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1.	Buckland, Philip I., 1973-, et al. (author) SEAD - The Strategic Environmental Archaeology Database : Progress Report Spring 2014 2014 Reports (other academic/artistic)abstract This report provides an overview of the progress and results of the VR:KFI infrastructure projects 2007-7494 and (825-)2010-5976. It should be considered as a status report in an on-going long-term research infrastructure development project.
2.	Weis, Franz A., et al. (author) Magmatic water contents determined through clinopyroxene : Examples from the Western Canary Islands, Spain 2015 In: Geochemistry Geophysics Geosystems. - 1525-2027. ; 16:7, s. 2127-2146 Journal article (peer-reviewed)abstract Water is a key parameter in magma genesis, magma evolution, and resulting eruption styles, because it controls the density, the viscosity, as well as the melting and crystallization behavior of a melt. The parental water content of a magma is usually measured through melt inclusions in minerals such as olivine, a method which may be hampered, however, by the lack of melt inclusions suitable for analysis, or postentrapment changes in their water content. An alternative way to reconstruct the water content of a magma is to use nominally anhydrous minerals (NAMs), such as pyroxene, which take up low concentrations of hydrogen as a function of the magma's water content. During magma degassing and eruption, however, NAMs may dehydrate. We therefore tested a method to reconstruct the water contents of dehydrated clinopyroxene phenocrysts from the Western Canary islands (n=28) through rehydration experiments followed by infrared and Mossbauer spectroscopy. Employing currently available crystal/melt partitioning data, the results of the experiments were used to calculate parental water contents of 0.710.07 to 1.490.15 wt % H2O for Western Canary magmas during clinopyroxene crystallization at upper mantle conditions. This H2O range is in agreement with calculated water contents using plagioclase-liquid-hygrometry, and with previously published data for mafic lavas from the Canary Islands and comparable ocean island systems elsewhere. Utilizing NAMs in combination with hydrogen treatment can therefore serve as a proxy for pre-eruptive H2O contents, which we anticipate becoming a useful method applicable to mafic rocks where pyroxene is the main phenocryst phase.
3.	Bobrowski, Nicole, et al. (author) Multi-component gas emission measurements of the active lava lake of Nyiragongo, DR Congo 2017 In: Journal of African Earth Sciences. - : Elsevier BV. - 1879-1956 .- 1464-343X. ; 134, s. 856-865 Journal article (peer-reviewed)abstract Between 2007 and 2011 four measurement campaigns (June 2007, July 2010, June 2011, and December 2011) were carried out at the crater rim of Nyiragongo volcano, DR Congo. Nyiragongo is one of the most active volcanoes in Africa. The ground-based remote sensing technique Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS), which uses scattered sunlight, the in-situ Multi-Component Gas Analyzer System (Multi-GAS) and alkaline impregnated filter were simultaneously applied during all field trips. The bromine monoxide to sulfur dioxide (BrO/SO2) and carbon dioxide to sulfur dioxide (CO2/SO2) molar ratios were determined, among other ratios. During the different field trips variations of the level of the lava lake up to several tens of meters were observed during intervals of the order of minutes up to days and also between the years. The measured gas ratios presented covariations with the lava lake level changes. BrO/SO2 ratios and CO2/SO2 ratios showed similar behavior. Annual CO2/SO2 and BrO/SO2 average values are generally positively correlated. In June 2011 increased BrO/SO2 as well as increased CO2/SO2 ratios have been observed before a sudden decrease of the lava lake. Overall the Cl/S ratio, determined by filter-pack sampling, shows an increasing trend with time, which is accompanied by a decreasing sulfur dioxide flux, the later measured nearly continuously by automated MAX-DOAS instruments since 2004. Mean gas emission fluxes of CO2, Cl and ‘minimum-BrO’ fluxes are calculated using their ratio to SO2. The first two show an increase with time, in contrast to the SO2 fluxes. A simple conceptual model is proposed which can explain in particular the June 2011 data, but as well our entire data set. The proposed model takes up the idea of convective magma cells inside the conduit and the possible temporary interruption of part of the cycling. We propose than two alternatives to explain the observed gas emission variation: 1. It is assumed that the diffuse and fumarolic degassing could have significant influence on measured gas composition. The measured gas composition might rather represent a gas mixture of plume, diffuse and fumarolic degassing than only representing the volcanic plume. 2. It is proposed that the interruption of the convection has taken place in the upper part of the conduit and deep degassing of CO2 and bromine initially continues while mixing already with gas emissions from an ageing source, which is characterized by an already diminishing sulfur content. These complex process but as well as the gas mixing of different sources, could explain general features of our dataset, but can unfortunately neither be confirmed nor disproven by the data available today.
4.	Åkesson, Sofia, et al. (author) Characterizing natural degradation of tetrachloroethene (PCE) using a multidisciplinary approach 2020 In: Ambio: a Journal of the Human Environment. - : Springer Science and Business Media LLC. - 0044-7447 .- 1654-7209. ; 50, s. 1074-1088 Journal article (peer-reviewed)abstract A site in mid-western Sweden contaminated with chlorinated solvents originating from a previous dry cleaning facility, was investigated using conventional groundwater analysis combined with compound-specific isotope data of carbon, microbial DNA analysis, and geoelectrical tomography techniques. We show the value of this multidisciplinary approach, as the different results supported each interpretation, and show where natural degradation occurs at the site. The zone where natural degradation occurred was identified in the transition between two geological units, where the change in hydraulic conductivity may have facilitated biofilm formation and microbial activity. This observation was confirmed by all methods and the examination of the impact of geological conditions on the biotransformation process was facilitated by the unique combination of the applied methods. There is thus significant benefit from deploying an extended array of methods for these investigations, with the potential to reduce costs involved in remediation of contaminated sediment and groundwater.
5.	Barnes, Paul W., et al. (author) Ozone depletion, ultraviolet radiation, climate change and prospects for a sustainable future 2019 In: Nature Sustainability. - : Springer Science and Business Media LLC. - 2398-9629. ; 2:7, s. 569-579 Research review (peer-reviewed)abstract © 2019, Springer Nature Limited. Changes in stratospheric ozone and climate over the past 40-plus years have altered the solar ultraviolet (UV) radiation conditions at the Earth’s surface. Ozone depletion has also contributed to climate change across the Southern Hemisphere. These changes are interacting in complex ways to affect human health, food and water security, and ecosystem services. Many adverse effects of high UV exposure have been avoided thanks to the Montreal Protocol with its Amendments and Adjustments, which have effectively controlled the production and use of ozone-depleting substances. This international treaty has also played an important role in mitigating climate change. Climate change is modifying UV exposure and affecting how people and ecosystems respond to UV; these effects will become more pronounced in the future. The interactions between stratospheric ozone, climate and UV radiation will therefore shift over time; however, the Montreal Protocol will continue to have far-reaching benefits for human well-being and environmental sustainability.
6.	Aldenhoff, Wiebke, 1985, et al. (author) Comparison of ice/water classification in Fram Strait from C- and L-band SAR imagery 2018 In: Annals of Glaciology. - : Cambridge University Press (CUP). - 0260-3055 .- 1727-5644. ; 59:76pt2, s. 112-123 Journal article (peer-reviewed)abstract In this paper an algorithm for ice/water classification of C- and L-band dual polarization synthetic aperture radar data is presented. A comparison of the two different frequencies is made in order to investigate the potential to improve classification results with multi-frequency data. The algorithm is based on backscatter intensities in co- and cross-polarization and autocorrelation as a texture feature. The mapping between image features and ice/water classification is made with a neural network. Accurate ice/water maps for both frequencies are produced by the algorithm and the results of two frequencies generally agree very well. Differences are found in the marginal ice zone, where the time difference between acquisitions causes motion of the ice pack. C-band reliably reproduces the outline of the ice edge, while L-band has its strengths for thin ice/calm water areas within the icepack. The classification shows good agreement with ice/water maps derived from met.no ice-charts and radiometer data from AMSR-2. Variations are found in the marginal ice zone where the generalization of the ice charts and lower accuracy of ice concentration from radiometer data introduce deviations. Usage of high-resolution dual frequency data could be beneficial for improving ice cover information for navigation and modelling.
7.	Maskenskaya, Olga M., et al. (author) Source and character of syntaxial hydrothermal calcite veins in Paleoproterozoic crystalline rocks revealed by fine-scale investigations 2014 In: Geofluids. - : Wiley. - 1468-8115 .- 1468-8123. ; 14:4, s. 495-511 Journal article (peer-reviewed)abstract Calcite veins in Paleoproterozoic granitoids on the Baltic Shield are the focus of this study. These veins are distinguished by their monomineralic character, unusual thickness and closeness to Neoproterozoic dolerite dykes and therefore have drawn attention. The aim of this study was to define the source of these veins and to unravel their isotopic and chemical nature by carrying out fine-scale studies. Seven calcite veins covering a depth interval of 50-420m below the ground surface and composed of breccias or crack-sealed fillings typically expressing syntaxial growth were sampled and analysed for a variety of physicochemical variables: homogenization temperature (T-h) and salinity of fluid inclusions, and stable isotopes (Sr-87/Sr-86, C-13/C-12, O-18/O-16), trace-element concentrations (Fe, Mn, Mg, Sr, rare earth elements) and cathodoluminescence (CL) of the solid phase. The fluid-inclusion data show that the calcites were precipitated mainly from relatively low-temperature (T-h=73-106 degrees C) brines (13.4-24.5wt.% CaCl2), and the Sr-87/Sr-86 is more radiogenic than expected for Rb-poor minerals precipitated from Neoproterozoic fluids. These features, together with the distribution of C-13 and O-18 values, provide evidence that the calcite veins are not genetic with the nearby Neoproterozoic dolerite dykes, but are of Paleozoic age and were precipitated from warm brines expressing a rather large variability in salinity. Whereas the isotopic and chemical variables express rather constant average values among the individual veins, they vary considerably on fine-scale across individual veins. This has implications for understanding processes causing calcite-rich veins to form and capture trace metals in crystalline bedrock settings.
