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1.
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2.
  • Chen, Zhe, et al. (författare)
  • Nano-scale characterization of white layer in broached Inconel 718
  • 2017
  • Ingår i: Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing. - Amsterdam : Elsevier BV. - 0921-5093 .- 1873-4936. ; 684, s. 373-384
  • Tidskriftsartikel (refereegranskat)abstract
    • The formation mechanism of white layers during broaching and their mechanical properties are not well investigated and understood to date. In the present study, multiple advanced characterization techniques with nano-scale resolution, including transmission electron microscopy (TEM), transmission Kikuchi diffraction (TKD), atom probe tomography (APT) as well as nano-indentation, have been used to systematically examine the microstructural evolution and corresponding mechanical properties of a surface white layer formed when broaching the nickel-based superalloy Inconel 718.TEM observations showed that the broached white layer consists of nano-sized grains, mostly in the range of 20–50 nm. The crystallographic texture detected by TKD further revealed that the refined microstructure is primarily caused by strong shear deformation. Co-located Al-rich and Nb-rich fine clusters have been identified by APT, which are most likely to be γ′ and γ′′ clusters in a form of co-precipitates, where the clusters showed elongated and aligned appearance associated with the severe shearing history. The microstructural characteristics and crystallography of the broached white layer suggest that it was essentially formed by adiabatic shear localization in which the dominant metallurgical process is rotational dynamic recrystallization based on mechanically-driven subgrain rotations. The grain refinement within the white layer led to an increase of the surface nano-hardness by 14% and a reduction in elastic modulus by nearly 10% compared to that of the bulk material. This is primarily due to the greatly increased volume fraction of grain boundaries, when the grain size was reduced down to the nanoscale.
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3.
  • Eivazihollagh, Alireza, et al. (författare)
  • On chelating surfactants : Molecular perspectives and application prospects
  • 2019
  • Ingår i: Journal of Molecular Liquids. - : Elsevier BV. - 0167-7322 .- 1873-3166. ; 278, s. 688-705
  • Tidskriftsartikel (refereegranskat)abstract
    • Chelating agents, molecules that very strongly coordinates certain metal ions, are used industrially as well as in consumer products to minimize disturbances and increase performance of reactions and applications. The widely used sequestering agents, nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA) and diethylenetriaminepentaacetic acid (DTPA) belong to this branch of readily water-soluble compounds. When these chemical structures also have hydrophobic parts, they are prone to adsorb at air-water interfaces and to self-assemble. Such bifunctional molecules can be called chelating surfactants and will have more extended utilization prospects than common chelating agents or ordinary ionic surfactants. The present review attempts to highlight the fundamental behavior of chelating surfactants in solution and at interfaces, and their very specific interactions with metal ions. Methods to recover chelating surfactants from metal chelates are also described. Moreover, utilization of chelating surfactants in applications for metal removal in environmental engineering and mineral processing, as well as for metal control in the fields of biology, chemistry and physics, is exemplified and discussed.
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4.
  • Moldenhauer, Patrick, 1983, et al. (författare)
  • Chemical-looping combustion with heavy liquid fuels in a 10 kW pilot plant
  • 2017
  • Ingår i: Fuel Processing Technology. - : Elsevier BV. - 0378-3820. ; 156, s. 124-137
  • Tidskriftsartikel (refereegranskat)abstract
    • In this study, chemical-looping combustion was performed with highly viscous vacuum residue. A fuel reactor with a fuel-injection system for liquid fuels was designed and built for a chemical-looping reactor with the nominal fuel input of 10 kWth. The gas velocities in the riser section and at the gas-distribution nozzles of this unit are comparable to those of industrial circulating fluidized-bed boilers. Reference experiments were performed with an ilmenite oxygen carrier and two different fuel blends that contained 40 wt.% and respectively 80 wt.% of vacuum residue in fuel oil 1. Fuel conversion was in line with that of experiments from an earlier campaign, where fuel oil 1 was used as fuel. The fuel contained a significant fraction of sulfur, but no SO2 was detected in the flue gas of the air reactor. More experiments were performed using an oxygen carrier based on calcium manganite. The oxygen carrier was exposed to fluidization at hot conditions (more than 600°C) for about 95 h, out of which fuel was injected during a total of 9.6 h. Undiluted vacuum residue, fuel oil 1 as well as different blends of these two were used as fuel. Furthermore, the parameters fuel flow, fuel-reactor temperature and air flow in the air reactor were varied to observe trends in fuel conversion. The experiments were carried out with a fuel flow corresponding to 4.0-6.2 kWth and an oxygen carrier-to-fuel ratio of about 1300-2000 kg/MWth (fuel-reactor bed mass per thermal fuel-power). With undiluted vacuum residue as fuel and a fuel-reactor temperature of 1000°C, up to 93% of all carbon leaving the fuel reactor was in the form of CO2. Carbon leakage from fuel reactor to air reactor was usually below 1% for all fuel types tested, but no SO2 was detected in the off-gas from the air reactor. The reactivity of the calcium manganite-based material decreased over the course of the experiments, which is likely due to sulfur poisoning. No defluidization or agglomeration problems were experienced over the course of the experimental campaign.
