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Sökning: WFRF:(Wiell T)

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1.
  • Butorin, S.M, et al. (författare)
  • Tunable excitation x-ray-fluorescence spectroscopy in phase-analysis of high-Tc superconductors
  • 1994
  • Ingår i: Journal of physics-condensed matter. - 0953-8984. ; 6:43, s. 9267-9274
  • Tidskriftsartikel (refereegranskat)abstract
    • O Kalpha x-ray fluorescence of YBa2Cu3O7-delta and Sr0.85Nd0.15CuO2 samples containing CO3(2-) impurities, as well as pure BaCO3, have been studied using tunable monochromatic synchrotron radiation excitation. When the excitation energy is set to the most intense features in the O 1s absorption edge of cuprates and to bound states above this edge the O Kalpha spectra recorded are very similar to those of pure BaCO3 even if the admixture of CO3(2-) is small. The observed changes in the O Kalpha profiles of multi-phase YBa2Cu3O7-delta and Sr0.85Nd0.15CuO2 samples are discussed in terms of different x-ray absorption cross sections for O in the main phase and in the CO3(2-) fraction.
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2.
  • Attauabi, Mohamed, et al. (författare)
  • Influence of Genetics, Immunity and the Microbiome on the Prognosis of Inflammatory Bowel Disease (IBD Prognosis Study) : the protocol for a Copenhagen IBD Inception Cohort Study
  • 2022
  • Ingår i: BMJ Open. - : BMJ Publishing Group Ltd. - 2044-6055. ; 12:6, s. e055779-e055779
  • Tidskriftsartikel (refereegranskat)abstract
    • Introduction: Inflammatory bowel diseases (IBD), encompassing Crohn's disease and ulcerative colitis, are chronic, inflammatory diseases of the gastrointestinal tract. We have initiated a Danish population-based inception cohort study aiming to investigate the underlying mechanisms for the heterogeneous course of IBD, including need for, and response to, treatment.Methods and analysis: IBD Prognosis Study is a prospective, population-based inception cohort study of unselected, newly diagnosed adult, adolescent and paediatric patients with IBD within the uptake area of Hvidovre University Hospital and Herlev University Hospital, Denmark, which covers approximately 1 050 000 inhabitants (~20% of the Danish population). The diagnosis of IBD will be according to the Porto diagnostic criteria in paediatric and adolescent patients or the Copenhagen diagnostic criteria in adult patients. All patients will be followed prospectively with regular clinical examinations including ileocolonoscopies, MRI of the small intestine, validated patient-reported measures and objective examinations with intestinal ultrasound. In addition, intestinal biopsies from ileocolonoscopies, stool, rectal swabs, saliva samples, swabs of the oral cavity and blood samples will be collected systematically for the analysis of biomarkers, microbiome and genetic profiles. Environmental factors and quality of life will be assessed using questionnaires and, when available, automatic registration of purchase data. The occurrence and course of extraintestinal manifestations will be evaluated by rheumatologists, dermatologists and dentists, and assessed by MR cholangiopancreatography, MR of the spine and sacroiliac joints, ultrasonography of peripheral joints and entheses, clinical oral examination, as well as panoramic radiograph of the jaws. Fibroscans and dual-energy X-ray absorptiometry scans will be performed to monitor occurrence and course of chronic liver diseases, osteopenia and osteoporosis.Ethics and dissemination: This study has been approved by Ethics Committee of the Capital Region of Denmark (approval number: H-20065831). Study results will be disseminated through publication in international scientific journals and presentation at (inter)national conferences.
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5.
  • Karis, O., et al. (författare)
  • Observation of short- and long-range hybridization of a buried Cu monolayer in Ni
  • 2000
  • Ingår i: Physical Review B Condensed Matter. - 0163-1829 .- 1095-3795. ; 62:24, s. R16239-R16242
  • Tidskriftsartikel (refereegranskat)abstract
    • The electronic structure of a Cu monolayer buried in Ni fcc(100) is studied by means of x-ray emission and absorption spectroscopies in combination with first principles calculations. The local character of the x-ray probes allows us to investigate changes in the chemical interaction for these ultrathin film systems. In comparison to bulk Cu, the occupied d states of a buried Cu monolayer, as mapped in the x-ray emission spectrum, remain mostly unaltered. The absorption spectrum on the other hand shows that the empty states of the buried Cu monolayer are modified, and instead resemble the unoccupied electronic density of bulk Ni. These findings agree well with our first principle electronic structure calculations and the results are interpreted in terms of short- and long-range hybridization.
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6.
  • Karis, O, et al. (författare)
  • Observation of short- and long-range hybridization of a buried Cu monolayer in Ni
  • 2000
  • Ingår i: PHYSICAL REVIEW B. - 0163-1829. ; 62:24, s. R16239-R16242
  • Tidskriftsartikel (refereegranskat)abstract
    • The electronic structure of a Cu monolayer buried in Ni fcc(100) is studied by means of x-ray emission and absorption spectroscopies in combination with first principles calculations. The local character of the x-ray probes allows us to investigate change
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7.
