1. |
- Yang, Xi-Xi, et al.
(författare)
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Theoretical study of the mechanism of the manganese catalase KatB
- 2019
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Ingår i: Journal of Biological Inorganic Chemistry. - : Springer Science and Business Media LLC. - 0949-8257 .- 1432-1327. ; 24:1, s. 103-115
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Tidskriftsartikel (refereegranskat)abstract
- The mechanism of the H2O2 disproportionation catalyzed by the manganese catalase (MnCat) KatB was studied using the hybrid density functional theory B3LYP and the quantum chemical cluster approach. Compared to the previous mechanistic study at the molecular level for the Thermus thermophilus MnCat (TTC), more modern methodology was used and larger models of increasing sizes were employed with the help of the high-resolution X-ray structure. In the reaction pathway suggested for KatB using the Large chemical model, the O-O homolysis of the first substrate H2O2 occurs through a -(1):(1) coordination mode and requires a barrier of 10.9kcal/mol. In the intermediate state of the bond cleavage, two hydroxides form as terminal ligands of the dimanganese cluster at the Mn-2(III,III) oxidation state. One of the two Mn(III)-OH- moieties and a second-sphere tyrosine stabilize the second substrate H2O2 in the second-sphere of the active site via hydrogen bonding interactions. The H2O2, unbound to the metals, is first oxidized into HO2 through a proton-coupled electron transfer (PCET) step with a barrier of 9.5kcal/mol. After the system switches to the triplet surface, the uncoordinated HO2 replaces the product water terminally bound to the Mn(II) and is then oxidized into O-2 spontaneously. Transition states with structural similarities to those obtained for TTC, where -(2)-OH-/O2- groups play important roles, were found to be higher in energy.
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2. |
- Beal, Jacob, et al.
(författare)
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Robust estimation of bacterial cell count from optical density
- 2020
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Ingår i: Communications Biology. - : Springer Science and Business Media LLC. - 2399-3642. ; 3:1
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Tidskriftsartikel (refereegranskat)abstract
- Optical density (OD) is widely used to estimate the density of cells in liquid culture, but cannot be compared between instruments without a standardized calibration protocol and is challenging to relate to actual cell count. We address this with an interlaboratory study comparing three simple, low-cost, and highly accessible OD calibration protocols across 244 laboratories, applied to eight strains of constitutive GFP-expressing E. coli. Based on our results, we recommend calibrating OD to estimated cell count using serial dilution of silica microspheres, which produces highly precise calibration (95.5% of residuals <1.2-fold), is easily assessed for quality control, also assesses instrument effective linear range, and can be combined with fluorescence calibration to obtain units of Molecules of Equivalent Fluorescein (MEFL) per cell, allowing direct comparison and data fusion with flow cytometry measurements: in our study, fluorescence per cell measurements showed only a 1.07-fold mean difference between plate reader and flow cytometry data.
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3. |
- Kristanl, Matej, et al.
(författare)
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The Seventh Visual Object Tracking VOT2019 Challenge Results
- 2019
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Ingår i: 2019 IEEE/CVF INTERNATIONAL CONFERENCE ON COMPUTER VISION WORKSHOPS (ICCVW). - : IEEE COMPUTER SOC. - 9781728150239 ; , s. 2206-2241
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Konferensbidrag (refereegranskat)abstract
- The Visual Object Tracking challenge VOT2019 is the seventh annual tracker benchmarking activity organized by the VOT initiative. Results of 81 trackers are presented; many are state-of-the-art trackers published at major computer vision conferences or in journals in the recent years. The evaluation included the standard VOT and other popular methodologies for short-term tracking analysis as well as the standard VOT methodology for long-term tracking analysis. The VOT2019 challenge was composed of five challenges focusing on different tracking domains: (i) VOT-ST2019 challenge focused on short-term tracking in RGB, (ii) VOT-RT2019 challenge focused on "real-time" short-term tracking in RGB, (iii) VOT-LT2019 focused on long-term tracking namely coping with target disappearance and reappearance. Two new challenges have been introduced: (iv) VOT-RGBT2019 challenge focused on short-term tracking in RGB and thermal imagery and (v) VOT-RGBD2019 challenge focused on long-term tracking in RGB and depth imagery. The VOT-ST2019, VOT-RT2019 and VOT-LT2019 datasets were refreshed while new datasets were introduced for VOT-RGBT2019 and VOT-RGBD2019. The VOT toolkit has been updated to support both standard short-term, long-term tracking and tracking with multi-channel imagery. Performance of the tested trackers typically by far exceeds standard baselines. The source code for most of the trackers is publicly available from the VOT page. The dataset, the evaluation kit and the results are publicly available at the challenge website(1).
