| 1. |
- Serge, M. A., et al.
(författare)
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Testing the Effect of Relative Pollen Productivity on the REVEALS Model : A Validated Reconstruction of Europe-Wide Holocene Vegetation
- 2023
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Ingår i: Land. - : MDPI. - 2073-445X. ; 12:5
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Tidskriftsartikel (refereegranskat)abstract
- Reliable quantitative vegetation reconstructions for Europe during the Holocene are crucial to improving our understanding of landscape dynamics, making it possible to assess the past effects of environmental variables and land-use change on ecosystems and biodiversity, and mitigating their effects in the future. We present here the most spatially extensive and temporally continuous pollen-based reconstructions of plant cover in Europe (at a spatial resolution of 1 degrees x 1 degrees) over the Holocene (last 11.7 ka BP) using the 'Regional Estimates of VEgetation Abundance from Large Sites' (REVEALS) model. This study has three main aims. First, to present the most accurate and reliable generation of REVEALS reconstructions across Europe so far. This has been achieved by including a larger number of pollen records compared to former analyses, in particular from the Mediterranean area. Second, to discuss methodological issues in the quantification of past land cover by using alternative datasets of relative pollen productivities (RPPs), one of the key input parameters of REVEALS, to test model sensitivity. Finally, to validate our reconstructions with the global forest change dataset. The results suggest that the RPPs.st1 (31 taxa) dataset is best suited to producing regional vegetation cover estimates for Europe. These reconstructions offer a long-term perspective providing unique possibilities to explore spatial-temporal changes in past land cover and biodiversity.
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| 2. |
- Yafa, C., et al.
(författare)
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Development of an ombrotrophic peat bog (low ash) reference material for the determination of elemental concentrations
- 2004
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Ingår i: Journal of Environmental Monitoring. - : Royal Society of Chemistry (RSC). - 1464-0325 .- 1464-0333. ; 6:493, s. 501-
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Tidskriftsartikel (refereegranskat)abstract
- Given the increasing interest in using peat bogs as archives of atmospheric metal deposition, the lack of validated sample preparation methods and suitable certified reference materials has hindered not only the quality assurance of the generated analytical data but also the interpretation and comparison of peat core metal profiles from different laboratories in the international community. Reference materials play an important role in the evaluation of the accuracy of analytical results and are essential parts of good laboratory practice. An ombrotrophic peat bog reference material has been developed by 14 laboratories from nine countries in an inter-laboratory comparison between February and October 2002. The material has been characterised for both acid-extractable and total concentrations of a range of elements, including Al, As, Ca, Cd, Cr, Cu, Fe, Hg, Mg, Mn, Na, Ni, P, Pb, Ti, V and Zn. The steps involved in the production of the reference material (i.e. collection and preparation, homogeneity and stability studies, and certification) are described in detail.
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| 3. |
- Gallego-Sala, Angela V., et al.
(författare)
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Latitudinal limits to the predicted increase of the peatland carbon sink with warming
- 2018
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Ingår i: Nature Climate Change. - : Springer Science and Business Media LLC. - 1758-678X .- 1758-6798. ; 8:10, s. 907-
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Tidskriftsartikel (refereegranskat)abstract
- The carbon sink potential of peatlands depends on the balance of carbon uptake by plants and microbial decomposition. The rates of both these processes will increase with warming but it remains unclear which will dominate the global peatland response. Here we examine the global relationship between peatland carbon accumulation rates during the last millennium and planetary-scale climate space. A positive relationship is found between carbon accumulation and cumulative photosynthetically active radiation during the growing season for mid- to high-latitude peatlands in both hemispheres. However, this relationship reverses at lower latitudes, suggesting that carbon accumulation is lower under the warmest climate regimes. Projections under Representative Concentration Pathway (RCP)2.6 and RCP8.5 scenarios indicate that the present-day global sink will increase slightly until around AD 2100 but decline thereafter. Peatlands will remain a carbon sink in the future, but their response to warming switches from a negative to a positive climate feedback (decreased carbon sink with warming) at the end of the twenty-first century.
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| 4. |
- Sjöström, Jenny K., 1978-, et al.
