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- Tozri, A., et al.
(författare)
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Investigation of the magnetocaloric effect and the critical behavior of the interacting superparamagnetic nanoparticles of La0.8Sr0.15Na0.05MnO3
- 2022
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Ingår i: Journal of Alloys and Compounds. - : Elsevier. - 0925-8388 .- 1873-4669. ; 890
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Tidskriftsartikel (refereegranskat)abstract
- We report on structural, magnetic properties of Na-doped La0.8Sr0.15Na0.05MnO3 (LSNMO) nanoparticles (NP) with size about 50 nm elaborated via sol-gel route. The chemical composition was verified using the energy dispersive X-ray analysis (EDAX) and by X-ray photoelectron spectroscopy (XPS). Magnetic characterizations demonstrate that LSMNO exhibits a coexistence of interacting superparamagnetic (ISPM) phase with blocking temperature T-B = 194 K and a ferromagnetic phase with Curie temperature T-C = 255.5 K. At low temperatures, the SPM state undergoes a collective freezing state at T-f = 46 K. the high-temperature regime (well above TC) reveals that NP-LSNMO has a strengthened Griffiths-like phase compared to their bulk counterpart. An itemized investigation of the critical behavior of the material was carried out in the vicinity of T-C. The critical exponents [beta = 0.546(7), gamma = 0.972(6), and delta = 2.94 (5)] were found to be in close agreement with of the mean-field theory. The maximum magnetic entropy change (-Delta(pk)(M)) is about 1.41 Jkg(-1) K-1 and the refrigeration capacity (RC) is 288 Jkg(-1) for a field change of 5 T at T = 215 K. This magnetocaloric response is reasonably high for nanomaterials and, together with its cost-effectiveness, makes NP LSMNO a potential candidate material for active magnetic refrigerators. Besides, the ISPM properties are desirable for hyperthermia applications. Our findings suggest that the magnetic inhomogeneity and the dipolar interaction between the SPM and FM phases in the range T-B < T < T-C are crucial factors in determining the magnetic properties of NP-LSNMO. (C) 2021 Elsevier B.V. All rights reserved.
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- Sassi, Atfa, et al.
(författare)
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Hypomorphic homozygous mutations in phosphoglucomutase 3 (PGM3) impair immunity and increase serum IgE levels
- 2014
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Ingår i: Journal of Allergy and Clinical Immunology. - : Elsevier BV. - 0091-6749 .- 1097-6825. ; 133:5, s. 1410-U681
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Tidskriftsartikel (refereegranskat)abstract
- Background: Recurrent bacterial and fungal infections, eczema, and increased serum IgE levels characterize patients with the hyper-IgE syndrome (HIES). Known genetic causes for HIES are mutations in signal transducer and activator of transcription 3 (STAT3) and dedicator of cytokinesis 8 (DOCK8), which are involved in signal transduction pathways. However, glycosylation defects have not been described in patients with HIES. One crucial enzyme in the glycosylation pathway is phosphoglucomutase 3 (PGM3), which catalyzes a key step in the synthesis of uridine diphosphate N-acetylglucosamine, which is required for the biosynthesis of N-glycans. Objective: We sought to elucidate the genetic cause in patients with HIES who do not carry mutations in STAT3 or DOCK8. Methods: After establishing a linkage interval by means of SNPchip genotyping and homozygosity mapping in 2 families with HIES from Tunisia, mutational analysis was performed with selector-based, high-throughput sequencing. Protein expression was analyzed by means of Western blotting, and glycosylation was profiled by using mass spectrometry. Results: Mutational analysis of candidate genes in an 11.9-Mb linkage region on chromosome 6 shared by 2 multiplex families identified 2 homozygous mutations in PGM3 that segregated with disease status and followed recessive inheritance. The mutations predict amino acid changes in PGM3 (p. Glu340del and p. Leu83Ser). A third homozygous mutation (p. Asp502Tyr) and the p. Leu83Ser variant were identified in 2 other affected families, respectively. These hypomorphic mutations have an effect on the biosynthetic reactions involving uridine diphosphate N-acetylglucosamine. Glycomic analysis revealed an aberrant glycosylation pattern in leukocytes demonstrated by a reduced level of tri-antennary and tetra-antennary N-glycans. T-cell proliferation and differentiation were impaired in patients. Most patients had developmental delay, and many had psychomotor retardation. Conclusion: Impairment of PGM3 function leads to a novel primary (inborn) error of development and immunity because biallelic hypomorphic mutations are associated with impaired glycosylation and a hyper-IgE-like phenotype.