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5.
  • Grolig, Jan Gustav, 1986 (författare)
  • Coated Ferritic Stainless Steels as Interconnects in Solid Oxide Fuel Cells - Material Development and Electrical Properties
  • 2015
  • Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
    • Solid oxide fuel cells (SOFCs) are attracting increasing interest as devices with potentialuses in decentralized and clean electricity and heat production. Several challengeswith respect to materials have to be overcome to achieve efficiencies and life-spansthat are sufficient for long-term applications.An important element of an SOFC stack is the interconnect component, which connectstwo adjacent fuel cell elements. Interconnects, which are commonly composedof ferritic stainless steels, have to be corrosion-resistant, mechanically stable and costoptimized.This work aimed to investigate economic solutions for interconnect materials and tounderstand the underlying mechanisms of degradation and electrical conduction ofthese materials. Mainly two substrates, a commercially available steel (AISI 441) anda ferritic stainless steel that was optimized for an SOFC application (Sandvik SanergyHT) were combined with different barrier coatings and exposed to a cathode-sideatmosphere. A method was developed that allows for the electrical characterizationof promising material systems and model alloys, thereby facilitating a fundamentalunderstanding of the dominant electrical conduction processes linked to the oxidescales that grow on interconnects. The AISI 441 steel coated with reactive elementsand cobalt showed good corrosion and chromium evaporation profiles, while AISI 441coated with cerium and cobalt also had promising electrical properties. The SanergyHT steel was examined with coatings of copper and iron and copper and manganese,respectively. The corrosion and chromium evaporation profiles of Sanergy HT wereimproved by coating with copper and iron. The copper and iron-coated Sanergy HTshowed lower area specific resistance values than cobalt-coated Sanergy HT. Chromia,which is the main constituent of oxide scales, was synthesized using differentmethods. The electrical properties of chromia were found to be sensitive to not onlyimpurities, but also heat treatment. Finally the electrical properties of cobalt- andcobalt cerium-coated Sanergy HT steels were investigated. It was revealed that theaddition of cerium improved the conductivity of the interconnect by both slowingdown chromia growth and preventing the outward diffusion of iron into the spinel.
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6.
  • Hosseini Bab Anari, Elham, 1982, et al. (författare)
  • Fluorine-free salts for aqueous lithium-ion and sodium-ion battery electrolytes
  • 2016
  • Ingår i: RSC Advances. - : Royal Society of Chemistry (RSC). - 2046-2069. ; 6:88, s. 6, 85194-85201
  • Tidskriftsartikel (refereegranskat)abstract
    • A first generation of fluorine-free lithium and sodium salts based on the concept of pseudo-delocalized anions has been synthesized with both high purity and yield using water as the solvent in the reaction medium. The salts have been fully characterized by Raman and FT-IR spectroscopies, thermogravimetry, and X-ray crystallography to reveal both basic properties in terms of thermal stability and solubility as well as the local, mainly ion–ion interaction dictated, coordination details and by ionic conductivity and electrochemical stability window measurements as aqueous electrolytes. Together a picture is created of the salts' promise as components in electrolytes – primarily aiming at application in low voltage fluorinefree aqueous lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs).
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7.
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8.
  • Method and models used in the project Pathways to Sustainable European Energy Systems
  • 2011
  • Samlingsverk (redaktörskap) (refereegranskat)abstract
    • This book describes the research that has been carried out during the first period (2006-2010) of the Alliance for Global Sustainability (AGS) project "Pathways to Sustainable European Energy Systems". this interdisciplinary project involves more that 40 researchers and addresses various aspects of the challenges faced in transforming the European energy system. Presented in this book are the energy-related methods and models that originate from different scientific disciplines and traditions and that were applied in the Pathways project. Some of the analytical tools are well-known, well-documented, and widely used in academic research. Others have been developed (or refined) during the Pathways project and are therefore unique. The chapters of this book cover around 30 different methods and models used in the Pathways project and presents an overview of the processes through which the research was conducted and the methods and models were co-ordinated.
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9.