  • Karis, O, et al. (författare)
  • One-step and two-step description of deexcitation processes in weakly interacting systems
  • 1996
  • Ingår i: PHYSICAL REVIEW LETTERS. - : AMER INST PHYSICS. ; 76:8, s. 1380-1383
  • Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
    • The origin of one- and two-step behavior of core-hole decay processes is identified in connection with high resolution autoionization spectra for Ar/Pt(111). The spectra simultaneously show features of the two types (resonant Raman vs Auger-like behavior)
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8.
  • Karis, O, et al. (författare)
  • Probing surface states of Cu/Ni thin films using x-ray absorption spectroscopy
  • 2001
  • Ingår i: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 63:11
  • Tidskriftsartikel (refereegranskat)abstract
    • Surface and interface properties of Cu thin films (1–4 monolayers) deposited on Ni(100) have been extracted by means of x-ray absorption spectroscopy and analyzed in combination with ab initio density-functional calculations. An unoccupied Cu surface state is identified in an x-ray absorption spectra and studied as a function of film thickness. Experimental data is supported by calculations of the layer-resolved density of states and the results from this combined theoretical-experimental effort show that the surface state is almost entirely located on the atomic layer closest to the vacuum. Our results also indicate strong hybridization between unoccupied states at the Cu/Ni interface boundary.
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10.
  • Nilsson, A, et al. (författare)
  • An atom-specific look at the surface chemical bond
  • 1997
  • Ingår i: PHYSICAL REVIEW LETTERS. - : AMER INST PHYSICS. - 0031-9007. ; 78:14, s. 2847-2850
  • Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
    • High resolution x-ray emission spectroscopy is shown to reveal unprecedented details of the chemical bond formed between a molecule and a transition metal surface. An atom and symmetry projected view of the bonding orbitals is obtained. We find that all o
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13.
  • Nilsson, A, et al. (författare)
  • Local probing of the surface chemical bond using X-ray emission spectroscopy
  • 1997
  • Ingår i: APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING. - : SPRINGER VERLAG. - 0947-8396. ; 65:2, s. 147-154
  • Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
    • X-ray emission spectroscopy applied to adsorbate systems is shown to reveal new details of the chemical bond formed at surfaces. An atom and symmetry projected view of the bonding orbitals is obtained. We will present recent studies of N-2 and CO on Ni(10
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14.
  • Wassdahl, N., et al. (författare)
  • Soft x-ray emission studies of adsorbates
  • 1992
  • Ingår i: Physical Review Letters. - 0031-9007. ; 69:5, s. 812-815
  • Tidskriftsartikel (refereegranskat)abstract
    • Soft x-ray emission spectroscopy is for the first time applied to surfaces and adsorbates. Surface sensitivity is achieved by employing synchrotron radiation in grazing incidence for the excitation. We present O K emission from adsorbed atomic oxygen on Ni(100) and Cu(100) and molecular CO on Ni(100). The observed spectral features correspond to the occupied 2p partial density of states of the adsorbates.
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15.
  • Weinelt, M, et al. (författare)
  • Electronic structure of benzene on Ni(100) and Cu(110): An x-ray-spectroscopy study
  • 1998
  • Ingår i: PHYSICAL REVIEW B-CONDENSED MATTER. - : AMERICAN PHYSICAL SOC. - 0163-1829. ; 58:11, s. 7351-7360
  • Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
    • The valence electronic structure of benzene chemisorbed on Ni(100) and Cu(110) has been studied using angle-dependent x-ray emission and x-ray absorption spectroscopy. These techniques allow us to resolve the benzene p contributions involved in the chemic
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17.
  • Weinelt, M., et al. (författare)
  • Resonant Photoemission at the 2p Edges of Ni: Resonant Raman and Interference Effects
  • 1997
  • Ingår i: Physical Review Letters. - 0031-9007 .- 1079-7114. ; 78:5, s. 967-970
  • Tidskriftsartikel (refereegranskat)abstract
    • Unambiguous evidence for resonant photoemission in Ni is presented. Interference effects are identified at the 2p edges for the valence band and the 6 eV satellite. A rapid transition from a resonant Raman to an Auger-like regime shows that the core-excited states above threshold are not localized enough to significantly enhance the photoemission intensity, implying a large fraction of incoherent intensity. The results indicate that the appearance of interference effects does not require strong localization of the intermediate state.
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18.
  • Weinelt, M, et al. (författare)
  • Resonant photoemission at the 2p edges of Ni: Resonant Raman and interference effects
  • 1997
  • Ingår i: PHYSICAL REVIEW LETTERS. - 0031-9007. ; 78:5, s. 967-970
  • Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
    • Unambiguous evidence for resonant photoemission in Ni is presented. Interference effects are identified at the 2p edges for the valence band and the 6 eV satellite. A rapid transition from a resonant Raman to an Auger-like regime shows that the core-excit
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19.
  • Wiell, T, et al. (författare)
  • Local aspects of the adsorbate-substrate chemical bond in N/Cu(100) and O/Cu(100)
  • 1998
  • Ingår i: PHYSICAL REVIEW B-CONDENSED MATTER. - : AMERICAN PHYSICAL SOC. - 0163-1829. ; 58:3, s. 1655-1664
  • Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
    • Both the occupied and unoccupied adsorbate valence states have been probed by x-ray emission and x-ray absorption spectroscopies for N/Cu(100) and the low coverage phase of O/Cu(100). By carrying out experiments using two different measurement geometries,
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