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- Lee, Sang-Han, et al.
(författare)
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Distribution of plutonium and americium in the marginal seas of the nothwest pacific ocean.
- 2003
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Ingår i: Deep-sea research. Part II, Topical studies in oceanography. - 0967-0645 .- 1879-0100. ; 50, s. 2727-2750
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Tidskriftsartikel (refereegranskat)abstract
- Plutonium isotopes and 241Am were studied in seawater and sediment from the East China Sea, the Yellow Sea, the East Sea/Sea of Japan, the Sea of Okhotsk, and the northwest Pacific Ocean, collected between 1993 and 1996 with the aim to contribute to better understanding the behaviour of plutonium and americium in the marine environment. 239,240Pu concentrations in surface water varied from 2.3 to 13 µBq l-1 in the East China Sea and from 3.5 to 9.4 µBq l-1 in the East Sea. The 239,240Pu vertical profiles in water showed a broad subsurface maximum between 500 and 1000 m with a range of 30-40 µBq l-1, and gradually decreased from 1000 m depth down to the seafloor. 241Am concentrations in surface water showed values from 1.1 to 2.2 µBq l -1 in the East Sea, from 1.0 to 3.1 µBq l-1 in the Sea of Okhotsk, and from 0.68 to 12.0 µBq l-1 in the northwest Pacific Ocean. The activity ratios of 241Am/239,240Pu in seawater showed values similar to the global fallout ratio, which suggests that the source of these radionuclides in the northwest Pacific Ocean is global fallout. However, the 241Am/239,240Pu activity ratios in sediment were found to be much higher (1.0-1.9) than the global fallout ratio (0.37), confirming that 241Am is scavenged from the water column more rapidly than 239,240Pu. The 239,240Pu inventories in the water column of the East Sea were from 0.98 to 93 Bq m-2 depending on water depth and sedimentation rates. The 241Am inventory in the water column east of Kamchatka was 6.3 ± 1.0 Bq m -2 and the sediment inventory in the Sea of Okhotsk was 16 ± 2 Bq m-2. 239,240Pu concentrations in sinking particles in the southwest Japan Basin were from 3.7 to 5.2 Bq kg-1 (dry weight) with fluxes of 0.19-4.50 mBq m-2 d-1 and at the Ulleung Basin from 2.4 to 3.7 Bq kg-1 (dry weight) with fluxes of 0.77-1.10 mBq m-2 d-1. The mean residence time of 239,240Pu in the water column of the East Sea derived from sediment trap data was 140 ± 20 years, 2-3 times less than in the Atlantic and Pacific oceans.
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| 2. |
- Luis Mas, Jose, et al.
(författare)
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Analysis of a major Aeolian dust input event and its impact on element fluxes and inventories at the DYFAMED site (Northwestern Mediterranean)
- 2020
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Ingår i: Marine Chemistry. - : ELSEVIER. - 0304-4203 .- 1872-7581. ; 223
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Tidskriftsartikel (refereegranskat)abstract
- Continental dust can be suspended and transported by the wind, reaching seawater masses far away from its source. The deposition of the aerosols on the ocean surface can alter the abundance of chemical species in the water column and contribute to element inventories in seafloor sediments. A major Saharan dust intrusion into the Western Mediterranean Sea was recorded at the DYFAMED site (Ligurian Sea) in 20th February 2004. We determined the influence of this dust event on the concentration of 30 minor and trace level elements (TE) in sinking particles collected by sediment traps deployed at 200 m and 1000 m depth, and how a dust flux event like this contributed to the exchange of TE, including Fe, with the water column during major dust events. With coupled sediment traps and aerosol samples, we assessed the short-term implications of dust events in the water column. The event produced a flux of fast (>111 m d(-1)) and slow ( < 20 m d(-1)) sinking dust particles, detected during 3 weeks at 200 m and 4 weeks at 1000 m depth. Additionally, the obtained results of element concentrations and particles flux show that a single dust deposition event can produce a sinking flux equivalent to annual deposition rates of elements relevant to biogeochemical cycles and/or pollution studies: (>60% for Cr and Cu, >70% for Al, > 80% for Ni and Zn, > 90% for V and Mn, > 100% for Fe and Pb). The corresponding Enrichment Factors (EF) for the minor and TE analyzed in the sediment traps during the dust event were calculated. EF was used to determine how minor and trace element concentrations in sinking particles vary. The values ranged between 0.35 and 421 in both 200 m and 1000 m sediment traps. For most of the analyzed elements, the obtained EF values were higher than 1. On the contrary, V, Y, Zr, Nb, and Ce showed EF similar to 1 while Cr, Ni, Cu, Zn, Sn, and Pb showed EF < 1. Despite the variability in the EF values, vertical fluxes integrated during the dust deposition event increased from 200 m to 1000 m, except for I, which decreased. This contrasts strongly with the element fluxes integrated for the complete sampling period, which decrease or increase from 200 m to 1000 m, depending on the element. This suggests that sinking dust particles were acting generally as sinks of the TE. We conclude that, apart from I, a substantial portion of the elements from atmospheric dust input from a single deposition event can reach the mesopelagic layer of the Western Mediterranean basin without increasing the budget of those elements in the water column.
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| 3. |
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| 4. |
- Povinec, Pavel, et al.
(författare)
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Reference material for radionuclides in sediment. IAEA-384 (Fangataufa lagoon sediment).
- 2007
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Ingår i: Journal of Radioanalytical and Nuclear Chemistry. - Dordrecht : Springer. - 0236-5731 .- 1588-2780. ; 273:2, s. 383-393
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Tidskriftsartikel (refereegranskat)abstract
- A reference material designed for the determination of anthropogenic and natural radionuclides in sediment, IAEA-384 (Fangataufa Lagoon sediment), is described and the results of certification are presented. The material has been certified for 8 radionuclides (40K, 60Co, 155Eu, 230Th, 238U, 238Pu, 239+240Pu and 241Am). Information values are given for 12 radionuclides (90Sr, 137Cs, 210Pb (210Po), 226Ra, 228Ra, 232Th, 234U, 235U, 239Pu, 240Pu and 241Pu). Less reported radionuclides include 228Th, 236U, 239Np and 242Pu. The reference material may be used for quality management of radioanalytical laboratories engaged in the analysis of radionuclides in the environment, as well as for the development and validation of analytical methods and for training purposes. The material is available from IAEA in 100 g units.
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