  • Eriksson, Gunnar, et al. (författare)
  • Combustion and fuel characterisation of wheat distillers dried grain with solubles (DDGS) and possible combustion applications
  • 2012
  • Ingår i: Fuel. - : Elsevier. - 0016-2361 .- 1873-7153. ; 102, s. 208-220
  • Tidskriftsartikel (refereegranskat)abstract
    • The present transition to a sustainable global energy system requires that biomass is increasingly combusted for heat and power production. Agricultural fuels considered include alkali-rich fuels with high phosphorus content. One such fuel is wheat distiller’s dried grain with solubles (wheat DDGS) from wheat-based ethanol production. Further increases in ethanol production may saturate the current market for wheat DDGS as livestock feed, and fuel uses are therefore considered. Fuel properties of wheat DDGS have been determined. The ash content (5.4 ± 1.6 %wt d.s.) is similar to many agricultural fuels. In comparison to most other biomass fuels the sulphur content is high (0.538 ± 0.232 %wt d.s.), and so are the contents of nitrogen (5.1 ± 0.6 %wt d.s.), phosphorus (0.960. ± 0.073 %wt d.s.) and potassium (1.30 ± 0.35 %wt d.s.). To determine fuel-specific combustion properties, wheat DDGS and mixes between wheat DDGS and logging residues (LR 60 %wt d.s. and DDGS 40 %wt d.s.), and wheat straw (wheat straw 50 %wt d.s., DDGS 50 %wt d.s.) were pelletized and combusted in a bubbling fluidised bed combustor (5 kW) and in a pellets burner combustor (20 kW). Pure wheat DDGS powder was also combusted in a powder burner (150 kW). Wheat DDGS had a high bed agglomeration and slagging tendency compared to other biomass fuels, although these tendencies were significantly lower for the mixture with the Ca-rich LR, probably reflecting the higher first melting temperatures of K–Ca/Mg-phosphates compared to K-phosphates. Combustion and co-combustion of wheat DDGS resulted in relatively large emissions of fine particles (<1 μm) for all combustion appliances. For powder combustion PMtot was sixteen times higher than from softwood stem wood. While the Cl concentrations of the fine particles from the the mixture of LR and wheat DDGS in fluidised bed combustion were lower than from combustion of pure LR, the Cl- and P-concentrations were considerably higher from the wheat DDGS mixtures combusted in the other appliances at higher fuel particle temperature. The particles from powder combustion of wheat DDGS contained mainly K, P, Cl, Na and S, and as KPO3 (i.e. the main phase identified with XRD) is known to have a low melting temperature, this suggests that powder combustion of wheat DDGS should be used with caution. The high slagging and bed agglomeration tendency of wheat DDGS, and the high emissions of fine particles rich in K, P and Cl from combustion at high temperature, mean that it is best used mixed with other fuels, preferably with high Ca and Mg contents, and in equipment where fuel particle temperatures during combustion are moderate, i.e. fluidised beds and possibly grate combustors rather than powder combustors.
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10.
  • Larsson, Ann-Charlotte, et al. (författare)
  • Targeting by Comparison with Laboratory Experiments the SCR Catalyst Deactivation Process by Potassium and Zinc Salts in a Large-Scale Biomass Combustion Boiler
  • 2006
  • Ingår i: Energy & Fuels. - : American Chemical Society (ACS). - 0887-0624 .- 1520-5029. ; 20:4, s. 1398-1405
  • Tidskriftsartikel (refereegranskat)abstract
    • The deactivation of a commercial selective catalytic reduction (SCR) catalyst of type V2O5−WO3/TiO2 has been studied in this work through comparisons of results from a full-scale biomass combustion plant with those from laboratory experiments. In the latter, the catalyst was exposed to KCl, K2SO4, and ZnCl2 by both wet impregnation with diluted salt solutions and deposition of generated submicrometer aerosol particles by means of an electrostatic field. The reactivity of freshly prepared and deactivated catalyst samples was examined in the SCR reaction, for which the influence of the different salts and the method of exposure were explored. Chemical and physical characterizations of the catalyst samples were carried out focusing on surface area, pore volume, pore size, chemical composition, and the penetration profiles of potassium and zinc. Particle-deposition deactivation as well as commercially exposed catalyst samples were shown to impact surface area and catalyst activity similarly and to have penetration profiles with pronounced peaks. Salt impregnation influenced pore sizes and catalyst activity more strongly and showed flat penetration profiles. Deposition of submicrometer-sized particles on the monolithic SCR catalyst has been shown to induce deactivation of the catalyst with characteristics resembling those obtained in a commercial biomass combustion plant; the laboratory process can be used to further assess the deactivation mechanism by biomass combustion.
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11.
  • Salvador, Christian Mark, 1989, et al. (författare)
  • Indoor ozone/human chemistry and ventilation strategies
  • 2019
  • Ingår i: Indoor Air. - : Hindawi Limited. - 1600-0668 .- 0905-6947. ; 29:6, s. 913-925
  • Tidskriftsartikel (refereegranskat)abstract
    • This study aimed to better understand and quantify the influence of ventilation strategies on occupant-related indoor air chemistry. The oxidation of human skin oil constituents was studied in a continuously ventilated climate chamber at two air exchange rates (1 h-1 and 3 h-1 ) and two initial ozone mixing ratios (30 and 60 ppb). Additional measurements were performed to investigate the effect of intermittent ventilation ("off" followed by "on"). Soiled t-shirts were used to simulate the presence of occupants. A time-of-flight-chemical ionization mass spectrometer (ToF-CIMS) in positive mode using protonated water clusters was used to measure the oxygenated reaction products geranyl acetone, 6-methyl-5-hepten-2-one (6-MHO) and 4-oxopentanal (4-OPA). The measurement data were used in a series of mass balance models accounting for formation and removal processes. Reactions of ozone with squalene occurring on the surface of the t-shirts are mass transport limited; ventilation rate has only a small effect on this surface chemistry. Ozone-squalene reactions on the t-shirts produced gas-phase geranyl acetone, which was subsequently removed almost equally by ventilation and further reaction with ozone. About 70% of gas-phase 6-MHO was produced in surface reactions on the t-shirts, the remainder in secondary gas-phase reactions of ozone with geranyl acetone. 6-MHO was primarily removed by ventilation, while further reaction with ozone was responsible for about a third of its removal. 4-OPA was formed primarily on the surfaces of the shirts (~60%); gas-phase reactions of ozone with geranyl acetone and 6-MHO accounted for ~30% and ~10%, respectively. 4-OPA was removed entirely by ventilation. The results from the intermittent ventilation scenarios showed delayed formation of the reaction products and lower product concentrations compared to continuous ventilation.
