| 1. |
- Demirci, Yunus, et al.
(författare)
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The Effect of Crystal Mismatch on the Thermoelectric Performance Enhancement of Nano Cu2Se
- 2021
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Ingår i: FRONTIERS IN MATERIALS. - : Frontiers Media SA. - 2296-8016. ; 7
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Tidskriftsartikel (refereegranskat)abstract
- In the past decades, Cu2-x Se compounds have attracted great attention due to the inclusion of non-toxic and abundant elements, besides having a promising thermoelectric (TE) performance. In this work, we investigated the effect of a crystal mismatch of a nanoinclusion phase on the TE properties of Cu2-x Se. Nano-Cu2Se was synthesized using microwave assisted thermolysis, while the p-type skutterudite, Fe3.25Co0.75Sb12 (FeCoSb), compound was synthesized using a chemical alloying route. Nano-Cu2Se, and (nano-Cu2Se)(1-x )(nano-FeCoSb)( x ) composites, where x = 0.05 and 0.1, were prepared via mechanical alloying followed by Spark Plasma Sintering process. Structural properties were evaluated by PXRD and SEM analysis, while the high temperature transport properties were examined via electrical conductivity, Seebeck coefficient, and thermal conductivity measurements in the temperature range of 300-800 K. Powder X-ray diffraction (PXRD) confirmed a single phase of nano Cu2Se, while the samples with FeCoSb inclusion consist of two phases as Cu2Se and CoSb3. SEM micrographs of all samples show that Cu2Se has randomly oriented grains with different sizes. Cu2Se samples with a FeCoSb inclusion show a rather different structure. In these samples, a rod-shaped FeCoSb phase, with a size varying between 20 and 100 nm, showed an inhomogeneous distribution in the structure and stacked between the Cu2Se layers. Transport data indicate that crystal mismatch between Cu2Se and FeCoSb has a strong effect on the TE transport properties. Electrical conductivity decreases but Seebeck coefficient enhances with nano FeCoSb inclusion. Total thermal conductivity was suppressed by 30% and ZT value enhanced by 15% with 5% nano FeCoSb inclusion at 750 K, likely due to a decrease in the electronic contribution of the thermal conductivity. Structural and transport data show that small amount of nanoinclusion of FeCoSb has a beneficial effect on the TE performance of nano Cu2Se at temperatures below 800 K.
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| 2. |
- Hamawandi, Bejan, PhD, et al.
(författare)
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Facile Solution Synthesis, Processing and Characterization of n- and p-Type Binary and Ternary Bi-Sb Tellurides
- 2020
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Ingår i: Applied Sciences. - : MDPI AG. - 2076-3417. ; 10:3
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Tidskriftsartikel (refereegranskat)abstract
- The solution synthesis route as a scalable bottom-up synthetic method possesses significant advantages for synthesizing nanostructured bulk thermoelectric (TE) materials with improved performance. Tuning the composition of the materials directly in the solution, without needing any further processing, is important for adjusting the dominant carrier type. Here, we report a very rapid (2 min) and high yield (>8 g/batch) synthetic method using microwave-assisted heating, for the controlled growth of Bi2-xSbxTe3 (x: 0-2) nanoplatelets. Resultant materials exhibit a high crystallinity and phase purity, as characterized by XRD, and platelet morphology, as revealed by SEM. Surface chemistry of as-made materials showed a mixture of metallic and oxide phases, as evidenced by XPS. Zeta-potential analysis exhibited a systematic change of isoelectric point as a function of the material composition. As-made materials were directly sintered into pellets by using spark plasma sintering process. TE performance of Bi2-xSbxTe3 pellets were studied, where the highest ZT values of 1.04 (at 440 K) for Bi2Te3 and 1.37 (at 523 K) for Sb2Te3 were obtained, as n- and p-type TE materials. The presented microwave-assisted synthesis method is energy effective, a truly scalable and reproducible method, paving the way for large scale production and implementation of towards large-area TE applications.
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| 3. |
- Yusuf, Aminu, et al.
(författare)
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Multi-objective optimization of concentrated Photovoltaic-Thermoelectric hybrid system via non-dominated sorting genetic algorithm (NSGA II)
- 2021
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Ingår i: Energy Conversion and Management. - : Elsevier BV. - 0196-8904 .- 1879-2227. ; 236
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Tidskriftsartikel (refereegranskat)abstract
- Thermoelectric generators harvest additional electrical power when used in combination with concentrated photovoltaic cells given rise to a hybrid system. Overall cost of the system is high; therefore, the parameters of the system need to be optimized to obtain high output performance. This study determines the output performances of four sets of equations (models) used in the hybrid system, using the performance of recently developed nanostructured thermoelectric materials. Seven parameters of the system were optimized through these models using non-dominated genetic algorithm. Models 1 and 2 have the highest performance chosen by TOPSIS decision-making method. The power output and conversion efficiencies of the hybrid system in models 1 and 2 are 426.5 W, 11.45% and 461.12 W, 10.77%, respectively. Likewise, the highest TOPSIS solution for power output of one TEG module operating in the hybrid system and its corresponding efficiency is obtained in model 4 and are 1.97 W and 0.078%, respectively. This validates the fact that TEG operating in a hybrid system has optimum performance at a point when the load resistance is less than its internal resistance.
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