| 1. |
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| 2. |
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| 3. |
- Diaz Fernandez, Paloma, 1983, et al.
(författare)
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Quasifree (p, pN) scattering of light neutron-rich nuclei near N=14
- 2018
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Ingår i: Physical Review C. - 2469-9985 .- 2469-9993. ; 97:2
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Tidskriftsartikel (refereegranskat)abstract
- Background: For many years, quasifree scattering reactions in direct kinematics have been extensively used to study the structure of stable nuclei, demonstrating the potential of this approach. The (RB)-B-3 collaboration has performed a pilot experiment to study quasifree scattering reactions in inverse kinematics for a stable C-12 beam. The results from that experiment constitute the first quasifree scattering results in inverse and complete kinematics. This technique has lately been extended to exotic beams to investigate the evolution of shell structure, which has attracted much interest due to changes in shell structure if the number of protons or neutrons is varied. Purpose: In this work we investigate for the first time the quasifree scattering reactions (p, pn) and (p, 2p) simultaneously for the same projectile in inverse and complete kinematics for radioactive beams with the aim to study the evolution of single-particle properties from N = 14 to N = 15. Method: The structure of the projectiles O-23, O-22, and N-21 has been studied simultaneously via (p, pn) and (p, 2p) quasifree knockout reactions in complete inverse kinematics, allowing the investigation of proton and neutron structure at the same time. The experimental data were collected at the (RB)-B-3-LAND setup at GSI at beam energies of around 400 MeV/u. Two key observables have been studied to shed light on the structure of those nuclei: the inclusive cross sections and the corresponding momentum distributions. Conclusions: The knockout reactions (p, pn) and (p, 2p) with radioactive beams in inverse kinematics have provided important and complementary information for the study of shell evolution and structure. For the (p, pn) channels, indications of a change in the structure of these nuclei moving from N = 14 to N = 15 have been observed, i.e., from the 0d(5/2) shell to the 1s(1/2). This supports previous observations of a subshell closure at N = 14 for neutron-rich oxygen isotopes and its weakening for the nitrogen isotopes.
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| 4. |
- Halbach, Laura, et al.
(författare)
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Tidewater Glaciers and Bedrock Characteristics Control the Phytoplankton Growth Environment in a Fjord in the Arctic
- 2019
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Ingår i: Frontiers in Marine Science. - : Frontiers Media SA. - 2296-7745. ; 6
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Tidskriftsartikel (refereegranskat)abstract
- Meltwater discharge from tidewater glaciers impacts the adjacent marine environment. Due to the global warming, tidewater glaciers are retreating and will eventually terminate on land. Yet, the mechanisms through which meltwater runoff and subglacial discharge from tidewater glaciers influence marine primary production remain poorly understood, as data in close proximity to glacier fronts are scarce. Here, we show that subglacial meltwater discharge and bedrock characteristics of the catchments control the phytoplankton growth environment inside the fjord, based on data collected in close proximity to tidewater glacier fronts in Kongsfjorden, Svalbard from 26 to 31 July 2017. In the southern part of the inner fjord, glacial meltwater from subglacial discharge was rich in fine sediments derived from erosion of Devonian Old Red Sandstone and carbonate rock deposits, limiting light availability for phytoplankton (0.6 mg m(-3) Chl a on average, range 0.2-1.9 mg m(-3)). In contrast, coarser sediments derived from gneiss and granite bedrock and lower subglacial discharge rates were associated with more favourable light conditions facilitating a local phytoplankton bloom in the northern part of the inner fjord with mean Chl a concentration of 2.8 mg m(-3) (range 1.3-7.4 mg m(-3)). In the northern part, glacier meltwater was a direct source of silicic acid through weathering of the silica-rich gneiss and granite bedrock. Upwelling of the subglacial freshwater discharge plume at the Kronebreen glacier front in the southern part entrained large volumes of ambient, nutrient-rich bottom waters which led to elevated surface concentrations of ammonium, nitrate, and partly silicic acid. Total dissolved inorganic nitrogen transported to the surface with the upwelling of the subglacial discharge plume has a significant potential to enhance summer primary production in Kongsfjorden, with ammonium released from the seafloor being of particular importance. The transition from tidewater to land-terminating glaciers may, thus, reduce the input of nutrients to the surface layer with negative consequences for summer productivity.
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| 5. |
- Cederkäll, Joakim, et al.
(författare)
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Sub-Barrier Coulomb Excitation of ^110Sn and Its Implications for the ^100Sn Shell Closure
- 2007
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Ingår i: Physical Review Letters. - 1079-7114. ; 98:17, s. 172501-
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Tidskriftsartikel (refereegranskat)abstract
- The first excited 2+ state of the unstable isotope 110Sn has been studied in safe Coulomb excitation at 2.82 MeV/u using the MINIBALL array at the REX-ISOLDE post accelerator at CERN. This is the first measurement of the reduced transition probability of this state using this method for a neutron deficient Sn isotope. The strength of the approach lies in the excellent peak-to-background ratio that is achieved. The extracted reduced transition probability, B(E2:0+-->2+)=0.220±0.022e2b2, strengthens the observation of the evolution of the B(E2) values of neutron deficient Sn isotopes that was observed recently in intermediate-energy Coulomb excitation of 108Sn. It implies that the trend of these reduced transition probabilities in the even-even Sn isotopes is not symmetric with respect to the midshell mass number A=116 as 100Sn is approached.
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| 6. |
- Heine, M., et al.
(författare)
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Determination of the neutron-capture rate of C-17 for r-process nucleosynthesis
- 2017
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Ingår i: Physical Review C. - 2469-9985 .- 2469-9993. ; 95:1, s. Article no 014613 -
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Tidskriftsartikel (refereegranskat)abstract
- With the (RB)-B-3-LAND setup at GSI we have measured exclusive relative-energy spectra of the Coulomb dissociation of C-18 at a projectile energy around 425A MeV on a lead target, which are needed to determine the radiative neutron-capture cross sections of C-17 into the ground state of C-18. Those data have been used to constrain theoretical calculations for transitions populating excited states in C-18. This allowed to derive the astrophysical cross section sigma(n gamma)*. accounting for the thermal population of C-17 target states in astrophysical scenarios. The experimentally verified capture rate is significantly lower than those of previously obtained Hauser-Feshbach estimations at temperatures T-9
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| 7. |
- Petri, M., et al.