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4. |
- Ablikim, M., et al.
(författare)
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Measurements of cross section of e(+)e(-) -> p(p)over-bar pi(0) at center-of-mass energies between 4.008 and 4.600 GeV
- 2017
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Ingår i: Physics Letters B. - : ELSEVIER SCIENCE BV. - 0370-2693 .- 1873-2445. ; 771, s. 45-51
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Tidskriftsartikel (refereegranskat)abstract
- Based on e(+)e(-) annihilation data samples collected with the BESIII detector at the BEPCII collider at 13 center-of-mass energies from 4.008 to 4.600 GeV, measurements of the Born cross section of e(+)e(-) -> p (p) over bar pi(0) are performed. No significant resonant structure is observed in the measured energy dependence of the cross section. The upper limit on the Born cross section of e(+)e(-) -> Y (4260) -> p (p) over bar pi(0) at the 90% C. L. is determined to be 0.01 pb. The upper limit on the ratio of the branching fractions B(Y(4260) -> p (p) over bar pi(0))/B(Y(4260) -> pi(+)pi(-) j/Psi) at the 90% C. L. is determined to be 0.02%.
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5. |
- Chen, Xi, et al.
(författare)
-
Nanosecond Photothermal Effects in Plasmonic Nanostructures
- 2012
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Ingår i: ACS Nano. - : American Chemical Society (ACS). - 1936-0851 .- 1936-086X. ; 6:3, s. 2550-2557
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Tidskriftsartikel (refereegranskat)abstract
- Photothermal effects in plasmonic nanostructures have great potentials in applications for photothermal cancer therapy, optical storage, thermo-photovoltaics, etc. However, the transient temperature behavior of a nanoscale material system during an ultrafast photothermal process has rarely been accurately investigated. Here a heat transfer model is constructed to investigate the temporal and spatial variation of temperature in plasmonic gold nanostructures. First, as a benchmark scenario, we study the light-induced heating of a gold nanosphere in water and calculate the relaxation time of the nanosphere excited by a modulated light. Second, we investigate heating and reshaping of gold nanoparticles in a more complex metamaterial absorber structure induced by a nanosecond pulsed light. The model shows that the temperature of the gold nanoparticles can be raised from room temperature to >795 K in just a few nanoseconds with a low light luminance, owing to enhanced light absorption through strong plasmonic resonance. Such quantitative predication of temperature change, which Is otherwise formidable to measure experimentally, can serve as an excellent guideline for designing devices for ultrafast photothermal applications.
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6. |
- Chen, Xi, et al.
(författare)
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Ordered Au nanocrystals on a substrate formed by light-induced rapid annealing
- 2014
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Ingår i: Nanoscale. - : Royal Society of Chemistry (RSC). - 2040-3364 .- 2040-3372. ; 6:3, s. 1756-1762
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Tidskriftsartikel (refereegranskat)abstract
- Light-induced rapid annealing (LIRA) is a widely used method to modify the morphology and crystallinity of noble metal nanoparticles, and the nanoparticles generally evolve into nanospheres. It is rather challenging to form faceted Au nanocrystals on a substrate using LIRA. Here the formation of spatially ordered Au nanocrystals using a continuous wave infrared laser is reported, assisted by a metamaterial perfect absorber. Faceted Au nanocrystals in truncated-octahedral or multi-twinned geometries can be obtained. The evolution of morphology and crystallinity of the Au nanoparticles during laser annealing is also revealed, where the crystal grain growth and the surface melting are shown to play key roles in nanocrystal formation. The evolution of morphology also gives the freedom of tuning the absorption spectrum of the metamaterial absorber. These findings provide a novel way for tailoring the morphology and crystallinity of metallic nanoparticles and may pave the way to fabricate refined nano-devices in many potential applications for optics, electronics, catalysis, surface-chemistry and biology.
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7. |
- Chen, Xi, et al.
(författare)
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Photothermal direct writing of metallic microstructure for frequency selective surface at terahertz frequencies
- 2012
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Ingår i: Proceedings of the 2012 International Workshop on Metamaterials, Meta 2012. - : IEEE. - 9781467328081 ; , s. 6464923-
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Konferensbidrag (refereegranskat)abstract
- Maskless photothermal direct writing technique was investigated to fabricate planar microscale metallic structures. In this technique, we use a tightly focused nanosecond pulsed infrared light to heat the metallic thin film on substrate. With sufficient volumic power density, the metal inside a "hot spot" could be removed from substrate. This technique benefits from not only the enhanced optical absorption, thanks to the surface plasmon resonance of metallic thin film, but also the reduced thermal conductivity, due to the frequent boundary scattering of phonons inside the thin film. To verify the performance of our direct writing technique, a cross-slot periodic array is scribed in gold thin film on silica substrate. Such a pattern can serve as a frequency selective surface at terahertz, which has many applications in terahertz radio system, e. g. rejecting thermal noise before terahertz receiver or serving as reflectors in Fabry-Perot etalon for astronomy spectroscopy.