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12.
  • Zhou, Ming, et al. (författare)
  • Oligoamine ionic liquids supported on mesoporous microspheres for CO2 separation with good sorption kinetics and low cost
  • 2020
  • Ingår i: Journal of CO2 Utilization. - : Elsevier. - 2212-9820 .- 2212-9839. ; 39
  • Tidskriftsartikel (refereegranskat)abstract
    • Ionic liquids display good CO2 absorption capacity but poor absorption kinetics and high costs. In the present work, we show that these problems can be solved by impregnating the new low cost ionic liquid pentaethylenehexammonium chloride [PEHA][Cl] and the corresponding amine precursor on a low cost mesoporous microsphere support. Nitrogen adsorption/ desorption, high-resolution SEM and thermogravimetric analysis were employed to analyze the structural and thermal properties of the prepared sorbents. The CO2 adsorption and desorption performance was studied by column experiments and mathematical models were fitted to the data. The results showed that sorbents displayed excellent sorption kinetics and capacity, comparable to the best reports in the literature. In addition, the sorbents could be regenerated and displayed high thermal stability. Finally, the costs of the sorbents developed in the present work is much lower than previously reported sorbents. Therefore this novel supported IL system could be promising for industrial CO2 removal and recovery applications.
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13.
  • Yu, Xiaowen, et al. (författare)
  • Hydrogen Evolution Linked to Selective Oxidation of Glycerol over CoMoO4—A Theoretically Predicted Catalyst
  • 2022
  • Ingår i: Advanced Energy Materials. - : Wiley. - 1614-6832 .- 1614-6840. ; 12:14
  • Tidskriftsartikel (refereegranskat)abstract
    • Electrochemical valorization of biomass waste (e.g., glycerol) for production of value-added products (such as formic acid) in parallel with hydrogen production holds great potential for developing renewable and clean energy sources. Here, a synergistic effort between theoretical calculations at the atomic level and experiments to predict and validate a promising oxide catalyst for the glycerol oxidation reaction (GOR) are reported, providing a good example of designing novel, cost-effective, and highly efficient electrocatalysts for producing value-added products at the anode and high-purity hydrogen at the cathode. The predicted CoMoO4 catalyst is experimentally validated as a suitable catalyst for GOR and found to perform best among the investigated metal (Mn, Co, Ni) molybdate counterparts. The potential required to reach 10 mA cm−2 is 1.105 V at 60 °C in an electrolyte of 1.0 ᴍ KOH with 0.1 ᴍ glycerol, which is 314 mV lower than for oxygen evolution. The GOR reaction pathway and mechanism based on this CoMoO4 catalyst are revealed by high-performance liquid chromatography and in situ Raman analysis. The coupled quantitative analysis indicates that the CoMoO4 catalyst is highly active toward C—C cleavage, thus presenting a high selectivity (92%) and Faradaic efficiency (90%) for formate production. 
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14.
  • Akhtar, Farid, et al. (författare)
  • Preparation of graded silicalite-1 substrates for all-zeolite membranes with excellent CO2/H-2 separation performance
  • 2015
  • Ingår i: Journal of Membrane Science. - : Elsevier BV. - 0376-7388 .- 1873-3123. ; 493, s. 206-211
  • Tidskriftsartikel (refereegranskat)abstract
    • Graded silicalite-1 substrates with a high gas permeability and low surface roughness have been produced by pulsed current processing of a thin coating of a submicron silicalite-1 powder onto a powder body of coarser silicalite-1 crystals. Thin zeolite films have been hydrothermally grown onto the graded silicalite-1 support and the all-zeolite membranes display an excellent CO2/H-2 separation factor of 12 at 0 degrees C and a CO2 permeance of 21.3 x 10(-7) mol m(-2) s(-1) Pa-1 for an equimolar CO2/H-2 feed at 505 kPa and 101 kPa helium sweep gas. Thermal cracking estimates based on calculated surface energies and measured thermal expansion coefficients suggest that all-zeolite membranes with a minimal thermal expansion mismatch between the graded substrate and the zeolite film should remain crack-free during thermal cycling and the critical calcination step.
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15.