(författare)
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Structure of C-16: Testing shell model and ab initio approaches
- 2012
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Ingår i: Physical Review C - Nuclear Physics. - 2469-9985 .- 2469-9993. ; 86:4, s. Art. no. 044329-
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Tidskriftsartikel (refereegranskat)abstract
- Excited states in C-16 were populated via the Be-9(N-17,C-16+gamma)X one-proton knockout reaction. The lifetime of the 2(1)(+) state in C-16 was measured using the recoil distance method. The extracted lifetime of tau(+)(21) = 11.4(-0.9)(+0.8)(stat) +/- 0.7(syst(B rho))(-1.5)(+0.0)(syst(feeding)) ps yields a deduced B(E2;2(1)(+) -> 0(1)(+)) = 4.21(-0.26)(+0.34)(stat)(-0.24)(+0.28)(syst(B rho))(-0.00)(+0.64)(syst(feeding)) e(2)fm(4) value in good agreement with a previous measurement. The one-proton knockout cross section is used to extract the proton amplitude of the C-16 2(1)(+) state, which confirms the neutron dominant character of this state. Gamma-ray branching ratios between the 2(2)(+) state and the 2(1)(+) and ground states were also determined. The results are compared with p-sd shell model and no-core shell model (with NN and NN + NNN) calculations. The inclusion of three-body forces are essential in order for the no-core shell model calculations to reproduce the experimental findings on the gamma-ray branching ratios.
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| 8. |
- Ribeiro, G., et al.
(författare)
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Structure of Be-13 studied in proton knockout from B-14
- 2018
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Ingår i: Physical Review C. - 2469-9985 .- 2469-9993. ; 98:2
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Tidskriftsartikel (refereegranskat)abstract
- The neutron-unbound isotope Be-13 has been studied in several experiments using different reactions, different projectile energies, and different experimental setups. There is, however, no real consensus in the interpretation of the data, in particular concerning the structure of the low-lying excited states. Gathering new experimental information, which may reveal the Be-13 structure, is a challenge, particularly in light of its bridging role between Be-12, where the N = 8 neutron shell breaks down, and the Borromean halo nucleus Be-14. The purpose of the present study is to investigate the role of bound excited states in the reaction product Be-12 after proton knockout from B-14, by measuring coincidences between Be-12, neutrons, and gamma rays originating from de-excitation of states fed by neutron decay of Be-13. The Be-13 isotopes were produced in proton knockout from a 400 MeV/nucleon B-14 beam impinging on a CH2 target. The Be-12-n relative-energy spectrum d sigma/dE(fn) was obtained from coincidences between Be-12(g.s.) and a neutron, and also as threefold coincidences by adding gamma rays, from the de-excitation of excited states in Be-12. Neutron decay from the first 5/2(+) state in Be-13 to the 2(+) state in Be-12 at 2.11 MeV is confirmed. An energy independence of the proton-knockout mechanism is found from a comparison with data taken with a 35 MeV/nucleon B-14 beam. A low-lying p-wave resonance in Be-13(1/2(-)) is confirmed by comparing proton- and neutron-knockout data from B-14 and Be-14.
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| 9. |
- Vandebrouck, M., et al.
(författare)
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Effective proton-neutron interaction near the drip line from unbound states in F-25,F-26
- 2017
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Ingår i: Physical Review C. - 2469-9985 .- 2469-9993. ; 96:5
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Tidskriftsartikel (refereegranskat)abstract
- Background: Odd-odd nuclei, around doubly closed shells, have been extensively used to study proton-neutron interactions. However, the evolution of these interactions as a function of the binding energy, ultimately when nuclei become unbound, is poorly known. The F-26 nucleus, composed of a deeply bound pi 0d(5/2) proton and an unbound v0d(3/2) neutron on top of an O-24 core, is particularly adapted for this purpose. The coupling of this proton and neutron results in a J(pi) = 1(1)(+) - 4(1)(+) multiplet, whose energies must be determined to study the influence of the proximity of the continuum on the corresponding proton-neutron interaction. The J(pi) = 1(1)(+), 2(1)(+), 4(1)(+) bound states have been determined, and only a clear identification of the J(pi) = 3(1)(+) is missing. Purpose: We wish to complete the study of the J(pi) = 1(1)(+) - 4(1)(+) multiplet in F-26, by studying the energy and width of the J(pi) = 3(1)(+) unbound state. The method was first validated by the study of unbound states in F-25, for which resonances were already observed in a previous experiment. Method: Radioactive beams of Ne-26 and Ne-27, produced at about 440AMeV by the fragment separator at the GSI facility were used to populate unbound states in F-25 and F-26 via one-proton knockout reactions on a CH2 target, located at the object focal point of the (RB)-B-3/LAND setup. The detection of emitted. rays and neutrons, added to the reconstruction of the momentum vector of the A - 1 nuclei, allowed the determination of the energy of three unbound states in F-25 and two in F-26. Results: Based on its width and decay properties, the first unbound state in F-25, at the relative energy of 49(9) keV, is proposed to be a J(pi) = 1/ 2(-) arising from a p1/2 proton- hole state. In F-26, the first resonance at 323(33) keV is proposed to be the J(pi) = 3(1)(+) member of the J(pi) = 1(1)(+) - 4(1)(+) multiplet. Energies of observed states in F-25,F-26 have been compared to calculations using the independent-particle shell model, a phenomenological shell model, and the ab initio valence-space in-medium similarity renormalization group method. Conclusions: The deduced effective proton- neutron interaction is weakened by about 30-40% in comparison to the models, pointing to the need for implementing the role of the continuum in theoretical descriptions or to a wrong determination of the atomic mass of F-26.
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| 10. |
- Altstadt, S.G., et al.
(författare)
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B-13,B-14(n,gamma) via Coulomb Dissociation for Nucleosynthesis towards the r-Process
- 2014
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Ingår i: Nuclear Data Sheets. - : Elsevier BV. - 1095-9904 .- 0090-3752. ; 120, s. 197-200
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Konferensbidrag (refereegranskat)abstract
- Radioactive beams of 14,15B produced by fragmentation of a primary 40Ar beam were directed onto a Pb target to investigate the neutron breakup within the Coulomb field. The experiment was performed at the LAND/R3B setup. Preliminary results for the Coulomb dissociation cross sections as well as for the astrophysically interesting inverse reactions, 13,14B(n,γ), are presented.
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| 11. |
- Caesar, C., et al.
