractive nutritional profile and its ability to grow under extreme conditions such as salinity, acidity, drought, flooding, and frost as well as the functionality of its component. Starch is the main component of quinoa grain which constitutes up to 60% of the dry grain and plays a crucial role in the functional properties of quinoa. Quinoa starch granules are small, polygonal, and in the range of 0.5–3 μm, with unique physicochemical properties. These unique features have created research interest in the application of the quinoa starch for functional products such as stabilizer for creating Pickering emulsions. This chapter summarizes the application of starch granules in native and modified forms as particles in the stabilization of Pickering emulsions.
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| 11. |
- Marefati, Ali, et al.
(författare)
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Starch granule stabilized Pickering emulsions : an 8-year stability study
- 2020
-
Ingår i: Journal of the Science of Food and Agriculture. - : Wiley. - 0022-5142 .- 1097-0010. ; 100:6, s. 2807-2811
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Tidskriftsartikel (refereegranskat)abstract
- BACKGROUND: Pickering emulsions are known to have advantages over conventional emulsions, in particular, improved and long-term stability against coalescence. This research is an eight-year stability investigation of oil-in-water Pickering emulsions stabilized by quinoa starch granules modified by octenyl succinic anhydride (OSA). Two different concentrations of starch (i.e. 200 and 600 mg mL−1 based on oil) were used at oil fraction (ϕ) of 0.1. The emulsions were prepared using a high-pressure homogenizer. The emulsions were stored in a refrigerator (at 6 °C) and evaluated using particle size analyzer over the storage period and light microscopy at the end of the storage period. RESULTS: Starch granule stabilized Pickering emulsions produced by a high-pressure homogenizer displayed remarkable storage stability over the eight years with no indication of coalescence. In addition, the results showed that increasing the concentration of starch granules resulted in a decrease in droplet sizes. The sizes measured by the particle size analyzer showed a decline over the storage period which was due to dissociation of some networks of aggregated droplets that, in addition to representing smaller droplet sizes, resulted in the release of free and unbound starch entrapped in these networks. CONCLUSIONS: This study showed that Pickering emulsions produced by OSA modified starch granules from quinoa can be used in practical applications for the development of highly stable formulations when prolonged storage is required.
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| 12. |
- Marefati, Ali
(författare)
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Starch Pickering Emulsions : Process and Encapsulation Stability
- 2018
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- The emulsion stabilization functionality of surfactants and biopolymers can be replaced by solid particles adsorbed at the interface, where they create a category of emulsions known as Pickering emulsions. Recently, health and environmental concerns have led to new market demand for natural, biodegradable and renewable sources of ingredients. Starch granules meet these ingredient requirements and are also good candidates for stabilization of Pickering type emulsions due to their properties such as neutral color, taste, odor and being non-allergic. Starch granules are generally hydrophilic and in order to improve their emulsifying capacity they are modified with hydrophobic groups. The most widely used chemical modification is esterification with acid anhydride, such as octenyl succinic anhydride (OSA). Emulsions stabilized by OSA modified starch have shown to have high stability. Moreover, the application of a heat treatment can induce a partial gelatinization of the starch at the oil-water interface, which leads to changes in interfacial properties of the starch granule stabilized emulsions. This thesis focuses on the development and application of starch Pickering emulsions and has been carried out along three main lines of investigation where each line has its own section in the thesis. In the first section, the preparation and properties of oil-in-water emulsions stabilized by starch granules with small sizes, including quinoa, rice and amaranth, were investigated. In the second section, the process and encapsulation stabilities of the emulsions were evaluated in the context of simple oil-in-water and double water-in-oil-in-water emulsions, with or without heat treatment. In the third section, the physical and encapsulation stabilities of the emulsions during in vitro digestion were evaluated. Quinoa starch granules showed to have higher emulsifying efficiency both in the initial state and after accelerated stability testing. Moreover, the heat induced gelatinized layer showed to not only contribute to initial general stability, but also increased the process and encapsulation stabilities of the emulsions. Modified starch granules appeared to protect the emulsions against destabilization mechanisms during processing (i.e. freezing and freeze-drying). It was possible to create powders from starch stabilized Pickering emulsions with high oil content (up to 80%). Furthermore, emulsions stabilized by starch granules showed high stability for encapsulation of bioactive compounds during in vitro digestion. The results of this work can be used for the development of lipid-based encapsulated systems, in both liquid and powder forms for the delivery of bioactive compounds in food, pharmaceutical and cosmetic applications.
