1. |
- Velkov, Zhivko A., et al.
(författare)
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Melatonin : Quantum-chemical and biochemical investigation of antioxidant activity
- 2009
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Ingår i: European Journal of Medicinal Chemistry. - : Elsevier. - 0223-5234 .- 1768-3254. ; 44:7, s. 2834-2839
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Tidskriftsartikel (refereegranskat)abstract
- Experimental and theoretical investigation of the antioxidant activity of melatonin is carried out. The theoretical approach comprises the evaluation of several appropriate descriptors of scavenging activity with the help of quantum-chemistry methods. The values obtained are compared with available data for substances with established antioxidant properties. One of the most widely used markers for in vivo free radical oxidation processes is malondialdehyde (MDA) as an end product of membrane lipid peroxidation. Experimental support of the computed scavenging parameters is provided by estimation of the effect of supplementary melatonin therapy on the plasma levels of MDA in CRF patients on maintenance HD therapy. Different reaction paths have been considered and related to the obtained data, allowing speculations about the reaction mechanism and the antioxidant potential of melatonin for practical purposes.
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2. |
- Feifel, R., et al.
(författare)
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X-ray absorption and resonant Auger spectroscopy of O(2) in the vicinity of the O 1s ->sigma* resonance : Experiment and theory
- 2008
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Ingår i: Journal of Chemical Physics. - : American Institute of Physics (AIP). - 0021-9606 .- 1089-7690. ; 128:6
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Tidskriftsartikel (refereegranskat)abstract
- We report on an experimental and theoretical investigation of x-ray absorption and resonant Auger electron spectra of gas phase O(2) recorded in the vicinity of the O 1s ->sigma* excitation region. Our investigation shows that core excitation takes place in a region with multiple crossings of potential energy curves of the excited states. We find a complete breakdown of the diabatic picture for this part of the x-ray absorption spectrum, which allows us to assign an hitherto unexplained fine structure in this spectral region. The experimental Auger data reveal an extended vibrational progression, for the outermost singly ionized X (2)Pi(g) final state, which exhibits strong changes in spectral shape within a short range of photon energy detuning (0 eV>Omega>-0.7 eV). To explain the experimental resonant Auger electron spectra, we use a mixed adiabatic/diabatic picture selecting crossing points according to the strength of the electronic coupling. Reasonable agreement is found between experiment and theory even though the nonadiabatic couplings are neglected. The resonant Auger electron scattering, which is essentially due to decay from dissociative core-excited states, is accompanied by strong lifetime-vibrational and intermediate electronic state interferences as well as an interference with the direct photoionization channel. The overall agreement between the experimental Auger spectra and the calculated spectra supports the mixed diabatic/adiabatic picture.
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3. |
- Hikosaka, Y., et al.
(författare)
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X-ray absorption measured in the resonant Auger scattering mode
- 2008
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Ingår i: Physical Review Letters. - 0031-9007 .- 1079-7114. ; 101:7
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Tidskriftsartikel (refereegranskat)abstract
- We report both experimental and theoretical studies on x-ray absorption measured in the resonant Auger scattering mode of gas phase carbon monoxide near the O1s -> 2 pi region. Both experiment and theory display a crucial difference between the x-ray absorption profiles obtained in the conventional and resonant scattering modes. Lifetime vibrational interference is the main source of the difference. It is demonstrated that such interference, which arises from a coherent excitation to overlapping intermediate levels, ruins the idea for obtaining x-ray absorption spectra in a lifetime broadening free regime.
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4. |
- Liu, Ji-Cai, et al.
(författare)
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Resonant inelastic X-ray Raman scattering induced by Rabi flopping of core holes
- 2008
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Ingår i: Chemical Physics Letters. - : Elsevier BV. - 0009-2614 .- 1873-4448. ; 453:1-3, s. 117-121
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Tidskriftsartikel (refereegranskat)abstract
- A new scheme of X-ray pump-probe experiment is suggested in this Letter, namely resonant inelastic X-ray scattering accompanied by core-hole hopping induced by a strong laser field. In particular, we study the dynamics of X-ray Raman scattering of N-2 molecules in a strong IR field. The laser-induced mixing of the core holes of opposite parities opens symmetry forbidden scattering channels. The strength of the symmetry forbidden channels strongly depends on the interrelationship between the time of Rabi flopping of the core holes and the scattering duration or the duration of the X-ray pulse.
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5. |
- Liu, Ji-Cai, et al.
(författare)
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Symmetry-forbidden x-ray Raman scattering induced by a strong infrared-laser field
- 2008
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - 1050-2947 .- 1094-1622. ; 77:4, s. 043405-
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Tidskriftsartikel (refereegranskat)abstract
- Resonant inelastic x-ray scattering accompanied by core-hole hopping induced by a strong infrared-laser field is studied for the nitrogen molecule. This process involves a strong laser-field-induced promotion of ungerade core holes created by a weak x-ray pulse to a gerade core level, which opens symmetry-forbidden scattering channels and gives rise to new features in the x-ray scattering spectrum. The core-hole hopping within the short lifetime of the core-excited state required for observation of the described process can be achieved at moderate intensities of the infrared field (similar to 10(12) W/cm(2)) because of the large transition dipole moment between the relevant core levels. The dynamics of resonant inelastic x-ray scattering assisted by change of core-hole parity is studied in detail versus the intensity, detuning, phase, and duration of the incident infrared-laser and x-ray pulses.
