| 1. |
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| 2. |
- Cao, Danyang, et al.
(author)
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Biolubricant
- 2023
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In: Sustainable Production Innovations. - : John Wiley & Sons. ; , s. 1-56
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Book chapter (other academic/artistic)
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| 3. |
- Jiang, Cong, et al.
(author)
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F-doped LiNi0.8Co0.15Al0.05O2-? : cathodes with enhanced ORR catalytic activity for LT-SOFCs
- 2023
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In: Journal of Alloys and Compounds. - : Elsevier BV. - 0925-8388 .- 1873-4669. ; 940
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Journal article (peer-reviewed)abstract
- Developing highly effective catalysts for oxygen reduction reaction (ORR) is crucial to enable the low-temperature operation of solid oxide fuel cells (SOFCs). Recent studies have proposed a promising O2-/H+/e- conducting oxide, LiNi0.8Co0.15Al0.05O2-delta (LNCA) with good ORR catalytic activity for SOFC cathode uses. Herein, to further optimize the cathode functionality of LNCA, a fluorine anion (F-) doping strategy is ap-plied to develop highly active LNCAF0.1 and LNCAF0.2 cathodes for Sm-doped ceria (SDC) electrolyte-based SOFCs. It is found the successful doping of F- in the oxygen site of LNCA leads to improved oxygen ionic conductivity and facilitated surface exchange and bulk diffusion of oxygen in LNCAF0.1 and LNCAF0.2, which thus gain distinctly promoted ORR catalytic activity at 450-550 degrees C, as confirmed by the decreased area specific resistances (ASR) and activation energy on symmetrical cells. The as-fabricated two SDC-based SOFCs with LNCAF0.1 and LNCAF0.2 cathodes exhibit peak power densities of 497 and 591 mW cm-2 at 550 degrees C, respectively, which are higher than that of the cell with LNCA cathode. Furthermore, the single cell with the best-performing LNCAF0.2 cathode demonstrates a good stability for 110 h at 550 degrees C. The present study thus provides a feasible strategy of F anion doping to promote the ORR catalytic activity of LNCA cathode for developing low-temperature SOFCs.
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| 4. |
- Liang, Yuanyuan, et al.
(author)
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Spatial distribution and seasonal variations of atmospheric organophosphate esters (OPEs) in Tianjin, China based on gridded field observations
- 2020
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In: Environmental Pollution. - : Elsevier BV. - 0269-7491 .- 1873-6424. ; 263
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Journal article (peer-reviewed)abstract
- The atmospheric concentrations of 14 organophosphate esters (OPEs) were monitored by passive air sampling at 33 sites to determine their spatial distributions, and seasonal variations (summer and winter) in Tianjin, North China. The total concentrations of the OPEs (Sigma 9OPEs) in the summer ranged from 0.08 to 1113 ng/sample with a median of 98.4 ng/sample, which was non-statistically different from the concentrations obtained in the winter (which ranged from 1.93 to 548 ng/sample with a median of 46.2 ng/sample). Among the observed OPEs, the concentrations of TnBP and TCiPP were statistically higher in the summer compared with the winter (p < 0.05). For grouped OPEs, only a significantly higher level of chlorinated OPEs was found in summer than that in winter. In the winter, spatial differences were found to be significantly different between the concentrations of TnBP, TiBP, TCEP, and TEHP in the suburban and rural areas (p < 0.05). Considering the possible point-sources, in the summer, the concentrations of TDCPP, TCiPP, DPEHP, TEHP, and the total concentration of TCPs (denoted as Sigma 3TCP, comprised of the concentrations of TCP, TmCP, and ToCP) in an electronic-waste (e-waste) dismantling area were higher than those obtained at the other sampling sites. Sigma 9OPEs at the e-waste site and another site located near a manufacturing plant of organophosphate flame retardants (OFRs) were both higher than the median concentrations obtained at the other sampling sites, and TCiPP was the most abundant pollutant. In the winter, the concentrations of Sigma 9OPEs at the e-waste site were still higher than their median concentrations at the other sites. Because OPEs are used in aircraft lubricating oils and hydraulic fluids, an airport was thought to be another important source of TiBP and TPhP in the present study. Therefore, the e-waste site, airport, and OFR manufacturing plant may be the major sources of OPEs in the environment.
