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- Revelli, A., et al.
(author)
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Spin-orbit entangled j=1/2 moments in Ba(2)CWeIrO(6) : A frustrated fcc quantum magnet
- 2019
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In: Physical Review B. - : American Physical Society. - 2469-9950 .- 2469-9969. ; 100:8
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Journal article (peer-reviewed)abstract
- We establish the double perovskite Ba2CeIrO6 as a nearly ideal model system for j = 1/2 moments, with resonant inelastic x-ray scattering indicating that the ideal j = 1/2 state contributes by more than 99% to the ground-state wave function. The local j = 1/2 moments form an fcc lattice and are found to order antiferromagnetically at T-N = 14 K, more than an order of magnitude below the Curie-Weiss temperature. Model calculations show that the geometric frustration of the fcc Heisenberg antiferromagnet is further enhanced by a next-nearest neighbor exchange, and a significant size of the latter is indicated by ab initio theory. Our theoretical analysis shows that magnetic order is driven by a bond-directional Kitaev exchange and by local distortions via a strong magnetoelastic effect. Both, the suppression of frustration by Kitaev exchange and the strong magnetoelastic effect are typically not expected for j = 1/2 compounds making Ba2CeIrO6 a riveting example for the rich physics of spin-orbit entangled Mott insulators.
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| 5. |
- Revelli, A., et al.
(author)
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Spin-orbit entangled j=1/2 moments in Ba2CeIrO6 : A frustrated fcc quantum magnet
- 2019
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In: Physical Review B. - 2469-9950 .- 2469-9969. ; 100:8
-
Journal article (peer-reviewed)abstract
- We establish the double perovskite Ba2CeIrO6 as a nearly ideal model system for j = 1/2 moments, with resonant inelastic x-ray scattering indicating that the ideal j = 1/2 state contributes by more than 99% to the ground-state wave function. The local j = 1/2 moments form an fcc lattice and are found to order antiferromagnetically at T-N = 14 K, more than an order of magnitude below the Curie-Weiss temperature. Model calculations show that the geometric frustration of the fcc Heisenberg antiferromagnet is further enhanced by a next-nearest neighbor exchange, and a significant size of the latter is indicated by ab initio theory. Our theoretical analysis shows that magnetic order is driven by a bond-directional Kitaev exchange and by local distortions via a strong magnetoelastic effect. Both, the suppression of frustration by Kitaev exchange and the strong magnetoelastic effect are typically not expected for j = 1/2 compounds making Ba2CeIrO6 a riveting example for the rich physics of spin-orbit entangled Mott insulators.
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- Eschmann, T., et al.
(author)
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Thermodynamics of a gauge-frustrated Kitaev spin liquid
- 2019
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In: Physical Review Research. - : American Physical Society (APS). - 2643-1564. ; 1:3
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Journal article (peer-reviewed)abstract
- Two- and three-dimensional Kitaev magnets are prototypical frustrated quantum spin systems, in which the original spin degrees of freedom fractionalize into Majorana fermions and a Z2 gauge field—a purely local phenomenon that reveals itself as a thermodynamic crossover at a temperature scale set by the strength of the bond-directional interactions. For conventional Kitaev magnets, the low-temperature thermodynamics reveals a second transition at which the Z2 gauge field orders and the system enters a spin-liquid ground state. Here, we discuss an explicit example that goes beyond this paradigmatic scenario—the Z2 gauge field is found to be subject to geometric frustration, the thermal ordering transition is suppressed, and an extensive residual entropy arises. Deep in the quantum regime, at temperatures of the order of one per mil of the interaction strength, the degeneracy in the gauge sector is lifted by a subtle interplay between the gauge field and the Majorana fermions, resulting in the formation of a Majorana metal. We discuss the thermodynamic signatures of this physics obtained from large-scale, sign-free quantum Monte Carlo simulations.
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| 7. |
- Eschmann, T., et al.
(author)
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Thermodynamics of a gauge-frustrated Kitaev spin liquid
- 2019
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In: Physical Review Research. - : American Physical Society (APS). - 2643-1564. ; 1:3
-
Journal article (peer-reviewed)abstract
- Two- and three-dimensional Kitaev magnets are prototypical frustrated quantum spin systems, in which the original spin degrees of freedom fractionalize into Majorana fermions and a Z2 gauge field - a purely local phenomenon that reveals itself as a thermodynamic crossover at a temperature scale set by the strength of the bond-directional interactions. For conventional Kitaev magnets, the low-temperature thermodynamics reveals a second transition at which the Z2 gauge field orders and the system enters a spin-liquid ground state. Here, we discuss an explicit example that goes beyond this paradigmatic scenario - the Z2 gauge field is found to be subject to geometric frustration, the thermal ordering transition is suppressed, and an extensive residual entropy arises. Deep in the quantum regime, at temperatures of the order of one per mil of the interaction strength, the degeneracy in the gauge sector is lifted by a subtle interplay between the gauge field and the Majorana fermions, resulting in the formation of a Majorana metal. We discuss the thermodynamic signatures of this physics obtained from large-scale, sign-free quantum Monte Carlo simulations.