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8. |
- Chen, Xi, 1983-
(författare)
-
Photothermal Effect in Plasmonic Nanostructures and its Applications
- 2014
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Plasmonic resonances are characterized by enhanced optical near field and subwavelength power confinement. Light is not only scattered but also simultaneously absorbed in the metal nanostructures. With proper structural design, plasmonic-enhanced light absorption can generate nanoscopically confined heat power in metallic nanostructures, which can even be temporally modulated by varying the pump light. These intrinsic characters of plasmonic nanostructures are investigated in depth in this thesis for a range of materials and nanophotonic applications. The theoretical basis for the photothermal phenomenon, including light absorption, heat generation, and heat conduction, is coherently summarized and implemented numerically based on finite-element method. Our analysis favours disk-pair and particle/dielectric-spacer/metal-film nanostructures for their high optical absorbance, originated from their antiparallel dipole resonances. Experiments were done towards two specific application directions. First, the manipulation of the morphology and crystallinity of Au nanoparticles (NPs) in plasmonic absorbers by photothermal effect is demonstrated. In particular, with a nanosecond-pulsed light, brick-shaped Au NPs are reshaped to spherical NPs with a smooth surface; while with a 10-second continuous wave laser, similar brick-shaped NPs can be annealed to faceted nanocrystals. A comparison of the two cases reveals that pumping intensity and exposure time both play key roles in determining the morphology and crystallinity of the annealed NPs. Second, the attempt is made to utilize the high absorbance and localized heat generation of the metal-insulator-metal (MIM) absorber in Si thermo-optic switches for achieving all-optical switching/routing with a small switching power and a fast transient response. For this purpose, a numerical study of a Mach-Zehnder interferometer integrated with MIM nanostrips is performed. Experimentally, a Si disk resonator and a ring-resonator-based add-drop filter, both integrated with MIM film absorbers, are fabricated and characterized. They show that good thermal conductance between the absorber and the Si light-guiding region is vital for a better switching performance. Theoretical and experimental methodologies presented in the thesis show the physics principle and functionality of the photothermal effect in Au nanostructures, as well as its application in improving the morphology and crystallinity of Au NPs and miniaturized all-optical Si photonic switching devices.
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9. |
- Chen, Xi, et al.
(författare)
-
Photothermal phenomena in plasmonics and metamaterials
- 2011
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Ingår i: ADVANCES IN OPTICAL THIN FILMS IV. - : SPIE. - 9780819487940 ; , s. 81681K-
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Konferensbidrag (refereegranskat)abstract
- Our recent theoretical and experimental investigation of the photothermal effect in a planar metamaterial absorber is reviewed in the present paper. The observed ultrasensitive photothermal heating in such an absorber nanostructure irradiated by a pulsed white-light source is elaborated with a simple yet compelling heat transfer model, which is subsequently solved with a finite-element method. The simulation results not only agree with the experimental finding, but also provide more detailed understanding of the temperature transition in the complex system.
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10. |
- Chen, Xi, et al.
(författare)
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Photothermal Switching of SOI Waveguide-Based Mach-Zehnder Interferometer with Integrated Plasmonic Nanoheater
- 2014
-
Ingår i: Plasmonics. - : Springer. - 1557-1955 .- 1557-1963. ; 9:5, s. 1197-1205
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Tidskriftsartikel (refereegranskat)abstract
- We theoretically and numerically investigated the photothermal switching of a Mach-Zehnder interferometer (MZI) based on two Si waveguides integrated with plasmonic nanoheaters. The nanoheater is a composite nanowire with Au/Al2O3/Au three-layer structure, which is designed to have a highly efficient optical absorption peak at wavelength of 1,064 nm. Based on this finding, we further analyze a MZI built with two 40-μm-long symmetric waveguide branches, each integrated with a 20-μm-long nanoheater. The optical switching power of the MZI device is 190 mW (280 mW) for the capped (buried) channel waveguide, when pumped by a circular Gaussian beam with a waist of 10 μm. Alternatively, the switching power can be reduced to 38 mW (56 mW) by using an astigmatic Gaussian beam, with a semi-major axis of 10 μm and an aspect ratio of 5. The switching response time of the MZI is 0.7 μs (1.0 μs) for capped (buried) channel waveguide design. Our design opens a new route for optically driven non-contact optical on-off switching with sub-microsecond time response.
