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1.
  • Anderson, Leif G, 1951, et al. (författare)
  • Export of calcium carbonate corrosive waters from the East Siberian Sea
  • 2017
  • Ingår i: Biogeosciences. - : Copernicus GmbH. - 1726-4170 .- 1726-4189. ; 14:7, s. 1811-1823
  • Tidskriftsartikel (refereegranskat)abstract
    • The Siberian shelf seas are areas of extensive biogeochemical transformation of organic matter, both of marine and terrestrial origin. This in combination with brine production from sea ice formation results in a cold bottom water of relative high salinity and partial pressure of carbon dioxide (pCO(2)). Data from the SWERUS-C3 expedition compiled on the icebreaker Oden in July to September 2014 show the distribution of such waters at the outer shelf, as well as their export into the deep central Arctic basins. Very high pCO(2) water, up to similar to 1000 mu atm, was observed associated with high nutrients and low oxygen concentrations. Consequently, this water had low saturation state with respect to calcium carbonate down to less than 0.8 for calcite and 0.5 for aragonite. Waters undersaturated in aragonite were also observed in the surface in waters at equilibrium with atmospheric CO2; however, at these conditions the cause of undersaturation was low salinity from river runoff and/or sea ice melt. The calcium carbonate corrosive water was observed all along the continental margin and well out into the deep Makarov and Canada basins at a depth from about 50 m depth in the west to about 150 m in the east. These waters of low aragonite saturation state are traced in historic data to the Canada Basin and in the waters flowing out of the Arctic Ocean north of Greenland and in the western Fram Strait, thus potentially impacting the marine life in the North Atlantic Ocean.
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2.
  • Andersson, Anastasia, et al. (författare)
  • Lack of trophic polymorphism despite substantial genetic differentiation in sympatric brown trout (Salmo trutta) populations
  • 2017
  • Ingår i: Ecology of Freshwater Fish. - : Wiley. - 0906-6691 .- 1600-0633. ; 26:4, s. 643-652
  • Tidskriftsartikel (refereegranskat)abstract
    • Sympatric populations occur in many freshwater fish species; such populations are typically detected through morphological distinctions that are often coupled to food niche and genetic separations. In salmonids, trophic and genetically separate sympatric populations have been reported in landlocked Arctic char, whitefish and brown trout. In Arctic char and brown trout rare cases of sympatric, genetically distinct populations have been detected based on genetic data alone, with no apparent morphological differences, that is cryptic structuring. It remains unknown whether such cryptic, sympatric structuring can be coupled to food niche separation. Here, we perform an extensive screening for trophic divergence of two genetically divergent, seemingly cryptic, sympatric brown trout populations documented to remain in stable sympatry over several decades in two interconnected, tiny mountain lakes in a nature reserve in central Sweden. We investigate body shape, body length, gill raker metrics, breeding status and diet (stomach content analysis and stable isotopes) in these populations. We find small significant differences for body shape, body size and breeding status, and no evidence of food niche separation between these two populations. In contrast, fish in the two lakes differed in body shape, diet, and nitrogen and carbon isotope signatures despite no genetic difference between lakes. These genetically divergent populations apparently coexist using the same food resources and showing the same adaptive plasticity to the local food niches of the two separate lakes. Such observations have not been reported previously but may be more common than recognised as genetic screenings are necessary to detect the structures.
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  • Bignert, Anders, et al. (författare)
  • Comments Concerning the National Swedish Contaminant Monitoring Programme in Marine Biota, 2015
  • 2015
  • Rapport (övrigt vetenskapligt/konstnärligt)abstract
    • The environmental toxicants examined in this report can be classified into five groups – heavy metals, chlorinated compounds, brominated flame retardants, polyaromatic hydrocarbons and perfluorinated compounds. Each of these contaminants have been examined from various sites for up to six different fish species, in blue mussels, and in guillemot eggs, for varying lengths of time. The following summary examines overall trends, spatial and temporal, for the five groups.Condition and Fat ContentCondition and fat content in different species tended to follow the same pattern at the same sites, with a few exceptions. Most of the fish species generally displayed a decreasing trend in both condition and fat content at most sites examined. Exceptions to this were increases in condition factor seen in cod liver at Fladen, perch muscle at Kvädöfjärden, and for herring at Ängskärsklubb in spring. Also, an increase in fat content was seen during the most recent ten years for herring at Ängskärsklubb in spring. There were also some sites where no log linear trends were seen.Heavy MetalsDue to a change in methods for metal analysis (not mercury) in 2004, values between 2003 and 2007 should be interpreted with care. From 2009 metals are analyzed at ACES, Stockholm University.Generally, higher mercury concentrations are found in the Bothnian Bay, but also from one station in the Northern parts of Baltic Proper, compared to other parts of the Swedish coastline. The time series show varying concentrations over the study period. The longer time series in guillemot egg and spring-caught herring from the southern Bothnian Sea and southern Baltic Proper show significant decreases of mercury. On the other hand, increasing concentrations are seen in e.g., cod muscle, but the concentrations are fairly low compared to measured concentrations in perch from fresh water and coastal sites. In most cases, the mercury concentrations are above the EQSbiota of 20 ng/g wet weight.Lead is generally decreasing over the study period (in time series of sufficient length), supposedly due to the elimination of lead in gasoline. The highest concentrations are seen in the southern part of the Baltic Sea. Elevated lead concentrations between 2003 and 2007 (e.g. Harufjärden) should be viewed with caution (see above regarding change in analysis methods). Lead concentrations are below the suggested target level at all stations.Cadmium concentrations show varying non-linear trends over the monitored period. It is worth noting that despite several measures taken to reduce discharges of cadmium, generally the most recent concentrations are similar to concentrations measured 30 yearsago in