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| 5. |
- Song, Liwen, et al.
(author)
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Synthesis and Photochromism of Naphthopyrans Bearing Naphthalimide Chromophore : Predominant Thermal Reversibility in Color-Fading and Fluorescence Switch
- 2011
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In: Journal of Physical Chemistry B. - : American Chemical Society (ACS). - 1520-6106 .- 1520-5207. ; 115:49, s. 14648-14658
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Journal article (peer-reviewed)abstract
- Two novel photochromic naphthopyrans containing naphthalimide moieties (Nip1 and Nip2) were studied in solution under flash photolysis conditions, exhibiting highly photochromic response, rapid thermal bleaching rate and good fatigue-resistance. Owing to the different N-substituted imide groups at the naphthalimide units, the thermal bleaching rate of Nip2 bearing phenyl on the naphthalimide unit is found to be approximately 2 times that of Nip1 bearing n-butyl, indicating that the photochromic properties can be modulated with introduction of different functional groups on the naphthalimide unit. In Nip1 and Nip2, the strong electron-withdrawing effect of the imide group incorporated at the naphthalimide moiety maintains several merits: (i) shifting absorption bands to longer wavelength, (ii) beneficial to an enhancement in the ratio of transoid-cis (TC) isomer and an increase in the transformation rate from transoid-trans (TT) to TC with respect to reference compound NP, and (iii) resulting in a preferable color bleaching rate and fading absolutely to their colorless state with thermal reversibility. As demonstrated in the system of NP, the slow transformation process from TT to TC might be the predominant dynamic step in thermal back process, leading to the residual color of NP being only faded to its original colorless state by visible light irradiation. The optical densities of colored forms for Nip1 and Nip2 are dependent upon the intensity of incident light, ensuring a possible application in the manufacture of ophthalmic lenses and smart windows. Moreover, the fluorescence of Nip1 and Nip2 can be switched on and off by photoinduced conversion between the closed and open forms.
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| 6. |
- Voon, Chia P., et al.
(author)
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Modulating the activities of chloroplasts and mitochondria promotes adenosine triphosphate production and plant growth
- 2021
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In: Quantitative Plant Biology. - : Cambridge University Press. - 2632-8828. ; 2
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Journal article (peer-reviewed)abstract
- Efficient photosynthesis requires a balance of ATP and NADPH production/consumption in chloroplasts, and the exportation of reducing equivalents from chloroplasts is important for balancing stromal ATP/NADPH ratio. Here, we showed that the overexpression of purple acid phosphatase 2 on the outer membranes of chloroplasts and mitochondria can streamline the production and consumption of reducing equivalents in these two organelles, respectively. A higher capacity of consumption of reducing equivalents in mitochondria can indirectly help chloroplasts to balance the ATP/NADPH ratio in stroma and recycle NADP+, the electron acceptors of the linear electron flow (LEF). A higher rate of ATP and NADPH production from the LEF, a higher capacity of carbon fixation by the Calvin-Benson-Bassham (CBB) cycle and a greater consumption of NADH in mitochondria enhance photosynthesis in the chloroplasts, ATP production in the mitochondria and sucrose synthesis in the cytosol and eventually boost plant growth and seed yields in the overexpression lines.
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| 7. |
- Wei, Jingjiang, et al.