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6. |
- Samoc, Marek, et al.
(författare)
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Cubic Nonlinear Optical Properties of Platinum-Terminated Polyynediyl Chains
- 2008
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Ingår i: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X. ; 47:21, s. 9946-9957
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Tidskriftsartikel (refereegranskat)abstract
- The wavelength dependence of the cubic nonlinearity of ligated platinum-terminated polyynes trans, trans-{(P-MeC6H4)(3)P}(2)(p-MeC6H4)Pt(C C)(n)Pt(p-C6H4Me){P(p-C6H4Me)(3)}(2) (n = 3-6, 8, 10, 12) has been examined by femtosecond Z-scan studies in the wavelength range 520-1500 nm and the results rationalized by density functional theory calculations on the model complexes trans, trans-(H3P)(2)(C6H5)Pt(C C)(n)Pt(C6H5)(PH3)(2) (n = 2-8, 10, 12). Although the final states for one- and two-photon transitions are not the same in these centrosymmetric molecules, the Z-scan studies reveal coincidences in one-photon absorption with features in the frequency dependencies of both real and imaginary parts of the cubic hyperpolarizability, as well as inflections in the frequency dependencies of the real part of gamma that correspond to resonances in the imaginary part of gamma. The theoretical studies suggest that the linear absorption spectra are dominated by (XAg)-Ag-1 -> n(1)B(3u) transitions, with the first state of B-3u symmetry playing a steadily diminishing role upon oligoyne chain lengthening. The theoretical studies also predict a red-shift of two-photon absorption (TPA) profile with increasing conjugation length, and a significant enhancement on proceeding from the shortest to the longest chromophore, trends that are observed experimentally. The experimental low-energy TPA maxima for these complexes can be approximated by a simple Gaussian profile. The sp-carbon chain-length dependence of linear and nonlinear absorption maxima enable an estimate (neglecting saturation) of 660 and 1000 nm for the infinite carbon chain, carbyne.
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7. |
- Sorensen, S. L., et al.
(författare)
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Electronic Doppler effect in resonant Auger decay of CO molecules upon excitation near a shake-up Pi resonance
- 2007
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - : APS. - 1050-2947 .- 1094-1622. ; 76:062704
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Tidskriftsartikel (refereegranskat)abstract
- Wepresent an experimental observation of the electronic Doppler effect inresonant Auger spectra upon core excitation slightly above the carbonK edge of the CO molecule. Thus the electronic Dopplereffect has been identified in above-threshold excitation, and in atransition of symmetry. Ab initio calculations of the potentialenergy curves of the relevant states of CO and thewave packet technique have been employed to provide a theoreticalbackground to the experimental studies. The weak feature around 299.4 eVin the photoabsorption spectrum, whose decay has been investigated bythe present experiment, is assigned to double (core-valence) excitations toC 1s shake-up states |1s1−1*2 with a strong dissociative character,and the Doppler splitting of the atomic peak has beenreproduced by the simulation.
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8. |
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9. |
- Velkov, Yasen, et al.
(författare)
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Origin of fine structures on the dissociative 1s ->sigma* resonance in X-ray absorption spectra of O-2
- 2009
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Ingår i: Chemical Physics Letters. - : Elsevier BV. - 0009-2614 .- 1873-4448. ; 476:4-6, s. 147-150
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Tidskriftsartikel (refereegranskat)abstract
- We attempt to explain a puzzling long-tailed peak shape of the X-ray absorption spectrum of the oxygen molecule in the energy region around 539 eV taking into account the Rydberg-valence and vibronic couplings. The long-tailed feature is found to arise from two dissociative sigma* states and the sudden drop in intensity is related to decrease in transition dipole near the crossing point between the repulsive sigma* and weak 3s Rydberg states with the quartet ion cores. This is supported by numerical wave-packet simulations allowing for all interchannel couplings between the Rydberg and valence manifolds with the quartet and doublet ion cores in a diabatic representation of the core-excited states.