(författare)
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Beyond the neutron drip line: The unbound oxygen isotopes O-25 and O-26
- 2013
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Ingår i: Physical Review C - Nuclear Physics. - 2469-9985 .- 2469-9993 .- 0556-2813. ; 88:3
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Tidskriftsartikel (refereegranskat)abstract
- The very neutron-rich oxygen isotopes O-25 and O-26 are investigated experimentally and theoretically. The unbound states are populated in an experiment performed at the R3B-LAND setup at GSI via proton-knockout reactions from F-26 and F-27 at relativistic energies around 442 and 414 MeV/nucleon, respectively. From the kinematically complete measurement of the decay into O-24 plus one or two neutrons, the O-25 ground-state energy and width are determined, and upper limits for the O-26 ground-state energy and lifetime are extracted. In addition, the results provide indications for an excited state in O-26 at around 4 MeV. The experimental findings are compared to theoretical shell-model calculations based on chiral two- and three-nucleon (3N) forces, including for the first time residual 3N forces, which are shown to be amplified as valence neutrons are added.
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| 12. |
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| 13. |
- Gobel, K., et al.
(författare)
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Measurement of the Mo-92,Mo-93,Mo-94,Mo-100(gamma,n) reactions by Coulomb Dissociation
- 2016
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Ingår i: Journal of Physics: Conference Series. - : IOP Publishing. - 1742-6588 .- 1742-6596. ; 665:1, s. art. no. 012034-
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Konferensbidrag (refereegranskat)abstract
- The Coulomb Dissociation (CD) cross sections of the stable isotopes Mo-92,Mo-94,Mo-100 and of the unstable isotope Mo-93 were measured at the LAND/(RB)-B-3 setup at GSI Helmholtzzentrum fur Schwerionenforschung in Darmstadt, Germany. Experimental data on these isotopes may help to explain the problem of the underproduction of Mo-92,Mo-94 and Ru-96,Ru-98 in the models of p-process nucleosynthesis. The CD cross sections obtained for the stable Mo isotopes are in good agreement with experiments performed with real photons, thus validating the method of Coulomb Dissociation. The result for the reaction Mo-93(gamma,n) is especially important since the corresponding cross section has not been measured before. A preliminary integral Coulomb Dissociation cross section of the Mo-94(gamma,n) reaction is presented. Further analysis will complete the experimental database for the (gamma,n) production chain of the p-isotopes of molybdenum.
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| 14. |
- Klimkiewicz, A., et al.
(författare)
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Pygmy Dipole Strength in Exotic Nuclei and the Equation of State
- 2009
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Ingår i: AIP Conference Proceedings. - 1551-7616 .- 0094-243X. ; 1165, s. 181-184 461
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Konferensbidrag (refereegranskat)abstract
- A concentration of dipole strength at energies below the giant dipole resonance was observed in neutron-rich nuclei around Sn-132 in an experiment using the FRS-LAND setup. This so-called "pygmy" dipole strength can be related to the parameters of the symmetry energy and to the neutron skin thickness on the grounds of a relativistic quasiparticle random-phase approximation. Using this ansatz and the experimental findings for Sn-130 and 132 Sri, we derive a value of the symmetry energy pressure of (p) over bar (0) = 2.2 +/- 0.5 MeV/fm(3). Neutron skin thicknesses of R-n-R-p = 0.23 +/- 0.03 fm and 0.24 +/- 0.03 fm for Sn-130 and Sn-132, respectively, have been determined. Preliminary results on Ni-68 from a similar experiment using an improved setup indicate an enhanced cross section at low energies, while the results for Ni-58 are in accordance with results from photoabsorption measurements.
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| 15. |
- Le Bleis, T., et al.
(författare)
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Target dependence in the study of collective modes in stable and exotic Ni nuclei
- 2010
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Ingår i: Journal of Physics: Conference Series. ; 202:1, s. 012035-
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Konferensbidrag (refereegranskat)abstract
- The appearance of the pygmy-dipole-resonance is a recently observed phenomenon that can be related to neutron-matter properties. Its study can be a tool to determine the nuclear symmetry-energy parameters and thus can contribute constraining neutron star models. We present the ( γ,n ) cross sections for different Ni isotopes obtained from a measurement in inverse kinematics at about 500 MeV/u in the LAND reaction setup at GSI. The question of the disentanglement of the Coulomb and nuclear contributions is addressed.
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| 16. |
- Mahata, K., et al.
(författare)
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Study of dipole excitations and the single particle structure of neutron rich Ni isotopes
- 2008
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Ingår i: AIP Conference Proceedings. - 1551-7616 .- 0094-243X. ; 1012, s. 389-391 453
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Konferensbidrag (refereegranskat)abstract
- An experiment was performed using the FRS-LAND setup at GSI to study the dipole strength distributions above neutron separation threshold for neutron-rich Ni isotopes. Measurements, using the same experimental setup, were also carried out to extract single particle occupancies via knockout reactions to investigate the structure and magicity of the neutron-rich Ni isotopes. The status of the data analysis and preliminary results are presented.
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| 17. |
- Pramanik, P., et al.
(författare)
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Vibrational properties of monoclinic CoTeO4
- 2024
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Ingår i: Physical Review B. - : American Physical Society. - 2469-9950 .- 2469-9969. ; 110:5
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Tidskriftsartikel (refereegranskat)abstract
- The vibrational properties of monoclinic dirutile-type CoTeO4 (space group P21/c) were investigated by means of Raman and infrared (IR) spectroscopy on stoichiometric single crystals and theoretical density-functional theory (DFT) calculations. Experimental in situ investigations under pressure and temperature variations up to 10.1 GPa and 750 K confirmed the singular phase stability of the monoclinic lattice and the absence of any structural transition. The IR spectra exhibit modes that are not observed in the Raman spectra, thus offering a comprehensive understanding of the vibrational behavior of the title compound. The symmetry and degeneracy of modes and their contributions to the overall vibrational spectrum of CoTeO4 were analyzed using group theory. DFT calculations were performed both on a cluster level and based on the crystal structure of monoclinic CoTeO4 in order to gain further insights into the vibrational properties. The calculated vibrational frequencies and modes were compared with the experimental data, allowing for a detailed investigation of the lattice dynamics and the nature of the vibrational modes in CoTeO4, and are corroborated with the analytical Wilson's F-G matrix method. These findings provide fundamental insights into the crystal symmetry and lattice dynamics of CoTeO4. The results are discussed and compared to those of isoformular systems.
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| 18. |
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| 19. |
- Rossi, D., et al.