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| 13. |
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| 14. |
- Matos González, Maria, et al.
(författare)
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Combined emulsifying capacity of polysaccharide particles of different size and shape
- 2017
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Ingår i: Carbohydrate Polymers. - : Elsevier BV. - 0144-8617. ; 169, s. 127-138
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Tidskriftsartikel (refereegranskat)abstract
- The aim of this study is to understand mixed systems of two types of particles with different size and shape, quinoa starch granules (NQ) and cellulose nanocrystals (CNC), to stabilize oil-in-water (O/W) emulsions. This study considers the extent of Pickering stabilization with respect to which particle type dominates at droplet interfaces and how stability is affected by the addition of one particle type to already formed emulsions, or combining both, simultaneously. Results demonstrate that the order of addition has an influence allowing to predominantly have NQ particles at the interface when both types are added simultaneously. However when CNC is added first, both types are responsible for emulsion stabilization leading to a system with an intermediate droplet size yet with a higher stability compared to single particle formulations. A dual stabilization mechanism is observed, large particles prevent coalescence and small particles regulate the curvature of the interface and govern the droplet size.
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| 15. |
- Matos González, Maria, et al.
(författare)
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Comparative Emulsifying Properties of Octenyl Succinic Anhydride (OSA)-Modified Starch: Granular Form vs Dissolved State
- 2016
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Ingår i: PLoS ONE. - : Public Library of Science (PLoS). - 1932-6203. ; 11:8, s. 0160140-0160140
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Tidskriftsartikel (refereegranskat)abstract
- The emulsifying ability of OSA-modified and native starch in the granular form, in the dissolved state and a combination of both was compared. This study aims to understand mixed systems of particles and dissolved starch with respect to what species dominates at droplet interfaces and how stability is affected by addition of one of the species to already formed emulsions. It was possible to create emulsions with OSA-modified starch isolated from Quinoa as sole emulsifier. Similar droplet sizes were obtained with emulsions prepared at 7% (w/w) oil content using OSA-modified starch in the granular form or molecularly dissolved but large differences were observed regarding stability. Pickering emulsions kept their droplet size constant after one month while emulsions formulated with OSA-modified starch dissolved exhibited coalescence. All emulsions stabilized combining OSA-modified starch in granular form and in solution showed larger mean droplet sizes with no significant differences with respect to the order of addition. These emulsions were unstable due to coalescence regarding presence of free oil. Similar results were obtained when emulsions were prepared by combining OSA-modified granules with native starch in solution. The degree of surface coverage of starch granules was much lower in presence of starch in solution which indicates that OSA-starch is more surface active in the dissolved state than in granular form, although it led to unstable systems compared to starch granule stabilized Pickering emulsions, which demonstrated to be extremely stable.
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| 16. |
- McNamee, Cathy E., et al.
