| 1. |
- Hu, Wei, et al.
(författare)
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Axisymmetric and Asymmetric Naphthalene-Bisthienothiophene Based Nonfullerene Acceptors: On Constitutional Isomerization and Photovoltaic Performance
- 2020
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Ingår i: ACS Applied Energy Materials. - : American Chemical Society (ACS). - 2574-0962. ; 3:6, s. 5734-5744
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Tidskriftsartikel (refereegranskat)abstract
- Two pairs of constitutional isomers of fused-octacyclic nonfullerene acceptors (NFAs) based on a naphthalene-bisthienothiophene core with or without fluorination at the ending groups have been developed. Compared with the axisymmetric NFAs N66-IC and N66-2FIC with two six-member-ring bridges, their asymmetric constitutional isomers N65-IC and N65-2FIC both with one six-member-ring bridge and one five-member-ring bridge exhibit remarkable red-shifted absorption, higher crystallinity, and slightly down-shifted LUMO energy levels. Organic solar cells based on PBDB-T-2F:N65-2FIC achieved a promising power conversion efficiency of 10.19%, which is three times higher than that of its counterpart PBDB-T-2F:N66-2FIC cell (3.46%). While being blended with PBDB-T as the donor material, the asymmetric acceptor analogue N65-IC based solar cell pronounces a PCE of 9.03%, being significantly improved from that of 5.45% for the PBDB-T:N66-IC based cell, which is in consistency with the results from those cells from their both fluorinated donor and acceptor counterparts. Design rules on either both fluorinated, both nonfluorinated, or cross-combined donor/acceptors for device fabrication has been explored. In addition, PBDB-T-2F:N65-2FIC possesses very promising device stability with 85% of its initial PCE after an exposure time of 1500 h under one sun illumination, which is meaningful for their future commercial devices.
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| 2. |
- Liu, Shungang, et al.
(författare)
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The role of connectivity in significant bandgap narrowing for fused-pyrene based non-fullerene acceptors toward high-efficiency organic solar cells
- 2020
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Ingår i: Journal of Materials Chemistry A. - : Royal Society of Chemistry (RSC). - 2050-7488 .- 2050-7496. ; 8:12, s. 5995-6003
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Tidskriftsartikel (refereegranskat)abstract
- Great attention has been paid to developing low bandgap non-fullerene acceptors (NFAs) for matching wide bandgap donor polymers to increase the photocurrent and therefore the power conversion efficiencies (PCEs) of NFA organic solar cells, while pyrene-core based acceptor-donor-acceptor (A-D-A) NFAs have been mainly reported via the 2,9-position connection due to their bisthieno[3′,2′-b']thienyl[a,h]pyrene fused via a five-membered ring bridge at the ortho-position of pyrene as the representative one named FPIC5, which has prohibited further narrowing their energy gap. Herein, an acceptor FPIC6 was exploited by creating the 1,8-position connection through fusing as bisthieno[3′,2′-b′]thienyl[f-g,m-n]pyrene linked at the bay-position via a six-membered bridge, with enhanced push-pull characteristics within such A-D-A structure. As a structural isomer of FPIC5, FPIC6 exhibited a much lower bandgap of 1.42 eV (1.63 eV for FPIC5). Therefore, the photocurrent and PCE of PTB7-Th:FPIC6 cells were improved to 21.50 mA cm-2 and 11.55%, respectively, due to the balanced mobilities, better photoluminescence quenching efficiency and optimized morphology, which are both ∼40% better than those of PTB7-Th:FPIC5 cells. Our results clearly proved that a pyrene fused core with 1,8-position connection with electron-withdrawing end groups instead of 2,9-position connection is an efficient molecular design strategy to narrow the optical bandgap and improve the photovoltaic performance of NFA based OSCs.
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| 3. |
- Papaioannou, Georgios, et al.
(författare)
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A K-Seat-Based PID Controller for Active Seat Suspension to Enhance Motion Comfort
- 2022
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Ingår i: SAE International Journal of Connected and Automated Vehicles. - : SAE International. - 2574-0741 .- 2574-075X. ; 5:2
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Tidskriftsartikel (refereegranskat)abstract
- Autonomous vehicles (AVs) are expected to have a great impact on mobility by decreasing commute time and vehicle fuel consumption and increasing safety significantly. However, there are still issues that can jeopardize their wide impact and their acceptance by the public. One of the main limitations is motion sickness (MS). Hence, the last year's research is focusing on improving motion comfort within AVs. On one hand, users are expected to perceive AVs driving style as more aggressive, as it might result in excessive head and body motion. Therefore, speed reduction should be considered as a countermeasure of MS mitigation. On the other hand, the excessive reduction of speed can have a negative impact on traffic. At the same time, the user's dissatisfaction, i.e., acceptance and subjective comfort, will increase due to a longer journey time. Therefore, additional approaches to mitigating MS should be considered without affecting journey time, such as vehicle and seat suspension designs. In this direction, this article investigates a novel active seat suspension (ActiveK) that operates according to K-seat. The K-seat is a novel passive isolator with negative stiffness (NS) elements proven to enhance comfort, but has difficulties in design, which can be overcome with ActiveK. The ActiveK-seat is benchmarked against a passive seat model, a semi-active model with a continuously controllable electromagnetic damper (EMD), and a simple active model. The seat models are not only compared with regard to comfort but also for their ability to mitigate MS while the vehicle is driving on a real road path with a Class C road roughness. The results are very promising and show up to a 70% and 25% decrease in metrics for discomfort and MS incidence, respectively, compared to the rest of the seat model.
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| 4. |
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| 5. |
- Xia, Xiangjun, et al.
(författare)
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Event-Triggered H ∞ Controller for a Semi-active Seat Suspension to Enhance Motion Comfort of Automated Vehicles
- 2022
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Ingår i: SAE International Journal of Connected and Automated Vehicles. - : SAE International. - 2574-075X. ; 5:2
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Tidskriftsartikel (refereegranskat)abstract
- This article proposes a disturbance observer-based event-triggered H ∞ controller for a semi-active seat suspension that equips an advanced electromagnetic damper (EMD) system. Automated driving is one of the leading technologies of the automotive industry. However, automated vehicles (AVs) may increase the incidence of motion sickness (MS) and deteriorate motion comfort. This article investigates a semi-active seat suspension system and an advanced controller to improve the motion comfort of AVs. The disturbance force of the seat suspension has considerable influence on the system dynamic, and applying a constant model to describe the real-time disturbance force is unreliable. Therefore, a disturbance observer is designed to estimate the seat suspension disturbance force, and it is used to compensate the controller. The Bouc-Wen model is selected to compare with the disturbance observer and validate its effectiveness. Then an event-triggered H ∞ controller combined with the disturbance observer is proposed. The performance of the proposed controller is validated with experiments. Experimental results show that the proposed event-triggered H ∞ controller not only can save the communication resources of data transmission but also can work as a filter to increase motion comfort.
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