the longer time series. Cadmium concentrations in herring and perch are all below the suggested target level of 160 μg/kg wet weight.The reported nickel concentrations show no consistent decreasing trends. Some series begin with two elevated values that exert a strong leverage effect on the regression line and may give a false impression of decreasing trends. Chromium generally shows decreasing concentrations, possibly explained by a shift in analytical method. The essential trace metals, copper and zinc, show no consistent trends during the monitored period.Generally higher concentrations of arsenic and silver are found along the west coast compared to other parts of the Sweadish coast line. However for silver a few stations in the Bothnian Sea and Bothnian Bay show comparable concentrations to the west coast stations.Chlorinated CompoundsGenerally, a decreasing concentrations were observed for all compounds (DDT’s, PCB’s, HCH’s, HCB) in all species examined, with a few exceptions, such as no change in TCDD-equivalents being seen in herring muscle (except at Änskärsklubb where very high concentrations at the beginning of the sampling period were seen and also at the west coast station Fladen). The longer time-series in guillemot also show a marked decrease in TCDD-equivalents from the start in the late 1960s until about 1985 from where no change occurred for many years, however, during the most recent ten years a decrease in the concentration is seen. Concentrations of DDE and CB-118 are for some species and sites still above their respective target levels.The chlorinated compounds generally show higher concentrations in the Bothnian Sea and/or Baltic Proper when compared to the Bothnian Bay and the Swedish west coast.Brominated Flame RetardantsElevated levels of HBCDD are seen in sites from the Baltic Proper, while the investigated PBDEs show higher concentrations in the Bothnian Bay. In addition, lower concentrations of all investigated PBDEs and HBCDD are seen on the Swedish west coast compared to the east coast. Temporally, significant increases in BDE-47, -99 and -100 have been seen in guillemot eggs since the late 1960s until the early 1990s, where concentrations then began to show decreases. Also, the concentration of HBCDD in guillemot eggs shows a decrease during the most recent ten years. For fish and blue mussels, BDE-47, -99, and -153 decreased at some sites and showed no trend at other sites. The concentration of HBCDD in fish and blue mussels showed inconsistent trends. The concentration of HBCDD is below the EQSbiota of 167 μg/kg wet weight for all fish species from all areas, while the concentration of BDE-47 alone is above the EQSbiota for sumPBDE of 0.0085 ng/g wet weight.PAHsOnly blue mussels have been examined for spatial differences in PAH concentrations. Concentration of ΣPAH was found to be higher from Kvädöfjärden in the Baltic Proper compared to stations at the West coast, but individual PAHs showed varying spatial patterns. Over time, acenaphthalene was rarely found above the detection limit. Significant decreasing trends were observed for ΣPAH, chrysene, fluoranthene and pyrene at Fjällbacka; for naphthalene at Kvädöfjärden; and for pyrene at Fladen.All time series where concentrations of various PAHs were compared with the target value based on OSPAR Ecological Assessment Criteria, or EC Environmental Quality Standards were below the target value.PFASsPFHxS and PFOS show a similar spatial pattern, but PFOS concentrations were approximately 25 times higher than PFHxS levels. The distribution of PFOS is quite homogenous along the Swedish coast but with somewhat higher concentrations in the Baltic Proper. PFOS concentrations in guillemot eggs are about 100-200 times higher than in herring liver. An overall increasing concentration of PFOS in guillemot eggs has been observed throughout the whole time period, however, during the most recent ten years, a change of direction is detected. The longer herring time series from Harufjärden, Landsort, and Utlängan show increasing concentrations for PFOS and most carboxylates. For FOSA, on the other hand, decreasing concentrations are seen during the most recent ten years.Organotin compoundsThe majority of the analysed tinorganic compounds showed concentrations below LOQ. However TBT and DPhT showed concentrations above LOQ at all stations with highest reported concentrations in fish from Örefjärden in the northern part of Bothnian Sea.
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5.
  • Borg, Hans, et al. (författare)
  • Long-term trends of water chemistry in mountain streams in Sweden - slow recovery from acidification
  • 2014
  • Ingår i: Biogeosciences. - Göttingen : COPERNICUS GESELLSCHAFT MBH. - 1726-4170 .- 1726-4189. ; 11:1, s. 173-184
  • Tidskriftsartikel (refereegranskat)abstract
    • The water chemistry of streams and precipitation in the province of Jamtland, northern Sweden has been monitored since the 1980s to study long-term trends, occurrence of acid episodes, and effects of liming. The acidity in precipitation increased in the 1970s, followed by a loss of acid neutralizing capacity (ANC) and low pH in the streams. Sulfur deposition began to decrease in the 1980s, until approximately 2000, after which the decrease levelled out. Stream water sulfate concentration followed the precipitation trend but decreased more slowly and since the late 1990s a subtle increase was observed. Sulfate concentrations in the snow typically have been higher than or equal to the stream sulfate levels. However, during the period of rapid deposition decrease and also since 2005 stream sulfate has sometimes exceeded snow sulfate, indicating desorption of stored soil sulfate, possibly because of climate-related changes in runoff routes through the soil profiles, following shorter periods of frost. From 1982 to 2000, total organic carbon (TOC) increased by approximately 0.1 mg L-1 yr(-1). The mean trends in sulfate and TOC from approximately 1990 until today were generally opposite. Acidic episodes with pH 4.0 at flow peaks occurred frequently in the unlimed streams, despite relatively well-buffered waters at baseflow. To evaluate the main causes for the loss of ANC during episodes, the changes in major ion concentrations during high flow episodes were evaluated. The most important factors contributing to ANC loss were dilution of base cations (Na+, K+, Ca2+, Mg2+), enrichment of organic anions and enrichment of sulfate. Wetland liming started in 1985 after which the earlier observed extreme peak values of iron, manganese and aluminium, did not reoccur. The studied area is remote from emission sources in Europe, but the critical load of acidity is still exceeded. The long-term recovery observed in the unlimed streams is thus slow, and severe acidic episodes still occur.
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9.