8.	Ranta, E., et al. (author) Fluid-rock reactions in the 1.3Ga siderite carbonatite of the GrOnnedal-ika alkaline complex, Southwest Greenland 2018 In: Contributions to Mineralogy and Petrology. - : Springer Science and Business Media LLC. - 0010-7999 .- 1432-0967. ; 173:10 Journal article (peer-reviewed)abstract Petrogenetic studies of carbonatites are challenging, because carbonatite mineral assemblages and mineral chemistry typically reflect both variable pressure-temperature conditions during crystallization and fluid-rock interaction caused by magmatic-hydrothermal fluids. However, this complexity results in recognizable alteration textures and trace-element signatures in the mineral archive that can be used to reconstruct the magmatic evolution and fluid-rock interaction history of carbonatites. We present new LA-ICP-MS trace-element data for magnetite, calcite, siderite, and ankerite-dolomite-kutnohorite from the iron-rich carbonatites of the 1.3Ga GrOnnedal-ika alkaline complex, Southwest Greenland. We use these data, in combination with detailed cathodoluminescence imaging, to identify magmatic and secondary geochemical fingerprints preserved in these minerals. The chemical and textural gradients show that a 55m-thick basaltic dike that crosscuts the carbonatite intrusion has acted as the pathway for hydrothermal fluids enriched in F and CO2, which have caused mobilization of the LREEs, Nb, Ta, Ba, Sr, Mn, and P. These fluids reacted with and altered the composition of the surrounding carbonatites up to a distance of 40m from the dike contact and caused formation of magnetite through oxidation of siderite. Our results can be used for discrimination between primary magmatic minerals and later alteration-related assemblages in carbonatites in general, which can lead to a better understanding of how these rare rocks are formed. Our data provide evidence that siderite-bearing ferrocarbonatites can form during late stages of calciocarbonatitic magma evolution.
9.	Bagherbandi, Mohammad, Professor, et al. (author) Mantle Viscosity Derived From Geoid and Different Land Uplift Data in Greenland 2022 In: Journal of Geophysical Research - Solid Earth. - : AGU. - 2169-9313 .- 2169-9356. ; 127:8 Journal article (peer-reviewed)abstract The Earth's mass redistribution due to deglaciation and recent ice sheet melting causes changes in the Earth's gravity field and vertical land motion in Greenland. The changes are because of ongoing mass redistribution and related elastic (on a short time scale) and viscoelastic (on time scales of a few thousands of years) responses. These signatures can be used to determine the mantle viscosity. In this study, we infer the mantle viscosity associated with the glacial isostatic adjustment (GIA) and long-wavelength geoid beneath the Greenland lithosphere. The viscosity is determined based on a spatio-spectral analysis of the Earth's gravity field and the land uplift rate in order to find the GIA-related gravity field. We used different land uplift data, that is, the vertical land motions obtained by the Greenland Global Positioning System (GPS) Network (GNET), gravity recovery and climate experiment (GRACE) and glacial isostatic adjustment (GIA) data, and also combined them using the Kalman filtering technique. Using different land uplift rates, one can obtain different GIA-related gravity fields. As shown in this study, the mantle viscosities of 1.9 × 1022 Pa s and 7.8 × 1021 Pa s for a depth of 200–700 km are obtained using ICE-6G (VM5a) model and the combined land uplift model, respectively, and the GIA-related gravity potential signal
10.	Sopher, Daniel (author) Characterization of the structure, stratigraphy and CO2 storage potential of the Swedish sector of the Baltic and Hanö Bay basins using seismic reflection methods 2016 Doctoral thesis (other academic/artistic)abstract An extensive multi-channel seismic dataset acquired between 1970 and 1990 by Oljeprospektering AB (OPAB) has recently been made available by the Geological Survey of Sweden (SGU). This thesis summarizes four papers, which utilize this largely unpublished dataset to improve our understanding of the geology and CO2 storage capacity of the Baltic and Hanö Bay basins in southern Sweden.A range of new processing workflows were developed, which typically provide an improvement in the final stacked seismic image, when compared to the result obtained with the original processing. A method was developed to convert scanned images of seismic sections into SEGY files, which allows large amounts of the OPAB dataset to be imported and interpreted using modern software. A new method for joint imaging of multiples and primaries was developed, which is shown to provide an improvement in signal to noise for some of the seismic lines within the OPAB dataset. For the first time, five interpreted regional seismic profiles detailing the entire sedimentary sequence within these basins, are presented. Depth structure maps detailing the Outer Hanö Bay area and the deeper parts of the Baltic Basin were also generated. Although the overall structure and stratigraphy of the basins inferred from the reprocessed OPAB dataset are consistent with previous studies, some new observations have been made, which improve the understanding of the tectonic history of these basins and provide insight into how the depositional environments have changed throughout time. The effective CO2 storage potential within structural and stratigraphic traps is assessed for the Cambrian Viklau, När and Faludden sandstone reservoirs. A probabilistic methodology is utilized, which allows a robust assessment of the storage capacity as well as the associated uncertainty. The most favourable storage option in the Swedish sector of the Baltic Basin is assessed to be the Faludden stratigraphic trap, which is estimated to have a mid case (P50) storage capacity of 3390 Mt in the deeper part of the basin, where CO2 can be stored in a supercritical phase.
11.	Löfgren, Johan, 1983, et al. (author) Sea Level Monitoring Using a GNSS-Based Tide Gauge 2009 In: 2nd International Colloquium - Scientific and Fundamental Aspects of the Galileo Programme, 14 - 16 October 2009, Padua, Italy. Conference paper (other academic/artistic)abstract Global climate change is believed to result in the melting of large masses of ice in Polar Regions, bringing freshwater into the ocean, and changing the sea level. The traditional way to measure the sea level, by tide gauges, results in measurements relative to the Earth’s crust. However, in order to fully understand the sea level changes, absolute measurements (change in sea level in relation to the Earth’s center of gravity) are necessary, in particular in regions affected by post-glacial uplift, e.g., Fennoscandia. Satellite techniques, e.g., GNSS can be used to determine the motion of the Earth’s crust in relation to the center of gravity. By measuring reflected GNSS-signals from the sea surface, information of the sea level change can be obtained. Therefore a GNSS-based tide gauge is proposed.The proposed GNSS-based tide gauge installation consists of two antennas, one zenith looking right hand circular polarized (RHCP) and one nadir looking left hand circular polarized (LHCP), mounted back-to-back on a beam over the ocean. The RHCP antenna receives the GNSS-signals directly, whereas the LHCP antenna receives the signals reflected from the sea surface. Because of the additional path delay of the reflected signal, the LHCP antenna will appear to be a virtual GNSS-antenna located below the sea surface. When the sea level changes, the path delay of the reflected signal changes, thus the LHCP antenna will appear to be in a new position. The vertical position change corresponds to twice the sea level change, and therefore monitors sea level changes.Multiple satellites with different elevation and azimuth angles are observed each epoch and will give rise to reflected signals with different incidence angles from different directions. This means that the estimated sea level change can not be considered to originate from one specific point on the surface, but rather represents the change of an average surface formed by the reflection points.An experimental setup was installed in December 2008 over the ocean at Onsala Space Observatory (OSO) at the west coast of Sweden. Data was collected during three days using two Leica GRX1200+ receivers (one for the direct and one for the reflected signal). The receivers recorded 40 hours of continuous 20Hz data. The signal-to-noise ratio (SNR) as determined by the two receivers was used as a first data quality check. On average the SNR difference between the directly received and the reflected signals was less than 3dB.The data was analyzed using an in-house developed software in MATLAB. Solutions were made using L1 phase delays for relative positioning. Two approaches to estimate the vertical difference between the RHCP and the LHCP antenna were tested: hourly estimates of the vertical difference, and high-rate estimates of the vertical difference. For the hourly estimates 40 hours of continuous 1Hz data (reduced for faster processing using the TEQC software) were used. Each solution was made using 20 minutes of data every full hour, solving for differences in the local vertical components together with receiver clock and phase ambiguities differences for each epoch.The solution for the high-rate vertical component was made in two steps. First, the phase ambiguity differences were determined. This was done using equally distributed short intervals of ~1 second (21 epochs) from ~20 minutes of 20Hz data, solving for difference in phase ambiguities and receiver clocks every epoch together with differences in vertical coordinate for each short interval. The processing was done based on the assumptions that the sea surface does not change significantly during ~1 second and that the satellite geometry changes considerably in ~20 minutes. Second, the differences in phase ambiguities were rounded to the nearest integer and inserted as known values for a reprocessing of the 20Hz data. In this reprocessing the receiver clock parameters were estimated every epoch and the vertical coordinate difference with different time resolutions (e.g. 0.05s, 1s, 30s).The resulting time-series for the sea level change from the hourly solutions were compared to data from two traditional tide gauges operated by the Swedish Meteorological and Hydrological Institute at Ringhals and Göteborg, about 18 km south of and 33 km north of OSO, respectively. The GNSS-derived sea level change resembles reasonably well the independently observed sea level change. This indicates that the GNSS-tide gauge gives valuable results for sea level monitoring. Furthermore, the use of the high-rate GNSS-receivers additionally allows a flexible time resolution for sea level monitoring.