(författare)
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Coulomb excitation of exotic nuclei at the R3B-LAND setup
- 2013
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Ingår i: Journal of Physics: Conference Series. - : IOP Publishing. - 1742-6588 .- 1742-6596. ; 420:1
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Konferensbidrag (refereegranskat)abstract
- Exotic Ni isotopes have been measured at the R3B-LAND setup at GSI in Darmstadt, using Coulomb excitation in inverse kinematics at beam energies around 500 MeV/u. As the experimental setup allows kinematically complete measurements, the excitation energy was reconstructed using the invariant mass method. The GDR and additional low-lying strength have been observed in 68Ni, the latter exhausting 4.1(1.9)% of the E1 energy-weighted sum rule. Also, the branching ratio for the non-statistical decay of the excited 68Ni nuclei was measured and amounts to 24(4)%.
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| 20. |
- Rossi, D. M., et al.
(författare)
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Investigation of the Dipole Response in Exotic Nuclei-Experiments at the LAND-(RB)-B-3 Setup
- 2012
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Ingår i: Progress of Theoretical Physics Supplement. - 1347-4081 .- 0375-9687. ; :196, s. 465-470
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Tidskriftsartikel (refereegranskat)abstract
- We present experimental results on the electromagnetic excitation of neutron-rich nickel isotopes, making use of the (RB)-B-3-LAND setup at GSI. Exotic beams were produced at approximately 500 MeV/u and their reactions were studied in inverse kinematics. Integral cross sections for Ni-58 are discussed and compared to previous data, providing a validation of our experimental method. The El excitation-energy distribution of the unstable Ni-68 is presented as well, showing an excess in cross section in the 1n decay channel when compared only with a typical Giant Dipole Resonance.
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| 21. |
- Rossi, D., et al.
(författare)
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Measurement of the dipole polarizability of the unstable neutron-rich nucleus Ni68
- 2013
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Ingår i: Physical Review Letters. - 1079-7114 .- 0031-9007. ; 111:24
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Tidskriftsartikel (refereegranskat)abstract
- The E1 strength distribution in Ni68 has been investigated using Coulomb excitation in inverse kinematics at the RB3-LAND setup and by measuring the invariant mass in the one- and two-neutron decay channels. The giant dipole resonance and a low-lying peak (pygmy dipole resonance) have been observed at 17.1(2) and 9.55(17) MeV, respectively. The measured dipole polarizability is compared to relativistic random phase approximation calculations yielding a neutron-skin thickness of 0.17(2) fm. A method and analysis applicable to neutron-rich nuclei has been developed, allowing for a precise determination of neutron skins in nuclei as a function of neutron excess.
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| 22. |
- Röder, M., et al.
(författare)
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Coulomb dissociation of 20,21 N
- 2016
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Ingår i: Physical Review C - Nuclear Physics. - 2469-9985 .- 2469-9993 .- 0556-2813. ; 93:6
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Tidskriftsartikel (refereegranskat)abstract
- Neutron-rich light nuclei and their reactions play an important role in the creation of chemical elements. Here, data from a Coulomb dissociation experiment on N20,21 are reported. Relativistic N20,21 ions impinged on a lead target and the Coulomb dissociation cross section was determined in a kinematically complete experiment. Using the detailed balance theorem, the N19(n,γ)N20 and N20(n,γ)N21 excitation functions and thermonuclear reaction rates have been determined. The N19(n,γ)N20 rate is up to a factor of 5 higher at T
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| 23. |
- Syndikus, I., et al.
(författare)
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Probing the Z = 6 spin-orbit shell gap with (p,2p) quasi-free scattering reactions
- 2020
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Ingår i: Physics Letters, Section B: Nuclear, Elementary Particle and High-Energy Physics. - : Elsevier BV. - 0370-2693. ; 809
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Tidskriftsartikel (refereegranskat)abstract
- The evolution of the traditional nuclear magic numbers away from the valley of stability is an active field of research. Experimental efforts focus on providing key spectroscopic information that will shed light into the structure of exotic nuclei and understanding the driving mechanism behind the shell evolution. In this work, we investigate the Z=6 spin-orbit shell gap towards the neutron dripline. To do so, we employed NA(p,2p)CA−1 quasi-free scattering reactions to measure the proton component of the 21+ state of 16,18,20C. The experimental findings support the notion of a moderate reduction of the proton 1p1/2−1p3/2 spin-orbit splitting, at variance to recent claims for a prevalent Z=6 magic number towards the neutron dripline.
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| 24. |
- Aksyutina, Yu, et al.
(författare)
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Lithium isotopes beyond the drip line
- 2008
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Ingår i: Physics Letters B. - : Elsevier BV. - 0370-2693. ; 666:5, s. 430-434
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Tidskriftsartikel (refereegranskat)abstract
- The unbound isotopes 10Li, 12Li and 13Li have been observed after nucleon-knockout reactions at relativistic energies with 11Li and 14Be beams impinging on a liquid hydrogen target. The channels , and were analysed in the ALADIN-LAND setup at GSI. The 10Li data confirm earlier findings, while the 12Li and 13Li nuclei were observed for the first time. The relative-energy spectrum shows that the ground state of 12Li can be described as a virtual s-state with a scattering length of -13.7(1.6) fm. A broad energy spectrum was found for the channel. Based on the assumption that the relative-energy spectrum is dominated by a correlated background presumably stemming from initial correlations in the 14Be ground-state, evidence for a 13Li resonance at 1.47(31) MeV above the threshold with a width around 2 MeV has been found.
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| 25. |
- Chanda, Somen, et al.
(författare)
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Seven-quasiparticle bands in Ce-139
- 2009
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Ingår i: Physical Review C (Nuclear Physics). - 0556-2813. ; 79:5
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Tidskriftsartikel (refereegranskat)abstract
- The high spin states in the Ce-139 nucleus have been studied by in-beam gamma-spectroscopic techniques using the reaction Te-130(C-12,3n)Ce-139 at E-beam=65 MeV. A gamma detector array, consisting of five Compton-suppressed Clover detectors was used for coincidence measurements. 15 new levels have been proposed and 28 new gamma transitions have been assigned to Ce-139 on the basis of gamma gamma coincidence data. The level scheme of Ce-139 has been extended above the known 70 ns 19/2 isomer up to similar to 6.1 MeV in excitation energy and 35/2h in spin. The spin-parity assignments for most of the newly proposed levels have been made using the deduced Directional Correlation from Oriented states of nuclei (DCO ratio) and the Polarization Directional Correlation from Oriented states (PDCO ratio) for the de-exciting transitions. The observed level structure has been compared with a large basis shell model calculation and also with the predictions from cranked Nilsson-Strutinsky (CNS) calculations. A general consistency has been observed between these two different theoretical approaches.
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| 26. |
- Clevestig, P, et al.