  • Heshmati, Mohsen, 1987, et al. (författare)
  • Dependency of cohesive laws of a structural adhesive in Mode-I and Mode-II loading on moisture, freeze-thaw cycling, and their synergy
  • 2017
  • Ingår i: Materials and Design. - : Elsevier BV. - 1873-4197 .- 0264-1275. ; 122, s. 433-447
  • Tidskriftsartikel (refereegranskat)abstract
    • In recent years, adhesive bonding has found its way to construction applications such as bridges. Given the harsh conditions that such structures are usually exposed to, it is necessary to account for environmental factors, particularly moisture and temperature, in the design phase. Cohesive zone modelling has attracted much attention in the last decade as a promising method to design adhesive joints. Despite this interest, the effects of moisture and thermal cycles on cohesive laws have not been investigated to the knowledge of the authors. In this paper, we present a method to directly measure the environmental-dependent cohesive laws of a structural adhesive loaded in pure Mode-I and Mode-II. Special consideration is given to overcome issues such as the time-consuming nature of moisture ingression and specimen dimensions, which could be problematic due to the size-limitations of conditioning equipment. The accuracy of this method was verified through simulation of the experiments using the finite element analysis. The effects of exposure to 95% relative humidity, immersion in saltwater and distilled water, and freeze-thaw cycles in the presence or absence of moisture were investigated. The results indicate the damaging effects of combined saltwater and freeze-thaw cycles which were clearly reflected on the shape of the cohesive laws.
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16.
  • Systems Perspectives on Biorefineries 2013
  • 2013
  • Samlingsverk (redaktörskap) (refereegranskat)abstract
    • Replacing fossil fuels with biomass for the production of energy carriers, materialsand specialty chemicals is a challenge that now confronts humanity. In whichapplications shall we use limited resources of biomass? How can biomass berefined into the products we want? What are the consequences of demanding toomuch? What is an optimal design of a biorefinery? Where should they be located?What policy instruments are required to realise the biorefineries of the future?There is not one final answer to these questions. However, different systems studiescan provide us with complementary pieces of the puzzle. These can be valuableby themselves, or be brought together into a larger and more complex picture.Systems Perspectives on Biorefineries 2013 is an updated edition of SystemsPerspectives on Biorefineries 2012 and contains twelve chapters that address differenttopics related to the immensely important issue of how the world’s biomassresources can, or should, be converted into the goods we need and desire. Thebook is still far from complete, but it is a contribution and a start...
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17.
  • Andersson, Viktor, 1983, et al. (författare)
  • Alkali-wall interactions in a laboratory-scale reactor for chemical looping combustion studies
  • 2021
  • Ingår i: Fuel Processing Technology. - : Elsevier BV. - 0378-3820 .- 1873-7188. ; 217
  • Tidskriftsartikel (refereegranskat)abstract
    • Alkali metal-containing compounds are readily released during thermal conversion of solid fuels, and may have both detrimental and beneficial effects on chemical looping combustion. Here, we characterize alkali interactions with the inner walls of a laboratory-scale reactor under oxidizing, reducing and inert conditions at temperatures up to 900 °C. KCl aerosol particles are continuously introduced to the stainless steel reactor and the alkali concentration is measured on-line with a surface ionization detector. Aerosol particles evaporate at temperatures above 500 °C and KCl molecules rapidly diffuse to the reactor wall. Up to 92% of the alkali reaching the wall below 700 °C remains adsorbed, while re-evaporation is important at higher temperatures, where up to 74% remains adsorbed. Transient changes in alkali concentration are observed during repeated redox cycles, which are associated with changes in chemical composition of the wall material. Metal oxides on the reactor wall are partially depleted under reducing conditions, which allow for the formation of a new potassium-rich phase that is stable in a reducing atmosphere, but not under inert conditions. The observed wall effects are concluded to be extensive and include major transient effects depending on gas composition, and the implications for laboratory studies and improved experimental methodology are discussed.
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18.
  • Mukesh, Chandrakant, et al. (författare)
  • Production of C-14 Levulinate Ester from Glucose Fermentation Liquors Catalyzed by Acidic Ionic Liquids in a Solvent-Free Self-Biphasic System
  • 2020
  • Ingår i: ACS Omega. - : American Chemical Society (ACS). - 2470-1343. ; 5:10, s. 4828-4835
  • Tidskriftsartikel (refereegranskat)abstract
    • Herein, we present the C-14 levulinate ester of 2,3-butanediol as the product of sugar fermentation liquors. The designed Brønsted acidic ionic liquid (BAIL) catalysts enable self-induced phase separation with ester products, and the role of anions has been investigated. Esterification reactions were carried out by 2,3-butanediol (2,3-BDO) and levulinic acid in solvent-free media and low temperatures (60–105 °C). For comparison, sulfuric acid, amberlite IR-120, and sulfonic acid-functionalized pyridinium ionic liquids with different anions were utilized as a catalyst upon esterification reaction. The diester product, namely, butane-2,3-diyl bis(4-oxopentanoate), was formed with a good yield (85%) and selectivity (85%) after complete conversion of 2,3-BDO in 24 h at 80 °C. The low yield (8%) of the monoester was observed. The monoester and diester were separated by a liquid–liquid extraction method. The ester products were characterized by various instrumental techniques such as 1H and 13C NMR, GC–FID, LC–MS, and FT-IR spectroscopy. The Hammett acidity functions of BAILs were determined from UV–vis spectroscopy. The catalyst was successfully recycled and reused in the processes. The spent BAILs were reused in six consecutive cycles with only a ∼7% diminished diester yield and selectivity. The produced levulinate ester will be useful as biofuel additives, solvents, plasticizers, and other applications.
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19.