12.	Kylander, Malin E., et al. (author) Potentials and problems of building detailed dust records using peat archives : An example from Store Mosse (the "Great Bog"), Sweden 2016 In: Geochimica et Cosmochimica Acta. - : Elsevier BV. - 0016-7037 .- 1872-9533 .- 0046-564X. ; 190, s. 156-174 Journal article (peer-reviewed)abstract Mineral dust deposition is a process often overlooked in northern mid-latitudes, despite its potential effects on ecosystems. These areas are often peat-rich, providing ample material for the reconstruction of past changes in atmospheric deposition. The highly organic (up to 99% in some cases) matrix of atmospherically fed mires, however, makes studying the actual dust particles (grain size, mineralogy) challenging. Here we explore some of the potentials and problems of using geochemical data from conservative, lithogenic elements (Al, Ga, Rb, Sc, Y, Zr, Th, Ti and REE) to build detailed dust records by using an example from the 8900-yr peat sequence from Store Mosse (the "Great Bog"), which is the largest mire complex in the boreo-nemoral region of southern Sweden. The four dust events recorded at this site were elementally distinct, suggesting different dominant mineral hosts. The oldest and longest event (6385-5300 cal yr BP) sees a clear signal of clay input but with increasing contributions of mica, feldspar and middle-REE- rich phosphate minerals over time. These clays are likely transported from a long-distance source (< 100 km). While dust deposition was reduced during the second event (5300-4370 cal yr BP), this is the most distinct in terms of its source character with [Eu/Eu*] UCC revealing the input of plagioclase feldspar from a local source, possibly active during this stormier period. The third (2380- 2200 cal yr BP) and fourth (1275-1080 cal yr BP) events are much shorter in duration and the presence of clays and heavy minerals is inferred. Elemental mass accumulation rates reflect these changes in mineralogy where the relative importance of the four dust events varies by element. The broad changes in major mineral hosts, grain size, source location and approximated net dust deposition rates observed in the earlier dust events of longer duration agree well with paleoclimatic changes observed in northern Europe. The two most recent dust events are much shorter in duration, which in combination with evidence of their local and regional character, may explain why they have not been seen elsewhere.
13.	Lorenz, Henning, Dr. 1972-, et al. (author) COSC-2 – drilling the basal décollement and underlying margin of palaeocontinent Baltica in the Paleozoic Caledonide Orogen of Scandinavia 2022 In: Scientific Drilling. - Göttingen : Copernicus Publications. - 1816-8957 .- 1816-3459. ; 30, s. 43-57 Journal article (peer-reviewed)abstract Abstract.The Collisional Orogeny in the Scandinavian Caledonides (COSC) scientific drilling project aims to characterise the structure and orogenic processes involved in a major collisional mountain belt by multidisciplinary geoscientific research. Located in western central Sweden, the project has drilled two fully cored deep boreholes into the bedrock of the deeply eroded Early Paleozoic Caledonide Orogen. COSC-1 (2014) drilled a subduction-related allochthon and the associated thrust zone. COSC-2 (2020, this paper) extends this section deeper through the underlying nappes (Lower Allochthon), the main Caledonian décollement, and the upper kilometre of basement rocks. COSC-2 targets include the characterisation of orogen-scale detachments, the impact of orogenesis on the basement below the detachment, and the Early Paleozoic palaeoenvironment on the outer margin of palaeocontinent Baltica. This is complemented by research on heat flow, groundwater flow, and the characterisation of the microbial community in the present hard rock environment of the relict mountain belt. COSC-2 successfully, and within budget, recovered a continuous drill core to 2276 m depth. The retrieved geological section is partially different from the expected geological section with respect to the depth to the main décollement and the expected rock types. Although the intensity of synsedimentary deformation in the rocks in the upper part of the drill core might impede the analysis of the Early Paleozoic palaeoenvironment, the superb quality of the drill core and the borehole will facilitate research on the remaining targets and beyond. Protocols for sampling in the hard rock environment and subsequent sample preservation were established for geomicrobiological research and rock mechanical testing. For the former, a sparse sample series along the entire drill core was taken, while the target of the latter was the décollement. COSC-2 was surveyed by a comprehensive post-drilling downhole logging campaign and a combined borehole/land seismic survey in autumn 2021. This paper provides an overview of the COSC-2 (International Continental Scientific Drilling Project – ICDP 5054_2_A and 5054_2_B boreholes) operations and preliminary results. It will be complemented by a detailed operational report and data publication.
14.	Klopotek, Grzegorz, 1990 (author) Observations of Artificial Radio Sources within the Framework of Geodetic Very Long Baseline Interferometry 2020 Doctoral thesis (other academic/artistic)abstract Very long baseline interferometry (VLBI) is a mature and fascinating technique with unique and indisputable applications in radio astronomy, planetary sciences, and space geodesy. The latter discipline is a field of science facilitating our understanding of various global-scale phenomena connected to Earth dynamics. Space geodesy provides, in the microwave regime, accurate and long-term stable celestial and terrestrial reference frames, to which those environmental changes can be properly referenced and their spatio-temporal variability can be subsequently accurately investigated. In order to attain better knowledge on complex, and yet subtle, geodynamical phenomena of scientific and economic importance, there is a need for an improved global geodetic infrastructure and enhanced quality of space-geodetic measurements. The common effort of the geodetic community known as the Global Geodetic Observing System (GGOS) shall address that need and provide the highest possible accuracy of geodetic products and reference frames as well as the high consistency across space-geodetic techniques. The ambitious goals of GGOS necessitate appropriate changes to be made also in the area of geodetic/astrometric VLBI, realized at preset in the form of the VLBI Global Observing System (VGOS), a next-generation system aiming to meet the requirements of GGOS and deliver geodetic products with an unprecedented quality. In order to make VGOS succeed, the key components of this complex system need to be refined, including also new observing concepts and scheduling strategies, in order to fully exploit the enhanced performance that this system can bring. Thanks to its characteristics, VGOS creates also a great opportunity for extending the current VLBI research with new applications, for the benefit of the scientific community and society at large. The subject of this thesis concerns observations of artificial radio sources within the framework of geodetic VLBI, in connection to both the current VLBI system and VGOS. This includes information on the combination of observations of natural radio sources and satellite/lunar objects as well as benefits and challenges related to the observing strategy and the technical feasibility of the presented concept. The thesis is based mostly on extensive simulation studies concerning objects on the Moon and geodetic Earth-orbiting satellites, but it also includes an analysis of VLBI observations of the lunar lander performed during dedicated experiments and with a global network of radio telescopes. The information content of this thesis may be treated as a further step towards global observations of artificial radio sources with VLBI in the VGOS era and stimulate new observing concepts for space geodesy.
15.	MINEARC WEBINAR : Mineral resource and sustainable exploration, 23–24 April 2024, Abstracts 2024 Editorial proceedings (other academic/artistic)
16.	Carn, Simon, et al. (author) Daily monitoring of Ecuadorian volcanic degassing from space 2008 In: Journal of Volcanology and Geothermal Research. - 0377-0273. ; 176:1, s. 141-150 Journal article (peer-reviewed)abstract We present daily measurements of sulfur dioxide (SO2) emissions from active volcanoes in Ecuador and southern Colombia between September 2004 and September 2006, derived from the Ozone Monitoring Instrument (OMI) on NASA's EOS/Aura satellite. OMI is an ultraviolet/visible spectrometer with an unprecedented combination of spatial and spectral resolution, and global coverage, that permits daily measurements of passive volcanic degassing from space. We use non-interactive processing methods to automatically extract daily SO2 burdens and information on SO2 sources from the OMI datastream. Maps of monthly average SO2 vertical columns retrieved by OMI over Ecuador and S. Colombia are also used to illustrate variations in regional SO2 loading and to pinpoint sources. The dense concentration of active volcanoes in Ecuador provides a stringent test of OMI's ability to distinguish SO2 from multiple emitting sources. Our analysis reveals that Tungurahua, Reventador and Galeras were responsible for the bulk of the SO2 emissions in the region in the timeframe of our study, with no significant SO2 discharge detected from Sangay. At Galeras and Reventador, we conclude that OMI can detect variations in SO2 release related to cycles of conduit sealing and degassing, which are a critical factor in hazard assessment. The OMI SO2 data for Reventador are the most extensive sequence of degassing measurements available for this remote volcano, which dominated regional SO2 production in June–August 2005. At Tungurahua, the OMI measurements span the waning stage of one eruptive cycle and the beginning of another, and we observe increasing SO2 burdens in the months prior to explosive eruptions of the volcano in July and August 2006. Cumulative SO2 loadings measured by OMI yield a total of ~ 1.16 Tg SO2 emitted by volcanoes on mainland Ecuador/S. Colombia between September 2004 and September 2006; as much as 95% of this SO2 may originate from non-eruptive degassing. Approximate apportionment of the total SO2 loading indicates that ~ 40% originated from Tungurahua, with ~ 30% supplied by both Reventador and Galeras. These measurements of volcanic SO2 degassing in Ecuador confirm OMI's potential as an effective, economical and risk-free tool for daily monitoring of SO2 emissions from hazardous volcanoes.
17.	Hobiger, Thomas, 1978, et al. (author) Software-Defined Radio Direct Correlation GNSS Reflectometry by Means of GLONASS 2016 In: IEEE Journal of Selected Topics in Applied Earth Observations and Remote Sensing. - 2151-1535 .- 1939-1404. ; 9:10, s. 4834-4842 Journal article (peer-reviewed)abstract Ground-based GNSS reflectometry (GNSS-R)systems can be realized by different means. The concept ofcorrelation between direct and reflected GNSS signals is basicallypossible with all GNSS systems. However, using signals fromthe Russian GLONASS system simplifies the signal processingso that software-defined radio (SDR) components can be usedat replace expensive hardware solutions. This paper discusseshow such a solution, called GLONASS-R, can be realized usingentirely off-the-shelf components. Field tests with such a systemdemonstrate the capability to monitor sea surface heights with aprecision of 3 cm or better even with a sampling rate of 1.5 Hz.The flexibility of a SDR and the simple concept of GLONASS-Rallow build such a system with low costs and adapt it to the needsof any ground-based GNSS-R problem.