  • Ek, Caroline, et al. (författare)
  • Evaluation of different stable isotope methods to estimate trophic position of perch (Perca fluviatilis) in Swedish lakes
  • 2019
  • Rapport (övrigt vetenskapligt/konstnärligt)abstract
    • The Water Framework Directive (WFD) requires member states to implement a strategy to meet the environmental quality standards (EQS) set by the WFD for a number of priority substances. Since the EQSs listed in the WFD are derived to protect the most sensitive species in the ecosystem, often top predators or humans, it has been decided that for certain priority substances the quality standards should be compared to a monitoring species with a trophic position (TP) similar to the diet of the most sensitive species. To enable such adjustment require both knowledge about the monitoring species TP in the food web as well as the relationship between contaminant concentration and trophic position. In this study, we focus on finding a suitable method for TP estimates of perch in Swedish lakes by evaluating both traditional stable isotope analysis in bulk samples (BSIA) using different baseline matrices and the more recent development of compound-specific stable isotope analysis in amino acids (CSIA-AA). For this, three representative monitoring lakes were selected in which perch together with potential baseline matrices (bivalves, gastropods and sediment) were sampled. We applied triple-isotope analyses, d15N, d13C and d34S, of bulk material of all sampled matrices, and in addition d15N in perch using CSIA-AA. Results showed that TP estimates derived from CSIA-AA were significantly (p<0.001) lower compared to all the BSIA-derived methods and further that the BSIA-derived TP estimates using gastropods as a baseline were significantly higher (p<0.001) than all other TP estimates. Since no statistical differences could be detected between TP estimates based on bivalves, sediment or a ‘mixture’ baseline these were assumed to produce similar results and therefore all valid baseline matrices for TP estimates of perch in these three lakes. In the present study we also attempted to adjust mercury contaminant data to a specific TP of 3.5 according to the WFD. The adjustment resulted in significantly different concentration for one of the two tested lakes but did not influence the chemical status classification as all lakes were well above the threshold for mercury in freshwater lakes.
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10.
  • Ek, caroline, et al. (författare)
  • Utvärdering av stabila isotoper som metod för att uppskatta trofinivå i abborre (Perca fluviatilis) från Svenska sjöar
  • 2022
  • Rapport (övrigt vetenskapligt/konstnärligt)abstract
    • The Water Framework Directive (WFD) requires member states to implement a strategy to meet the environmental quality standards (EQS) set by the WFD for a number of priority substances. Since the EQSs listed in the WFD are derived to protect the most sensitive species in the ecosystem, often top predators or humans, it has been decided that for certain priority substances the quality standards should be compared to a monitoring species with a trophic position (TP) similar to the diet of the most sensitive species. To enable such adjustment require both knowledge about the monitoring species TP in the food web as well as the relationship between contaminant concentration and trophic position. In this study, we focus on finding a suitable method for TP estimates of perch in Swedish lakes by evaluating both traditional stable isotope analysis in bulk samples (BSIA) using different baseline matrices and the more recent development of compound-specific stable isotope analysis in amino acids (CSIA-AA). For this, three representative monitoring lakes were selected in which perch together with potential baseline matrices (bivalves, gastropods and sediment) were sampled. We applied triple-isotope analyses, δ15N, δ13C and δ34S, of bulk material of all sampled matrices, and in addition δ15N in perch using CSIA-AA. Results showed that TP estimates derived from CSIA-AA were significantly (p<0.001) lower compared to all the BSIA-derived methods and further that the BSIA-derived TP estimates using gastropods as a baseline were significantly higher (p<0.001) than all other TP estimates. Since no statistical differences could be detected between TP estimates based on bivalves, sediment or a ‘mixture’ baseline these were assumed to produce similar results and therefore all valid baseline matrices for TP estimates of perch in these three lakes. In the present study we also attempted to adjust mercury contaminant data to a specific TP of 3.5 according to the WFD. The adjustment resulted in significantly different concentration for one of the two tested lakes but did not influence the chemical status classification as all lakes were well above the threshold for mercury in freshwater lakes.
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11.
  • Fredriksson Sundbom, Marcus, et al. (författare)
  • Respiratory and circulatory insufficiency during emergent long-distance critical care interhospital transports to tertiary care in a sparsely populated region : a retrospective analysis of late mortality risk
  • 2022
  • Ingår i: BMJ Open. - : BMJ Publishing Group Ltd. - 2044-6055. ; 12:2
  • Tidskriftsartikel (refereegranskat)abstract
    • Objectives: To test if impaired oxygenation or major haemodynamic instability at the time of emergency intensive care transport, from a smaller admitting hospital to a tertiary care centre, are predictors of long-term mortality.Design: Retrospective observational study. Impaired oxygenation was defined as oxyhaemoglobin %–inspired oxygen fraction ratio (S/F ratio)<100. Major haemodynamic instability was defined as a need for treatment with norepinephrine infusion to sustain mean arterial pressure (MAP) at or above 60 mm Hg or having a mean MAP <60. Logistic regression was used to assess mortality risk with impaired oxygenation or major haemodynamic instability.Setting: Sparsely populated Northern Sweden. A fixed-wing interhospital air ambulance system for critical care serving 900 000 inhabitants.Participants: Intensive care cases transported in fixed-wing air ambulance from outlying hospitals to a regional tertiary care centre during 2000–2016 for adults (16 years old or older). 2142 cases were included.Primary and secondary outcome measures: All-cause mortality at 3 months after transport was the primary outcome, and secondary outcomes were all-cause mortality at 1 and 7 days, 1, 6 and 12 months.Results: S/F ratio <100 was associated with increased mortality risk compared with S/F>300 at all time-points, with adjusted OR 6.3 (2.5 to 15.5, p<0.001) at 3 months. Major haemodynamic instability during intensive care unit (ICU) transport was associated with increased adjusted OR of all-cause mortality at 3 months with OR 2.5 (1.8 to 3.5, p<0.001).Conclusion: Major impairment of oxygenation and/or major haemodynamic instability at the time of ICU transport to get to urgent tertiary intervention is strongly associated with increased mortality risk at 3 months in this cohort. These findings support the conclusion that these conditions are markers for many fold increase in risk for death notable already at 3 months after transport for patients with these conditions.
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12.