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11. |
- Chen, Xi, et al.
(författare)
-
Photothermally tunable silicon-microring-based optical add-drop filter through integrated light absorber
- 2014
-
Ingår i: Optics Express. - 1094-4087. ; 22:21, s. 25233-25241
-
Tidskriftsartikel (refereegranskat)abstract
- An optically pumped thermo-optic (TO) silicon ring add-drop filter with fast thermal response is experimentally demonstrated. We propose that metal-insulator-metal (MIM) light absorber can be integrated into silicon TO devices, acting as a localized heat source which can be activated remotely by a pump beam. The MIM absorber design introduces less thermal capacity to the device, compared to conventional electrically-driven approaches. Experimentally, the absorber-integrated add-drop filter shows an optical response time of 13.7 mu s following the 10%-90% rule (equivalent to a exponential time constant of 5 mu s) and a wavelength shift over pump power of 60 pm/mW. The photothermally tunable add-drop filter may provide new perspectives for all-optical routing and switching in integrated Si photonic circuits.
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12. |
- Chen, Xi, et al.
(författare)
-
Photothermally tunable silicon-microring-based optical add-drop filter through integrated light absorber
- 2014
-
Ingår i: Optics Express. - : Optica Publishing Group. - 1094-4087. ; 22:21, s. 25233-25241
-
Tidskriftsartikel (refereegranskat)abstract
- An optically pumped thermo-optic (TO) silicon ring add-drop filter with fast thermal response is experimentally demonstrated. We propose that metal-insulator-metal (MIM) light absorber can be integrated into silicon TO devices, acting as a localized heat source which can be activated remotely by a pump beam. The MIM absorber design introduces less thermal capacity to the device, compared to conventional electrically-driven approaches. Experimentally, the absorber-integrated add-drop filter shows an optical response time of 13.7 μs following the 10%–90% rule (equivalent to a exponential time constant of 5 μs) and a wavelength shift over pump power of 60 pm/mW. The photothermally tunable add-drop filter may provide new perspectives for all-optical routing and switching in integrated Si photonic circuits.
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13. |
- Chen, Xi, et al.
(författare)
-
Photothermally tunable silicon microring-resonator-based optical add-drop filter
-
Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- A themro-optic (TO) silicon photonic add-drop filterwith small switching power and fast response is experimentallydemonstrated. We propose that metal-insulator-metal (MIM)absorbers can be integrated into the silicon TO devices, acting asan efficient and localized heat source. The MIM absorber designintroduces less thermal capacity to the device, comparing to theelectrically driven heater used in conventional TO devices. As a keyelement in silicon photonics, microring resonators have applicationin wavelength-division-multiplexing (WDM) devices, owning to theirunique spectrum properties. In this work, a silicon microring add-dropfilter is equipped with a MIM absorber. Experimentally, the deviceshows a measured optical response time of 5.0 μs and pumping powerderivative of the wavelength shift of 60 pm/mW.
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14. |
- Chen, Yiting, et al.
(författare)
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Plasmonic analog of microstrip transmission line and effect of thermal annealing on its propagation loss
- 2013
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Ingår i: Optics Express. - 1094-4087. ; 21:2, s. 1639-1644
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Tidskriftsartikel (refereegranskat)abstract
- We fabricated a plasmonic analog of the microwave microstrip transmission line and measured its propagation loss before and after thermal annealing. It is found that its propagation loss at 980 nm wavelength can be reduced by more than 50%, from 0.45 to 0.20 dB/μm, after thermal annealing at 300 °C. The reduction in loss can be attributed to the improved gold surface condition and probably also to the change in the metal's inner structure. Less evident loss reduction is noticed at 1550 nm, which is owing to extremely small portion of the modal electric field located in the metal regions at this wavelength.
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15. |
- Chen, Yiting, et al.
(författare)
-
Plasmonic analog of microstrip transmission line and effect of thermal annealing on its propagation loss
- 2013
-
Ingår i: Optics Express. - : Optical Society of America. - 1094-4087. ; 21:2, s. 1639-1644
-
Tidskriftsartikel (refereegranskat)abstract
- We fabricated a plasmonic analog of the microwave microstrip transmission line and measured its propagation loss before and after thermal annealing. It is found that its propagation loss at 980 nm wavelength can be reduced by more than 50%, from 0.45 to 0.20 dB/μm, after thermal annealing at 300 °C. The reduction in loss can be attributed to the improved gold surface condition and probably also to the change in the metal’s inner structure. Less evident loss reduction is noticed at 1550 nm, which is owing to extremely small portion of the modal electric field located in the metal regions at this wavelength.