18.	Arellano, Santiago, 1981 (author) Studies of Volcanic Plumes with Remote Spectroscopic Sensing Techniques -DOAS and FTIR measurements on volcanoes of the Network for Observation of Volcanic and Atmospheric Change- 2014 Doctoral thesis (other academic/artistic)abstract Volcanism is a rich geodynamical process, closely linked to the origin and ongoing evolution of the lithosphere, atmosphere, hydrosphere and biosphere. Humans have benefited from the resources provided by volcanoes but also been threatened by the dangers of volcanic eruptions, which accurate prediction remains elusive. This is partly due to the inherent complexity of volcanic systems and partly because of the difficulty of conducting key observations to characterize them. In particular, since the segregation and escape of magmatic volatiles are essential mechanisms behind volcanic eruptions, monitoring the intensity and composition of the resulting emissions in the atmosphere is essential to characterize the state of volcanic activity; however, their direct measurement is not always feasible.Remote spectroscopic sensing, whereby gas species can be quantified by their spectral signatures in electromagnetic radiation gathered at a prudent distance from the plume, offers the possibility to conduct reliable and sustainable monitoring of volcanic emissions. To expand the remote sensing capabilities of volcanological observatories the Network for Observation of Volcanic and Atmospheric Change (NOVAC) was established in 2005. The central theme of this thesis is the acquisition, analysis and interpretation of measurements of volcanic gas emissions on volcanoes of NOVAC. Measurements of the mass flow rate of SO2 and the molar ratios of SO2 against BrO and HCl were obtained by scanning-Differential Optical Absorption Spectroscopy (DOAS) of scattered solar ultraviolet radiation and by Fourier-Transform Spectroscopy (FTIR) of direct solar infrared radiation. The uncertainty of the measurements is characterized and methods for combining observations from different sensors implemented. Statistical and physical models of degassing are proposed for selected volcanoes of the network. The resulting time-series of emission on 16 volcanoes is one of the more detailed compilations of volcanic degassing in the last decade, particularly from passive emissions which are difficult to detect from satellite platforms. This work aims at advancing our knowledge of volcanic eruptions for a better mitigation of their risks.
19.	Kirchner, N., et al. (author) Capabilities and limitations of numerical ice sheet models : a discussion for Earth-scientists and modelers 2011 In: Quaternary Science Reviews. - : Elsevier. - 0277-3791 .- 1873-457X. ; 30:25-26, s. 3691-3704 Journal article (peer-reviewed)abstract The simulation of dynamically coupled ice sheet, ice stream, and ice shelf-systems poses a challenge to most numerical ice sheet models. Here we review present ice sheet model limitations targeting a broader audience within Earth Sciences, also those with no specific background in numerical modeling, in order to facilitate cross-disciplinary communication between especially paleoglaciologists, marine and terrestrial geologists, and numerical modelers. The ‘zero order’(Shallow Ice Approximation, SIA)-,‘higher order’-, and‘full Stokes’ice sheet models are described conceptually and complemented by an outline of their derivations. We demonstrate that higher order models are required to simulate coupled ice sheetice shelf and ice sheet-ice stream systems, in particular if the results are aimed to complement spatial ice flow reconstructions based on higher resolution geological and geophysical data. The zero order SIA model limitations in capturing ice stream behavior are here illustrated by conceptual simulations of a glaciation on Svalbard. The limitations are obvious from the equations comprising a zero order model. However, under certain circumstances, simulation results may falsely give the impression that ice streams indeed are simulated with a zero order SIA model.
20.	Lages, J., et al. (author) Volcanic Gas Emissions Along the Colombian Arc Segment of the Northern Volcanic Zone (CAS-NVZ): Implications for volcano monitoring and volatile budget of the Andean Volcanic Belt 2019 In: Geochemistry, Geophysics, Geosystems. - 1525-2027. ; 20:11, s. 5057-5081 Journal article (peer-reviewed)abstract Studying spatial and temporal trends in volcanic gas compositions and fluxes is crucial both to volcano monitoring and to constrain the origin and recycling efficiency of volatiles at active convergent margins. New volcanic gas compositions and volatile fluxes are here reported for Nevado del Ruiz, Galeras, and Purace, three of the most persistently degassing volcanoes located in the Colombian Arc Segment of the Northern Volcanic Zone. At Nevado del Ruiz, from 2014 to 2017, plume emissions showed an average molar CO2/S-T ratio of 3.9 +/- 1.6 (S-T is total sulfur, S). Contemporary, fumarolic chemistry at Galeras progressively shifted toward low-temperature, S-depleted fumarolic gas discharges with an average CO2/S-T ratio in excess of 10 (6.0-46.0, 2014-2017). This shift in volcanic gas compositions was accompanied by a concurrent decrease in SO2 emissions, confirmed on 21 March 2017 by high-resolution ultraviolet camera-based SO2 fluxes of similar to 2.5 kg/s (similar to 213 t/day). For comparison, SO2 emissions remained high at Nevado del Ruiz (weighted average of 8 kg/s) between 2014 and 2017, while Purace maintained rather low emission levels (<1 kg/s of SO2, CO2/SO2 approximate to 14). We here estimate carbon dioxide fluxes for Nevado del Ruiz, Galeras, and Purace of similar to 23, 30, and 1 kg/s, respectively. These, combined with recent CO2 flux estimates for Nevado del Huila of similar to 10 kg/s (similar to 860 t/day), imply that this arc segment contributes about 50% to the total subaerial CO2 budget of the Andean Volcanic Belt. Furthermore, our work highlights the northward increase in carbon-rich sediment input into the mantle wedge via slab fluids and melts that is reflected in magmatic CO2/S-T values far higher than those reported for Southern Volcanic Zone and Central Volcanic Zone volcanoes. We estimate that about 20% (similar to 1.3 Mt C/year) of the C being subducted (similar to 6.19 Mt C/year) gets resurfaced through subaerial volcanic gas emissions in Colombia (Nevado del Ruiz similar to 0.7 Mt C/year). As global volcanic volatile fluxes continue to be quantified and refined, the contribution from this arc segment should not be underestimated.
21.	Salas Romero, Silvia (author) Multidisciplinary Near-Surface Investigation of a Quick-Clay Landslide Prone Area in Southwest Sweden 2019 Doctoral thesis (other academic/artistic)abstract Quick-clay landslides are considered one of the most important geohazards in Sweden, Norway, and Canada. The deposits involved are glacial and postglacial clays and silty clays, which are very sensitive to increased stress that may collapse their structure and cause liquefaction.A multidisciplinary approach was adopted in this study of quick clays in an area of southwest Sweden that is prone to landslides. It was mainly based on geophysical methods, but was complemented and validated with geotechnical, geological, and hydrological data. Downhole geophysics, land and river reflection seismics, radio magnetotellurics, P-wave refraction tomography, magnetics, and multichannel analysis of surface waves comprised the main geophysical methods used in this research. Laboratory measurements of core samples, such as grain size analysis, mineral magnetic properties, fossil content, X-ray fluorescence, cation exchange capacity, X-ray powder diffraction, electrical conductivity, and pH were also taken. Hydrological modelling was used to obtain information on the properties of groundwater within a coarse-grained layer, given the importance of this information in the formation of quick clays.The evaluation of the physico-chemical properties of the coarse-grained layer revealed high values of magnetic susceptibility, probably as a result of fluvial sorting, which tends to accumulate denser minerals such as magnetite. Potential quick clays were visually observed above this layer, and their presence was also confirmed by geotechnical data acquired in previous studies. Marine fossils identified within the coarse-grained layer confirmed the glaciomarine origin of the clays. Geophysical results revealed the presence of large-scale structures, an undulating fractured bedrock and a coarse-grained layer sandwiched between clay deposits, with leached sediments on top and unleached sediments below. This layer, important for the development of quick clays in the area, was 3D modelled in a regional context. Magnetic data also revealed that the coarse-grained layer together with quick clays, have the potential to act as a sliding prone layer. Multichannel analysis of surface waves helped to geotechnically characterize the area. Although the results could not reach the deeper layers, it did yield information about the shallower layers of clay, silt and sand. The VS30 values indicated the presence of soft soils, as well as soft clays/silts with high plasticity index and high water content.This PhD is expected to improve the current knowledge of quick-clay landslides and how they are preconditioned. Climate change will probably affect the study area in the near future, most likely increasing landslide risk, therefore, research should continue and advance to new levels. Application of other geophysical methods such as borehole or geophysical monitoring, and induced polarization, could provide more information about the formation of quick clays and associated landslides.
22.	Wang, X. J., et al. (author) Contrasting characteristics, changes, and linkages of permafrost between the Arctic and the Third Pole 2022 In: Earth-Science Reviews. - : Elsevier BV. - 0012-8252. ; 230 Journal article (peer-reviewed)abstract Permafrost degradation poses serious threats to both natural and human systems through its influence on ecological-hydrological processes, infrastructure stability, and the climate system. The Arctic and the Third Pole (Tibetan Plateau, TP hereafter) are the two northern regions on Earth with the most extensive permafrost areas. However, there is a lack of systematic comparisons of permafrost characteristics and its climate and ecoenvironment between these two regions and their susceptibility to disturbances. This study provides a comprehensive review of the climate, ecosystem characteristics, ground temperature, permafrost extent, and active-layer thickness, as well as the past and future changes in permafrost in the Arctic and the TP. The potential consequences associated with permafrost degradation are also examined. Lastly, possible connections between the two regions through land-ocean-atmosphere interactions are explored. Both regions have experienced dramatic warming in recent decades, characterized by Arctic amplification and elevation-dependent warming on the TP. Permafrost temperatures have increased more rapidly in the Arctic than on the TP, and will likely be reinforced under a future high emission scenario. Near-surface permafrost extents are projected to shrink in both regions in the coming decades, with a more dramatic decline in the TP. The active layer on the TP is thicker and has substantially deepened, and is projected to thicken more than in the Arctic. Widespread permafrost degradation increases geohazard risk and has already wielded considerable effects on the human and natural systems. Permafrost changes have also exerted a pronounced impact on the climate system through changes in permafrost carbon and land-atmosphere interactions. Future research should involve comparative studies of permafrost dynamics in both regions that integrate long-term observations, high-resolution satellite measurements, and advanced Earth System models, with emphasis on linkages between the two regions.