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| 4. |
- Skini, Ridha, et al.
(författare)
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Magnetocaloric effect and critical behavior in La0.8K0.2MnO3 nanoparticle
- 2021
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Ingår i: RESULTS IN PHYSICS. - : Elsevier. - 2211-3797. ; 30
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Tidskriftsartikel (refereegranskat)abstract
- We report on the magnetocaloric effect and critical phenomenon on La0.8K0.2MnO3 nanoparticle through a systematic magnetic and electrical measurement. The magnetic entropy change (Delta S-M) presents close values obtained from resistivity and magnetic measurements, however, with a discrepancy in the magnetic entropy maximum values. This discrepancy is due to the presence of an extrinsic effect associated with the nanometric grain size affecting the electrical behavior. Interestingly, our results show a good agreement with the calculation of the critical exponents and the temperature coefficient of resistance shows positive and negative values. The obtained critical exponents are close to that of the mean-field theory (with beta = 0.5, gamma = 1, and delta = 3). This indicates a long-range interaction between spins a consequence of the presence the presence of dipole- dipole interaction in this system.
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| 5. |
- Alawsi, Mustafa A., et al.
(författare)
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Tuning ANN Hyperparameters by CPSOCGSA, MPA, and SMA for Short-Term SPI Drought Forecasting
- 2022
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Ingår i: Atmosphere. - : MDPI. - 2073-4433. ; 13:19
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Tidskriftsartikel (refereegranskat)abstract
- Modelling drought is vital to water resources management, particularly in arid areas, to reduce its effects. Drought severity and frequency are significantly influenced by climate change. In this study, a novel hybrid methodology was built, data preprocessing and artificial neural network (ANN) combined with the constriction coefficient-based particle swarm optimisation and chaotic gravitational search algorithm (CPSOCGSA), to forecast standard precipitation index (SPI) based on climatic factors. Additionally, the marine predators algorithm (MPA) and the slime mould algorithm (SMA) were used to validate the performance of the CPSOCGSA algorithm. Climatic factors data from 1990 to 2020 were employed to create and evaluate the SPI 1, SPI 3, and SPI 6 models for Al-Kut City, Iraq. The results indicated that data preprocessing methods improve data quality and find the best predictors scenario. The performance of CPSOCGSA-ANN is better than MPA-ANN and SMA-ANN algorithms based on various statistical criteria (i.e., R2, MAE, and RMSE). The proposed methodology yield R2 = 0.93, 0.93, and 0.88 for SPI 1, SPI 3, and SPI 6, respectively.
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| 6. |
- Ghorai, Sagar, et al.
(författare)
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Effect of reduced local lattice disorder on the magnetic properties of B-site substituted La0.8Sr0.2MnO3
- 2021
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Ingår i: Journal of Magnetism and Magnetic Materials. - : Elsevier. - 0304-8853 .- 1873-4766. ; 529
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Tidskriftsartikel (refereegranskat)abstract
- Disorder induced by chemical inhomogeneity and Jahn-Teller (JT) distortions is often observed in mixed valence perovskite manganites. The main reasons for the evolution of this disorder are connected with the cationic size differences and the ratio between JT active and non-JT active ions. The quenched disorder leads to a spin-cluster state above the magnetic transition temperature. The effect of Cu, a B-site substitution in the La0.8Sr0.2MnO3 compound, on the disordered phase has been addressed here. X-ray powder diffraction reveals rhombohedral (R-3c) structures for both the parent and B-site substituted compound with negligible change of lattice volume. The chemical compositions of the two compounds were verified by ion beam analysis technique. With the change of electronic bandwidth, the magnetic phase transition temperature has been tuned towards room temperature (318 K), an important requirement for room temperature magnetic refrigeration. However, a small decrease of the isothermal entropy change was observed with Cu-substitution, related to the decrease of the saturation magnetization.
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