| 1. |
- Panda, Swarup K., et al.
(författare)
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High photon energy spectroscopy of NiO : Experiment and theory
- 2016
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Ingår i: PHYSICAL REVIEW B. - 2469-9950. ; 93:23
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Tidskriftsartikel (refereegranskat)abstract
- We have revisited the valence band electronic structure of NiO by means of hard x-ray photoemission spectroscopy (HAXPES) together with theoretical calculations using both the GW method and the local density approximation + dynamical mean-field theory (LDA+DMFT) approaches. The effective impurity problem in DMFT is solved through the exact diagonalization (ED) method. We show that the LDA+DMFT method in conjunction with the standard fully localized limit (FLL) and around mean field (AMF) double-counting alone cannot explain all the observed structures in the HAXPES spectra. GW corrections are required for the O bands and Ni-s and p derived states to properly position their binding energies. Our results establish that a combination of the GW and DMFT methods is necessary for correctly describing the electronic structure of NiO in a proper ab initio framework. We also demonstrate that the inclusion of photoionization cross section is crucial to interpret the HAXPES spectra of NiO. We argue that our conclusions are general and that the here suggested approach is appropriate for any complex transition metal oxide.
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| 2. |
- Choudhury, D., et al.
(författare)
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Magnetization in electron- and Mn- doped SrTiO3
- 2013
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Ingår i: Scientific Reports. - : Springer Science and Business Media LLC. - 2045-2322. ; 3, s. 1433-
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Tidskriftsartikel (refereegranskat)abstract
- Mn- doped SrTiO3.0, when synthesized free of impurities, is a paramagnetic insulator with interesting dielectric properties. Since delocalized charge carriers are known to promote ferromagnetism in a large number of systems via diverse mechanisms, we have looked for the possibility of any intrinsic, spontaneous magnetization by simultaneous doping of Mn ions and electrons into SrTiO3 via oxygen vacancies, thereby forming SrTi1-xMnxO3-delta, to the extent of making the doped system metallic. We find an absence of any enhancement of the magnetization in the metallic sample when compared with a similarly prepared Mn doped, however, insulating sample. Our results, thus, are not in agreement with a recent observation of a weak ferromagnetism in metallic Mn doped SrTiO3 system.
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| 3. |
- Choudhury, D., et al.
(författare)
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Near-Room-Temperature Colossal Magnetodielectricity and Multiglass Properties in Partially Disordered La2NiMnO6
- 2012
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Ingår i: Physical Review Letters. - 0031-9007 .- 1079-7114. ; 108:12, s. 127201-
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Tidskriftsartikel (refereegranskat)abstract
- We report magnetic, dielectric, and magnetodielectric responses of the pure monoclinic bulk phase of partially disordered La2NiMnO6, exhibiting a spectrum of unusual properties and establish that this compound is an intrinsically multiglass system with a large magnetodielectric coupling (8%-20%) over a wide range of temperatures (150-300 K). Specifically, our results establish a unique way to obtain colossal magnetodielectricity, independent of any striction effects, by engineering the asymmetric hopping contribution to the dielectric constant via the tuning of the relative-spin orientations between neighboring magnetic ions in a transition-metal oxide system. We discuss the role of antisite (Ni-Mn) disorder in emergence of these unusual properties.
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| 4. |
- Choudhury, Debraj, et al.
(författare)
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Tuning of dielectric properties and magnetism of SrTiO3 by site-specific doping of Mn
- 2011
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Ingår i: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 84:12, s. 125124-
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Tidskriftsartikel (refereegranskat)abstract
- Combining experiments with first-principles calculations, we show that site-specific doping of Mn into SrTiO(3) has a decisive influence on the dielectric properties of these doped systems. We find that phonon contributions to the dielectric constant invariably decrease sharply on doping at any site. However, a sizable, random dipolar contribution only for Mn at the Sr site arises from a strong off-centric displacement of Mn in spite of Mn being in a non-d(0) state; this leads to a large dielectric constant at higher temperatures and gives rise to a relaxor ferroelectric behavior at lower temperatures. We also investigate magnetic properties in detail and critically reevaluate the possibility of a true multiglass state in such systems.