23.	Chen, Hans, 1988, et al. (author) A robust mode of climate variability in the Arctic: The Barents Oscillation 2013 In: Geophysical Research Letters. - : American Geophysical Union (AGU). - 0094-8276 .- 1944-8007. ; 40:11, s. 2856-2861 Journal article (peer-reviewed)abstract The Barents Oscillation (BO) is an anomalous wintertime atmospheric circulation pattern in the Northern Hemisphere that has been linked to the meridional flow over the Nordic Seas. There are speculations that the BO has important implications for the Arctic climate; however, it has also been suggested that the pattern is an artifact of Empirical Orthogonal Function (EOF) analysis due to an eastward shift of the Arctic Oscillation/North Atlantic Oscillation (AO/NAO). In this study, EOF analyses are performed to show that a robust pattern resembling the BO can be found during different time periods, even when the AO/NAO is relatively stationary. This BO has a high and stable temporal correlation with the geostrophic zonal wind over the Barents Sea, while the contribution from the AO/NAO is small. The surface air temperature anomalies over the Barents Sea are closely associated with this mode of climate variability.
24.	Cai, Yiting, 1994 (author) The impact of loading-induced stress variation on the seismicity of active faults 2023 Licentiate thesis (other academic/artistic)abstract Surface loads such as the ocean, atmosphere, and continental water, constantly modify the stress field of the Earth’s crust. Most earthquakes occur at tectonic plate boundaries and such stress perturbations on the active faults at the plate boundaries may trigger earthquakes. Several previous studies reported that tides or hydrological loading could modulate seismicity in some areas. We elaborate on this idea and further investigate the accumulative effect of various loadings. In this work, we compute the total Coulomb stress change created by hydrological loading, atmospheric loading, and non-tidal ocean loading from 2011 to 2016 in the Kamchatka-Kuril Islands-Japan region, and then compare it to the background earthquakes in the same period. This thesis contributes to our understanding of the complex interactions between surface loading and induced seismicity, which has important implications for earthquake hazard assessment and risk mitigation.
25.	Haas, Rüdiger, 1966, et al. (author) Twin Telescope and Tide Gauge Plans for the Onsala Space Observatory 2014 In: IVS General Meeting 2014, Shanghai. ; , s. 205-209 Conference paper (other academic/artistic)
26.	Löfgren, Johan, 1983, et al. (author) Sea level measurements using multi-frequency GPS and GLONASS observations 2014 In: Eurasip Journal on Advances in Signal Processing. - : Springer Science and Business Media LLC. - 1687-6172 .- 1687-6180. ; 2014:1 Journal article (peer-reviewed)abstract Global Positioning System (GPS) tide gauges have been realized in different configurations, e.g., with one zenith-looking antenna, using the multipath interference pattern for signal-to-noise ratio (SNR) analysis, or with one zenith- and one nadir-looking antenna, analyzing the difference in phase delay, to estimate the sea level height. In this study, for the first time, we use a true Global Navigation Satellite System (GNSS) tide gauge, installed at the Onsala Space Observatory. This GNSS tide gauge is recording both GPS and Globalnaya Navigatsionnaya Sputnikovaya Sistema (GLONASS) signals and makes it possible to use both the one- and two-antenna analysis approach. Both the SNR analysis and the phase delay analysis were evaluated using dual-frequency GPS and GLONASS signals, i.e., frequencies in the L-band, during a 1-month-long campaign. The GNSS-derived sea level results were compared to independent sea level observations from a co-located pressure tide gauge and show a high correlation for both systems and frequency bands, with correlation coefficients of 0.86 to 0.97. The phase delay results show a better agreement with the tide gauge sea level than the SNR results with root-mean-square differences of 3.5 cm (GPS L1 and L2) and 3.3/3.2 cm (GLONASS L1/L2 bands) compared to 4.0/9.0 cm (GPS L1/L2 ) and 4.7/8.9 cm (GLONASS L1/L2 bands). GPS and GLONASS show similar performance in the comparison, and the results show that for the phase delay analysis, it is possible to use both frequencies, whereas for the SNR analysis, the L2 band should be avoided if other signals are available. Note that standard geodetic receivers using code-based tracking, i.e., tracking the un-encrypted C/A-code on L1 and using the manufacturers’ proprietary tracking method for L2 , were used. Signals with the new C/A-code on L2 , the so-called L2C, were not tracked.Using wind speed as an indicator for sea surface roughness, we find that the SNR analysis performs better in rough sea surface conditions than the phase delay analysis. The SNR analysis is possible even during the highest wind speed observed during this campaign (17.5 m/s), while the phase delay analysis becomes difficult for wind speeds above 6 m/s.
27.	Dehkordi, Seyed Emad, et al. (author) Effect of groundwater flow in vertical and horizontal fractures on borehole heat exchanger temperatures 2015 In: Bulletin of Engineering Geology and the Environment. - : Springer Berlin/Heidelberg. - 1435-9529 .- 1435-9537. ; 74:2, s. 479-491 Journal article (peer-reviewed)abstract Vertical closed loop systems, also known as borehole heat exchangers (BHEs), are a popular way of extracting the ground source heat energy. Primary factors affecting the performance of BHEs are the thermal and hydrogeological properties of the subsurface. Groundwater flow is known to potentially influence heat transport and system performance. The effect of groundwater movement is more commonly studied under homogeneous conditions. However, in heterogeneous fractured rocks, BHEs are more common than horizontal or open loops due to lack of sufficient soil layers and productive aquifers. The finite-element modelling shows that fractures can play an important role in BHE functioning. Especially, vertical open fractures (≥1 mm) near the borehole (≤10 m) can have a considerable impact. Although increase in fracture aperture continuously affects the subsurface and BHE temperatures, the increase in its effect progressively lessens. Depending on the distance and aperture, one major fracture influencing the BHE operation performance can be identified; yet a larger number of fractures may govern heat transport (thermal plume outline) and thermal recovery. Individually, horizontal fractures may have less influence than vertical fractures. However, as the density of horizontal fractures increases, their impact can be major, exceeding that of fracture aperture. In particular, we propose that measurements of rock thermal properties be combined with fracture mapping, to better analyse the thermal response testing results and integrate the configuration of fractures in design and layout of the BHE(s). This is particularly valid for (vertical) fractures not intersecting with the borehole.
28.	Dehkordi, Seyed Emad, et al. (author) Impact of Groundwater Flow and Energy Load on Multiple Borehole Heat Exchangers 2014 In: Ground Water. - : John Wiley & Sons. - 0017-467X .- 1745-6584. Journal article (peer-reviewed)abstract The effect of array configuration, that is, number, layout, and spacing, on the performance of multiple borehole heat exchangers (BHEs) is generally known under the assumption of fully conductive transport. The effect of groundwater flow on BHE performance is also well established, but most commonly for single BHEs. In multiple-BHE systems the effect of groundwater advection can be more complicated due to the induced thermal interference between the boreholes. To ascertain the influence of groundwater flow and borehole arrangement, this study investigates single- and multi-BHE systems of various configurations. Moreover, the influence of energy load balance is also examined. The results from corresponding cases with and without groundwater flow as well as balanced and unbalanced energy loads are cross-compared. The groundwater flux value, 10−7 m/s, is chosen based on the findings of previous studies on groundwater flow interaction with BHEs and thermal response tests. It is observed that multi-BHE systems with balanced loads are less sensitive to array configuration attributes and groundwater flow, in the long-term. Conversely, multi-BHE systems with unbalanced loads are influenced by borehole array configuration as well as groundwater flow; these effects become more pronounced with time, unlike when the load is balanced. Groundwater flow has more influence on stabilizing loop temperatures, compared to array characteristics. Although borehole thermal energy storage (BTES) systems have a balanced energy load function, preliminary investigation on their efficiency shows a negative impact by groundwater which is due to their dependency on high temperature gradients between the boreholes and surroundings.
