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- Schantz Zackrisson, Anna, 1973, et al.
(författare)
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Concentration effects on irreversible colloid cluster aggregation and gelation of silica dispersions.
- 2006
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Ingår i: Journal of colloid and interface science. - : Elsevier BV. - 0021-9797 .- 1095-7103. ; 301:1, s. 137-44
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Tidskriftsartikel (refereegranskat)abstract
- Effects of particle concentration on the irreversible aggregation of colloidal silica are studied using in situ destabilization via the ionic strength increase derived from the enzymatic hydrolysis of urea by urease. Aggregation is monitored by time-resolved optical density and dynamic light scattering measurements. It terminates at a gel boundary, signaled by a prominent increase of the optical density and incipient non-ergodicity. Raman scattering is used to demonstrate that the enzymatic reaction continues, well beyond gelation for the compositions studied here, until the urea is consumed. Calibration of the ionic conductivity permits for constructing stability diagrams in terms of particle and salt concentration. As with reversible gelation, the process exhibits a collective character in that lower ionic strengths are required for gelation of concentrated dispersions and vice versa. However, light scattering demonstrates that the gel boundary is preceded here by a line marking the transition from reversible to irreversible cluster formation, with the two transition boundaries tracking each other. Comparisons are made with dispersions destabilized by direct addition of salt solutions, which gel under very different conditions.
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| 2. |
- Schantz Zackrisson, Anna, 1973, et al.
(författare)
-
A small-angle X-ray scattering study of aggregation and gelation of colloidal silica
- 2008
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Ingår i: Colloids and surfaces. A, Physicochemical and engineering aspects. - : Elsevier BV. - 0927-7757. ; 315:1-3, s. 23-30
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Tidskriftsartikel (refereegranskat)abstract
- Aggregation and gelation in colloidal silica dispersions have been studied by time-resolved, small-angle X-ray scattering. Two different ways of raising the ionic strength, leading to destabilization of the dispersions, have been examined. In situ destabilization by urease-catalyzed hydrolysis of urea has been used as well as an approach with simple mixing of sols with salt solutions. For concentrated dispersions different structures result from the two destabilization methods. Structures differ also in the gelled state, with essentially no fractal scattering from the directly mixed samples whereas fractal scattering on intermediate length scales is observed for the in situ destabilized samples. In contrast, for more dilute particle concentrations, similar structures are generated in both cases and at gelation structures are in close agreement. However, gel times differ drastically in some cases for the two methods, as do the conditions for gelation. These differences are tentatively rationalized by some degree of irreversible aggregation occurring in the mixing stage that, given sufficient time, leads to gelation.
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