(författare)
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Complex evolution of Holocene hydroclimate, fire and vegetation revealed by molecular, minerogenic and biogenic proxies, Marais Geluk wetland, eastern Free State, South Africa
- 2023
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Ingår i: Quaternary Science Reviews. - 0277-3791 .- 1873-457X. ; 314
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Tidskriftsartikel (refereegranskat)abstract
- The Holocene climate history of Southern Africa remains inconclusive despite the increasing number of proxy records from the region. This might be related to the diversity of proxy records, how the proxies are interpreted, or that proxies may respond to more than one forcing (e.g. hydroclimate, fire, temperature.). Here, a 175-cm peat sequence from Free State, South Africa (28°17′53″S, 29°25′10.9″E), was analyzed using a comprehensive set of novel and conventional proxies, including isotopic (δ13C), elemental (CS-XRF), mineral (pXRD), molecular (FTIR-ATR and pyrolysis-GC-MS), grain size (Malvern 3000) and GSSC phytolith composition. The chronology was constructed through AMS radiocarbon dating (n = 7). The early Holocene (10,380–7000 cal yr BP) was characterized by an initial wet phase, followed by relative dryness, at least seasonally, evidenced by slow accumulation rates, low organic content and dominance of terrestrial vegetation in the organic matter matrix. From 7000 cal yr BP, decreasing temperatures, as evidenced in regional climate reconstructions, were associated at Marias Geluk with higher biogenic silica and organic matter content and an increase of moisture-adapted grasses, indicating increasingly mesic conditions. This trend was amplified after 6000 cal yr BP, co-occurring with a southward displacement of the ITCZ. Complex proxy dynamics were observed between 4300 and 2180 cal yr BP, with bulk organic proxies indicating a drier environment (lower carbon content, slow accumulation rates, enriched δ13C values) but the phytolith record pointing towards relatively mesic conditions. The period was also associated with increased fire frequency, that also reached the local wetland. We suggest that the period was associated with seasonally mesic conditions together with increased fire incidence, which affected some of the organic proxies. Increased fire activity was also recorded in the region, while the hydroclimatic indications differed. The last 2000 years, during which human activity is known to have increased in the region, was characterized by lower fire incidence and variable, but relatively moist, conditions. The hydroclimatic inferences for the last 2000 years are in line with previous studies from the region, but additional studies are needed to decipher if the decline in fire incidence was associated to climate forcings, human activities, or a combination of both. The multiproxy approach applied here - in particular the inclusion of FTIR-ATR and pyrolysis GC-MS - revealed a complex interplay between vegetation dynamics, hydrology and paleofire variability. This study confirms that relatively small Holocene temperature variations (compared to northern higher latitudes) were associated with major hydrological variability at Marais Geluk, and reinforces concerns from earlier studies that the hydroclimate of the region is vulnerable to climate change. The result s also show that the southward displacement of the ITCZ, and associated tropical air masses, likely had significant effects on regional hydrology and fire incidence.
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| 5. |
- Ferro-Vázquez, C., et al.
(författare)
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Comparing podzolization under different bioclimatic conditions
- 2020
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Ingår i: Geoderma. - : Elsevier. - 0016-7061 .- 1872-6259. ; 377
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Tidskriftsartikel (refereegranskat)abstract
- Silicate weathering and within soil redistribution of released metals are a near universal process believed to drive the formation of Podzols in various bioclimatic zones, ranging from tropical forest to Arctic environments. Yet the importance of climate and the fractionation of Al, Fe and Si in Podzols remains largely unknown. The aim of this study was to increase our understanding of climate-related variability in the podzolization mechanisms by conducing high-resolution chemical probing of seven soils in different bioclimatic zones and under different hydrological regimes: one well drained and one seasonally hydromorphic from the boreal zone (Sweden), two well-drained Podzols from a mild and humid area (NW Spain) and three, two poorly drained and one well drained soils, from the tropics (Brazil). The analytical strategy included seven selective dissolution techniques, in order to understand the distribution of Fe, Al and Si in organic (high, medium and low stability metal-OM complexes) and inorganic secondary compounds (short-range order and crystalline forms) in relation to their bioclimatic setting. Results indicate that the translocation of metals is coupled to the soil organic matter (SOM) mobilization in all three bioclimatic zones. The accumulation of metals and organic matter in the spodic horizons, in contrast, is contingent upon temperature, as well as on the local hydrological conditions and pH. Multivariate statistics allowed to identify the effect of climate, of soil hydrological conditions and of parent material in the soil vertical development. The high vertical resolution sampling and the extended fractionation employed were key for detecting the differences in Al, Fe and SOM dynamics in the studied soils, and revealed that different podzolization mechanisms are active in each bioclimatic zone.
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| 6. |
- Margalef, O., et al.