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| 5. |
- Hazarika, Abhijit, et al.
(författare)
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Ultranarrow and Widely Tunable Mn2+-Induced Photoluminescence from Single Mn-Doped Nanocrystals of ZnS-CdS Alloys
- 2013
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Ingår i: Physical Review Letters. - 0031-9007 .- 1079-7114. ; 110:26, s. 267401-
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Tidskriftsartikel (refereegranskat)abstract
- Extensively studied Mn-doped semiconductor nanocrystals have invariably exhibited photoluminescence over a narrow energy window of width <= 150 meV in the orange-red region and a surprisingly large spectral width (>= 180 meV), contrary to its presumed atomic-like origin. Carrying out emission measurements on individual single nanocrystals and supported by ab initio calculations, we show that Mn PL emission, in fact, can (i) vary over a much wider range (similar to 370 meV) covering the deep green-deep red region and (ii) exhibit widths substantially lower (similar to 60-75 meV) than reported so far, opening newer application possibilities and requiring a fundamental shift in our perception of the emission from Mn-doped semiconductor nanocrystals.
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| 6. |
- Jagadeeswararao, Metikoti, et al.
(författare)
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Electrical and Plasmonic Properties of Ligand-Free Sn4+-Doped In2O3 (ITO) Nanocrystals
- 2016
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Ingår i: ChemPhysChem. - : Wiley. - 1439-4235 .- 1439-7641. ; 17:5, s. 710-716
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Tidskriftsartikel (refereegranskat)abstract
- Sn4+-doped In2O3 (ITO) is a benchmark transparent conducting oxide material. We prepared ligand-free but colloidal ITO (8nm, 10% Sn4+) nanocrystals (NCs) by using a post-synthesis surface-modification reaction. (CH3)(3)OBF4 removes the native oleylamine ligand from NC surfaces to give ligand-free, positively charged NCs that form a colloidal dispersion in polar solvents. Both oleylamine-capped and ligand-free ITO NCs exhibit intense absorption peaks, due to localized surface plasmon resonance (LSPR) at around =1950nm. Compared with oleylamine-capped NCs, the electrical resistivity of ligand-free ITO NCs is lower by an order of magnitude (approximate to 35mcm(-1)). Resistivity over a wide range of temperatures can be consistently described as a composite of metallic ITO grains embedded in an insulating matrix by using a simple equivalent circuit, which provides an insight into the conduction mechanism in these systems.
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| 7. |
- Knut, Ronny, et al.
(författare)
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Interface characterization of Co2MnGe/Rh2CuSn Heusler multilayers
- 2013
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Ingår i: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 88:13, s. 134407-
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Tidskriftsartikel (refereegranskat)abstract
- To address the amount of disorder and interface diffusion induced by annealing, all-Heusler multilayer structures, consisting of ferromagnetic Co2MnGe and nonmagnetic Rh2CuSn layers of varying thicknesses, have been investigated by means of hard x-ray photoelectron spectroscopy and x-ray magnetic circular dichroism. We find evidence for a 4 angstrom thick magnetically dead layer that, together with the identified interlayer diffusion, are likely reasons for the unexpectedly small magnetoresistance found for current-perpendicular-to-plane giant magnetoresistance devices based on this all-Heusler system. We find that diffusion begins already at comparably low temperatures between 200 and 250 degrees C, where Mn appears to be most prone to diffusion.
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| 8. |
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| 9. |
- Kocevski, Vancho, 1984-, et al.