(författare)
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CCR5 use by human immunodeficiency virus type 1 is associated closely with the gp120 V3 loop N-linked glycosylation site
- 2006
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Ingår i: The Journal of general virology. - : Microbiology Society. - 0022-1317 .- 1465-2099. ; 87:Pt 3, s. 607-612
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Tidskriftsartikel (refereegranskat)abstract
- Human immunodeficiency virus type 1 (HIV-1) enters cells through the chemokine receptors CCR5 (R5 virus) and/or CXCR4 (X4 virus). Loss of N-linked glycans and increased net charge of the third variable loop (V3) of the gp120 envelope glycoprotein have been observed to be important steps towards CXCR4 use. All reported sequences using CCR5 or CXCR4 exclusively, or using both, were gathered from the Los Alamos HIV Database and analysed with regard to the V3 N-linked glycosylation motifs (sequons) and charge. The V3 loop glycan had a sensitivity of 0·98 and a 0·92 positive predictive value in the context of CCR5 use. The difference from X4 was remarkable (P<10−12). Especially, the sequon motif NNT within the V3 loop was conserved in 99·2 % of the major clades. The results suggest a close association between the V3 loop glycan and CCR5 use and may provide new insight into HIV-1 tropism and help to improve phenotype-prediction models.
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| 27. |
- Clulow, Rebecca, et al.
(författare)
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Phase Stability and Magnetic Properties of Compositionally Complex n = 2 Ruddlesden-Popper Perovskites
- 2024
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Ingår i: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 63:15, s. 6616-6625
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Tidskriftsartikel (refereegranskat)abstract
- Four new compositionally complex perovskites with multiple (four or more) cations on the B site of the perovskites have been studied. The materials have the general formula La0.5Sr2.5(M)2O7−δ (M = Ti, Mn, Fe, Co, and Ni) and have been synthesized via conventional solid-state synthesis. The compounds are the first reported examples of compositionally complex n = 2 Ruddlesden-Popper perovskites. The structure and properties of the materials have been determined using powder X-ray diffraction, neutron diffraction, energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and magnetometry. The materials are isostructural and adopt the archetypal I4/mmm space group with the following unit cell parameters: a ∼ 3.84 Å, and c ∼ 20.1 Å. The measured compositions from energy dispersive X-ray spectroscopy were La0.51(2)Sr2.57(7)Ti0.41(2)Mn0.41(2)Fe0.39(2)Co0.38(1)Ni0.34(1)O7−δ, La0.59(4)Sr2.29(23)Mn0.58(5)Fe0.56(6)Co0.55(6)Ni0.42(4)O7−δ, La0.54(2)Sr2.49(13)Mn0.41(2)Fe0.81(5)Co0.39(3)Ni0.36(3)O7−δ, and La0.53(4)Sr2.55(19)Mn0.67(6)Fe0.64(5)Co0.31(2)Ni0.30(3)O7−δ. No magnetic contribution is observed in the neutron diffraction data, and magnetometry indicates a spin glass transition at low temperatures.
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| 28. |
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| 29. |
- Cortina-Gil, D., et al.
(författare)
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One-neutron knockout of O-23
- 2005
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Ingår i: European Physical Journal A. - : Springer Science and Business Media LLC. - 1434-601X .- 1434-6001. ; 25, s. 343-346
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Konferensbidrag (refereegranskat)abstract
- Breakup reactions were used to study the ground-state configuration of the neutron-rich isotope O-23. The O-22 fragments produced in one-nucleon removal from O-23 at 938 MeV/nucleon in a carbon target were detected in coincidence with de-exciting gamma rays, allowing to discern between 220 ground-state and excited-states contributions. From the comparison of exclusive experimental momentum distributions for the one-neutron removal channel to theoretical momentum distributions calculated in an Eikonal model for the knockout process, and spin and parity assignment of I-pi = 1/2(+) was deduced for the 230 ground state. This result solved the existent experimental discrepancy.
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| 30. |
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| 31. |
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| 32. |
- Dey, Dipanjan, et al.
(författare)
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An assessment of TropFlux and NCEP air-sea fluxes on ROMS simulations over the Bay of Bengal region
- 2017
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Ingår i: Dynamics of atmospheres and oceans (Print). - : Elsevier BV. - 0377-0265 .- 1872-6879. ; 80, s. 47-61
-
Tidskriftsartikel (refereegranskat)abstract
- This study presents an assessment of the TropFlux and the National Centers for Environmental Prediction (NCEP) reanalysis air-sea fluxes in simulating the surface and subsurface oceanic parameters over the Bay of Bengal (BoB) region during 2002-2014 using the Regional Ocean Modelling System (ROMS). The assessment has been made by comparing the simulated fields with in-situ and satellite observations. The simulated surface and subsurface temperatures in the TropFlux forced experiment (TropFlux-E) show better agreement with the Research Moored Array for African-Asian-Australian Monsoon Analysis (RAMA) and Argo observations than the NCEP forced experiment (NCEP-E). The BoB domain averaged sea surface temperature (SST) simulated in the NCEP-E is consistently cooler than the satellite SST, with a root mean square error (RMSE) of 0.79 C. Moreover, NCEP-E shows a limitation in simulating the observed seasonal cycle of the SST due to substantial underestimation of the pre-monsoon SST peak. These limitations are mostly due to the lower values of the NCEP net hedt flux. The seasonal and interannual variations of SST in the TropFlux-E are better comparable to the observations with correlations and skills more than 0.80 and 0.90 respectively. However, SST is overestimated during summer monsoon periods mainly due to higher net heat flux. The superiority of TropFlux forcing over the NCEP reanalysis can also.be seen when simulating the interannual variabilities of the magnitude and vertical extent of Wyrtki jets at two equatorial RAMA buoy locations. The jet is weaker in the NCEP-E relative to the TropFlux-E and observations. The simulated sea surface height anomalies (SSHA) from both the experiments are able to capture the regions of positive and negative SSHA with respect to satellite-derived altimeter data with better performance in the TropFlux-E. The speed of the westward propagating Rossby wave along 18 N in the TropFlux-E is found to be about 4.7 cm/s, which is close to the theoretical phase speed of Rossby waves.
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| 33. |
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| 34. |
- Joshi, D. C., et al.