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16. |
- Dong, Jianzhi, et al.
(författare)
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Statistical uncertainty analysis-based precipitation merging (SUPER) : A new framework for improved global precipitation estimation
- 2022
-
Ingår i: Remote Sensing of Environment. - : Elsevier BV. - 0034-4257. ; 283
-
Tidskriftsartikel (refereegranskat)abstract
- Multi-source merging is an established tool for improving large-scale precipitation estimates. Existing merging frameworks typically use gauge-based precipitation error statistics and neglect the inter-dependence of various precipitation products. However, gauge-observation uncertainties at daily and sub-daily time scales can bias merging weights and yield sub-optimal precipitation estimates, particularly over data-sparse regions. Likewise, frameworks ignoring inter-product error cross-correlation will overfit precipitation observation noise. Here, a Statistical Uncertainty analysis-based Precipitation mERging framework (SUPER) is proposed for addressing these challenges. Specifically, a quadruple collocation analysis is employed to estimate precipitation error variances and covariances for commonly used precipitation products. These error estimates are subsequently used for merging all products via a least-squares minimization approach. In addition, false-alarm precipitation events are removed via a reference rain/no-rain time series estimated by a newly developed categorical variable merging method. As such, SUPER does not require any rain gauge observations to reduce daily random and rain/no-rain classification errors. Additionally, by considering precipitation product inter-dependency, SUPER avoids overfitting measurement noise present in multi-source precipitation products. Results show that the overall RMSE of SUPER-based precipitation is 3.35 mm/day and the daily correlation with gauge observations is 0.71 [−] – metrics that are generally superior to recent precipitation reanalyses and remote sensing products. In this way, we seek to propose a new framework for robustly generating global precipitation datasets that can improve land surface and hydrological modeling skill in data-sparse regions.
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17. |
- Gong, Hanmo, et al.
(författare)
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Gold nanoparticle transfer through photothermal effects in a metamaterial absorber by nanosecond laser
- 2014
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Ingår i: Scientific Reports. - : Springer Science and Business Media LLC. - 2045-2322. ; 4, s. 6080-
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Tidskriftsartikel (refereegranskat)abstract
- A non-complicated, controllable method of metallic nanoparticle fabrication at low operating light power is proposed. The method is based on laser-induced forward transfer, using a metamaterial absorber as the donor to significantly enhance the photothermal effect and reduce the operating light fluence to 35 mJ/cm(2), which is much lower than that in previous works. A large number of metallic nanoparticles can be transferred by one shot of focused nanosecond laser pulses. Transferred nanoparticles exhibit good size uniformity and the sizes are controllable. The optical properties of transferred particles are characterized by dark-field spectroscopy and the experimental results agree with the simulation results.
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18. |
- Gong, H., et al.
(författare)
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Photothermal Switching Based on Silicon Mach-Zehnder Interferometer Integrated with Light Absorber
- 2016
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Ingår i: IEEE Photonics Journal. - : Institute of Electrical and Electronics Engineers (IEEE). - 1943-0655. ; 8:2
-
Tidskriftsartikel (refereegranskat)abstract
- We present an all-optical switch based on photothermal effects in a silicon Mach-Zehnder interferometer (MZI) integrated with a light absorber. The metal-insulator-metal light absorber located near the longer arm of the asymmetric MZI efficiently converts infrared light to heat. Pumped by a continuous-wave 1064-nm laser, the spectral transmittance of the fully etched strip waveguide (half-etched rib waveguide) MZI can be tuned with an efficiency of 38 pm/mW (98.5 pm/mW). Dynamic switching experiments show that the rise/fall time constant of the output probe light is 11.45/10.98 μs (8.25/7.13 μs) for the fully etched (half-etched) MZI.
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19. |
- Gong, Hanmo, et al.
(författare)
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Photothermal switching based on silicon mach–zehnder interferometer integrated with light absorber
- 2016
-
Ingår i: IEEE Photonics Journal. - : Institute of Electrical and Electronics Engineers (IEEE). - 1943-0655. ; 8:2
-
Tidskriftsartikel (refereegranskat)abstract
- We present an all-optical switch based on photothermal effects in a silicon Mach-Zehnder interferometer (MZI) integrated with a light absorber. The metal-insulator-metal light absorber located near the longer arm of the asymmetric MZI efficiently converts infrared light to heat. Pumped by a continuous-wave 1064-nm laser, the spectral transmittance of the fully etched strip waveguide (half-etched rib waveguide) MZI can be tuned with an efficiency of 38 pm/mW (98.5 pm/mW). Dynamic switching experiments show that the rise/fall time constant of the output probe light is 11.45/10.98 μs (8.25/7.13 μs) for the fully etched (half-etched) MZI.