(författare)
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First-principles study of the influence of different interfaces and core types on the properties of CdSe/CdS core-shell nanocrystals
- 2015
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Ingår i: Scientific Reports. - : Springer Science and Business Media LLC. - 2045-2322. ; 5
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Tidskriftsartikel (refereegranskat)abstract
- With the expanding field of nanoengineering and the production of nanocrystals (NCs) with higher quality and tunable size, having reliable theoretical calculations to complement the experimental results is very important. Here we present such a study of CdSe/CdS core-shell NCs using density functional theory, where we focus on dependence of the properties of these NCs on core types and interfaces between the core and the shell, as well as on the core/shell ratio. We show that the density of states and the absorption indices depend rather weakly on the type of interface and core type. We demonstrate that the HOMO wavefunction is mainly localised in the core of the nanocrystal, depending primarily on the core/shell ratio. On the other hand the LUMO wavefunction spreads more into the shell of the nanocrystal, where its confinement in the core is almost the same in each of the studied structural models. Furthermore, we show that the radiative lifetimes decrease with increasing core sizes due to changes in the dipolar overlap integral of the HOMO and LUMO wavefunctions. In addition, the electron-hole Coulomb interaction energies follow a similar pattern as the localisation of the wavefunctions, with the smaller NCs having higher Coulomb interaction energies.
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| 10. |
- Kumar, Anil P., et al.
(författare)
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Composition driven structural transition in La2-xSrxCuRuO6 (0 <= x <= 1) double perovskites
- 2017
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Ingår i: Journal of Alloys and Compounds. - : Elsevier BV. - 0925-8388 .- 1873-4669. ; 693, s. 1096-1101
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Tidskriftsartikel (refereegranskat)abstract
- We report results of detailed structural investigations on the system La2-xSrxCuRuO6 (0 <= x <= 1) as a function of composition using neutron powder diffraction. Our results reveal that this series of compounds exhibit an interesting structural transition manifested through Sr doping; with Ru in single valency, in end members, and mixed valency otherwise. The end members La2CuRuO6 and LaSrCuRuO6 crystallize in monoclinic structures with space group P2(1)/n. However, the compositions with intermediate Sr doping (x = 0.2 and 0.8) crystallize in triclinic structure with space group P-1, albeit with minute distortions. The detailed structural studies by neutron powder diffraction at room temperature and at 10 K, for compositions, x = 0.2, 0.8 and 1 are presented. While magnetic measurements are indicative of ferro and antiferromagnetic like transitions for x = 0 and x > 0 respectively, neutron diffraction patterns collected at 10 K and 30 K across the characteristic transition temperature suggested by the magnetic data, do not show any extra peaks or extra intensity at lower temperature as compared to the high temperature, thus, establishing the absence of any long-range magnetic ordering in these samples.
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| 11. |
- Kumar, P. Anil, et al.
(författare)
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All-alkoxide based deposition and properties of a multilayer La0.67Sr0.33MnO3/CoFe2O4/La0.67Sr0.33MnO3 film
- 2021
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Ingår i: European Journal of Inorganic Chemistry. - : John Wiley & Sons. - 1434-1948 .- 1099-1948 .- 1099-0682. ; 2021:18, s. 1736-1744
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Tidskriftsartikel (refereegranskat)abstract
- Single and multilayer films of La0.67Sr0.33MnO3 and CoFe2O4 were deposited by spin-coating. The all-alkoxide precursors allowed inorganic gel films of extreme homogeneity to be formed and converted to phase pure complex oxides at low temperatures. La0.67Sr0.33MnO3 films were made with La- and Ca-methoxy-ethoxides and Mn19O12(moe)(14)(moeH)(10) as precursors at 800 degrees C. The CoFe2O4 films were obtained at extremely low 275 degrees C, using a new CoFe2-methoxyethoxide precursor. The decomposition and microstructural development on heating was described by TG, TEM, XRD and IR spectroscopy. XRD showed no spurious phases and the unit-cell dimensions coincided quite well with literature values of the targeted phases. The structural, magnetic and electronic properties of these films established their phase purity and high quality with physical properties comparable to films deposited by physical deposition methods. The magnetic and magneto transport results are presented for single, bi- and tri- layer structures. The magnetically soft La0.67Sr0.33MnO3 layer was exchange coupled to the magnetically hard CoFe2O4 layer, giving rise to interesting switching behaviour in magnetism and magneto-transport properties.
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| 12. |
- Kumar, P. Anil, et al.