(författare)
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Nature of magnetic ordering in nanocomposites of Zn1-pNipO and NiO
- 2018
-
Ingår i: Physica. E, Low-Dimensional systems and nanostructures. - : ELSEVIER SCIENCE BV. - 1386-9477 .- 1873-1759. ; 103, s. 46-52
-
Tidskriftsartikel (refereegranskat)abstract
- A detailed study of the nature of magnetic exchange interactions and anisotropy in Zn-1_pNipO/NiO (0 <= p <= 1) two-phase nanocomposites is reported. The exchange constants |J(1)| and |J(2)| have been determined using the molecular field approximation for the two sublattice model which yields |J(2)| similar to 11.26 meV and |J(1)| similar to 7.17meV for p = 1, consistent with type-II antiferromagnetic ordering (i.e. |J2|>>|J(1)|). A novel core-shell surface layer model has been employed to explain the nature of magnetic anisotropy in these nanocomposites which yields anisotropy constants K-surface= 2.42 erg/cm(2), K-bulk = 2.61 x 10(6) erg/cm(3) and K-Shell = 9.56 x 10(5) erg/cm(3) for shell thickness d(Sh) similar to 1.34 nm (p = 1).
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| 35. |
- Langer, C., et al.
(författare)
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Thermonuclear reaction S-30(p,gamma)Cl-31 studied via Coulomb breakup of Cl-31
- 2014
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Ingår i: Physical Review C - Nuclear Physics. - 2469-9985 .- 2469-9993. ; 89:3
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Tidskriftsartikel (refereegranskat)abstract
- Coulomb breakup at high energy in inverse kinematics of proton-rich Cl-31 was used to constrain the thermonuclear S-30(p,gamma)Cl-31 capture reaction rate under typical Type I x-ray burst conditions. This reaction is a bottleneck during rapid proton-capture nucleosynthesis (rp process), where its rate depends predominantly on the nuclear structure of Cl-31. Two low-lying states just above the proton-separation threshold of S-p = 296( 50) keV in Cl-31 have been identified experimentally using the (RB)-B-3-LAND setup at the GSI Helmholtzzentrum fur Schwerionenforschung GmbH. Both states are considered to play a key role in the thermonuclear S-30( p,gamma)Cl-31 capture reaction. Excitation energies of the first J(pi) = 1/2(+), 5/2(+) states have been extracted and the reaction rate for proton capture on S-30 under typical rp-process temperatures has been investigated.
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| 36. |
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| 37. |
- Meister, Mikael, 1969, et al.
(författare)
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High-energy breakup of 8B
- 2003
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Ingår i: Nucl. Phys. A. ; 718, s. 431-433
-
Konferensbidrag (refereegranskat)
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| 38. |
- Nayak, S., et al.
(författare)
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Low-temperature anomalous magnetic behavior of Co2TiO4 and Co2SnO4
- 2016
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Ingår i: Journal of Applied Physics. - : AIP Publishing. - 0021-8979 .- 1089-7550. ; 120:16
-
Tidskriftsartikel (refereegranskat)abstract
- We report the low-temperature anomalous magnetic behavior of ferrimagnetic spinels cobalt orthotitanate (Co2TiO4), which exhibits magnetic compensation behavior across 31.74 K, and cobalt orthostannate (Co2SnO4) exhibiting two sequential magnetic transitions, namely (i) ferrimagnetic to paramagnetic transition with Neel temperature T-N similar to 41 K and reentrant spin-glass behavior with glass transition temperature T-SG similar to 39 K. The Arrott plot (H/M versus M-2) criterion has been used to extricate the order of sequential magnetic transitions occurring below TN. Negative slopes of the Arrott plots below 32 K, metamagnetic-like character of the M-H isotherms, anomalies in the specific-heat (C-P T-1 versus T) below 15 K, and a zero-crossover of isothermal magnetic-entropychange (Delta S) signify the presence of pseudo first-order discontinuous magnetic phase transition in the low-temperature regime 5K <= T <= 32 K. The dc- and ac-susceptibilities of both Co2TiO4 and Co2SnO4 are interpreted in terms of frozen-spin-clusters, which are responsible for very large magnitudes of the coercivity H-C similar to 20 kOe and bipolar-exchange bias H-EB similar to -20 kOe observed below 10 K.
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| 39. |
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| 40. |
- Pramanik, L, et al.
(författare)
-
Charged amino acid patterns of coreceptor use in the major subtypes of human immunodeficiency virus type 1
- 2011
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Ingår i: The Journal of general virology. - : Microbiology Society. - 1465-2099 .- 0022-1317. ; 92:Pt 8, s. 1917-1922
-
Tidskriftsartikel (refereegranskat)abstract
- Human immunodeficiency virus type 1 has several genetic subtypes and two coreceptor use phenotypes: R5 that uses CCR5, while X4 uses CXCR4. A high amino acid charge of the envelope glycoprotein 120 V3 region, common at positions 11 and 25, is important for CXCR4 use. We characterized charged V3 amino acids, retrieving all biologically phenotyped sequences from the HIV Sequence Database. Selecting individually unique ones randomly yielded 48 subtype A, 231 B, 180 C, 37 D and 32 CRF01_AE sequences; 482 were R5 and 46 were X4. Charged amino acids were conserved in both R5 and X4 with general and subtype-specific patterns. X4 viruses gained a higher charge from positive amino acids at positions other than in R5, and through the loss of negative amino acids. Other positions than 11/25 had a greater impact on charge (P<0.001). This describes how R5 evolves into X4 in a subtype-specific context, useful for computer-based predictions and vaccine design.
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| 41. |
- Pramanik, P., et al.
(författare)
-
Cationic distribution, exchange interactions, and relaxation dynamics in Zn-diluted MnCo2O4 nanostructures
- 2019
-
Ingår i: Journal of Applied Physics. - : AMER INST PHYSICS. - 0021-8979 .- 1089-7550. ; 125:12
-
Tidskriftsartikel (refereegranskat)abstract
- We report an experimental investigation of the electronic structure and magnetic properties of bulk and nanosized MnCo2O4 diluted with Zn. The cationic distribution for tetrahedral A-site dilution is (Co1-yA2+ZnyA2+)(A)[Mn3+Co3+](B)O-4 +/-delta, whereas B-site dilution results in (Co2+)(A)[Mn1-xB3+ZnxB2+Co3+](B)O4-delta. The strength of exchange interaction J(ij) between the magnetic ions in a bulk spinel lattice decreases by similar to 15% for A-site dilution relative to the undiluted compound; however, B-site dilution results in an enhancement in J(ij) by 17%. The frequency and temperature dependence of dynamic-susceptibility [chi(ac)(f, T)] studies of nanostructured compounds reveals the existence of spin-glass like behavior below the freezing temperature T-F similar to 125.7 K (for x(B) = 0.2) and 154.3 K (y(A) = 0.1). Relaxation time tau follows the Power-Law variation with a dynamical critical exponent zv = 6.17 and microscopic spin relaxation time tau(o) = 4.4 x 10(-15) s for x(B) = 0.2 (for y(A) = 0.1, zv = 5.2 and tau(o) = 5.4 x 10(-13) s). The amplitude and peak position in chi(ac)(T) decreases with an increase in the DC bias field, which indicates that the spin-glass phase can survive in the presence of low fields forming a critical line with an exponent 2/3. This behavior is similar to the de Almeida-Thouless (AT-line) analysis in the T-H phase diagram which supports the existence of spin-glass like behavior below T-F in these Zn diluted spinels.