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20. |
- Huang, Wuqing, et al.
(författare)
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PDE5 inhibition mitigates heart failure in hyperlipidemia
- 2024
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Ingår i: Biomedicine and Pharmacotherapy. - 0753-3322. ; 175
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Tidskriftsartikel (refereegranskat)abstract
- PDE5 inhibitors was reported to play a protective role in both regulating lipid metabolism and reducing heart failure (HF). This study aimed to clarify the effectiveness of PDE5 inhibitors against hyperlipidemia-related HF by combining evidence from population-based study and animal models. The nationwide cohort study found that post-diagnostic use of PDE5 inhibitors was associated with a significantly lower risk of HF compared with patients who used alprostadil, especially among individuals with hyperlipidemia (adjusted HR = 0.56, 95% CI = 0.40–0.78). In animal models, sildenafil significantly recovered the cardiac structure and function induced by AAB surgery, as well as reversed liver dysfunction and ameliorated hyperlipidemia induced by HFD via reducing the level of ALT, AST and serum lipids. Lipidomic analysis identified four lipid metabolites involved in sildenafil administration, including FA 16:3, LPC O-18:1, DG24:0_18:0 and SE28:1/20:4. This study revealed the protective effect of PDE5 inhibitors against HF in hyperlipidemia, indicating the potential of being repurposed as an adjuvant for HF prevention in patients with hyperlipidemia if these findings can be further confirmed in clinical trials.
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21. |
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22. |
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23. |
- Li, Zeya, et al.
(författare)
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Robustness of Trion State in Gated Monolayer MoSe2 under Pressure
- 2023
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Ingår i: Nano Letters. - : American Chemical Society (ACS). - 1530-6984 .- 1530-6992. ; 23:22, s. 10282-10289
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Tidskriftsartikel (refereegranskat)abstract
- Quasiparticles consisting of correlated electron(s) and hole(s), such as excitons and trions, play important roles in the optical phenomena of van der Waals semiconductors and serve as unique platforms for studies of many-body physics. Herein, we report a gate-tunable exciton-to-trion transition in pressurized monolayer MoSe2, in which the electronic band structures are modulated continuously within a diamond anvil cell. The emission energies of both the exciton and trion undergo large blueshifts over 90 meV with increasing pressure. Surprisingly, the trion binding energy remains constant at 30 meV, regardless of the applied pressure. Combining ab initio density functional theory calculations and quantum Monte Carlo simulations, we find that the remarkable robustness of the trion binding energy originates from the spatially diffused nature of the trion wave function and the weak correlation between its constituent electron-hole pairs. Our findings shed light on the optical properties of correlated excitonic quasiparticles in low-dimensional materials.
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24. |
- Qiu, Chunjing, et al.
(författare)
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A strong mitigation scenario maintains climate neutrality of northern peatlands
- 2022
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Ingår i: One Earth. - : Elsevier BV. - 2590-3330 .- 2590-3322. ; 5:1, s. 86-97
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Tidskriftsartikel (refereegranskat)abstract
- Northern peatlands store 300–600 Pg C, of which approximately half are underlain by permafrost. Climate warming and, in some regions, soil drying from enhanced evaporation are progressively threatening this large carbon stock. Here, we assess future CO2 and CH4 fluxes from northern peatlands using five land surface models that explicitly include representation of peatland processes. Under Representative Concentration Pathways (RCP) 2.6, northern peatlands are projected to remain a net sink of CO2 and climate neutral for the next three centuries. A shift to a net CO2 source and a substantial increase in CH4 emissions are projected under RCP8.5, which could exacerbate global warming by 0.21°C (range, 0.09–0.49°C) by the year 2300. The true warming impact of peatlands might be higher owing to processes not simulated by the models and direct anthropogenic disturbance. Our study highlights the importance of understanding how future warming might trigger high carbon losses from northern peatlands.
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25. |
- Qiu, Min, et al.
(författare)
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Nanostructured plasmonic devices and their applications
- 2013
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Ingår i: 2013 IEEE 6th International Conference on Advanced Infocomm Technology, ICAIT 2013. - : IEEE. - 9781479904655 ; , s. 79-80
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Konferensbidrag (refereegranskat)abstract
- In this talk, we will review our recent works on nanostructured plasmonic devices, and their applications in high performance light absorption, photothermal effects, and partly in photonic integrations.