(författare)
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Effect of "dipolar-biasing" on the tunability of tunneling magnetoresistance in transition metal oxide systems
- 2012
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 100:26, s. 262407-
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Tidskriftsartikel (refereegranskat)abstract
- We observe an unusual tunneling magnetoresistance (TMR) phenomenon in a composite of La2/3Sr1/3MnO3 with CoFe2O4 where the TMR versus applied magnetic field loop suggests a "negative coercive field." Tracing its origin back to a "dipolar-biasing" of La2/3Sr1/3MnO3 by CoFe2O4, we show that the TMR of even a single composite can be tuned continuously so that the resistance peak or the highest sensitivity of the TMR can be positioned anywhere on the magnetic field axis with a suitable magnetic history of the sample. This phenomenon of an unprecedented tunability of the TMR should be present in general in all such composites.
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| 13. |
- Kumar, P. Anil, et al.
(författare)
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Ferrimagnetism, antiferromagnetism, and magnetic frustration in La2-xSrxCuRuO6 (0 <= x <= 1)
- 2012
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Ingår i: Physical Review B. Condensed Matter and Materials Physics. - : APS. - 1098-0121 .- 1550-235X. ; 86:9, s. 094421-
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Tidskriftsartikel (refereegranskat)abstract
- We studied structural and magnetic properties of a series of insulating double perovskite compounds, La2-xSrxCuRuO6 (0 <= x <= 1), representing doping via A-site substitution. The end members La2CuRuO6 and LaSrCuRuO6 form in monoclinic structure while the intermediate Sr doped compounds stabilize in triclinic structure. The Cu and Ru ions sit on alternate B sites of the perovskite lattice with similar to 15% antisite defects in the undoped sample while the Sr-doped samples show a tendency to higher ordering at B sites. The undoped (x = 0) compound shows a ferrimagnetic-like behavior at low temperatures. In surprising contrast to the usual expectation of an enhancement of ferromagnetic interaction on doping, an antiferromagnetic-like ground state is realized for all doped samples (x > 0). Heat capacity measurements indicate the absence of any long-range magnetic order in any of these compounds. The magnetic relaxation and memory effects observed in all compounds suggest glassy dynamical properties associated with magnetic disorder and frustration. We show that the observed magnetic properties are dominated by the competition between the nearest-neighbor Ru-O-Cu 180 degrees superexchange interaction and the next-nearest-neighbor Ru-O-O-Ru 90 degrees superexchange interaction as well as by the formation of antisite defects with interchanged Cu and Ru positions. Our calculated exchange interaction parameters from first principles calculations for x = 0 and x = 1 support this interpretation.
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| 14. |
- Kumar Puri, Anil, et al.
(författare)
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Reentrant Superspin Glass Phase in a La0.82Ca0.18MnO3 Ferromagnetic Insulator
- 2014
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Ingår i: Physical Review X. - 2160-3308. ; 4:1, s. 011037-
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Tidskriftsartikel (refereegranskat)abstract
- We report results of the magnetization and ac susceptibility measurements down to very low fields on a single crystal of the perovskite manganite, La-0.82 Ca-0.18 MnO3. This composition falls in the intriguing ferromagnetic insulator region of the manganite phase diagram. In contrast to earlier beliefs, our investigations reveal that magnetically (and in every other sense), this is a single- phase system with a ferromagnetic ordering temperature of around 170 K. However, this ferromagnetic state is magnetically frustrated, and the system exhibits pronounced glassy dynamics below 90 K. Based on measured dynamical properties, we propose that this quasi-long-ranged ferromagnetic phase, and the associated superspin glass behavior, is the true magnetic state of the system, rather than being a macroscopic mixture of ferromagnetic and antiferromagnetic phases, as often suggested. Our results provide an understanding of the quantum phase transition from an antiferromagnetic insulator to a ferromagnetic metal via this ferromagnetic state as a function of x in La1-xCaxMnO3, in terms of the possible formation of magnetic polarons.
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| 15. |
- Lindblad, Rebecka, et al.