(författare)
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Environmental processes in Rano Aroi (Easter Island) peat geochemistry forced by climate variability during the last 70 kyr
- 2014
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Ingår i: Palaeogeography, Palaeoclimatology, Palaeoecology. - : Elsevier BV. - 0031-0182 .- 1872-616X. ; 414, s. 438-450
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Tidskriftsartikel (refereegranskat)abstract
- We analyze the geochemistry of Rano Aroi mire record (Easter Island) using bulk peat composition (C, N, S) and stable isotopes (delta C-13, delta N-15, delta S-34) and major, minor and trace elemental compositions obtained by ICP-AES (Al, Ti, Zr, Sc, V, Y, Fe, Mn, Th, Ba, Ca, Mg and Sr). Peat geochemistry and the pollen record are used to reconstruct the environmental changes during the last 70 kyr BP. Principal component analysis on ICP-AES data revealed that three main components account for the chemical signatures of the peat. The first component, characterized by lithogenic elements (combined signal of V. Al, Sc, Y, Cr, Cd, Ti, Zr and Cu), evidences long-term changes in the basal fluxes of mineral material into the mire. This component, in combination with stable isotopes and pollen data suggests a link between soil erosion and vegetation cover changes in the Rano Aroi watershed. The second component is identified by the signal of Fe, Mn, Th, Ba, Zr and Ti, and is indicative of strong runoff events during enhanced precipitation periods. The third component (tied mainly to Ca, Sr and Mg) reflects a strong peat oxidation event that occurred during an arid period with more frequent droughts, sometime between 39 and 31 kyr BP. Correlation coefficients and a multiple regression model (PCR analysis) between peat organic chemistry and the principal components of ICP-AES analysis were calculated. Isotope chemistry of the peat organic matter further contributes to define Rano Aroi environmental history: delta C-13 data corroborates a vegetation shift documented by the palynological record from C-4 to C-3 between 55 and 45 cal kyr BP; the delta N-15 record identifies periods of changes in mire productivity and denitrification processes, while the delta S-34 peat signature indicates a marine origin of S and significant diagenetic cycling. The geochemical and environmental evolution of Rano Aroi mire is coherent with the regional climatic variability and suggests that climate was the main forcing in mire evolution during the last 70 kyr BP. The coupling of geochemical and biological proxies improves our ability to decipher depositional processes in tropical and subtropical peatlands and to use these sequences for paleoenvironmental and paleoclimate reconstructions.
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| 7. |
- Martinez Cortizas, A., et al.
(författare)
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Reconstructing historical Pb and Hg pollution in NW Spain using multiple cores from the Chao de Lamoso bog (Xistral Mountains)
- 2012
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Ingår i: Geochimica et Cosmochimica Acta. - : Elsevier BV. - 0016-7037 .- 1872-9533. ; 82, s. 68-78
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Tidskriftsartikel (refereegranskat)abstract
- We have applied a single-bog multi-core approach to reconstruct historical Pb and Hg accumulation in an ombrotrophic bog from NW Spain, Chao de Lamoso (Xistral Mountains). Mercury was determined using a LECO-ALTEC AMA-254 analyzer, Pb with an EMMA-XRF analyzer and stable lead isotopes (four cores) by Quadrupole ICP-MS. Maximum concentrations were 74-122 mu g g(-1) for Pb and 142-300 ng g(-1) for Hg. Higher variability was found for Hg than for Pb (2-3 times and 1.5 times, respectively). The slopes of the relationship between Hg and Pb cumulative inventories also suggested differences in relative accumulation of both elements. This substantial spatial variability indicates that, compared with Pb, a more extended sampling may be needed for an accurate estimation of Hg accumulation in mires. The isotopic records showed higher and almost constant Pb-206/Pb-207 ratios (average 1.174 +/- 0.004) in the lower sections and a continuous decrease to the surface (minimum 1.141). By using the change in the isotopic composition of Pb we estimated a chronology for the last similar to 200 years which enabled and approximation of the temporal trends in metal pollution. Based on the average isotopic composition of the studied cores and the application of a simple binary mixing model, six periods with increasing proportions of pollution Pb were identified: prior to similar to 1875 AD, with an average proportion lower than 16%; similar to 1875-1910 AD, increasing up to 24%; similar to 1910-1950 AD, up to 35%; similar to 1950-1970, up to 54%; similar to 1970-1980 AD, up to 74%; and after similar to 1980 AD, increasing up to 80%. The period with the highest rate of increase in recent (since similar to 1900 AD) pollution Pb (equivalent to 2% year(-1)) seems to have started at the maximum in Pb accumulation around the early 1970s. The Hg records showed a more simple evolution with four main phases: prior to similar to 1875 AD with enrichments around 1.5-fold the background, similar to 1875-1955 AD with increasing enrichments; from similar to 1955 AD to similar to 1980 AD with maximum values (up to 4.2-fold); and from similar to 1980 AD to present, with a steady decline to 2.4-fold. For the most recent period (after similar to 1980 AD), the combination of decreasing Pb and Hg concentrations and accumulation rates/enrichments, and low Pb-206/Pb-207 ratios, may point to a higher relative importance of local sources (i.e. coal burning in a nearby power plant) in atmospheric metal pollution in the area.
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| 8. |
- Serrano, O., et al.