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26. |
- Qiu, Min, et al.
(författare)
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Photothermal effects in a plasmonic metamaterial structure
- 2011
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Konferensbidrag (refereegranskat)abstract
- Heat generation due to photothermal effects in plasmonic nanostructures have generated many important applications, due to the strong enhancement of light absorption through plasmonic resonance at visible and near-infrared region. In this talk, we review our recent experimental efforts on photothermal effects in a metamaterial nanostructure, which has an ultrasensitive heating response owing to plasmonic resonance. We observed close-to-instantaneous fusion and re-shaping of the nanoparticles with a nanosecond pulse train. The generated heat profile has a subwavelength resolution, and the resonance wavelength can be in principle tailored to arbitrary wavelength region by choosing an appropriate geometry for the resonator structure.
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27. |
- Qiu, Min, et al.
(författare)
-
Plasmonic enhanced photothermal effects and its applications
- 2014
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Konferensbidrag (refereegranskat)abstract
- We review here our recent studies on plasmonic enhanced photothermal effects in metallic nanostructure, and the applications of such effects. When light is shined on a prefect metamaterial absorber patterned with e-beam lithography, the gold nanoparticles (NPs) forming the absorber can be either transformed to nano-spherical-domes, or to truncated-octahedral shaped or multi-twined nanocrystals with large crystal grain sizes and flat boundary facets. The evolution of morphology and crystallinity of the gold NPs can be also observed. Evidences clearly show that the surface melting and the coalescence mechanism play a key role on nanocrystals formation. These melted gold nanospheres can even be transferred to another substrate, on which the transferred NPs exhibit excellent size uniformity. The strong photothermal effects can also be utilized to tune silicon photonics waveguides and resonators. It is shown that all-optical photothermal switching of Mach-Zehnder interferometers (MZI), silicon disk resonators, and silicon ring resonators is possible with the help of plasmonic nanoheaters. The switching response time and power consumption are all at reasonably low level.
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28. |
- Shi, Yuechun, et al.
(författare)
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All-optical switching of silicon disk resonator based on photothermal effect in metal-insulator-metal absorber
- 2014
-
Ingår i: Optics Letters. - 0146-9592 .- 1539-4794. ; 39:15, s. 4431-4434
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Tidskriftsartikel (refereegranskat)abstract
- Efficient narrowband light absorption by a metal-insulator-metal (MIM) structure can lead to high-speed light-to-heat conversion at a micro-or nanoscale. Such a MIM structure can serve as a heater for achieving all-optical light control based on the thermo-optical (TO) effect. Here we experimentally fabricated and characterized a novel all-optical switch based on a silicon microdisk integrated with a MIM light absorber. Direct integration of the absorber on top of the microdisk reduces the thermal capacity of the whole device, leading to high-speed TO switching of the microdisk resonance. The measurement result exhibits a rise time of 2.0 mu s and a fall time of 2.6 mu s with switching power as low as 0.5 mW; the product of switching power and response time is only about 1.3 mW.mu s. Since no auxiliary elements are required for the heater, the switch is structurally compact, and its fabrication is rather easy. The device potentially can be deployed for new kinds of all-optical applications.
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29. |
- Shi, Yuechun, et al.
(författare)
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All-optical switching of silicon disk resonator based on photothermal effect in metal–insulator–metal absorber
- 2014
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Ingår i: Optics Letters. - : Optica Publishing Group. - 0146-9592 .- 1539-4794. ; 39:15, s. 4431-4434
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Tidskriftsartikel (refereegranskat)abstract
- Efficient narrowband light absorption by a metal–insulator–metal (MIM) structure can lead to high-speed light-to-heat conversion at a micro- or nanoscale. Such a MIM structure can serve as a heater for achieving all-optical light control based on the thermo-optical (TO) effect. Here we experimentally fabricated and characterized a novel all-optical switch based on a silicon microdisk integrated with a MIM light absorber. Direct integration of the absorber on top of the microdisk reduces the thermal capacity of the whole device, leading to high-speed TO switching of the microdisk resonance. The measurement result exhibits a rise time of 2.0 μs and a fall time of 2.6 μs with switching power as low as 0.5 mW; the product of switching power and response time is only about 1.3 mW·μs1.3 mW·μs. Since no auxiliary elements are required for the heater, the switch is structurally compact, and its fabrication is rather easy. The device potentially can be deployed for new kinds of all-optical applications.
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30. |
- Sun, Xu, 1987-, et al.