(författare)
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Rice starch particle interactions at air/aqueous interfaces-effect of particle hydrophobicity and solution ionic strength
- 2018
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Ingår i: Frontiers in Chemistry. - : Frontiers Media SA. - 2296-2646. ; 6:MAY
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Tidskriftsartikel (refereegranskat)abstract
- Starch particles modified by esterification with dicarboxylic acids to give octenyl succinic anhydride (OSA) starch is an approved food additive that can be used to stabilize oil in water emulsions used in foods and drinks. However, the effects of the OSA modification of the starch particle on the interfacial interactions are not fully understood. Here, we directly measured the packing of films of rice starch granules, i.e., the natural particle found inside the plant, at air/aqueous interfaces, and the interaction forces in that system as a function of the particle hydrophobicity and ionic strength, in order to gain insight on how starch particles can stabilize emulsions. This was achieved by using a combined Langmuir trough and optical microscope system, and the Monolayer Interaction Particle Apparatus. Native rice starch particles were seen to form large aggregates at air/water interfaces, causing films with large voids to be formed at the interface. The OSA modification of the rice starches particles decreased this aggregation. Increasing the degree of modification improved the particle packing within the film of particles at the air/water interface, due to the introduction of inter-particle electrostatic interactions within the film. The introduction of salt to the water phase caused the particles to aggregate and form holes within the film, due to the screening of the charged groups on the starch particles by the salt. The presence of these holes in the film decreased the stiffness of the films. The effect of the OSA modification was concluded to decrease the aggregation of the particles at an air/water interface. The presence of salts, however, caused the particles to aggregate, thereby reducing the strength of the interfacial film.
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| 17. |
- Morán, Diana, et al.
(författare)
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Bio-based starch nanoparticles with controlled size as antimicrobial agents nanocarriers
- 2024
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Ingår i: Reactive and Functional Polymers. - 1381-5148. ; 198
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Tidskriftsartikel (refereegranskat)abstract
- Starch nanoparticles (SNPs) have been synthesized by nanoprecipitation method using starches from different botanical sources in native form and modified with octenyl succinic anhydride (OSA). SNPs were characterized in terms of size, morphology, charge, XRPD, FTIR and thermal properties. Spherical particles were obtained with sizes ranging from 54 to 108 nm and zeta potential values from −2 to −27 mV. Changes in size and stability related to the % OSA were observed for each starch. Starch granules showed A-type crystalline pattern while a loss of crystallinity was observed for SNPs. FTIR spectra demonstrated that OSA modification was barely affected by the nanoprecipitation and SNPs showed thermal properties similar to those of starch granules. SNPs with specific size can be synthesized by selecting the appropriate starch granules as raw material. This is especially relevant in certain bio-applications, where size must be precisely controlled, e.g., as nanocarriers for drug release or food fortification. To investigate the feasibility of SNPs as nanocarriers, vanillin-loaded SNPs were synthesized, achieving encapsulation efficiencies of 30% and loading capacities of 60%. The antimicrobial activity of vanillin-loaded SNPs was tested against Escherichia Coli (E. coli) with satisfactory results.
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| 18. |
- Morán, Diana, et al.
(författare)
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Synthesis of starch nanoparticles and their applications for bioactive compound encapsulation
- 2021
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Ingår i: Applied Sciences (Switzerland). - : MDPI AG. - 2076-3417. ; 11:10
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Tidskriftsartikel (refereegranskat)abstract
- In recent years, starch nanoparticles (SNPs) have attracted growing attention due to their unique properties as a sustainable alternative to common nanomaterials since they are natural, renewable and biodegradable. SNPs can be obtained by the breakdown of starch granules through different techniques which include both physical and chemical methods. The final properties of the SNPs are strongly influenced by the synthesis method used as well as the operational conditions, where a controlled and monodispersed size is crucial for certain bioapplications. SNPs are considered to be a good vehicle to improve the controlled release of many bioactive compounds in different research fields due to their high biocompatibility, potential functionalization, and high surface/volume ratio. Their applications are frequently found in medicine, cosmetics, biotechnology, or the food industry, among others. Both the encapsulation properties as well as the releasing processes of the bioactive compounds are highly influenced by the size of the SNPs. In this review, a general description of the different types of SNPs (whole and hollow) synthesis methods is provided as well as on different techniques for encapsulating bioactive compounds, including direct and indirect methods, with application in several fields. Starches from different botanical sources and different bioactive compounds are compared with respect to the efficacy in vitro and in vivo. Applications and future research trends on SNPs synthesis have been included and discussed.
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| 19. |
- Simsek, Senay, et al.