(författare)
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Millennial scale impact on the marine biogeochemical cycle of mercury from early mining on the Iberian Peninsula
- 2013
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Ingår i: Global Biogeochemical Cycles. - : American Geophysical Union (AGU). - 0886-6236 .- 1944-9224. ; 27:1, s. 21-30
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Tidskriftsartikel (refereegranskat)abstract
- The high-resolution mercury record of a Posidonia oceanica mat in the northwest Mediterranean provides an unprecedented testimony of changes in environmental mercury (Hg) loading to the coastal marine environment over the past 4315 yr BP. The period reconstructed made it possible to establish tentative preanthropogenic background Hg levels for the area (6.8 +/- 1.5 ng g(-1) in bulk sediments). A small, but significant, anthropogenic Hg increase was identifiable by similar to 2500 yr BP, in agreement with the beginning of intense mining in Spain. Changes in the record suggest four major periods of anthropogenic Hg pollution inputs to the Mediterranean: first, during the Roman Empire (2100-1800 yr BP); second, in the Late Middle Ages (970-650 yr BP); third, in the modern historical era (530-380 yr BP); and fourth, in the industrial period (last 250 years), with Hg concentrations two-, four-, five-, and tenfold higher than background concentrations, respectively. Hg from anthropogenic sources has dominated during the last millennium (increase from similar to 12 to similar to 100 ng g(-1)), which can be related to the widespread historical exploitation of ore resources on the Iberian Peninsula. The chronology of Hg concentrations in the mat archive, together with other Hg pollution records from the Iberian Peninsula, suggests regional-scale Hg transport and deposition and shows earlier marine Hg pollution than elsewhere in Europe. Moreover, the mat also records a higher number of historic contamination phases, in comparison with other natural archives, probably due to the fact that the bioaccumulating capacity of P. oceanica magnify environmental changes in Hg concentrations. In this study, we demonstrate the uniqueness of P. oceanica meadows as a long-term archive recording trends in Hg abundance in the marine coastal environment, as well as its potential role in the Mediterranean as a long-term Hg sink.
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| 9. |
- Beister, H, et al.
(författare)
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Mercury records in peat bogs
- 2006
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Ingår i: Peatlands: basin evolution and depository of records on global environmental and climatic changes. ; , s. 465–478-
-
Bokkapitel (refereegranskat)
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| 10. |
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| 11. |
- Boes, Xavier, et al.
(författare)
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Evaluation of conservative lithogenic elements (Ti, Zr, Al, and Rb) to study anthropogenic element enrichments in lake sediments
- 2011
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Ingår i: Journal of Paleolimnology. - Dordrecht : Springer. - 0921-2728 .- 1573-0417. ; 46:1, s. 75-87
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Tidskriftsartikel (refereegranskat)abstract
- In lake sediment investigations of heavy metal pollution history, it has become a common approach to calculate enrichment factors (EFs) by normalizing elemental distributions to a reference lithogenic element. However, this approach requires that the reference element remains stable once it has been deposited to the sediment (it is not affected by diagenetic processes). This is rarely studied in well-controlled field experiments. Here, we test the commonly used reference elements titanium (Ti), zirconium (Zr), aluminum (Al), and rubidium (Rb). We use a unique series of freeze cores collected in different years since 1979 in Lake Nylandssjon in northern Sweden. This lake has sediment with distinct varves (annually laminated deposit). Element concentrations in individual varves were analyzed using X-ray fluorescence (XRF) spectroscopy. By tracking the newly formed surface varve from different cores across this core series, i.e., following the element concentration in a specific varve as it becomes progressively aged, it was possible to assess the potential impact of diagenetic processes on geochemical signatures. Results confirm the conservative character of the studied elements; there was neither an increasing nor a decreasing concentration trend with time during sediment ageing for any of these elements. Secondly, we addressed the question 'which of them is the most appropriate for EFs estimates with the aim of distinguishing anthropogenic from geogenic inputs, for example in pollution studies'. To assess the reliability of the EFs we used lead (Pb) as an example, because anthropogenic Pb in the sediment could be independently calculated using stable Pb isotopes. When anthropogenic Pb concentrations calculated with Pb-EFs were compared to the anthropogenic Pb concentrations derived from stable Pb isotopes, the differences found were 20% for Ti, 10% for Zr, 11% for Al, and 27% for Rb when upper continental crust concentrations were used for the background ratio. Based on the results from Nylandssjon our suggestions are that (1) when using EFs on a single core, which is the normal case in paleolimnology, multiple reference elements should be used together and (2) the results from those should be critically evaluated.
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| 12. |
- Cooke, Colin A., et al.
(författare)
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Environmental archives of atmospheric Hg deposition : a review
- 2020
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Ingår i: Science of the Total Environment. - : Elsevier. - 0048-9697 .- 1879-1026. ; 709
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Forskningsöversikt (refereegranskat)abstract
- Environmental archives offer an opportunity to reconstruct temporal trends in atmospheric Hg deposition at various timescales. Lake sediment and peat have been the most widely used archives; however, new records from ice, tree rings, and the measurement of Hg stable isotopes, are offering new insights into past Hg cycling. Preindustrial Hg deposition has been studied over decadal to millennial timescales extending as far back as the late Pleistocene. Exploitation of mercury deposits (mainly cinnabar) first began during the mid to late Holocene in South America, Europe, and Asia, but increased dramatically during the Colonial era (1532-1900) for silver production. However, evidence for preindustrial Hg pollution is restricted to regions directly downwind or downstream of cinnabar or precious metal mining centers. Excluding these areas, there has been an approximately four-fold increase in atmospheric deposition globally over the industrial era (i.e., since 1800-1850), though regional differences exist, especially during the early 20th Century. Lake sediments, peat, ice, and tree rings are all influenced by (and integrate) a range of processes. For example, lake sediments are influenced by atmospheric deposition, sediment focusing, and the input of allochthonous material from the watershed, peat records reflect atmospheric deposition and biotic uptake, ice cores are a record of Hg scrubbed during precipitation, and tree rings record atmospheric concentrations. No archive represents an absolute record of past Hg deposition or concentrations, and post-depositional transformation of Hg profiles remains an important topic of research. However, natural archives continue to provide important insight into atmospheric Hg cycling over various timescales.