(författare)
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All-Optical Switching Using a Hybrid Plasmonic Donut Resonator With Photothermal Absorber
- 2016
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Ingår i: IEEE Photonics Technology Letters. - : Institute of Electrical and Electronics Engineers (IEEE). - 1041-1135 .- 1941-0174. ; 28:15, s. 1609-1612
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Tidskriftsartikel (refereegranskat)abstract
- A novel hybrid plasmonic (HP) donut resonator integrated with a photothermal plasmonic absorber has been developed, which can be used as a compact all-optical switch or modulator. The radius of the fabricated HP donut resonator is 1.8 mu m, with a resonant wavelength around 1550 nm and a quality factor (Q factor) around 600. The photothermal plasmonic absorber is directly integrated above the HP device, which can absorb as much as 75% of impinging optical power at 1064 nm wavelength. Since the absorber is in tight contact to the Si ridge of the HP waveguide, the absorbed optical power can efficiently heat up the Si ridge, and hence change the resonant wavelength of the HP donut resonator by Si thermal expansion effect. Experimental results show that the power used for 15 dB amplitude switch is only 10 mW, with rise and fall response times around 18 and 14 mu s, respectively.
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31. |
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32. |
- Wang, Jing, et al.
(författare)
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Photothermal reshaping of gold nanoparticles in a plasmonic absorber
- 2011
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Ingår i: Optics Express. - 1094-4087. ; 19:15, s. 14726-14734
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Tidskriftsartikel (refereegranskat)abstract
- We experimentally demonstrate that a metamaterial nanostructure can have a localized heating response owing to plasmonic resonances in the near-infrared wavelength range (from 1.5 to 2 mu m). With a broadband nanosecond-pulse light, the temperature of composing gold particles in the nanostructure can be easily increased to over 900K within only several nanoseconds, resulting in re-shaping of the particles. The photothermal effect is elaborated with finite-element based numerical simulations. The absorption resonance can in principle be tailored with a great freedom by choosing appropriate metamaterial parameters. The light-induced heating in an artificial metamaterial can be potentially used for all-optical acute temperature tuning in a micro-environment, which may open new frontiers especially in nanotechnology and biotechnology.
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33. |
- Wang, Jing, et al.
(författare)
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Photothermal reshaping of gold nanoparticles in a plasmonic absorber
- 2011
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Ingår i: Optics Express. - : Optical Society of America. - 1094-4087. ; 19:15, s. 14726-14734
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Tidskriftsartikel (refereegranskat)abstract
- We experimentally demonstrate that a metamaterial nanostructure can have a localized heating response owing to plasmonic resonances in the near-infrared wavelength range (from 1.5 to 2µm). With a broadband nanosecond-pulse light, the temperature of composing gold particles in the nanostructure can be easily increased to over 900K within only several nanoseconds, resulting in re-shaping of the particles. The photothermal effect is elaborated with finite-element based numerical simulations. The absorption resonance can in principle be tailored with a great freedom by choosing appropriate metamaterial parameters. The light-induced heating in an artificial metamaterial can be potentially used for all-optical acute temperature tuning in a micro-environment, which may open new frontiers especially in nanotechnology and biotechnology.
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34. |
- Zheng, Yan, et al.
(författare)
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Precursors and Pathways Leading to Enhanced Secondary Organic Aerosol Formation during Severe Haze Episodes
- 2021
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Ingår i: Environmental Science and Technology. - : American Chemical Society (ACS). - 0013-936X .- 1520-5851. ; 55:23, s. 15680-15693
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Tidskriftsartikel (refereegranskat)abstract
- Molecular analyses help to investigate the key precursors and chemical processes of secondary organic aerosol (SOA) formation. We obtained the sources and molecular compositions of organic aerosol in PM2.5 in winter in Beijing by online and offline mass spectrometer measurements. Photochemical and aqueous processing were both involved in producing SOA during the haze events. Aromatics, isoprene, long-chain alkanes or alkenes, and carbonyls such as glyoxal and methylglyoxal were all important precursors. The enhanced SOA formation during the severe haze event was predominantly contributed by aqueous processing that was promoted by elevated amounts of aerosol water for which multifunctional organic nitrates contributed the most followed by organic compounds having four oxygen atoms in their formulae. The latter included dicarboxylic acids and various oxidation products from isoprene and aromatics as well as products or oligomers from methylglyoxal aqueous uptake. Nitrated phenols, organosulfates, and methanesulfonic acid were also important SOA products but their contributions to the elevated SOA mass during the severe haze event were minor. Our results highlight the importance of reducing nitrogen oxides and nitrate for future SOA control. Additionally, the formation of highly oxygenated long-chain molecules with a low degree of unsaturation in polluted urban environments requires further research.
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