29.	Högberg, Charlotta, et al. (author) The SPARC water vapour assessment II: Profile-to-profile and climatological comparisons of stratospheric δd(H2O) observations from satellite 2019 In: Atmospheric Chemistry and Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 19:4, s. 2497-2526 Journal article (peer-reviewed)abstract Within the framework of the second SPARC (Stratosphere-troposphere Processes And their Role in Climate) water vapour assessment (WAVAS-II), we evaluated five data sets of δD(H2O) obtained from observations by Odin/SMR (Sub-Millimetre Radiometer), Envisat/MIPAS (Environmental Satellite/Michelson Interferometer for Passive Atmospheric Sounding), and SCISAT/ACE-FTS (Science Satellite/Atmospheric Chemistry Experiment - Fourier Transform Spectrometer) using profile-to-profile and climatological comparisons. These comparisons aimed to provide a comprehensive overview of typical uncertainties in the observational database that could be considered in the future in observational and modelling studies. Our primary focus is on stratospheric altitudes, but results for the upper troposphere and lower mesosphere are also shown. There are clear quantitative differences in the measurements of the isotopic ratio, mainly with regard to comparisons between the SMR data set and both the MIPAS and ACE-FTS data sets. In the lower stratosphere, the SMR data set shows a higher depletion in δD than the MIPAS and ACE-FTS data sets. The differences maximise close to 50hPa and exceed 200%. With increasing altitude, the biases decrease. Above 4hPa, the SMR data set shows a lower δD depletion than the MIPAS data sets, occasionally exceeding 100%. Overall, the δD biases of the SMR data set are driven by HDO biases in the lower stratosphere and by H2O biases in the upper stratosphere and lower mesosphere. In between, in the middle stratosphere, the biases in δD are the result of deviations in both HDO and H2O. These biases are attributed to issues with the calibration, in particular in terms of the sideband filtering, and uncertainties in spectroscopic parameters. The MIPAS and ACE-FTS data sets agree rather well between about 100 and 10hPa. The MIPAS data sets show less depletion below approximately 15hPa (up to about 30%), due to differences in both HDO and H2O. Higher up this behaviour is reversed, and towards the upper stratosphere the biases increase. This is driven by increasing biases in H2O, and on occasion the differences in δD exceed 80%. Below 100hPa, the differences between the MIPAS and ACE-FTS data sets are even larger. In the climatological comparisons, the MIPAS data sets continue to show less depletion in δD than the ACE-FTS data sets below 15hPa during all seasons, with some variations in magnitude. The differences between the MIPAS and ACE-FTS data have multiple causes, such as differences in the temporal and spatial sampling (except for the profile-to-profile comparisons), cloud influence, vertical resolution, and the microwindows and spectroscopic database chosen. Differences between data sets from the same instrument are typically small in the stratosphere. Overall, if the data sets are considered together, the differences in δD among them in key areas of scientific interest (e.g. tropical and polar lower stratosphere, lower mesosphere, and upper troposphere) are too large to draw robust conclusions on atmospheric processes affecting the water vapour budget and distribution, e.g. the relative importance of different mechanisms transporting water vapour into the stratosphere.
30.	Haas, Rüdiger, 1966, et al. (author) Observing UT1‑UTC with VGOS 2021 In: Earth, Planets and Space. - : Springer Science and Business Media LLC. - 1880-5981 .- 1343-8832. ; 73:1 Journal article (peer-reviewed)abstract We present first results for the determination of UT1-UTC using the VLBI Global Observing System (VGOS). During December 2019 through February 2020, a series of 1 h long observing sessions were performed using the VGOS stations at Ishioka in Japan and the Onsala twin telescopes in Sweden. These VGOS-B sessions were observed simultaneously to standard legacy S/X-band Intensive sessions. The VGOS-B data were correlated, post-correlation processed, and analysed at the Onsala Space Observatory. The derived UT1-UTC results were compared to corresponding results from standard legacy S/X-band Intensive sessions (INT1/INT2), as well as to the final values of the International Earth Rotation and Reference Frame Service (IERS), provided in IERS Bulletin B. The VGOS-B series achieves 3–4 times lower formal uncertainties for the UT1-UTC results than standard legacy S/X-band INT series. The RMS agreement w.r.t. to IERS Bulletin B is slightly better for the VGOS-B results than for the simultaneously observed legacy S/X-band INT1 results, and the VGOS-B results have a small bias only with the smallest remaining standard deviation.
31.	Hobiger, Thomas, 1978, et al. (author) Hard- and software tools for the education of Geodetic VLBI 2016 In: 9th IVS General Meeting, March 2016, Johannesburg, South Africa. Conference paper (other academic/artistic)abstract Onsala Space Observatory hosts two 2.3 m radio telescopes called SALSA ("Such a lovely small antenna") which are utilised to bring front-line interactive astronomy to the classroom. Until now SALSA has been used for astronomical educational purposes solely, in particular demonstrating the concept of single dish measurements. However, it is possible to combine both SALSAs to an interferometer by making use of hardware which has been developed for software-defined radio. In doing so, one can utilise the SALSA antenna pair as a student demonstrator for geodetic Very Long Baseline Interferometry. We will discuss the COTS hardware components that are necessary to turn the SALSA installation into an interferometer. Moreover, we will show how a simple correlator has been used to detect fringes and provide single-band delays. Such delays were then processed with our analysis software c5++. We are going to discuss how it is possible to mimic the complete processing chain of geodetic VLBI and how this can be used for training of students and other interested parties.
32.	Kulmala, M., et al. (author) General overview: European Integrated project on Aerosol Cloud Climate and Air Quality interactions (EUCAARI) - integrating aerosol research from nano to global scales 2011 In: Atmospheric Chemistry And Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 11:24, s. 13061-13143 Journal article (peer-reviewed)abstract In this paper we describe and summarize the main achievements of the European Aerosol Cloud Climate and Air Quality Interactions project (EUCAARI). EUCAARI started on 1 January 2007 and ended on 31 December 2010 leaving a rich legacy including: (a) a comprehensive database with a year of observations of the physical, chemical and optical properties of aerosol particles over Europe, (b) comprehensive aerosol measurements in four developing countries, (c) a database of airborne measurements of aerosols and clouds over Europe during May 2008, (d) comprehensive modeling tools to study aerosol processes fron nano to global scale and their effects on climate and air quality. In addition a new Pan-European aerosol emissions inventory was developed and evaluated, a new cluster spectrometer was built and tested in the field and several new aerosol parameterizations and computations modules for chemical transport and global climate models were developed and evaluated. These achievements and related studies have substantially improved our understanding and reduced the uncertainties of aerosol radiative forcing and air quality-climate interactions. The EUCAARI results can be utilized in European and global environmental policy to assess the aerosol impacts and the corresponding abatement strategies.
33.	Mårtensson, Stig-Göran (author) Simple computation of coordinates and uncertainty of ‘hidden’ points from two coordinated points that are collinear with the hidden point 2022 In: Survey review - Directorate of Overseas Surveys. - : Informa UK Limited. - 0039-6265 .- 1752-2706. ; 54:387, s. 543-553 Journal article (peer-reviewed)abstract Estimating the measurement uncertainties of coordinates of points that are not accessible by direct geodetic surveying (hidden points) is the topic of this study. The simplicity by which the uncertainties can be found for such hidden points when practicing indirect observations by total station or by Global Navigation Satellite System (GNSS) is demonstrated. A three-dimensional solution is obtained by total station observations using a two-prism hidden-point rod and a two-dimensional solution by GNSS observations on the ground. An intention with the study is that methods and results should apply for general geodetic purposes, like engineering surveying. The derived uncertainty formulae have been verified by Monte Carlo simulations. An important finding is their geometric dependence by the quotient between the two distances involved when two coordinated points are collinear with a third hidden point.
34.	Xu, Shulan, et al. (author) Effects of compartmental model structure and long-term inflow on model predictions 2005 In: Radioprotection - Revue de la Societé Francaise de Radioprotection. - : EDP Sciences. - 0033-8451 .- 1769-700X. ; 40:1, s. 477-483 Journal article (peer-reviewed)abstract Model predictions of solute transport in a wetland were compared with tracer experimental data to illustrate that the number of compartments in a compartmental model should be selected according to certain rules to accurately describe the transport process. If the input pulse is short, the model structure affects the output significantly. The temporal moments of the residence time distribution was obtained from a general solution of the compartmental model in the Laplace domain derived with an arbitrary inflow pollutograph. The variance of the residence time can be used as a useful tool to analyse the effect of model structure and long-term inflow pollutograph on the response of the model predictions.
35.	Bagherbandi, Mohammad, et al. (author) Moho depth uncertainties in the Vening-Meinesz Moritz inverse problem of isostasy 2014 In: Studia Geophysica et Geodaetica. - : Springer Science and Business Media LLC. - 0039-3169 .- 1573-1626. ; 58:2, s. 227-248 Journal article (peer-reviewed)abstract We formulate an error propagation model based on solving the Vening Meinesz-Moritz (VMM) inverse problem of isostasy. The system of observation equations in the VMM model defines the relation between the isostatic gravity data and the Moho depth by means of a second-order Fredholm integral equation of the first kind. The corresponding error model (derived in a spectral domain) functionally relates the Moho depth errors with the commission errors of used gravity and topographic/bathymetric models. The error model also incorporates the non-isostatic bias which describes the disagreement, mainly of systematic nature, between the isostatic and seismic models. The error analysis is conducted at the study area of the Tibetan Plateau and Himalayas with the world largest crustal thickness. The Moho depth uncertainties due to errors of the currently available global gravity and topographic models are estimated to be typically up to 1-2 km, provided that the GOCE gravity gradient observables improved the medium-wavelength gravity spectra. The errors due to disregarding sedimentary basins can locally exceed similar to 2 km. The largest errors (which cause a systematic bias between isostatic and seismic models) are attributed to unmodeled mantle heterogeneities (including the core-mantle boundary) and other geophysical processes. These errors are mostly less than 2 km under significant orogens (Himalayas, Ural), but can reach up to similar to 10 km under the oceanic crust.
36.	Mouyen, Maxime, 1982, et al. (author) Expected temporal absolute gravity change across the Taiwanese Orogen, a modeling approach 2009 In: Journal of Geodynamics. - : Elsevier BV. - 0264-3707. ; 48:3-5 Journal article (peer-reviewed)abstract The island of Taiwan is located on the convergent boundary between the Philippine Sea plate and the Chinese continental margin. It offers very active mountain building and collapsing processes well illustrated by the rugged topography, rapid uplift and denudation, young tectonic landforms, active faulting and numerous earthquakes. In this paper, using simple models, we have estimated vertical movements and associated absolute gravity variations which can be expected along a profile crossing the southern part of the island and probably suffering the highest rates of rising. The two different tectonic styles proposed for the island, thin-skinned and thick-skinned, were taken into account. Horizontal and vertical movements were modeled by an elastic deformation code. Gravity variations due to these deformations are then modeled at a second step. They are dominated by plate and free-air effects, i.e. elevation of the topography, with several μGal yr-1. By comparison, gravity changes generated by mass transfers are weak: maximum 0.1 μGal yr-1 with the thin-skinned tectonic and 0.3 μGal yr-1 with the thick-skinned tectonic. Though elastic rheology has limitations, this modeling offers interesting results on what gravity signal can be expected from the AGTO project (Absolute Gravity in the Taiwanese Orogen), which proposes to study the dynamic of these mountain ranges using absolute gravimetry (AG) and also including relative gravimetry (RG) and GPS measurements.