  • Wetterlund, Elisabeth, et al. (författare)
  • Implications of system expansion for the assessment of well-to-wheel CO2 emissions from biomass-based transportation
  • 2010
  • Ingår i: International Journal of Energy Research. - : Hindawi Limited. - 0363-907X .- 1099-114X. ; 34:13, s. 1136-1154
  • Tidskriftsartikel (refereegranskat)abstract
    • In this paper we show the effects of expanding the system when evaluating well-to-wheel (WTW) CO2 emissions for biomass-based transportation, to include the systems surrounding the biomass conversion system. Four different cases are considered: DME via black liquor gasification (BLG), methanol via gasification of solid biomass, lignocellulosic ethanol and electricity from a biomass integrated gasification combined cycle (BIGCC) used in a battery-powered electric vehicle (BPEV). All four cases are considered with as well as without carbon capture and storage (CCS). System expansion is used consistently for all flows. The results are compared with results from a conventional WTW study that only uses system expansion for certain co-product flows. It is shown that when expanding the system, biomass-based transportation does not necessarily contribute to decreased CO2 emissions and the results from this study in general indicate considerably lower CO2 mitigation potential than do the results from the conventional study used for comparison. It is shown that of particular importance are assumptions regarding future biomass use, as by expanding the system, future competition for biomass feedstock can be taken into account by assuming an alternative biomass usage. Assumptions regarding other surrounding systems, such as the transportation and the electricity systems are also shown to be of significance. Of the four studied cases without CCS, BIGCC with the electricity used in a BPEV is the only case that consistently shows a potential for CO2 reduction when alternative use of biomass is considered. Inclusion of CCS is not a guarantee for achieving CO2 reduction, and in general the system effects are equivalent or larger than the effects of CCS. DME from BLG generally shows the highest CO2 emission reduction potential for the biofuel cases. However, neither of these options for biomass-based transportation can alone meet the needs of the transport sector. Therefore, a broader palette of solutions, including different production routes, different fuels and possibly also CCS, will be needed.
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20.
  • Zacharias, Savannah C., et al. (författare)
  • Exploring Supramolecular Gels in Flow-Type Chemistry-Design and Preparation of Stationary Phases
  • 2021
  • Ingår i: Industrial & Engineering Chemistry Research. - : American Chemical Society (ACS). - 0888-5885 .- 1520-5045. ; 60:28, s. 10056-10063
  • Tidskriftsartikel (refereegranskat)abstract
    • Two major challenges facing chemical synthesis are product isolation and catalyst recovery. One method to overcome these challenges is to perform the synthesis in a flow system with a catalytic stationary phase. However, the polymeric catalytic materials used in flow systems are often laborious to produce. In this study, we investigate a novel supramolecular gel as a catalytic stationary phase material. The gel is based on a modular, easy to synthesize, oxotriphenylhexanoate (OTHO) gelator comprised of a catalytic unit designed to catalyze the Knoevenagel reaction. The catalytic organogel enhances the rate of product formation and can be reused five times. Use of the OTHO to construct catalytic gels is a flexible technique that can be utilized to improve product isolation and reduce wastage of the catalyst.
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21.
  • Pardon, Gaspard, 1983- (författare)
  • From Macro to Nano : Electrokinetic Transport and Surface Control
  • 2014
  • Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
    • Today, the growing and aging population, and the rise of new global threats on human health puts an increasing demand on the healthcare system and calls for preventive actions. To make existing medical treatments more efficient and widely accessible and to prevent the emergence of new threats such as drug-resistant bacteria, improved diagnostic technologies are needed. Potential solutions to address these medical challenges could come from the development of novel lab-on-chip (LoC) for point-of-care (PoC) diagnostics.At the same time, the increasing demand for sustainable energy calls for the development of novel approaches for energy conversion and storage systems (ECS), to which micro- and nanotechnologies could also contribute.This thesis has for objective to contribute to these developments and presents the results of interdisciplinary research at the crossing of three disciplines of physics and engineering: electrokinetic transport in fluids, manufacturing of micro- and nanofluidic systems, and surface control and modification. By combining knowledge from each of these disciplines, novel solutions and functionalities were developed at the macro-, micro- and nanoscale, towards applications in PoC diagnostics and ECS systems.At the macroscale, electrokinetic transport was applied to the development of a novel PoC sampler for the efficient capture of exhaled breath aerosol onto a microfluidic platform.At the microscale, several methods for polymer micromanufacturing and surface modification were developed. Using direct photolithography in off-stoichiometry thiol-ene (OSTE) polymers, a novel manufacturing method for mold-free rapid prototyping of microfluidic devices was developed. An investigation of the photolithography of OSTE polymers revealed that a novel photopatterning mechanism arises from the off-stoichiometric polymer formulation. Using photografting on OSTE surfaces, a novel surface modification method was developed for the photopatterning of the surface energy. Finally, a novel method was developed for single-step microstructuring and micropatterning of surface energy, using a molecular self-alignment process resulting in spontaneous mimicking, in the replica, of the surface energy of the mold.At the nanoscale, several solutions for the study of electrokinetic transport toward selective biofiltration and energy conversion were developed. A novel, comprehensive model was developed for electrostatic gating of the electrokinetic transport in nanofluidics. A novel method for the manufacturing of electrostatically-gated nanofluidic membranes was developed, using atomic layer deposition (ALD) in deep anodic alumina oxide (AAO) nanopores. Finally, a preliminary investigation of the nanopatterning of OSTE polymers was performed for the manufacturing of polymer nanofluidic devices.