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| 13. |
- Ferro-Vazquez, C., et al.
(författare)
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Metal and organic matter immobilization in temperate podzols : a high resolution study
- 2014
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Ingår i: Geoderma. - : Elsevier. - 0016-7061 .- 1872-6259. ; 217, s. 225-234
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Tidskriftsartikel (refereegranskat)abstract
- Aluminium and Fe fractions were obtained in samples from two temperate podzols by selective extraction with NaOH (Al-n, Fe-n), Na-dithionite-citrate (Al-d, Fe-d), acid NH4-oxalate (Al-o, Fe-o) and Na-pyrophosphate (Al-p, Fe-p) following the traditional fractionation procedures, and also by the use of the chlorides of K (Al-K), La (Al-La) and Cu (Al-cu) as non-buffered extractants for Al. Carbon content was also determined in the Na-pyrophosphate extract (C-p). Soil sampling was done at high-resolution to allow a more detailed characterization of the vertical processes than the traditional sampling by whole soil horizons. Results showed that Al-p and Fe-p make a large proportion of the Alo and Fe-o meaning that organoaluminic complexes dominated in the "active" metal pool instead of inorganic compounds. The degree of metal saturation of soil organic matter (estimated by the (Al-p Fe-p)/C-p molar ratios) increases with depth, especially in the uppermost samples of spodic horizons (Bhs1) where it increases up to 0.1. Aluminium dominates in the adsorption positions of the organic matter in the spodic horizon (Fe-p/Al-p ratios <0.5), except in the Bhs1 horizon (ratios > 1), indicating that the immobilization of Fe containing complexes occurs 10-15 cm above that of Al The highly stable Al-OM complexes accounted on average for 60% of the organoaluminic associations (>70% in the Bhs horizons). The moderately stable complexes predominate in A horizons (57-77% in ACB1 and 37-48% in ACB2) and the largest proportions of low stability complexes were found in the uppermost samples of the spodic horizons (Bhs1) of both soils (9-21%), together with the highest Fep contents and a decrease in pH values. From a stepwise multiple regression model it is suggested that pH is the main variable accounting for the stability of Al-OM compounds together with C and organically bound Fe contents. It is suggested that the illuviation of unsaturated organic acids lower the pH in upper spodic horizons, leading to the complexation of metals from formerly precipitated organometallic complexes and/or leading to their redissolution, enabling their migration to deeper soil layers. Iron complexes would be less soluble at soil pH, resulting in a differentiation of an upper Fe-rich Bhs1 horizon and a lower Bhs2 Al-rich horizon. The depth variation in C accumulation was found to be related to the proportion of highly stable Al-OM fraction.
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| 14. |
- Gälman, Veronika, 1969-, et al.
(författare)
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The role of iron and sulfur in the visual appearance of lake sediment varves
- 2009
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Ingår i: Journal of Paleolimnology. - : Springer Netherlands. - 0921-2728 .- 1573-0417. ; 42:1, s. 141-153
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Tidskriftsartikel (refereegranskat)abstract
- Easily discernible sediment varves (annual laminations) may be formed in temperate zone lakes, and reflect seasonal changes in the composition of the accumulating material derived from the lake and its catchment (minerogenic and organic material). The appearance of varves may also be influenced by chemical processes. We assessed the role of iron (Fe) and sulfur (S) in the appearance of varves in sediments from Lake Nylandssjön in northern Sweden. We surveyed Fe in the lake water and established whether there is internal transport of Fe within the sediment. We used a unique collection of seven stored freeze cores of varved sediment from the lake, collected from 1979 to 2004. This suite of cores made it possible to follow long-term changes in Fe and S in the sediment caused by processes that occur in the lake bottom when the sediment is ageing. We compared Fe and S concentrations using X-ray fluorescence spectroscopy (XRF) in specific years in the different cores. No diagenetic front was found in the sediment and the data do not suggest that there is substantial vertical transport of Fe and S in the sediment. We also modeled Fe and S based on thermodynamic, limnological, and sediment data from the lake. The model was limited to the five components H+, e-, Fe3+, SO42-, H2CO3 and included the formation of solid phases such as Fe(OH)3 (amorphous), FeOOH (aged, microcrystalline), FeS and FeCO3. Modeling showed that there are pe (redox) ranges within which either FeS or Fe(OH)3/FeOOH is the only solid phase present and there are pe ranges within which the two solid phases co-exist, which supports the hypothesis that blackish and grey-brownish layers that occur in the varves were formed at the time of deposition. This creates new possibilities for deciphering high-temporal-resolution environmental information from varves.