37.	Rajner, Marcin, 1982 (author) Detection of ice mass variation using GNSS measurements at Svalbard 2018 In: Journal of Geodynamics. - : Elsevier BV. - 0264-3707. ; 121, s. 20-25 Journal article (peer-reviewed)abstract We compare observed uplift rates of Global Navigation Satellite Systems (GNSS) with geophysical predictions at sites located on Spitsbergen. We show here that using modern postglacial rebound models, realistic mass balance for Present Day Ice Melting (PDIM) and taking the deglaciation of the Little Ice Age (LIA) into account, we can close the overall uplift budget at a level of a few millimetres per year. For this study we used GNSS data from well-established geodetic sites in Ny-Ålesund and the new data from Hornsund. The significant increase of uplift rates since the beginning of 2011 was observed at both gnss sites. These height changes are attributed to recent increased ice mass loss of 6.0 Gt yr−1 for Svalbard. The total mass loss is estimated at 14.7 Gt yr−1. Ice unloading caused also a noticeable increase of distance between Ny-Ålesund and Hornsund. We show that the specific location of the two sites facilitates inference of differential mass loss within the Svalbard Archipelago.
38.	Sjöberg, Lars E., et al. (author) A study on the Fennoscandian post-glacial rebound as observed by present-day uplift rates and gravity field model GOCO02S 2013 In: Acta Geodaetica et Geophysica. - : Springer Science and Business Media LLC. - 2213-5812 .- 2213-5820 .- 1217-8977 .- 1587-1037. ; 48:3, s. 317-331 Journal article (peer-reviewed)abstract Repeated absolute gravity measurements in Fennoscandia have revealed that the on-going post-glacial rebound can be regarded as a pure viscous flow of mantle mass of density 3390 kg/m(3) towards the central part of the region caused by a gravity/uplift rate of -0.167 mu Gal/mm. Our model estimates the rebound induced rates of changes of surface gravity and geoid height to have peaks of -1.9 mu Gal/yr and 1.6 mm/yr, respectively, the former being consistent with absolute gravity observations. The correlation coefficient of the spherical harmonic representations of the geoid height and uplift rate for the spectral windows between degrees 10 and 70 is estimated to -0.99 +/- 0.006, and the maximum remaining land uplift is estimated to the order of 80 m. Both the (almost) linear increase of relaxation time with degree and the linear relation between geoid height and uplift rate support a model with mass flow in the major part of the mantle and disqualify the model with a flow in a thin channel below the crust. The mean viscosity of the flow in the central uplift region is estimated to 4x10(21) Pa s.
39.	Almqvist, Bjarne, et al. (author) Petrofabric development during experimental partial melting and recrystallization of a mica-schist analogue 2015 In: Geochemistry Geophysics Geosystems. - 1525-2027. ; 16:10, s. 3472-3483 Journal article (peer-reviewed)
40.	Bagherbandi, Mohammad, et al. (author) On the residual isostatic topography effect in the gravimetric Moho determination 2015 In: Journal of Geodynamics. - : Elsevier BV. - 0264-3707 .- 1879-1670. ; 83, s. 28-36 Journal article (peer-reviewed)abstract In classical isostatic models, a uniform crustal density is typically assumed, while disregarding the crustal density heterogeneities. This assumption, however, yields large errors in the Moho geometry determined from gravity data, because the actual topography is not fully isostatically compensated. Moreover, the sub-crustal density structures and additional geodynamic processes contribute to the overall isostatic balance. In this study we investigate the effects of unmodelled density structures and geodynamic processes on the gravity anomaly and the Moho geometry. For this purpose, we define the residual isostatic topography as the difference between actual topography and isostatic topography, which is computed based on utilizing the Vening Meinesz-Moritz isostatic theory. We show that the isostatic gravity bias due to disagreement between the actual and isostatically compensated topography varies between -382 and 596 mGal. This gravity bias corresponds to the Moho correction term of -16 to 25 km. Numerical results reveal that the application of this Moho correction to the gravimetrically determined Moho depths significantly improves the RMS fit of our result with some published global seismic and gravimetric Moho models. We also demonstrate that the isostatic equilibrium at long-to-medium wavelengths (up to degree of about 40) is mainly controlled by a variable Moho depth, while the topographic mass balance at a higher-frequency spectrum is mainly attained by a variable crustal density.
41.	Bagherbandi, Mohammad, Professor (author) Preliminary results of the GRACE and GRACE ofllow-on derived land uplift model in Fennoscandia 2024 Conference paper (other academic/artistic)
42.	Buckland, Philip I., 1973-, et al. (author) The Strategic Environmental Archaeology Database : a resource for international, multiproxy and transdisciplinary studies of environmental and climatic change 2015 Conference paper (peer-reviewed)abstract Climate and environmental change are global challenges which require global data and infrastructure to investigate. These challenges also require a multi-proxy approach, integrating evidence from Quaternary science and archaeology with information from studies on modern ecology and physical processes among other disciplines. The Strategic Environmental Archaeology Database (SEAD http://www.sead.se) is a Swedish based international research e-infrastructure for storing, managing, analysing and disseminating palaeoenvironmental data from an almost unlimited number of analysis methods. The system currently makes available raw data from over 1500 sites (>5300 datasets) and the analysis of Quaternary fossil insects, plant macrofossils, pollen, geochemistry and sediment physical properties, dendrochronology and wood anatomy, ceramic geochemistry and bones, along with numerous dating methods. This capacity will be expanded in the near future to include isotopes, multi-spectral and archaeo-metalurgical data. SEAD also includes expandable climate and environment calibration datasets, a complete bibliography and extensive metadata and services for linking these data to other resources. All data is available as Open Access through http://qsead.sead.se and downloadable software. SEAD is maintained and managed at the Environmental Archaeology Lab and HUMlab at Umea University, Sweden. Development and data ingestion is progressing in cooperation with The Laboratory for Ceramic Research and the National Laboratory for Wood Anatomy and Dendrochronology at Lund University, Sweden, the Archaeological Research Laboratory, Stockholm University, the Geoarchaeological Laboratory, Swedish National Historical Museums Agency and several international partners and research projects. Current plans include expanding its capacity to serve as a data source for any system and integration with the Swedish National Heritage Board's information systems. SEAD is partnered with the Neotoma palaeoecology database (http://www.neotomadb.org) and a new initiative for building cyberinfrastructure for transdisciplinary research and visualization of the long-term human ecodynamics of the North Atlantic funded by the National Science Foundation (NSF).
43.	Drake, Henrik, et al. (author) Extreme fractionation and micro-scale variation of sulphur isotopes during bacterial sulphate reduction in deep groundwater systems 2015 In: Geochimica Et Cosmochimica Acta. - : Elsevier BV. - 0016-7037 .- 1872-9533. ; 161, s. 1-18 Journal article (peer-reviewed)abstract This study conducted at the Aspo Hard Rock Laboratory, SE Sweden, determines the extent and mechanisms of sulphur-isotope fractionation in permanently reducing groundwater in fractured crystalline rock. Two boreholes > 400 m below the ground surface were investigated. In the 17-year-old boreholes, the Al instrumentation pipes had corroded locally (i.e., Al[oxy] hydroxides had formed) and minerals (i.e., pyrite, iron monosulphide, and calcite) had precipitated on various parts on the equipment. By chemically and isotopically comparing the precipitates on the withdrawn instrumentation and the borehole waters, we gained new insight into the dynamics of sulphate reduction, sulphide precipitation, and sulphur-isotope fractionation in deep-seated crystalline-rock settings. An astonishing feature of the pyrite is its huge variability in delta S-34, which can exceed 100 parts per thousand in total (i.e., -47.2 to +53.3 parts per thousand) and 60 parts per thousand over 50 mu m of growth in a single crystal. The values at the low end of the range are up to 71 parts per thousand lower than measured in the dissolved sulphate in the water (20-30 parts per thousand), which is larger than the maximum difference reported between sulphate and sulphide in pure-culture experiments (66 parts per thousand) but within the range reported from natural sedimentary settings. Although single-step reduction seems likely, further studies are needed to rule out the effects of possible S disproportionation. The values at the high end of the range (i.e., high delta S-34(py)) are much higher than could be produced from the measured sulphate under any biogeochemical conditions. This strongly suggests the development of closed-system conditions near the growing pyrite, i.e., the rate of sulphate reduction exceeds the rate of sulphate diffusion in the local fluid near the pyrite, causing the local aqueous phase (and thus the forming pyrite) to become successively enriched in heavy S (S-34). Consequently, the delta S-34 values of the forming pyrite become exceptionally high and strongly decoupled from the delta S-34 values of the sulphate in the bulk fluid. The Al-(oxy) hydroxide and calcite precipitates are explained by a combination of deposit and galvanic corrosion initiated by Al corrosion by H2S produced by sulphate-reducing microorganisms. (C) 2015 Elsevier Ltd. All rights reserved.