  • Fredriksson Sundbom, Marcus, et al. (författare)
  • Total Mission Time and Mortality in a Regional Interhospital Critical Care Transport System : A Retrospective Observational Study
  • 2021
  • Ingår i: Air Medical Journal. - : Elsevier. - 1067-991X .- 1532-6497. ; 40:6, s. 404-409
  • Tidskriftsartikel (refereegranskat)abstract
    • Objective: We assessed the mortality risk related to the time for intensive care unit transport in a geographically large regional health care system.Methods: Patient-level data from critical care ambulance missions were analyzed for 2,067 cases, mission time, and relevant patient factors. Mission time was used as a surrogate for the “distance” to tertiary care, and mortality at 7 days and other intervals was assessed.Results: No increased mortality risk was found at 7 days in an unadjusted regression analysis (odds ratio = 1.00; range, 0.999-1.002; P = .66). In a secondary analysis, an increased mortality risk was observed in longer mission time subgroups and at later mortality assessment intervals (> 375 mission minutes and 90-day mortality; adjusted hazard ratio = 1.56; range, 1.07-2.28; P = .02). Negative changes in oxygenation and hemodynamic status and transport-related adverse events were associated with the longest flight times. Measurable but small changes during flight were noted for mean arterial pressure and oxygenation.Conclusion: The main finding was that there was no overall difference in mortality risk based on mission time. We conclude that transport distances or accessibility to critical care in the tertiary care center in a geographically large but sparsely populated region is not clearly associated with mortality risk.
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13.
  • Gantner, Nikolaus, et al. (författare)
  • MERCURY CONCENTRATIONS IN LANDLOCKED ARCTIC CHAR (SALVELINUS ALPINUS) FROM THE CANADIAN ARCTIC. PART I : INSIGHTS FROM TROPHIC RELATIONSHIPS IN 18 LAKES
  • 2010
  • Ingår i: Environmental Toxicology and Chemistry. - : Wiley. - 0730-7268 .- 1552-8618. ; 29:3, s. 621-632
  • Tidskriftsartikel (refereegranskat)abstract
    • Concentrations of mercury (Hg) have increased slowly in landlocked Arctic char over a 10- to 15-year period in the Arctic. Fluxes of Hg to sediments also show increases in most Arctic lakes. Correlation of Hg with trophic level (TL) was used to investigate and compare biomagnification of Hg in food webs from lakes in the Canadian Arctic sampled from 2002 to 2007. Concentrations of Hg (total Hg and methylmercury [MeHg]) in food webs were compared across longitudinal and latitudinal gradients in relation to delta C-13 and delta N-15 in periphyton, zooplankton, benthic invertebrates, and Arctic char of varying size-classes. Trophic magnification factors (TMFs) were calculated for the food web in each lake and related to available physical and chemical characteristics of the lakes. The relative content of MeHg increased with trophic level from 4.3 to 12.2% in periphyton, 41 to 79% in zooplankton, 59 to 72% in insects, and 74 to 100% in juvenile and adult char. The delta C-13 signatures of adult char indicated coupling with benthic invertebrates. Cannibalism among char lengthened the food chain. Biomagnification was confirmed in all 18 lakes, with TMFs ranging from 3.5 +/- 1.1 to 64.3 +/- 0.8. Results indicate that TMFs and food chain length (FCL) are key factors in explaining interlake variability in biomagnification of [Hg] among different lakes. Environ. Toxicol. Chem. 2010; 29: 621-632. (C) 2009 SETAC
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14.
  • Gouveia-Figueira, Sandra, et al. (författare)
  • Characterisation of (R)-2-(2-Fluorobiphenyl-4-yl)-N-(3-Methylpyridin-2-yl)Propanamide as a Dual Fatty Acid Amide Hydrolase : Cyclooxygenase Inhibitor
  • 2015
  • Ingår i: PLOS ONE. - : Public Library of Science (PLoS). - 1932-6203. ; 10:9
  • Tidskriftsartikel (refereegranskat)abstract
    • Background Increased endocannabinoid tonus by dual-action fatty acid amide hydrolase (FAAH) and substrate selective cyclooxygenase (COX-2) inhibitors is a promising approach for pain-relief. One such compound with this profile is 2-(2-fluorobiphenyl-4-yl)-N-(3-methylpyridin-2-yl)propanamide (Flu-AM1). These activities are shown by Flu-AM1 racemate, but it is not known whether its two single enantiomers behave differently, as is the case towards COX-2 for the parent flurbiprofen enantiomers. Further, the effects of the compound upon COX-2-derived lipids in intact cells are not known. Methodology/Principal Findings COX inhibition was determined using an oxygraphic method with arachidonic acid and 2-arachidonoylglycerol (2-AG) as substrates. FAAH was assayed in mouse brain homogenates using anandamide (AEA) as substrate. Lipidomic analysis was conducted in unstimulated and lipopolysaccharide + interferon gamma-stimulated RAW 264.7 macrophage cells. Both enantiomers inhibited COX-2 in a substrate-selective and time-dependent manner, with IC50 values in the absence of a preincubation phase of: (R)-Flu-AM1, COX-1 (arachidonic acid) 6 mu M; COX-2 (arachidonic acid) 20 mu M; COX-2 (2-AG) 1 mu M; (S)-Flu-AM1, COX-1 (arachidonic acid) 3 mu M; COX-2 (arachidonic acid) 10 mu M; COX-2 (2-AG) 0.7 mu M. The compounds showed no enantiomeric selectivity in their FAAH inhibitory properties. (R)-Flu-AM1 (10 mu M) greatly inhibited the production of prostaglandin D2 and E2 in both unstimulated and lipopolysaccharide + interferon.-stimulated RAW 264.7 macrophage cells. Levels of 2-AG were not affected either by (R)-Flu-AM1 or by 10 mu M flurbiprofen, either alone or in combination with the FAAH inhibitor URB597 (1 mu M). Conclusions/Significance Both enantiomers of Flu-AM1 are more potent inhibitors of 2-AG compared to arachidonic acid oxygenation by COX-2. Inhibition of COX in lipopolysaccharide + interferon.-stimulated RAW 264.7 cells is insufficient to affect 2-AG levels despite the large induction of COX-2 produced by this treatment.
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15.