(författare)
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Electronic Structure of CH3NH3PbX3 Perovskites : Dependence on the Halide Moiety
- 2015
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Ingår i: The Journal of Physical Chemistry C. - American Chemical Society : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 119:4, s. 1818-1825
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Tidskriftsartikel (refereegranskat)abstract
- A combination of measurements using photoelectron spectroscopy and calculations using density functional theory (DFT) was applied to compare the detailed electronic structure of the organolead halide perovskites CH3NH3PbI3 and CH3NH3PbBr3. These perovskite materials are used to absorb light in mesoscopic and planar heterojunction solar cells. The Pb 4f core level is investigated to get insight into the chemistry of the two materials. Valence level measurments are also included showing a shift of the valence band edges where there is a higher binding energy of the edge for the CH3NH3PbBr3 perovskite. These changes are supported by the theoretical calculations which indicate that the differences in electronic structure are mainly caused by the nature of the halide ion rather than structural differences. The combination of photoelectron spectroscopy measurements and electronic structure calculations is essential to disentangle how the valence band edge in organolead halide perovskites is governed by the intrinsic difference in energy levels of the halide ions from the influence of chemical bonding.
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| 16. |
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| 17. |
- Mukherjee, S., et al.
(författare)
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Depth profiling and internal structure determination of low dimensional materials using X-ray photoelectron spectroscopy
- 2016
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Ingår i: Hard X-ray Photoelectron Spectroscopy (HAXPES). - Cham : Springer. - 9783319240435 - 9783319240411 ; , s. 309-339
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Bokkapitel (refereegranskat)abstract
- Properties of any heterostructured material depend critically on the specific composition profile of the constituent elements in the sample. X-ray photoelectron spectroscopy (XPS) is particularly well suited to probe elemental composition of any system. Tunable photon energies, available from any synchrotron centre, allow one to map out the compositional variation through a sample in a manner that can be termed non-invasive and non-destructive depth profiling. In addition, XPS is also able to provide depth resolved electronic structure information by directly mapping out occupied states at and near the Fermi energy. Recent developments at various synchrotron centers, providing access up to very high energy (~10 keV) photons with a good resolution and flux, have made it possible to estimate such compositional and electronic structure depth profiles with a greater accuracy for a wider range of materials. In this book chapter, we describe in detail the use of X-ray photoelectron spectroscopy in a selection of heterostructures, in order to illustrate the power of this technique.
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| 18. |
- Mukherjee, Sumanta, et al.
(författare)
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Determination of Internal Structures of Heterogeneous Nanocrystals Using Variable-Energy Photoemission Spectroscopy
- 2014
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Ingår i: The Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 118:28, s. 15534-15540
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Tidskriftsartikel (refereegranskat)abstract
- This article describes the determination of the internal structure of heterogeneous nanoparticle systems including inverted core-shell (CdS core and CdSe shell) and alloyed (CdSeS) quantum dots using depth-resolved, variable-energy X-ray photoelectron spectroscopy (XPS). A unique feature of this work is the combination of photoelectron spectroscopy performed at lower X-ray energies (400-700 eV), to achieve surface sensitivity, with bulk sensitive measurements at high photon energies (>2000 eV), thereby providing detailed information about the whole nanoparticle structure with a great accuracy. The use of high photon energies furthermore allows us to investigate nanoparticles much larger than those studied thus far. This capability is a consequence of the much-increased mean free path of the photoelectron achieved at high excitation energies. Our results show that the actual structures of the synthesized nanoparticles are considerably different from the nominal, targeted structures, which can be post facto rationalized in terms of the reactivity of different constituents.
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| 19. |
- Mukherjee, Soham, et al.