(författare)
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Chemical composition, digestibility and emulsification properties of octenyl succinic esters of various starches
- 2015
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Ingår i: Food Research International. - : Elsevier BV. - 0963-9969. ; 75, s. 41-49
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Tidskriftsartikel (refereegranskat)abstract
- Octenyl succinate starches are commonly used as emulsifiers and texturizing agents in many food-systems. Rice, tapioca, corn, wheat and potato starches were modified with octenyl succinic anhydride (OSA) at 3% level. Structural characterization, molecular weight, starch digestibility and physical properties of starch granule stabilized emulsions were studied for modified starches. Modified potato (0.022) and wheat (0.018) starches had the highest and lowest degrees of OSA substitution, respectively. For all starches, amylose and amylopectin molecular mass was significantly (P < 0.05) lower for OSA starches. OSA modification may have hydrolyzed the small amylose and amylopectin chains, or caused rearrangement of the starch molecules. Although the starch modification improved emulsification properties, botanical source showed more influence on this parameter. Overall, botanical source had more influence on functional properties than degree of substitution. Further studies on OSA group distribution and fine molecular structure of amylopectin and relationship with functional properties will be important Published by Elsevier Ltd.
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| 20. |
- Wahlgren, Marie, et al.
(författare)
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In vitro methods to study colon release : State of the art and an outlook on new strategies for better in-vitro biorelevant release media
- 2019
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Ingår i: Pharmaceutics. - : MDPI AG. - 1999-4923. ; 11:2
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Forskningsöversikt (refereegranskat)abstract
- The primary focus of this review is a discussion regarding in vitro media for colon release, but we also give a brief overview of colon delivery and the colon microbiota as a baseline for this discussion. The large intestine is colonized by a vast number of bacteria, approximately 10 12 per gram of intestinal content. The microbial community in the colon is complex and there is still much that is unknown about its composition and the activity of the microbiome. However, it is evident that this complex microbiota will affect the release from oral formulations targeting the colon. This includes the release of active drug substances, food supplements, and live microorganisms, such as probiotic bacteria and bacteria used for microbiota transplantations. Currently, there are no standardized colon release media, but researchers employ in vitro models representing the colon ranging from reasonable simple systems with adjusted pH with or without key enzymes to the use of fecal samples. In this review, we present the pros and cons for different existing in vitro models. Furthermore, we summarize the current knowledge of the colonic microbiota composition which is of importance to the fermentation capacity of carbohydrates and suggest a strategy to choose bacteria for a new more standardized in vitro dissolution medium for the colon.
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| 21. |
- Östbring, Karolina, et al.
(författare)
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The effect of ph and storage temperature on the stability of emulsions stabilized by rapeseed proteins
- 2021
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Ingår i: Foods. - : MDPI AG. - 2304-8158. ; 10:7
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Tidskriftsartikel (refereegranskat)abstract
- Rapeseed press cake (RPC), the by-product of rapeseed oil production, contains proteins with emulsifying properties, which can be used in food applications. Proteins from industrially produced RPC were extracted at pH 10.5 and precipitated at pH 3 (RPP3) and 6.5 (RPP6.5). Emulsions were formulated at three different pHs (pH 3, 4.5, and 6) with soy lecithin as control, and were stored for six months at either 4 °C or 30 °C. Zeta potential and droplet size distribution were analyzed prior to incubation, and emulsion stability was assessed over time by a Turbiscan instrument. Soy lecithin had significantly larger zeta potential (−49 mV to 66 mV) than rapeseed protein (−19 mV to 20 mV). Rapeseed protein stabilized emulsions with smaller droplets at pH close to neutral, whereas soy lecithin was more efficient at lower pHs. Emulsions stabilized by rapeseed protein had higher stability during storage compared to emulsions prepared by soy lecithin. Precipitation pH during the protein extraction process had a strong impact on the emulsion stability. RPP3 stabilized emulsions with higher stability in pHs close to neutral, whereas the opposite was found for RPP6.5, which stabilized more stable emulsions in acidic conditions. Rapeseed proteins recovered from cold-pressed RPC could be a suitable natural emulsifier and precipitation pH can be used to monitor the stability in emulsions with different pHs.
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