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- Gils, C., et al.
(author)
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Anyonic quantum spin chains : Spin-1 generalizations and topological stability
- 2013
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In: Physical Review B. Condensed Matter and Materials Physics. - : American Physical Society. - 1098-0121 .- 1550-235X. ; 87:23, s. 235120-
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Journal article (peer-reviewed)abstract
- There are many interesting parallels between systems of interacting non-Abelian anyons and quantum magnetism occurring in ordinary SU(2) quantum magnets. Here we consider theories of so-called SU(2)(k) anyons, well-known deformations of SU(2), in which only the first k + 1 angular momenta of SU(2) occur. In this paper, we discuss in particular anyonic generalizations of ordinary SU(2) spin chains with an emphasis on anyonic spin S = 1 chains. We find that the overall phase diagrams for these anyonic spin-1 chains closely mirror the phase diagram of the ordinary bilinear-biquadratic spin-1 chain including anyonic generalizations of the Haldane phase, the AKLT construction, and supersymmetric quantum critical points. A novel feature of the anyonic spin-1 chains is an additional topological symmetry that protects the gapless phases. Distinctions further arise in the form of an even/odd effect in the deformation parameter k when considering su(2)(k) anyonic theories with k >= 5, as well as for the special case of the su(2)(4) theory for which the spin-1 representation plays a special role. We also address anyonic generalizations of spin-1/2 chains with a focus on the topological protection provided for their gapless ground states. Finally, we put our results into the context of earlier generalizations of SU(2) quantum spin chains, in particular so-called (fused) Temperley-Lieb chains.
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- Svensson, Jenny, et al.
(author)
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Tumor selectivity at short times following systemic administration of a liposomal temoporfin formulation in a murine tumor model
- 2007
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In: Photochemistry and Photobiology. - 0031-8655. ; 83:5, s. 1211-1219
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Journal article (peer-reviewed)abstract
- Meso-tetra(hydroxyphenyl)chlorin (mTHPC) (INN: Temoporfin) is one of the most potent photodynamically active substances in clinical use. Treatment protocols for Temoporfin-mediated photodynamic therapy often rely on drug-light intervals of several days in order for the photosensitizer to accumulate within the target tissue, though tumor selectivity is limited. Here, the mTHPC localization was studied at 2-8 h following systemic administration of a liposomal Temoporfin formulation (0.15 mg kg(-1) b.w.) in HT29 human colon adermcarcinoma in NMRI nu/nu mice. Photosensitizer distribution within tumor and internal organs was investigated by means of high performance liquid chromatography following chemical extraction, as well as in situ fluorescence imaging and point-monitoring fluorescence spectroscopy. For tumor tissue, the Temoporfin concentrations at 4 h (0.16 +/- 0.024 ng mg(-1)) and 8 h (0.18 +/- 0.064 ng mg(-1)) were significantly higher than at 2 It (0.08 +/- 0.026 ng mg(-1)). The average tumor-to-muscle and the tumor-to-skin selectivity were 6.6 and 2, respectively, and did not vary significantly with time after photosensitizer injection. In plasma, the Temoporfin concentration was low (0.07 +/- 0.07 ng mg(-1)) and showed no significant variation with time. Our results indicate a rapid biodistribution and clearance from the bloodstream. Within the same type of organ, data from both fluorescence methods generally exhibited a significant correlation with the extraction results.
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| 10. |
- Wawrzik, D., et al.
(author)
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Topological semimetals and insulators in three-dimensional honeycomb materials
- 2018
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In: Physical Review B. - 2469-9950. ; 98:11
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Journal article (peer-reviewed)abstract
- Semimetals, in which conduction and valence bands touch but do not form Fermi surfaces, have attracted considerable interest for their anomalous properties starting with the discovery of Dirac matter in graphene and other two-dimensional honeycomb materials. Here we introduce a family of three-dimensional honeycomb systems whose electronic band structures exhibit a variety of topological semimetals with Dirac nodal lines. We show that these nodal lines appear in varying numbers and mutual geometries, depending on the underlying lattice structure. They are stabilized, in most cases, by a combination of time-reversal and inversion symmetries and are accompanied by topologically protected "drumhead" surface states. In the bulk, these nodal line systems exhibit Landau level quantization and flat bands upon applying a magnetic field. In the presence of spin-orbit coupling, these topological semimetals are found to generically form (strong) topological insulators. This comprehensive classification of the electronic band structures of three-dimensional honeycomb systems might serve as guidance for future material synthesis.
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