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22.
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23.
  • Almgren, Karin, et al. (författare)
  • Role of fibre-fibre and fibre-matrix adhesion in stress transfer in composites made from resin-impregnated paper sheets.
  • 2009
  • Ingår i: International Journal of Adhesion and Adhesives. - : Elsevier BV. - 0143-7496 .- 1879-0127. ; 29:5, s. 551-557
  • Tidskriftsartikel (refereegranskat)abstract
    • Paper-reinforced plastics are gaining increased interest as packaging materials, where mechanical properties are of great importance. Strength and stress transfer in paper sheets are controlled by fibre-fibre bonds. In paper-reinforced plastics, where the sheet is impregnated with a polymer resin, other stress-transfer mechanisms may be more important. The influence of fibre-fibre bonds on the strength of paper-reinforced plastics was therefore investigated. Paper sheets with different degrees of fibre-fibre bonding were manufactured and used as reinforcement in a polymeric matrix. Image analysis tools were used to verify that the difference in the degree of fibre-fibre bonding had been preserved in the composite materials. Strength and stiffness of the composites were experimentally determined and showed no correlation to the degree of fibre-fibre bonding, in contrast to the behaviour of unimpregnated paper sheets. The degree of fibre-fibre bonding is therefore believed to have little importance in this type of material, where stress is mainly transferred through the fibre-matrix interface.
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24.
  • Decrop, Deborah, et al. (författare)
  • Single-step manufacturing of femtoliter microwell arrays in a novel surface energy mimicking polymer
  • 2015
  • Ingår i: 18th International Conference on Solid-State Sensors, Actuators and Microsystems (IEEE TRANSDUCER 2015). - : IEEE.
  • Konferensbidrag (refereegranskat)abstract
    • We report a novel polymer material formulation and stamp-molding technique that enable rapid single-step manufacturing of hydrophilic-in-hydrophobic microwell arrays. We developed a modified thiol-ene-epoxy polymer (mOSTE+) formulation that mimics the surface energy of its mold during polymerization. The polymer inherits the surface energy from the mold through molecular self-assembly, in which functional monomers self-assemble at the interface between the liquid prepolymer and the mold surface. Combining this novel mOSTE+ material with a stamp-molding process leads to simultaneous surface energy mimicking and micro-structuring. This method was used to manufacture microwells with hydrophilic bottom and hydrophobic sidewall, depressed in a surrounding hydrophobic surface. The microwell arrays were successfully tested for the self-assembly of 62’000 femtoliter-droplets. Such femtoliter droplet arrays are useful for, e.g., digital ELISA and single cell/molecule analysis applications.
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25.
  • Ge, Yaxin, et al. (författare)
  • Effects of used bed materials on char gasification : Investigating the role of element migration using online alkali measurements
  • 2022
  • Ingår i: Fuel processing technology. - : Elsevier. - 0378-3820 .- 1873-7188. ; 238
  • Tidskriftsartikel (refereegranskat)abstract
    • Online alkali measurements using surface ionization are employed to study alkali release during heating of used industrial fluidized bed materials and gasification of biomass-based char and bed material mixtures. The alkali release from the bed materials starts at 820 °C and increases with temperature, the time a bed material has experienced in an industrial process, and in the presence of CO2. Online alkali measurement during heating of char mixed with used bed material shows significant alkali uptake by the char. Complementary SEM-EDS studies confirm the alkali results and indicate that other important inorganic elements including Si, Mg, and Ca also migrate from the bed material to the char. The migration of elements initially enhances alkali release and char reactivity, but significantly reduces both during the final stage of the gasification. The observed effects on char gasification become more pronounced with increasing amount of bed material and increasing time the material experienced in an industrial process. The ash-layer on the used bed material is concluded to play an important role as a carrier of alkali and other active components. The char and bed material systems are closely connected under operational conditions, and their material exchange has important implications for the thermal conversion.
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26.
  • Pilke, Nina, et al. (författare)
  • Organising Terminology Work in Sweden from the 1940s onwards – Participatory Expert Roles in Networks
  • 2021
  • Ingår i: Terminology as a Societal Resource. Possibilities and Responsibilities in a Changing World. Special Issue of Terminology International Journal of Theoretical and Applied Issues in Specialized Communication. - : John Benjamins Publishing Company. - 0929-9971 .- 1569-9994. ; 27:1, s. 80-109
  • Tidskriftsartikel (refereegranskat)abstract
    • The present study deals with organised terminology work in Sweden from the 1940s to the late 2010s. Using archive material, we describe how practical terminology work was carried out in Sweden during the period 1941–2018/ 2019, when the Swedish Centre for Technical Terminology/the Swedish Centre for Terminology (TNC) was the central actor. Thereafter, we discuss models for building a new infrastructure for terminology work after the clo- sure of the TNC in 2018/2019. This discussion is based on interviews and analyses of articles and current reports. The study shows that multifaceted contacts with experts, academia, industry and society have played an essen- tial role for terminology work in Sweden since the 1930s. In the current situ- ation (2019), the activities are being reorganised and responsibility for terminology work is distributed between several actors. A new main actor is the government agency known as the Institute of Language and Folklore (Isof ). Finally, we discuss future visions for terminology work in Sweden.