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| 42. |
- Pramanik, P., et al.
(författare)
-
Concentration and temperature dependence of the structural, magnetic, and dielectric properties of La2Ni(Mn1-xRux)O6 solid solutions
- 2023
-
Ingår i: Journal of Alloys and Compounds. - : Elsevier. - 0925-8388 .- 1873-4669. ; 968
-
Tidskriftsartikel (refereegranskat)abstract
- The crystal structure, magnetic ordering, and dielectric characteristics of polycrystalline powder samples of La2NiMn1-xRuxO6 (x = 0.25-0.75) solid solutions have been studied. The X-ray diffraction results were analysed in detail, and reliably show that all compounds have a monoclinic (P2(1)/n) structure with Ni and Mn/Ru ions occupying the 2c and 2d sites, respectively. Magnetic susceptibility measurements reveal a ferromagnetic order for La2NiMn0.75Ru0.25O6 and La2NiMn0.5Ru0.5O6. The ferromagnetic transition temperature decreases from 200 K for La2NiMn0.75Ru0.25O6 to 175 K for La2NiMn0.5Ru0.5O6. Dielectric measurements show large dielectric constants (similar to 10(4)) at room temperature. In addition, the temperature-dependent loss-tangent Tan delta(T) curves reveal relaxation characteristics due to charge transfer between nearest cations.
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| 43. |
- Pramanik, P., et al.
(författare)
-
Neutron diffraction evidence for local spin canting, weak Jahn-Teller distortion, and magnetic compensation in Ti1-xMnxCo2O4 spinel
- 2020
-
Ingår i: Journal of Physics. - : IOP PUBLISHING LTD. - 0953-8984 .- 1361-648X. ; 32:24
-
Tidskriftsartikel (refereegranskat)abstract
- A systematic study using neutron diffraction and magnetic susceptibility is reported on Mn substituted ferrimagnetic inverse spinel Ti1-xMnxCo2O4 in the temperature interval 1.6 K T 300 K. Our neutron diffraction study reveals cooperative distortions of the TO6 octahedra in the Ti1-xMnxCo2O4 system for all the Jahn-Teller active ions T = Mn3+ , Ti3+ and Co3+ , having the electronic configurations 3d(1), 3d(4) and 3d(6), respectively which are confirmed by the x-ray photoelectron spectroscopy. Two specific compositions (x = 0.2 and 0.4) have been chosen in this study because these two systems show unique features such as; (i) noncollinear Yafet-Kittel type magnetic ordering, and (ii) weak tetragonal distortion with c/a < 1, in which the apical bond length d(c)(T-B-O) is longer than the equatorial bond length d(ab)(T-B-O) due to the splitting of the e(g) level of Mn3+ ions into and . For the composition x = 0.4, the distortion in the TBO6 octahedra is stronger as compared to x = 0.2 because of the higher content of trivalent Mn. Ferrimagnetic ordering in Ti0.6Mn0.4Co2O4 and Ti0.8Mn0.2Co2O4 sets in at 110.3 and 78.2 K, respectively due to the presence of unequal magnetic moments of cations, where Ti3+ , Mn3+ , and Co3+ occupy the octahedral, whereas, Co2+ sits in the tetrahedral site. For both compounds an additional weak antiferromagnetic component could be observed lying perpendicular to the ferrimagnetic component. The analysis of static and dynamic magnetic susceptibilities combined with the heat-capacity data reveals a magnetic compensation phenomenon (MCP) at T-COMP = 25.4 K in Ti0.8Mn0.2Co2O4 and a reentrant spin-glass behaviour in Ti0.6Mn0.4Co2O4 with a freezing temperature of 110.1 K. The MCP in this compound is characterized by sign reversal of magnetization and bipolar exchange bias effect below T-COMP with its magnitude depending on the direction of external magnetic field and the cooling protocol.
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| 44. |
- Pramanik, Subrata, 1988-, et al.
(författare)
-
An engineered cellobiohydrolase I for sustainable degradation of lignocellulosic biomass
- 2021
-
Ingår i: Biotechnology and Bioengineering. - : John Wiley & Sons. - 0006-3592 .- 1097-0290. ; 118:10, s. 4014-4027
-
Tidskriftsartikel (refereegranskat)abstract
- This study provides computational-assisted engineering of the cellobiohydrolase I (CBH-I) from Penicillium verruculosum with simultaneous enhanced thermostability and tolerance in ionic liquids, deep eutectic solvent, and concentrated seawater without affecting its wild-type activity. Engineered triple variant CBH-I R1 (A65R-G415R-S181F) showed 2.48-fold higher thermostability in terms of relative activity at 65 degrees C after 1 h of incubation when compared with CBH-I wild type. CBH-I R1 exhibited 1.87-fold, 1.36-fold, and 1.57-fold higher specific activities compared with CBH-I wild type in [Bmim]Cl (50 g/L), [Ch]Cl (50 g/L), and two-fold concentrated seawater, respectively. In the multicellulases mixture, CBH-I R1 showed higher hydrolytic efficiency to hydrolyze aspen wood compared with CBH-I wild type in the buffer, [Bmim]Cl (50 g/L), and two-fold concentrated seawater, respectively. Structural analysis revealed a molecular basis for the higher stability of the CBH-I structure in which A65R and G415R substitutions form salt bridges (D64 horizontal ellipsis R65, E411 horizontal ellipsis R415) and S181F forms pi-pi interaction (Y155 horizontal ellipsis F181), leading to stabilize surface-exposed flexible alpha-helixes and loop in the multidomain beta-jelly roll fold structure, respectively. In conclusion, the variant CBH-I R1 could enable efficient lignocellulosic biomass degradation as a cost-effective alternative for the sustainable production of biofuels and value-added chemicals.
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| 45. |
- Revel, A., et al.