  • Guimarães, Jean R.D., et al. (författare)
  • Simultaneous radioassays of bacterial production and mercury methylation in the periphyton of a tropical and a temperate wetland
  • 2006
  • Ingår i: Journal of Environmental Management. - : Elsevier BV. - 0301-4797 .- 1095-8630. ; 81:2, s. 95-100
  • Tidskriftsartikel (refereegranskat)abstract
    • Laboratory radioassays were made to study mercury (Hg) methylation together with bacterial production in the periphyton of two aquatic macrophytes, the submerged Myriophyllum spicatum, from a constructed wetland in Sweden and the floating Eichhornia crassipes, from a eutrophied tropical lake in Brazil. Time course incubations were made by addition of 203HgCl2 and the methylmercury formed was extracted at pre-defined time intervals. Bacterial production (14C-leucine incorporation) was measured at the same time intervals, with plants removed from parallel incubations made with and without addition of cold HgCl2. For E. crassipes, higher methylmercury production was observed at elevated bacterial production, whereas for M. spicatum, the bacterial production was significantly lower, and Hg methylation was below the detection limit. The combined results confirm the importance of microbial processes for Hg methylation, although other factors are known to influence this process in complex ways. The addition of Hg did not significantly influence bacterial production, while the incubation temperatures used (25 and 35 1C) resulted in different methylation rates. Radiotracer techniques for measurements of bacterial production such as 14C-leucine uptake can provide useful insights into the Hg cycle in aquatic environments, and our data suggest that they may be used as a proxy of mercury methylation potentials.
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16.
  • Gustafsson, Erik, et al. (författare)
  • Carbon cycling on the East Siberian Arctic Shelf – a change in air-sea CO2 flux induced by mineralization of terrestrial organic carbon
  • 2017
  • Ingår i: Biogeosciences. - : Copernicus GmbH. - 1726-4170 .- 1726-4189.
  • Tidskriftsartikel (refereegranskat)abstract
    • Measurements from the SWERUS-C3 and ISSS-08 Arctic expeditions were used to calibrate and validate a new physical-biogeochemical model developed to quantify key carbon cycling processes on the East Siberian Arctic Shelf (ESAS). The model was used in a series of experimental simulations with the specific aim to investigate the pathways of terrestrial dissolved and particulate organic carbon (DOCter and POCter) supplied to the shelf. Rivers supply on average 8.5 Tg C yr−1 dissolved inorganic carbon (DIC), and further 8.5 and 1.1 Tg C yr−1 DOCter and POCter respectively. Based on observed and simulated DOC concentrations and stable isotope values (δ13CDOC) in shelf waters, we estimate that only some 20 % of the riverine DOCter is labile. According to our model results, an additional supply of approximately 14 Tg C yr−1 eroded labile POCter is however required to describe the observed stable isotope values of DIC (δ13CDIC). Degradation of riverine DOCter and POCter results in a 1.8 Tg C yr−1 reduction in the uptake of atmospheric CO2, while degradation of eroded POCter results in an additional 10 Tg C yr−1 reduction. Our calculations indicate nevertheless that the ESAS is an overall small net sink for atmospheric CO2 (1.7 Tg C yr−1). The external carbon sources are largely compensated by a net export from the shelf to the Arctic Ocean (31 Tg C yr−1), and to a smaller degree by a permanent burial in the sediments (2.7 Tg C yr−1).
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17.
  • Hajdarevic, Senada, et al. (författare)
  • Coping styles in decision making among men and women diagnosed with malignant melanoma
  • 2013
  • Ingår i: Journal of Health Psychology. - : Sage Publications. - 1359-1053 .- 1461-7277. ; 18:11, s. 1445-1455
  • Tidskriftsartikel (refereegranskat)abstract
    • Early care seeking is important for prognosis of malignant melanoma. Coping styles in decision-making to seek care can relate to prognosis since avoidant strategies could delay care seeking. The aim of this study was to compare self-reported coping styles in decision-making between men and women diagnosed with malignant melanoma. We used the Swedish version of the Melbourne Decision-Making Questionnaire to assess coping styles. Men generally scored higher in buck-passing while women and those living without a partner scored higher in hypervigilance. This knowledge could be used in the development of preventive programmes with intention to reach those who delay care seeking.
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18.
  • Hajdarevic, Senada, et al. (författare)
  • Health care delay in malignant melanoma : various pathways to diagnosis and treatment
  • 2014
  • Ingår i: Dermatology Research and Practice. - : Hindawi Publishing Corporation. - 1687-6105 .- 1687-6113. ; , s. 294287-
  • Tidskriftsartikel (refereegranskat)abstract
    • We aimed to describe and compare patients diagnosed with malignant melanoma (MM), depending on their initial contact with care andwith regard to age, sex, andMMtype and thickness, and to explore pathways and time intervals (lead times) between clinics from the initial contact to diagnosis and treatment.The sample from northern Sweden was identified via the Swedish melanoma register. Data regarding pathways in health care were retrieved from patient records. In our unselected population of 71 people diagnosedwith skinmelanoma of SSMandNMtypes, 75%of patients were primarily treated by primary health-care centres (PHCs). The time interval (delay) from primary excision until registration of the histopathological assessment in the medical records was significantly longer in PHCs than in hospital-based and dermatological clinics (Derm). Thicker tumors were more common in the PHC group. Older patients waited longer times for wide excision. Most MM are excised rapidly at PHCs, but some patients may not be diagnosed and treated in time. Delay of registration of results from histopathological assessments within PHCs seems to be an important issue for future improvement. Exploring shortcomings inMMpatients’ clinical pathways is important to improve the quality of care and patient safety.
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19.