44.	Eshagh, Mehdi, 1977-, et al. (author) Quality description for gravimetric and seismic Moho models of Fennoscandia through a combined adjustment 2012 In: Acta Geodaetica et Geophysica Hungarica. - : Akademiai Kiado. - 1217-8977 .- 1587-1037. ; 47:4, s. 388-401 Journal article (peer-reviewed)abstract The gravimetric model of the Moho discontinuity is usually derived based on isostatic adjustment theories considering floating crust on the viscous mantle. In computation of such a model some a priori information about the density contrast between the crust and mantle and the mean Moho depth are required. Due to our poor knowledge about them they are assumed unrealistically constant. In this paper, our idea is to improve a computed gravimetric Moho model, by the Vening Meinesz-Moritz theory, using the seismic model in Fennoscandia and estimate the error of each model through a combined adjustment with variance component estimation process. Corrective surfaces of bi-linear, bi-quadratic, bi-cubic and multi-quadric radial based function are used to model the discrepancies between the models and estimating the errors of the models. Numerical studies show that in the case of using the bi-linear surface negative variance components were come out, the bi-quadratic can model the difference better and delivers errors of 2.7 km and 1.5 km for the gravimetric and seismic models, respectively. These errors are 2.1 km and 1.6 km in the case of using the bi-cubic surface and 1 km and 1.5 km when the multi-quadric radial base function is used. The combined gravimetric models will be computed based on the estimated errors and each corrective surface.
45.	Klaminder, Jonatan, et al. (author) Carbon mineralization and pyrite oxidation in groundwater : Importance for silicate weathering in boreal forest soils and stream base-flow chemistry 2011 In: Applied Geochemistry. - : Elsevier BV. - 0883-2927 .- 1872-9134. ; 26:3, s. 319-324 Journal article (peer-reviewed)abstract What role does mineralized organic C and sulfide oxidation play in weathering of silicate minerals in deep groundwater aquifers? In this study, how H(2)CO(3), produced as a result of mineralization of organic matter during groundwater transport, affects silicate weathering in the saturated zone of the mineral soil along a 70 m-long boreal hillslope is demonstrated. Stream water measurements of base cations and delta(18)O are included to determine the importance of the deep groundwater system for downstream surface water. The results suggest that H2CO3 generated from organic compounds being mineralized during the lateral transport stimulates weathering at depths between 0.5 and 3 m in the soil. This finding is indicated by progressively increasing concentrations of base cations-, silica- and inorganic C (IC) in the groundwater along the hillslope that co-occur with decreasing organic C (OC) concentrations. Protons derived from sulfide oxidation appear to be an additional driver of the weathering process as indicated by a buildup of SO(4)(2-) in the groundwater during lateral transport and a delta(34)S parts per thousand value of +0.26-3.76 parts per thousand in the deep groundwater indicating S inputs from pyrite. The two identified active acids in the deep groundwater are likely to control the base-flow chemistry of streams draining larger catchments (>1 km(2)) as evident by delta(18)O signatures and base cation concentrations that overlap with that of the groundwater.
46.	Precigout, Jacques, et al. (author) Editorial for Special Issue “Mantle Strain Localization—How Minerals Deform at Deep Plate Interfaces” 2022 In: Minerals. - : MDPI. - 2075-163X. ; 12:12 Journal article (other academic/artistic)abstract Understanding Earth’s interior dynamics, the origin and factors of which maintain the present-day plate-like behavior of the lithosphere on our planet, is one of the main goals of geosciences [...]
47.	Routh, Joyanto, et al. (author) Distribution of arsenic and its mobility in shallow aquifer sediments from Ambikanagar, West Bengal, India 2011 In: Applied Geochemistry. - : Elsevier. - 0883-2927 .- 1872-9134. ; 26:4, s. 505-515 Journal article (peer-reviewed)abstract Sediments from a core retrieved during installation of a shallow drinking water well in Ambikanagar (West Bengal, India) were analyzed for various physical and chemical parameters. The geochemical analyses included: (1) a 4-step sequential extraction scheme to determine the distribution of As between different fractions, (2) As speciation (As(3+) vs. As(5+)), and (3) C, N and S isotopes. The sediments have a low percentage of organic C and N (0.10-0.56% and 0.01-0.05%, respectively). Arsenic concentration is between 2 and 7 mg kg(-1), and it is mainly associated with the residual fraction, less susceptible to chemical weathering. The proportion of As(3+) in these sediments is high and ranges from 24% to 74%. Arsenic in the second fraction (reducible) correlates well with Mn, and in the residual fraction As correlates well with several transition elements. The stable isotope results indicate microbial oxidation of organic matter involving SO(4) reduction. Oxidation of primary sulfide minerals and release of As from reduction of Fe(oxy)hydroxides do not seem important mechanisms in As mobilization. Instead, the dominance of As(3+) and presence of As(5+) reducing microorganisms in this shallow aquifer imply As remobilization involving microbial processes that needs further investigations.
48.	Sjöström, Jenny K., et al. (author) Paleodust deposition and peat accumulation rates : bog size matters 2020 In: Chemical Geology. - : Elsevier. - 0009-2541 .- 1872-6836. ; 554 Journal article (peer-reviewed)abstract We present a high-resolution peat paleodust and accumulation rate record spanning the last 8300 years from Draftinge Mosse (400 ha), southern Sweden (57 degrees 06'27.6 '' N 13 degrees 42'54.1 '' E). The record was analysed for peat accumulation rates (PAR), elemental concentrations, mineralogy, and plant macrofossil content. Five periods of increased mineral deposition were recorded. The first event occurred between similar to 6280 and similar to 5570 cal BP, during the fen to bog transition. This is followed by four atmospheric mineral dust events (DE) which were recorded in the ombrotrophic section of the sequence at (cal BP): similar to 2200; similar to 1385-1150; similar to 830-590, and from similar to 420 to the present. Statistical analysis and elemental ratios indicated that both the mineralogy and grain size shifted when the system transitioned from fen into bog, showing that the governing transport process shifted with the peat-land succession stages. This highlights the importance of identifying peatland succession stages within peat paleodust studies. Following all four DE, increases in PAR were observed, implying a coupling to dust deposition. Comparison of DE and PAR with a paleodust record from Store Mosse, a 20 times larger bog located ca 18 km away (Kylander et al. 2016), showed that both PAR and dust deposition are largely represented by single-core reconstructions, indicating that they are driven by a common climate forcing mechanism. However, higher PAR and dust deposition rates were observed in the more moderately sized Draftinge Mosse, suggesting that the size of the bog is important to consider in peat paleodust studies. Furthermore, the smaller bog responded more rapidly to hydrological changes, indicating that the size of the bog affects its' buffering capacity. Authigenic carbonates, observed here during episodes of rapid peat growth, coincide with changes in REE ratios, indicating that authigenic peat processes potentially cause REE fractionation.
49.	Stranne, Christian, 1979, et al. (author) Arctic Ocean perennial sea ice breakdown during the Early Holocene Insolation Maximum 2014 In: Quaternary Science Reviews. - : Elsevier BV. - 0277-3791 .- 1873-457X. ; 92, s. 123-132 Journal article (peer-reviewed)abstract Arctic Ocean sea ice proxies generally suggest a reduction in sea ice during parts of the early and middle Holocene (similar to 6000-10,000 years BP) compared to present day conditions. This sea ice minimum has been attributed to the northern hemisphere Early Holocene Insolation Maximum (EHIM) associated with Earth's orbital cycles. Here we investigate the transient effect of insolation variations during the final part of the last glaciation and the Holocene by means of continuous climate simulations with the coupled atmosphere sea ice ocean column model CCAM. We show that the increased insolation during EHIM has the potential to push the Arctic Ocean sea ice cover into a regime dominated by seasonal ice, i.e. ice free summers. The strong sea ice thickness response is caused by the positive sea ice albedo feedback. Studies of the GRIP ice cores and high latitude North Atlantic sediment cores show that the Bolling Allerod period (c. 12,700-14,700 years BP) was a climatically unstable period in the northern high latitudes and we speculate that this instability may be linked to dual stability modes of the Arctic sea ice cover characterized by e.g. transitions between periods with and without perennial sea ice cover.
50.	Sundman, Anneli, et al. (author) XAS study of iron speciation in soils and waters from a boreal catchment 2014 In: Chemical Geology. - : Elsevier. - 0009-2541 .- 1872-6836. ; 364, s. 93-102 Journal article (peer-reviewed)abstract Iron (Fe) is a key element, strongly influencing the biogeochemistry of soils, sediments and waters, but the knowledge about the variety of Fe species present in these systems is still limited. In this work we have used X-ray absorption spectroscopy (XAS) to study the speciation of Fe in soils and waters from a boreal catchment in northern Sweden. The aim was to better understand the controls of Fe speciation across different, but adjacent landscape elements including soil, soil solution, groundwater and stream water draining catchments with contrasting land characteristics. Our results showed that all samples contained mixtures of Fe(II) and Fe(III). The soils consisted of Fe phyllosilicates, Fe (hydr)oxides and Fe complexed by natural organic matter (NOM). All aqueous samples contained Fe(II)– and Fe(III)–NOM complexes, often in combination with Fe(III) (hydr)oxides that were associated with NOM. The variation in contribution from Fe–NOM and Fe (hydr)oxides was controlled by pH and total concentrations of NOM. The XAS spectra suggested formation of mononuclear Fe–NOM complexes consisting of chelate ring structures, but it could not be determined whether they originated solely from Fe(III)– or from a mixture of Fe(II)/Fe(III)–NOM complexes. Our collective results showed that the Fe speciation was highly variable across the different landscape elements and streams. This variation was manifested both in the distribution between mononuclear Fe–NOM complexes and Fe (hydr)oxides associated with NOM and between Fe(II) and Fe(III). These results highlight the complexity of Fe speciation in natural environmental systems and thus the challenges in interpreting Fe reactivity.

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