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| 15. |
- Kylander, Malin E., et al.
(författare)
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Mineral dust as a driver of carbon accumulation in northern latitudes
- 2018
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Ingår i: Scientific Reports. - : Springer Science and Business Media LLC. - 2045-2322 .- 2045-2322. ; 8:1
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Tidskriftsartikel (refereegranskat)abstract
- Peatlands in northern latitudes sequester one third of the world's soil organic carbon. Mineral dusts can affect the primary productivity of terrestrial systems through nutrient transport but this process has not yet been documented in these peat-rich regions. Here we analysed organic and inorganic fractions of an 8900-year-old sequence from Store Mosse (the "Great Bog") in southern Sweden. Between 5420 and 4550 cal yr BP, we observe a seven-fold increase in net peat-accumulation rates corresponding to a maximum carbon-burial rate of 150 g C m(-2) yr(-1) -more than six times the global average. This high peat accumulation event occurs in parallel with a distinct change in the character of the dust deposited on the bog, which moves from being dominated by clay minerals to less weathered, phosphate and feldspar minerals. We hypothesize that this shift boosted nutrient input to the bog and stimulated ecosystem productivity. This study shows that diffuse sources and dust dynamics in northern temperate latitudes, often overlooked by the dust community in favour of arid and semi-arid regions, can be important drivers of peatland carbon accumulation and by extension, global climate, warranting further consideration in predictions of future climate variability.
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| 16. |
- López-Merino, Lourdes, et al.
(författare)
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Reconstructing the impact of human activities in a NW Iberian Roman mining landscape for the last 2500 years
- 2014
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Ingår i: Journal of Archaeological Science. - : Elsevier. - 0305-4403 .- 1095-9238. ; 50, s. 208-218
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Tidskriftsartikel (refereegranskat)abstract
- Little is known about the impact of human activities during Roman times on NW Iberian mining landscapes beyond the geomorphological transformations brought about by the use of hydraulic power for gold extraction. We present the high-resolution pollen record of La Molina mire, located in an area intensely used for gold mining (Asturias, NW Spain), combined with other proxy data from the same peat core to identify different human activities, evaluate the strategies followed for the management of the resources and describe the landscape response to human disturbances. We reconstructed the timing and synchronicity of landscape changes of varying intensity and form occurred before, during and after Roman times. An open landscape was prevalent during the local Late Iron Age, a period of relatively environmental stability. During the Early Roman Empire more significant vegetation shifts took place, reflected by changes in both forest (Corylus and Quercus) and heathland cover, as mining/metallurgy peaked and grazing and cultivation increased. In the Late Roman Empire, the influence of mining/metallurgy on landscape change started to disappear. This decoupling was further consolidated in the Germanic period (i.e., Visigothic and Sueve domination of the region), with a sharp decrease in mining/metallurgy but continued grazing. Although human impact was intense in some periods, mostly during the Early Roman Empire, forest regeneration occurred afterwards: clearances were local and short-lived. However, the Roman mining landscape turned into an agrarian one at the onset of the Middle Ages, characterized by a profound deforestation at a regional level due to a myriad of human activities that resulted in an irreversible openness of the landscape.
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| 17. |
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| 18. |
- Martínez Cortizas, Antonio, et al.
(författare)
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Structural equation modeling of long-term controls on mercury and bromine accumulation in Pinheiro mire (Minas Gerais, Brazil)
- 2021
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Ingår i: Science of the Total Environment. - : Elsevier BV. - 0048-9697 .- 1879-1026. ; 757
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Tidskriftsartikel (refereegranskat)abstract
- The application of statistical modeling is still infrequent in mercury research in peat, despite the ongoing debate on the weight of the diverse factors (climate, peat decomposition, vegetation changes, etc.) that may affect mercury accumulation. One of the few exceptions is the Hg record of Pinheiro mire (souheast Brazil). Previous studies on this mire modeled mercury using principal components regression and partial least squares. These methods assume independence between factors, which is seldom the case in natural systems, thus hampering the identification of mediating effects and interactions. To overcome these limitations, in this reserach we use structural equation modeling (PLS-SEM) to model mercury and bromine peat records - bromine has been used in some investigations to normalize mercury accumuation. The mercury model explained 83% of the variance and suggested a complex control: increased peat decomposition, dust deposition and humid dimates enhanced mercury accumulation, while increased mineral fluxes resulted in a decrease in mercury accumulation. The bromine model explained 90% of the variation in concentrations: increased dust deposition and peat decomposition promoted bromine accumulation, while time (i.e. peat age) promoted bromine depletion. Thus, although mercury and bromine are both organically bound elements with relevant atmospheric cycles the weights of the factors involved in their accumulation differed significantly. Our results suggest caution when using bromine to normalize mercury accumulation. PLS-SEM results indicate a large time dependence of peat decomposition, catchment mineral fluxes, long-term climate change, and atmospheric deposition: while atmospheric dust, mineral fluxes and peat decomposition showed high to moderate climate dependency. In particular, they also point to a relevant role of autogenic processes (i.e. the build up and expansion of the mire within the catchment), which controlled local mineral fluxes; an aspect that has seldom been considered.