  • Hajdarevic, Senada, et al. (författare)
  • Malignant melanoma : gender patterns in care seeking for suspect marks
  • 2011
  • Ingår i: Journal of Clinical Nursing. - : Wiley-Blackwell. - 0962-1067 .- 1365-2702. ; 20:17-18, s. 2676-2684
  • Tidskriftsartikel (refereegranskat)abstract
    • Aims and objectives. Gender patterns in self-detection of melanoma are not sufficiently highlighted in the literature. The aim of the study was to identify specific patterns in the decision-making process to seek care for suspect melanoma, as narrated by women and men.Background. Females have a more favourable prognosis than males and also a higher level of perceived susceptibility and a higher level of knowledge about melanoma. Women are, furthermore, more prone to participate in screening.Method. Thirty patients (15 women and 15 men) with a mean age of 55.5 years and diagnosed with malignant melanoma were interviewed about their decisions to seek care for suspect skin marks. The interviews were transcribed and analysed with qualitative content analysis.Results. Care-seeking behaviour for suspect melanoma was influenced by gender constructions. Men seldom or never acknowledged interest in attention to bodily changes, but when they became aware of changes, they often took a quick decision and sought an expert's assessment. Men were compliant with wives' and relatives' advice about seeking care. All women reported that they paid attention to bodily changes, but they often delayed care seeking, due to family responsibilities and emotional struggles. The women also attempted self-care remedies, such as applying ointment, before seeking professional care.Conclusions. There are gender-specific patterns that may influence decision making in the care-seeking process. Such patterns are important to identify, since health care professionals must take these factors into account in communicating with men and women.Relevance to clinical practice. Nurses and in particular those working in telephone counselling, are often at the frontlines, deciding who can have access to health services. They are ideally placed to tackle the issue of gender constructions in the development of effective health care services.
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20.
  • Hajdarevic, Senada, et al. (författare)
  • Patients' decision making in seeking care for suspected malignant melanoma
  • 2010
  • Ingår i: Journal of Nursing and Healthcare of Chronic Illness. - : Wiley-Blackwell. - 1752-9816 .- 1752-9824. ; 2:2, s. 164-173
  • Tidskriftsartikel (refereegranskat)abstract
    • Aim. To explore patients' decision making about seeking care for malignant melanoma (MM).Background. Unlike other cancers, MM is generally visible and can be easily and cheaply cured if treated in time. It is the delay in diagnosis, most often attributable to the patient rather than to care providers, that results in mortality. Self-examination of suspicious lesions is important, but it is not a guarantee of immediate care-seeking, nor is early detection and increased melanoma awareness associated with early care-seeking.Method. During 2009, men (n = 10) and women (n = 11) diagnosed with malignant melanoma were interviewed within two years after excision and the text was analysed according to Grounded Theory.Results. The perception of a critical level of severity, feelings of fear and threat were found to be a key motivator for patients to seek care for suspected melanomas; as soon as sufficient insight into the severity of the disease was achieved, the patient reached a turning point and sought care immediately.Conclusions. Most of the participants described the process from the discovery of the lesion to the decision to seek care as a time-consuming inner negotiation about the severity of the disease, personal and social considerations, and interactions with the healthcare system.Relevance to clinical practice. We analysed the complex reasoning of the patients leading up to the turning point when they sought care. This study illustrates for caregivers the importance of simplifying the pathways to care, emphasising the seriousness of MM, and taking worried patients seriously from their first contact with health care. Health professionals, through their attitudes in contact with patients, can either facilitate or obstruct the patient's decision making process.
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  • Helander, Björn, 1946-, et al. (författare)
  • Major lead exposure from hunting ammunition in eagles from Sweden
  • 2021
  • Ingår i: Science of the Total Environment. - : Elsevier BV. - 0048-9697 .- 1879-1026. ; , s. 1-16
  • Tidskriftsartikel (refereegranskat)abstract
    • Exposure to lead (Pb) from ammunition in scavenging and raptorial birds has achieved worldwide recognition based on incidences of lethal poisoning, but exposure implies also sublethal levels with potential harmful effects.Background and elevated Pb levels in liver from 116 golden eagles (GE, Aquila chrysaetos) and 200 white-tailed sea eagles (WTSE, Haliaeetus albicilla) from Sweden 2003–2011 are here examined, with supporting data from a previous WTSE report and eagle owl (EO, Bubu bubo) report. GE and WTSE display seasonal patterns, with no Pb level exceeding a generally accepted threshold for subclinical effects during summer but strongly elevated levels from October. Fledged juveniles show significantly lower levels than all other age classes, but reach levels found in older birds in autumn after the start of hunting seasons. Pb levels in EO (non-scavenger) show no seasonal changes and indicate no influence from ammunition, and are close to levels observed in juvenile eagles before October. In all, 15% WTSE and 7% GE were lethally poisoned. In areas with high-exposure to hunting ammunition, 24% of WTSE showed lethal Pb levels, compared to 7% in both eagle species from low-exposure areas. Lethal poisoning of WTSE remained as frequent after (15%) as before (13%) a partial ban on use of Pb-based shotgun ammunition over shallow waters (2002). Pb levels increased significantly in WTSE 1981–2011,in contrast to other biota from the same period. A significant decrease of Pb in WTSE liver occurred below a threshold at 0.25 μg/g (dry weight), exceeded by 81% of the birds. Trend patterns in Pb isotope ratios lend further support to this estimated cut-off level for environmental background concentrations. Pb from spent ammunition affects a range of scavenging and predatory species. A shift to Pb-free ammunition to save wildlife from unnecessary harm is an important environmental and ethical issue.
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45.