(författare)
-
Strong Neutron Pairing in core+4n Nuclei
- 2018
-
Ingår i: Physical Review Letters. - 1079-7114 .- 0031-9007. ; 120:15
-
Tidskriftsartikel (refereegranskat)abstract
- The emission of neutron pairs from the neutron-rich N=12 isotones C18 and O20 has been studied by high-energy nucleon knockout from N19 and O21 secondary beams, populating unbound states of the two isotones up to 15 MeV above their two-neutron emission thresholds. The analysis of triple fragment-n-n correlations shows that the decay N19(-1p)C18∗→C16+n+n is clearly dominated by direct pair emission. The two-neutron correlation strength, the largest ever observed, suggests the predominance of a C14 core surrounded by four valence neutrons arranged in strongly correlated pairs. On the other hand, a significant competition of a sequential branch is found in the decay O21(-1n)O20∗→O18+n+n, attributed to its formation through the knockout of a deeply bound neutron that breaks the O16 core and reduces the number of pairs.
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| 46. |
- Singh, S, et al.
(författare)
-
Nanotechnology Facilitated Cultured Neuronal Network and Its Applications
- 2021
-
Ingår i: International journal of molecular sciences. - : MDPI AG. - 1422-0067. ; 22:11
-
Tidskriftsartikel (refereegranskat)abstract
- The development of a biomimetic neuronal network from neural cells is a big challenge for researchers. Recent advances in nanotechnology, on the other hand, have enabled unprecedented tools and techniques for guiding and directing neural stem cell proliferation and differentiation in vitro to construct an in vivo-like neuronal network. Nanotechnology allows control over neural stem cells by means of scaffolds that guide neurons to reform synaptic networks in suitable directions in 3D architecture, surface modification/nanopatterning to decide cell fate and stimulate/record signals from neurons to find out the relationships between neuronal circuit connectivity and their pathophysiological functions. Overall, nanotechnology-mediated methods facilitate precise physiochemical controls essential to develop tools appropriate for applications in neuroscience. This review emphasizes the newest applications of nanotechnology for examining central nervous system (CNS) roles and, therefore, provides an insight into how these technologies can be tested in vitro before being used in preclinical and clinical research and their potential role in regenerative medicine and tissue engineering.
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| 47. |
- Singha, A. D., et al.
(författare)
-
Reentrant canonical spin-glass dynamics and tunable field-induced transitions in (GeMn)Co2O4 Kagomé lattice
- 2024
-
Ingår i: Journal of Physics. - : Institute of Physics Publishing (IOPP). - 0953-8984 .- 1361-648X. ; 36:7
-
Tidskriftsartikel (refereegranskat)abstract
- We report on the reentrant canonical semi spin-glass characteristics and controllable field-induced transitions in distorted Kagomé symmetry of (GeMn)Co2O4. This B-site spinel exhibits complicated, yet interesting magnetic behaviour in which the longitudinal ferrimagnetic (FiM) order sets in below the Néel temperature TFN ∼ 77 K due to uneven moments of divalent Co (↑ 5.33 μB) and tetravalent Mn (↓ 3.87 μB) which coexists with transverse spin-glass state below 72.85 K. Such complicated magnetic behaviour is suggested to result from the competing anisotropic superexchange interactions (JAB/kB ∼ 4.3 K, JAA/kB ∼ −6.2 K and JBB/kB ∼ −3.3 K) between the cations, which is extracted following the Néel's expression for the two-sublattice model of FiM. Dynamical susceptibility (χac (f, T)) and relaxation of thermoremanent magnetization, MTRM (t) data have been analysed by means of the empirical scaling-laws such as Vogel–Fulcher law and Power law of critical slowing down. Both of which reveal the reentrant spin-glass like character which evolves through a number of intermediate metastable states. The magnitude of Mydosh parameter (Ω ∼ 0.002), critical exponent zυ = (6.7 ± 0.07), spin relaxation time τ0 = (2.33 ± 0.1) × 10−18 s, activation energy Ea/kB = (69.8 ± 0.95) K and interparticle interaction strength (T0 = 71.6 K) provide the experimental evidences for canonical spin-glass state below the spin freezing temperature TF = 72.85 K. The field dependence of TF obtained from χac (T) follows the irreversibility in terms of de Almeida–Thouless mean-field instability in which the magnitude of crossover scaling exponent Φ turns out to be ∼2.9 for the (Ge0.8Mn0.2)Co2O4. Isothermal magnetization plots reveal two field-induced transitions across 9.52 kOe (HSF1) and 45.6 kOe (HSF2) associated with the FiM domains and spin-flip transition, respectively. Analysis of the inverse paramagnetic susceptibility after subtracting the temperature independent diamagnetic term (=−3 × 10−3 emu mol−1 Oe−1) results in the effective magnetic moment = 7.654 μB/f.u. This agrees well with the theoretically obtained = 7.58 μB/f.u. resulting the cation distribution in support of the Hund's ground state spin configuration and of Mn4+ and Co2+, respectively. The H–T phase diagram has been established by analysing all the parameters (TF(H), TFN(H), HSF1(T) and HSF2(T)) extracted from various magnetization measurements. This diagram enables clear differentiation among the different phases of the (GeMn)Co2O4 and also illustrates the demarcation between short-range and long-range ordered regions.
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| 48. |
- Tjernberg, L O, et al.
(författare)
-
Amyloid beta-peptide polymerization studied using fluorescence correlation spectroscopy
- 1999
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Ingår i: Chemistry and Biology. - 1074-5521 .- 1879-1301. ; 6:1, s. 53-62
-
Tidskriftsartikel (refereegranskat)abstract
- Background: The accumulation of fibrillar deposits of amyloid beta-peptide (A beta) in brain parenchyma and cerebromeningeal blood vessels is a key step in the pathogenesis of Alzheimer's disease. In this report, polymerization of A beta was studied using fluorescence correlation spectroscopy (FCS), a technique capable of detecting small molecules and large aggregates simultaneously in solution. Results: The polymerization of A beta dissolved in Tris-buffered saline, pH 7.4, occurred above a critical concentration of 50 mu M and proceeded from monomers/dimers into two discrete populations of large aggregates, without any detectable amount of oligomers. The aggregation showed very high cooperativity and reached a maximum after 40 min, followed by an increase in the amount of monomers/dimers and a decrease in the size of the large aggregates. Electron micrographs of samples prepared at the time for maximum aggregation showed a mixture of an amorphous network and short diffuse fibrils, whereas only mature amyloid fibrils were detected after one day of incubation. The aggregation was reduced when A beta was incubated in the presence of A beta ligands, oligopeptides previously shown to inhibit fibril formation, and aggregates were partly dissociated after the addition of the ligands. Conclusions: The polymerization of A beta is a highly cooperative process in which the formation of very large aggregates precedes the formation of fibrils. The entire process can be inhibited and, at least in early stages, partly reversed by A beta ligands.
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| 49. |
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