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| 19. |
- Muller, Joanne, et al.
(författare)
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Possible evidence for wet Heinrich phases in tropical NE Australia: The Lynch's Crater deposit
- 2008
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Ingår i: Quaternary Science Reviews. ; 27, s. 468-475
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Tidskriftsartikel (refereegranskat)abstract
- Unarguably, one of the most significant paleoclimatological discoveries of the last two decades has been that of abrupt climate events (Dansgaard-Oeschger cycles and Heinrich events). Most evidence for these events has originated from the high-latitude Northern Hemisphere, with few records documenting the response of the low latitude Southern Hemisphere. Here we present new data from Lynch's Crater, a unique terrestrial record from NE-Australia that may show evidence for southward propagations of the Intertropical Convergence Zone (ITCZ) during abrupt climate perturbations as a result of alteration of the low latitude air masses. Proxies for precipitation/wetness indicate enhanced rainfall in the region during Heinrich events (H events 1-3) and the 8.2 ka Northern Hemisphere cold event. A fully coupled atmosphere/ocean climate model simulating a 1 Sv freshwater influx to the North Atlantic Ocean produces a scenario which agrees with the climate changes shown by the Lynch's Crater record. The model shows precipitation anomalies that include a southward migration of the ITCZ and a zonal shift in mid-latitude storm tracks over the Southern Hemisphere equatorial region. These data indicate large-scale shifts of the austral summer ITCZ position that is known to control monsoonal precipitation in NE Australia. This terrestrial record from Australia may demonstrate the involvement of the tropical western Pacific Ocean in ITCZ migrations during abrupt climate events of the last glacial period. Defining such past migrations offers insight into the importance and role of the equatorial region in global climate dynamics.
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| 20. |
- Muller, Joanne, et al.
(författare)
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The use of principle component analyses in characterising trace and major elemental distribution in a 55 kyr peat deposit in tropical Australia: Implications to paleoclimate
- 2008
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Ingår i: Geochimicia et Cosmochimica Acta. ; 72, s. 449-463
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Tidskriftsartikel (refereegranskat)abstract
- The Lynch's Crater peat deposit in NE-Australia is a sensitive environmental archive located in the tropical Southern Hemisphere. This unique deposit illustrates that local and regional changes had a profound effect on the local Australian ecosystem over the past 55 kyr. To obtain a proxy of past climate changes, trace and major element geochemistry analyses were applied to a 13 m peat core from the crater. Principle component analysis (PCA) was used to identify the main factors that control elemental distribution in the peat and to add interpretative strength to the geochemical behavior of selected major and trace elements. For example, Sc, Al, Cu, and Pb were found to be related to increased erosion of the basin soils, and from this, several periods of significant flux from atmospheric input and/or terrigenous run-off were identified. Geochemically mobile elements during rock weathering and pedogenesis, such as Mg, Ca, and Sr helped to identify the peat ombrotrophic-minerotrophic boundary at ~1.5 m depth and offered important information about fluxes of these nutrients to the mire and their dynamics within the deposit. Arsenic and V comparisons between the peat record (high concentrations in some peat sections) and in local basin rocks (very low concentrations), suggested the presence of a long range, atmospheric dust source early in the formation of the mire. The Lynch's Crater peat record presents a continuous record of environmental change in tropical Australia and contributes new understanding to geochemical processes in peatlands.
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| 21. |
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| 22. |
- Renson, V, et al.
(författare)
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Lead isotopic analysis within a multiproxy approach to trace pottery sources. The example of White Slip II sherds from Late Bronze Age sites in Cyprus and Syria.
- 2013
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Ingår i: Applied Geochemistry. - : Elsevier BV. - 0883-2927 .- 1872-9134. ; 28, s. 220-234
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Tidskriftsartikel (refereegranskat)abstract
- Lead isotope analyses were carried out on fragments of White Slip II ware, a Late Bronze Age Cypriote pottery ware, and on raw materials possibly used for their production. Sherds originate from three Late Bronze Age sites (Hala Sultan Tekke and Sanidha in Cyprus and Minet el-Beida in Syria) and clays come from the surroundings of Sanidha, a production site for White Slip ware. X-ray fluorescence (XRF) and a Principal Component Analysis (PCA) are combined with Pb isotope analyses to further investigate the effectiveness of the latter method within a multiproxy approach for pottery provenance study. The pottery sherds from the three sites are compared between themselves and with potential raw material. Additional X-ray diffraction (XRD) and analyses using a scanning electron microscope (SEM) equipped with an energy dispersive X-ray detection (EDX) facility were performed on selected sherds and clays. This work confirms that the clay source used for pottery production in Sanidha derives from local weathered gabbro. It also shows that different origins can be proposed for White Slip II ware sherds from Hala Sultan Tekke and Minet el-Beida and that clays were prepared prior to White Slip II ware production. It finally confirms the effectiveness of Pb isotopes in tracing pottery provenance not only by comparing sherd assemblages but also by comparing sherds to potential raw materials. (C) 2012 Elsevier Ltd. All rights reserved.