(författare)
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Microscopic description of the evolution of the local structure and an evaluation of the chemical pressure concept in a solid solution
- 2014
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Ingår i: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 89:22, s. 224105-
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Tidskriftsartikel (refereegranskat)abstract
- Extended x-ray absorption fine-structure studies have been performed at the Zn K and Cd K edges for a series of solid solutions of wurtzite Zn1-xCdxS samples with x = 0.0, 0.1, 0.25, 0.5, 0.75, and 1.0, where the lattice parameter as a function of x evolves according to the well-known Vegard's law. In conjunction with extensive, large-scale first-principles electronic structure calculations with full geometry optimizations, these results establish that the percentage variation in the nearest-neighbor bond distances are lower by nearly an order of magnitude compared to what would be expected on the basis of lattice parameter variation, seriously undermining the chemical pressure concept. With experimental results that allow us to probe up to the third coordination shell distances, we provide a direct description of how the local structure, apparently inconsistent with the global structure, evolves very rapidly with interatomic distances to become consistent with it. We show that the basic features of this structural evolution with the composition can be visualized with nearly invariant Zn-S-4 and Cd-S-4 tetrahedral units retaining their structural integrity, while the tilts between these tetrahedral building blocks change with composition to conform to the changing lattice parameters according to the Vegard's law within a relatively short length scale. These results underline the limits of applicability of the chemical pressure concept that has been a favored tool of experimentalists to control physical properties of a large variety of condensed matter systems.
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| 20. |
- Panda, Swarup K., et al.
(författare)
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A charge self-consistent LDA plus DMFT study of the spectral properties of hexagonal NiS
- 2014
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Ingår i: New Journal of Physics. - : IOP Publishing. - 1367-2630. ; 16, s. 093049-
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Tidskriftsartikel (refereegranskat)abstract
- The electronic structure and spectral properties of hexagonal NiS have been studied in the high temperature paramagnetic phase and low temperature anti-ferromagnetic phase. The calculations have been performed using charge self-consistent density-functional theory in local density approximation combined with dynamical mean-field theory (LDA+DMFT). The photoemission spectra (PES) and optical properties have been computed and compared with the experimental data. Our results show that the dynamical correlation effects are important to understand the spectral and optical properties of NiS. These effects have been analyzed in detail by means of the computed real and imaginary part of the self-energy.
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| 21. |
- Puri, Anil Kumar, et al.
(författare)
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Engineered spin-valve type magnetoresistance in Fe3O4-CoFe2O4 core-shell nanoparticles
- 2013
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 103:10, s. 102406-
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Tidskriftsartikel (refereegranskat)abstract
- Naturally occurring spin-valve-type magnetoresistance (SVMR), recently observed in Sr2FeMoO6 samples, suggests the possibility of decoupling the maximal resistance from the coercivity of the sample. Here we present the evidence that SVMR can be engineered in specifically designed and fabricated core-shell nanoparticle systems, realized here in terms of soft magnetic Fe3O4 as the core and hard magnetic insulator CoFe2O4 as the shell materials. We show that this provides a magnetically switchable tunnel barrier that controls the magnetoresistance of the system, instead of the magnetic properties of the magnetic grain material, Fe3O4, and thus establishing the feasibility of engineered SVMR structures.
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| 22. |
- Viswanatha, Ranjani, et al.
(författare)
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Magnetic Properties of Fe/Cu Codoped ZnO Nanocrystals
- 2012
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Ingår i: The Journal of Physical Chemistry Letters. - : American Chemical Society (ACS). - 1948-7185. ; 3:15, s. 2009-2014
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Tidskriftsartikel (refereegranskat)abstract
- Free-standing ZnO nanocrystals simultaneously doped with Fe and Cu with varying Fe/Cu compositions have been synthesized using colloidal methods with a mean size of similar to 7.7 nm. Interestingly, while the Cu-doped ZnO nanocrystal remains diamagnetic and Fe-doped samples show antiferromagnetic interactions between Fe sites without any magnetic ordering down to the lowest temperature investigated, samples doped simultaneously with Fe and Cu show a qualitative departure in exhibiting ferromagnetic interactions, with suggestions of ferromagnetic order at low temperature. XAS measurements establish the presence of Fe2+ and Fe3+ ions, with the concentration of the trivalent species increasing in the presence of Cu doping, providing direct evidence of the Fe2+ + Cu2+ sic Fe3+ + Cu+ redox couple being correlated with the ferromagnetic property. Using DFT, the unexpected ferromagnetic nature of these systems is explained in terms of a double exchange between Fe atoms, mediated by the Cu atom, in agreement with experimental observations.
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