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1.
  • Céolin, D., et al. (author)
  • Ultrafast Charge Transfer Processes Accompanying KLL Auger Decay in Aqueous KCl Solution
  • 2017
  • In: Physical Review Letters. - 0031-9007. ; 119:26
  • Journal article (peer-reviewed)abstract
    • X-ray photoelectron and KLL Auger spectra were measured for the K+ and Cl- ions in aqueous KCl solution. While the XPS spectra of these ions have similar structures, both exhibiting only weak satellites near the main line, the Auger spectra differ dramatically. Contrary to the chloride case, a very strong extra peak was found in the Auger spectrum of K+ at the low kinetic energy side of the D1 state. Using the equivalent core model and ab initio calculations this spectral feature was assigned to electron transfer processes from solvent water molecules to the solvated cation. The observed charge transfer processes are suggested to play an important role in charge redistribution following single and multiple core-hole creation in atoms and molecules placed into environment.
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2.
  • He, Z Q, et al. (author)
  • Band structure evolution in InAs overlayers on GaAs(110)
  • 1996
  • In: Applied Surface Science. - 0169-4332 .- 1873-5584. ; 104, s. 608-614
  • Journal article (peer-reviewed)abstract
    • An angle-resolved photoemission study of MBE grown InAs/GaAs(110) hetero-structures was carried out to investigate the establishment of valence bands as a function of overlayer thickness. The valence band spectra were found to change gradually up to thicknesses well above 10 nm. The data are interpreted in terms of excitations within the overlayer from a combination of substrate and overlayer initial states, the former tailing into the overlayer.
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