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| 23. |
- Rydberg, Johan, et al.
(författare)
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Geochemical assessment of an annually laminated lake sediment record from northern Sweden : a multi-core, multi-element approach
- 2014
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Ingår i: Journal of Paleolimnology. - : Springer Science and Business Media LLC. - 0921-2728 .- 1573-0417. ; 51:4, s. 499-514
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Tidskriftsartikel (refereegranskat)abstract
- We used seven annually laminated (varved) sediment cores from Nylandssjon, a lake in northern Sweden, to assess between-core variation and diagenetic changes at annual resolution. By using several cores, multiple elements and employing principal components analysis (PCA), we also studied how the geochemical composition changed over time, and assessed to what extent these changes were related to variations in the weather. There are between-core differences for aluminum, silica, lead, titanium, zirconium and dry-mass accumulation rate. Diagenesis causes a decrease in bromine, as well as carbon, nitrogen and varve thickness, as reported in previous publications. In spite of anoxic bottom waters phosphorus is not lost from the sediment. In fact, there is an increase in phosphorus concentrations with time. The PCA identified four principal components (PCs). PC-1 accounts for the relative content of mineral and organic material; PC-2 represents mineral-particle grain size; PC-3 reflects phosphorus loading and PC-4 reflects atmospheric pollution. Variations in the weather partly explain the temporal patterns in PC-1 and PC-2: cold winters, i.e. more accumulation of snow, resulted in more mineral than organic matter (i.e. higher PC-1 scores), and increased the relative amount of coarse-grained mineral particles in the sediment (i.e. lower PC-2 scores). Increased spring precipitation had a weak positive effect on the PC-2 scores by promoting the transport of fine-grained material. However, the influence of weather is weak, explaining at most 30 % of the variance, and hence, other factors, e.g. land use and its effect on soil erosion, seem to be more important for the sediment geochemical composition. The importance of land use is also exemplified by an increase in PC-3 scores in the late 1970s, which can be attributed to a shift in agricultural practices that resulted in increased phosphorus loading to the lake. In summary, our findings show that down-core trends are reproducible between cores, but between-core variability and diagenesis need to be considered when interpreting some elements. We also conclude that there is a need to constrain temporal changes in land use before using lake sediments to study changes in weather or climate.
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| 24. |
- Sjöström, Jenny K., 1978-, et al.
(författare)
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Late Holocene peat paleodust deposition in south-western Sweden : exploring geochemical properties, local mineral sources and regional aeolian activity
- 2022
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Ingår i: Chemical Geology. - : Elsevier. - 0009-2541 .- 1872-6836. ; 602
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Tidskriftsartikel (refereegranskat)abstract
- Atmospheric mineral dust not only interacts with the climate system by scattering incoming solar radiation and affecting atmospheric photochemistry, but also contributes critical nutrients to marine and terrestrial ecosystems. In a high-resolution analysis of paleodust deposition, peat development and soil dust sources, we assess the interplay between dust deposition and bog development of the Davidsmosse bog in south-western Sweden. Analyses of the 5400-year record (458 cm) included radiocarbon dating, bulk density, ash content, chemical and mineralogical composition and carbon stable isotopes, subsequently explored using principal component analysis. Fourteen dust events (DEs) were recorded (cal BP) in the peat sequence: 3580–3490; 3280; 3140; 3010–2840; 2740; 2610; 2480; 2340; 2240–2130; 1690; 1240; 960, 890–760, and 620–360. The majority of the DEs were coupled to increases in peat accumulation rates and increased nutrient content (N, P and K) suggesting that the DEs contributed with nutrients to the bog ecosystem, promoting increased accumulation. We also analyzed the chemical and mineral composition of potential mineral source deposits (separated into 6 grain-size fractions) from sites within a 4 km radius as well as aeolian dunes closer to the coast (25 km). The composition deposited on the present-day bog surface indicates that the bulk of the contemporary minerals have a local origin (<1.5 km), but the DEs may be of a more distant origin. The results also indicate that quartz and plagioclase feldspar content consistently increase with increasing grain-size, both in the source samples as well as in the peat sequence, and that the Si/Al ratio can be used to infer grain size changes in the peat. Two longer phases saw numerous DEs, between 2800 and 2130 cal BP and a stepwise increase from 960 towards 360 cal BP. The episodic character of the events, together with the inferred coarse grain size, suggest that the particles were deposited by (winter) storms. Future studies should include grain size analysis as well as a more in-depth comparison with regional paleo dust and storm records to increase knowledge on both transport processes (creep, saltation, suspension) and the climate processes driving late Holocene dust and storm events in Scandinavia.
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