  • Helander, Björn, et al. (författare)
  • Rapportering från undersökning av trofinivå hos havsörn - stabila isotoper och miljögifter : Överenskommelse Nr 2213-13-029
  • 2016
  • Rapport (övrigt vetenskapligt/konstnärligt)abstract
    • Höga koncentrationer av PCB och DDE har konstaterats i ägg från fem havsörnshonor vid Norrlands-kusten. Möjliga förklaringar kan vara regional förorening, eller att vissa örnar lever på en högre nivå i en näringskedja där koncentrationerna ökar i varje steg. Denna rapport redovisar resultat från analyser av PCB, DDE, HCB och stabila isotoper (SI) (δ15N, δ13C) i muskel från fiskar (fyra lokaler), skarvar (tre lokaler), ägg från skarv (tre lokaler) och havsörn (två lokaler) i Västernorrlands län, och SI i ägg och fjädrar från havsörn i olika biotoper vid Östersjökusten. PCB, DDE, HCB i fiskar visade inte påtagligt högre koncentrationer än vad som rapporterats från Norrlandskusten i övrigt, men hade högre värden för PCB och HCB än vid Kvädöfjärden, Holmöarna och Örefjärden, som används som referenslokaler längs Östersjökusten inom den nationella miljöövervakningen. Koncentrationerna i muskel från skarvungar jämfört med muskel från abborre på lipidbasis var ca 3-7 ggr högre för DDE och upp till två resp. tre ggr högre för HCB och PCB (CB-153). I skarvägg jämfört med abborre var förhöjningen av koncentrationer 30-400 ggr för DDE, 30-140 ggr för PCB och 7-30 ggr för HCB. Koncentrationer av DDE och PCB (CB-153) i de högbelastade havsörnsäggen från Västernorrland var 20 respektive 40 ggr högre än i skarväggen. Hos havsörn ses en tydlig trend för både ägg och fjädrar för δ13C, som blir tyngre ju mer marin fyndplatsen antagits vara, men ingen trend för δ15N. En stegvis ökning ses för δ15N i muskelprover från olika fiskar till skarvungar och skarvägg, dock inte vidare till havsörnsägg, men däremot till havsörnsfjädrar. Avsaknaden av skillnad i δ15N mellan skarv- och havsörnsägg indikerar att de inte är jämförbara med avseende på trofiska nivåer. Statistiskt signifikanta men relativt svaga samband ses mellan koncentrationer av DDE och PCB och δ15N i hela materialet av havsörnsägg. Havsörn är på högre trofisk nivå än skarv men δ15N i örnäggen som läggs redan i mars avspeglar troligen ett inslag av däggdjurskadaver under vintern, medan fjädrarna avspeglar sommarfödan (mest fisk och fågel). Möjligheten kvarstår att högre miljögiftshalter i äggen hos vissa havsörnar kan bero på högre trofisk nivå men detta bör undersökas på fjädrar.
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46.
  • Helander, Björn, et al. (författare)
  • Rapportering från undersökning av trofinivå hos havsörn - stabila isotoper och miljögifter
  • 2015
  • Rapport (övrigt vetenskapligt/konstnärligt)abstract
    • Höga koncentrationer av PCB och DDE har konstaterats i ägg från fem havsörnshonor vid Norrlands-kusten. Möjliga förklaringar kan vara regional förorening, eller att vissa örnar lever på en högre nivå i en näringskedja där koncentrationerna ökar i varje steg. Denna rapport redovisar resultat från analyser av PCB, DDE, HCB och stabila isotoper (SI) (δ15N, δ13C) i muskel från fiskar (fyra lokaler), skarvar (tre lokaler), ägg från skarv (tre lokaler) och havsörn (två lokaler) i Västernorrlands län, och SI i ägg och fjädrar från havsörn i olika biotoper vid Östersjökusten. PCB, DDE, HCB i fiskar visade inte påtagligt högre koncentrationer än vad som rapporterats från Norrlandskusten i övrigt, men hade högre värden för PCB och HCB än vid Kvädöfjärden, Holmöarna och Örefjärden, som används som referenslokaler längs Östersjökusten inom den nationella miljöövervakningen. Koncentrationerna i muskel från skarvungar jämfört med muskel från abborre på lipidbasis var ca 3-7 ggr högre för DDE och upp till två resp. tre ggr högre för HCB och PCB (CB-153). I skarvägg jämfört med abborre var förhöjningen av koncentrationer 30-400 ggr för DDE, 30-140 ggr för PCB och 7-30 ggr för HCB. Koncentrationer av DDE och PCB (CB-153) i de högbelastade havsörnsäggen från Västernorrland var 20 respektive 40 ggr högre än i skarväggen. Hos havsön ses en tydlig trend fö båe äg och fjärar fö δ13C, som blir tyngre ju mer marin fyndplatsen antagits vara, men ingen trend fö δ15N. En stegvis öning ses fö δ15N i muskelprover från olika fiskar till skarvungar och skarvägg, dock inte vidare till havsörnsägg, men däremot till havsörnsfjädrar. Avsaknaden av skillnad i δ15N mellan skarv- och havsörnsägg indikerar att de inte är jämförbara med avseende på trofiska nivåer. Statistiskt signifikanta men relativt svaga samband ses mellan koncentrationer av DDE och PCB och δ15N i hela materialet av havsönsäg. Havsön ä påhöre trofisk nivåä skarv men δ15N i örnäggen som läggs redan i mars avspeglar troligen ett inslag av däggdjurskadaver under vintern, medan fjädrarna avspeglar sommarfödan (mest fisk och fågel). Möjligheten kvarstår att högre miljögiftshalter i äggen hos vissa havsörnar kan bero på högre trofisk nivå men detta bör undersökas på fjädrar.
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47.
  • Helander, Björn, 1946-, et al. (författare)
  • Temporal Changes in Concentrations of Lead and Other Trace Metalsin Free‑Ranging Eurasian Eagle Owls Bubo bubo in Sweden
  • 2019
  • Ingår i: Archives of Environmental Contamination and Toxicology. - : Springer. - 0090-4341 .- 1432-0703. ; 77:3, s. 377-389
  • Tidskriftsartikel (refereegranskat)abstract
    • Patterns of lead and other trace metals were examined in 122 Eurasian eagle owls Bubo bubo found dead in Sweden in the period 1978–2013. Environmental lead (Pb) has decreased over recent decades from reduced anthropogenic emissions but mortality by Pb poisoning is still frequently reported for avian raptors and scavengers exposed to Pb ammunition. One objective here was to determine if Pb concentrations in a nocturnal non-scavenging raptor follow the general decline observed in other biota. Pb concentration in owl liver was significantly correlated with body weight, sex, latitude, longitude and season. Pb showed a significant decreasing trend towards north and west. Starved birds had significantly higher concentrations. Total Pb concentrations in liver averaged 0.179 μg g−1 dry weight (median 0.103) and decreased by 5.6% per year 1978–2013, or 5.3% after adjustment for confounding factors, similar to trends in other species. Among 14 other trace elements only antimony and arsenic showed decreasing trends. Lead isotope ratios 206Pb/207Pb and 208Pb/207Pb increased from 1.138 and 2.408 in 1978–1985 to 1.170 and 2.435 in 2010–2013, respectively, demonstrating that the decreasing Pb concentration in eagle owl is related to the phase-out of leaded gasoline in Europe, where Pb additives had much lower isotope ratios than natural lead in Swedish soils. Only one incidence of suspected Pb poisoning (40.7 μg g−1 in liver) was observed indicating that poisoning from ingestion of metallic lead is rare (< 1%) in eagle owl in Sweden, in contrast to what has been reported for eagles.