(author)
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Bioinspired 3D Printable, Self-Healable, and Stretchable Hydrogels with Multiple Conductivities for Skin-like Wearable Strain Sensors
- 2021
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In: ACS Applied Materials and Interfaces. - : American Chemical Society (ACS). - 1944-8244 .- 1944-8252. ; 13:2, s. 2952-2960
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Journal article (peer-reviewed)abstract
- Bioinspired hydrogels have promising prospects in applications such as wearable devices, human health monitoring equipment, and soft robots due to their multifunctional sensing properties resembling natural skin. However, the preparation of intelligent hydrogels that provide feedback on multiple electronic signals simultaneously, such as human skin receptors, when stimulated by external contact pressure remains a substantial challenge. In this study, we designed a bioinspired hydrogel with multiple conductive capabilities by incorporating carbon nanotubes into a chelate of calcium ions with polyacrylic acid and sodium alginate. The bioinspired hydrogel consolidates self-healing ability, stretchability, 3D printability, and multiple conductivities. It can be fabricated as an integrated strain sensor with simultaneous piezoresistive and piezocapacitive performances, exhibiting sensitive (gauge factor of 6.29 in resistance mode and 1.25 kPa(-1) in capacitance mode) responses to subtle pressure changes in the human body, such as finger flexion, knee flexion, and respiration. Furthermore, the bioinspired strain sensor sensitively and discriminatively recognizes the signatures written on it. Hence, we expect our ideas to provide inspiration for studies exploring the use of advanced hydrogels in multifunctional skin-like smart wearable devices.
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| 8. |
- Wei, Jingjiang, et al.
(author)
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Bioprocess-inspired synthesis of printable, self-healing mineral hydrogels for rapidly responsive, wearable ionic skin
- 2021
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In: Chemical Engineering Journal. - : Elsevier BV. - 1385-8947 .- 1873-3212. ; 424
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Journal article (peer-reviewed)abstract
- Oyster reefs, which can maintain coastal ecosystems by absorbing storm surge energy, are composed of aggregated oyster shells bonded by bioadhesive secretions containing inorganic minerals. Bioadhesive secretions are formed by cross-linking extracellular liquid, which is rich in organic and inorganic ions, with sand, bacteria, or diatoms. Inspired by such bioprocesses, a mineral hydrogel with excellent 3D printability, rapid self-healing ability (85% recovery within 1 min), high stretchability (>1500% tensile elongation) and ionic conductivity was synthesized by the chelation of polyacrylic acid (PAA) with calcium ions (Ca2+) and subsequent physical cross-linking of PAA with modified amorphous calcium phosphate (ACP) nanoparticles. With such mineral hydrogels, ionic skin was successfully prepared, which could recognize the bending degrees of the index finger and sensitively sense the tensile strain (approximately 33 ms). Moreover, the ionic skin can distinguish external temperature stimuli and work stably at a temperature of 75 degrees C. These performances exhibit the great mechanosensing and thermosensing abilities of ionic skin, showing promising applications in various fields, such as wearable sensors, for withstanding high ambient temperatures and the next generation of soft intelligent robots.
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| 9. |
- You, Liwen, 1976-, et al.
(author)
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Understanding Prediction Systems for HLA-Binding Peptides and T-Cell Epitope Identification
- 2007
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In: Pattern Recognition in Bioinformatics. - Berlin : Springer Berlin/Heidelberg. - 0302-9743 .- 1611-3349. - 9783540752851 ; , s. 337-348
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Conference paper (peer-reviewed)abstract
- Peptide binding to HLA molecules is a critical step in induction and regulation of T-cell mediated immune responses. Because of combinatorial complexity of immune responses, systematic studies require combination of computational methods and experimentation. Most of available computational predictions are based on discriminating binders from non-binders based on use of suitable prediction thresholds. We compared four state-of-the-art binding affinity prediction models and found that nonlinear models show better performance than linear models. A comprehensive analysis of HLA binders (A*0101, A*0201, A*0301, A*1101, A*2402, B*0702, B*0801 and B*1501) showed that non-linear predictors predict peptide binding affinity with high accuracy. The analysis of known T-cell epitopes of survivin and known HIV T-cell epitopes showed lack of correlation between binding affinity and immunogenicity of HLA-presented peptides. T-cell epitopes, therefore, can not be directly determined from binding affinities by simple selection of the highest affinity binders.
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