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10. |
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11. |
- Velkov, Yasen, 1980-
(författare)
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Quantum nuclear dynamics in x-ray scattering and lasing
- 2008
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- This thesis presents a theoretical study of the role of nuclear degrees of freedom in the x-ray absorption, x-ray resonant scattering and some aspects of the interaction of matter with strong laser fields. Most numerical simulations are performed with a time-dependent wave-packet program that have proved its robustness in previous investigations. The relevant experimental results are also presented for comparison when available. The first problem considered in the thesis is the possibility of obtaining x-ray absorption spectra with resolution beyond the natural lifetime broadening of the core-excited electronic states. It is shown that the method of measuring x-ray absorptionin the resonant scattering mode suggested earlier for that purpose exhibits severe limitations originating from the lifetime vibrational interference between the intermediate core-excited vibrational levels. However, a broad class of molecules is found for which spectra with super-high resolution can indeed be obtained. These molecules have parallel potential energy surfaces of the core-excited and final states for the x-ray scattering process. The interpretations of two interesting cases of x-ray absorption and Auger scattering follow. The first one is related to scattering through a doubly excited Π state in the CO molecule. A Doppler split feature near 299.4 eV and strong scattering anisotropy are observed. Both features are well explained and reproduced by the theory. Next, theelectron-vibrational fine structure of the excitation for O2 is investigated by means of different models. We are able to single out the electronic states and interpotential crossing points responsible for the peculiar absorption profile. Based on these findings we explain and reproduce the x-ray Auger scattering spectra through the same excitation. Here we encounter a rather unusual situation in which the Auger spectra are affected by three types of the interference: Apart from the lifetime vibrational interference, a strong interference between two intermediate electronic states and an interference with the direct-scattering amplitude is also present. The process of intramolecular vibrational redistribution (IVR) is investigated in the context of formation of amplified spontaneous emissions (ASE) inside laser-pumped gain media. IVR raises to a higher energy region the threshold pump intensity after which blue-shifted ASE is observed. Finally, we suggest a new scheme of x-ray pump-probe spectroscopy based on the core-hole hopping in N2 induced by an infrared laser field. We investigate the result from the core-hole hoping on the vibrational structure of the x-ray absorption profile. Furthermore, by populating core-excited states with opposite parities, the laser field opens up symmetry forbidden resonant inelastic scattering channels, which can give new insights about the electronic structure of matter.
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12. |
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13. |
- Velkov, Yasen, et al.
(författare)
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X-ray absorption of N2 accompanied by infrared-induced transitions between the ungerade and gerade core levels
- 2008
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Ingår i: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 41:14, s. 145601-
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Tidskriftsartikel (refereegranskat)abstract
- We study a two-colour pump–probe scheme of x-ray absorption accompanied by core-hole hopping in the field of a strong IR laser. The process is exemplified for fixed-in-space and randomly oriented homonuclear diatomic molecules N2 near the 1σu → 1πg x-ray absorption transition. The laser field mixes the core holes of opposite parities and causes Rabi splitting of the core-excited states. The IR field results in spectral broadening and shifts of the x-ray resonances as well as decrease of x-ray photoabsorption. The Stark broadening of the x-ray absorption spectrum depends on the orientation of the molecule and the angle between the polarization vectors of the x-ray and IR fields. The spectral changes caused by the IR field are weaker for randomly oriented molecules in comparison with fixed-in-space molecules.
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14. |
- Velkov, Yasen, et al.
(författare)
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X-ray-absorption spectroscopy beyond the natural width measured in partial Auger yield mode
- 2009
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - 1050-2947 .- 1094-1622. ; 79:2
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Tidskriftsartikel (refereegranskat)abstract
- We report both experimental and theoretical studies on x-ray absorption measured using partial Auger yields of gas phase nitrogen, carbon monoxide, and oxygen molecules near the N 1s ->pi(*), O 1s ->pi(*), and O 1s ->pi(*) regions, respectively. The main tool of our study is a two-dimensional map in which resonant Auger yields are plotted as a function of photon and kinetic energy. The partial yields of the three molecules are analyzed in detail by extracting profiles along various directions in the map. Narrowing of the absorption resonances is observed along the direction of constant kinetic energy. It is shown that such profiles are similar to the conventional x-ray-absorption spectrum for a broad class of molecules whose potential energy surfaces of the final and core-excited states are almost parallel. However, substantial differences with the conventional x-ray-absorption profiles are observed in the general case of nonparallel surfaces due to the lifetime vibrational interference. Here, we suggest a systematic way to eliminate the lifetime vibrational interference.
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15. |
- Velkov, Yasen, et al.
(författare)
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X-ray absorption spectroscopy measured in resonant X-ray scattering mode : How unnatural is the resolution beyond the natural width?
- 2008
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Ingår i: Chemical Physics Letters. - : Elsevier BV. - 0009-2614 .- 1873-4448. ; 465:1-3, s. 153-156
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Tidskriftsartikel (refereegranskat)abstract
- The aim of this work is to give a clarifying view of the ‘super-high resolution’ scheme employing X-ray absorption spectroscopy in the resonant scattering mode. If the idea is not applied carefully, unrealistic results, as ‘perfect’ resolution, can be produced. The background of the problem is that the technique of extracting lifetime-broadening-free spectra assumes a known location of the resonance in the two-dimensional map of X-ray scattering spectra. The accuracy of the latter is, however, related to the lifetime broadening of the core-excited state. Thus, a compromise must be found between the uncertainty in the position of the X-ray absorption peak and the width of the desired absorption profile.
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