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48.
  • Hoppe, Sabina, et al. (författare)
  • Predictions of Cu toxicity in three aquatic species using bioavailability tools in four Swedish soft freshwaters
  • 2015
  • Ingår i: Environmental Sciences Europe. - : Springer Science and Business Media LLC. - 2190-4707 .- 2190-4715. ; 27:25
  • Tidskriftsartikel (refereegranskat)abstract
    • BackgroundThe EU member countries are currently implementing the Water Framework Directive to promote better water quality and overview of their waters. The directive recommends the usage of bioavailability tools, such as biotic ligand models (BLM), for setting environmental quality standards (EQS) for metals. These models are mainly calibrated towards a water chemistry found in the south central parts of Europe. However, freshwater chemistry in Scandinavia often has higher levels of DOC (dissolved organic carbon), Fe and Al combined with low pH compared to the central parts of Europe. In this study, copper (Cu) toxicities derived by two different BLM software were compared to bioassay-derived toxicity for Pseudokirchneriella subcapitata, Daphnia magna and D. pulex in four Swedish soft water lakes.ResultsA significant under- and over prediction between measured and BLM calculated toxicity was found; for P. subcapitata in three of the four lakes and for the daphnids in two of the four lakes. The bioassay toxicity showed the strongest relationship with Fe concentrations and DOC. Furthermore, DOC was the best predictor of BLM results, manifested as positive relationships with calculated LC50 and NOEC for P. subcapitata and D. magna, respectively.ConclusionResults from this study indicate that the two investigated BLM softwares have difficulties calculating Cu toxicity, foremost concerning the algae. The analyses made suggest that there are different chemical properties affecting the calculated toxicity as compared to the measured toxicity. We recommend that tests including Al, Fe and DOC properties as BLM input parameters should be conducted. This to observe if a better consensus between calculated and measured toxicity can be established.
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49.
  • Humborg, Cristoph, et al. (författare)
  • CO2 supersaturation along the aquatic conduit in Swedish watersheds as constrained by terrestrial respiration, aquatic respiration and weathering
  • 2010
  • Ingår i: Global Change Biology. - : Wiley. - 1354-1013 .- 1365-2486. ; 6:7, s. 1966-1978
  • Tidskriftsartikel (refereegranskat)abstract
    • We tested the hypothesis that CO2 supersaturation along the aquatic conduit over Sweden can be explained by processes other than aquatic respiration. A first generalized-additive model (GAM) analysis evaluating the relationships between single water chemistry variables and pCO(2) in lakes and streams revealed that water chemistry variables typical for groundwater input, e.g., dissolved silicate (DSi) and Mg2+ had explanatory power similar to total organic carbon (TOC). Further GAM analyses on various lake size classes and stream orders corroborated the slightly higher explanatory power for DSi in lakes and Mg2+ for streams compared with TOC. Both DSi and TOC explained 22-46% of the pCO(2) variability in various lake classes (0.01-> 100 km2) and Mg2+ and TOC explained 11-41% of the pCO(2) variability in the various stream orders. This suggests that aquatic pCO(2) has a strong groundwater signature. Terrestrial respiration is a significant source of the observed supersaturation and we may assume that both terrestrial respiration and aquatic respiration contributed equally to pCO(2) efflux. pCO(2) and TOC concentrations decreased with lake size suggesting that the longer water residence time allow greater equilibration of CO2 with the atmosphere and in-lake mineralization of TOC. For streams, we observed a decreasing trend in pCO(2) with stream orders between 3 and 6. We calculated the total CO2 efflux from all Swedish lakes and streams to be 2.58 Tg C yr-1. Our analyses also demonstrated that 0.70 Tg C yr-1 are exported to the ocean by Swedish watersheds as HCO3- and CO(3)2- of which about 0.56 Tg C yr-1 is also a residual from terrestrial respiration and constitute a long-term sink for atmospheric CO2. Taking all dissolved inorganic carbon (DIC) fluxes along the aquatic conduit into account will lower the estimated net ecosystem C exchange (NEE) by 2.02 Tg C yr-1, which corresponds to 10% of the NEE in Sweden.
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50.
  • Humborg, Christoph, et al. (författare)
  • Riverine transport of biogenic elements to the Baltic Sea – past and possible future perspectives
  • 2007
  • Ingår i: Hydrology and Earth System Sciences. - 1027-5606 .- 1607-7938. ; 11:5, s. 1593-1607
  • Tidskriftsartikel (refereegranskat)abstract
    • The paper reviews critical processes for the land-sea fluxes of biogenic elements (C, N, P, Si) in the Baltic Sea catchment and discusses possible future scenarios as a consequence of improved sewage treatment, agricultural practices and increased hydropower demand (for N, P and Si) and of global warming, i.e., changes in hydrological patterns (for C). These most significant drivers will not only change the total amount of nutrient inputs and fluxes of organic and inorganic forms of carbon to the Baltic Sea, their ratio (C:N:P:Si) will alter as well with consequences for phytoplankton species composition in the Baltic Sea. In summary, we propose that N fluxes may increase due to higher livestock densities in those countries recently acceded to the EU, whereas P and Si fluxes may decrease due to an improved sewage treatment in these new EU member states and with further damming and still eutrophic states of many lakes in the entire Baltic Sea catchment. This might eventually decrease cyanobacteria blooms in the Baltic but increase the potential for other nuisance blooms. Dinoflagellates could eventually substitute diatoms that even today grow below their optimal growth conditions due to low Si concentrations in some regions of the Baltic Sea. C fluxes will probably increase from the boreal part of the Baltic Sea catchment due to the expected higher temperatures and heavier rainfall. However, it is not clear whether dissolved organic carbon and alkalinity, which have opposite feedbacks to global warming, will increase in similar amounts, because the spring flow peak will be smoothed out in time due to higher temperatures that cause less snow cover and deeper soil infiltration.
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