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27.
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28.
  • Bui, Thai Q., et al. (författare)
  • Mesoporous Melamine-Formaldehyde Resins as Efficient Heterogeneous Catalyst for Continuous Synthesis of Cyclic Carbonates from Epoxides and gaseous CO2
  • 2020
  • Ingår i: ACS Sustainable Chemistry and Engineering. - : American Chemical Society (ACS). - 2168-0485. ; 8:34, s. 12852-12869
  • Tidskriftsartikel (refereegranskat)abstract
    • Herein we report the application of inexpensive mesoporous melamine-formaldehyde resins (MMFR and MMFR250) obtained by a novel template-free and organosolvent-free hydrothermal method as efficient heterogeneous catalysts for direct synthesis of cyclic carbonates from CO2 and epoxides (epichlorohydrin, butylene oxide and styrene oxide). The catalytic activity of the melamine resins was attributed to the abundant Lewis basic N-sites capable of activating CO2 molecules. Based on CO2-Temperature programmed desorption, the concentration of surface basic sites for MMFR and MMFR250 were estimated to be 172 and 56 µmol/g, while the activation energy of CO2 desorption (strength of basic sites) were calculated to be 92.1 and 64.5 kJ/mol. We also observed considerable differences in the catalytic activity and stability of polymeric catalysts in batch and in continuous-flow mode; due to the existence of a synergism between adsorption of CO2 and cyclic carbonates (poison). Our experiments also revealed important role of catalyst surface chemistry and CO2 partial pressure upon catalyst poisoning. Nevertheless, owing to their unique properties (large specific surface area, large mesoporous and CO2 basicity) melamine resins presented excellent activity (turnover frequency 207-2147 h-1), selectivity (>99%) for carbonation of epoxides with CO2 (20 bar initial CO2 or CO2:epoxide mole ratio ~1.5) under solvent-free and co-catalyst-free conditions at 100-120 oC. Most importantly, these low-cost polymeric catalysts were reusable and demonstrated exceptional stability in a flow reactor (tested upto 13 days time on stream, weight hourly space velocity 0.26-1.91 h-1) for continuous cyclic carbonate production from gaseous CO2 with different epoxides (conversion 76-100% and selectivity >99%) under industrially relevant conditions (120 oC, 13 bar, solvent-free/co-catalyst-free) confirming their superiority over the previously reported catalytic materials.
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29.
  • Winikka, Henrik, et al. (författare)
  • Particle formation during pressurized entrained flow gasification of wood powder : Effects of process conditions on chemical composition, nanostructure, and reactivity
  • 2018
  • Ingår i: Combustion and Flame. - : Elsevier BV. - 0010-2180 .- 1556-2921. ; 189, s. 1339-1351
  • Tidskriftsartikel (refereegranskat)abstract
    • The influence of operating condition on particle formation during pressurized, oxygen blown gasification of wood powder with an ash content of 0.4 wt% was investigated. The investigation was performed with a pilot scale gasifier operated at 7 bar(a). Two loads, 400 and 600 kW were tested, with the oxygen equivalence ratio (λ) varied between 0.25 and 0.50. Particle concentration and mass size distribution was analyzed with a low pressure cascade impactor and the collected particles were characterized for morphology, elemental composition, nanostructure, and reactivity using scanning electron microscopy/high resolution transmission electron microscopy/energy dispersive spectroscopy, and thermogravimetric analysis. In order to quantify the nanostructure of the particles and identify prevalent sub-structures, a novel image analysis framework was used. It was found that the process temperature, affected both by λ and the load of the gasifier, had a significant influence on the particle formation processes. At low temperature (1060 °C), the formed soot particles seemed to be resistant to the oxidation process; however, when the oxidation process started at 1119 °C, the internal burning of the more reactive particle core began. A further increase in temperature (> 1313 °C) lead to the oxidation of the less reactive particle shell. When the shell finally collapsed due to severe oxidation, the original soot particle shape and nanostructure also disappeared and the resulting particle could not be considered as a soot anymore. Instead, the particle shape and nanostructure at the highest temperatures (> 1430 °C) were a function of the inorganic content and of the inorganic elements the individual particle consisted of. All of these effects together lead to the soot particles in the real gasifier environment having less and less ordered nanostructure and higher and higher reactivity as the temperature increased; i.e., they followed the opposite trend of what is observed during laboratory-scale studies with fuels not containing any ash-forming elements and where the temperature was not controlled by λ.
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30.
  • Cantatore, Valentina, 1986, et al. (författare)
  • Towards multifunctional coating in the boron-doped graphene/copper system
  • 2017
  • Ingår i: Carbon. - : Elsevier BV. - 0008-6223. ; 115, s. 375-379
  • Tidskriftsartikel (refereegranskat)abstract
    • A route to achieve multi-functional graphene coating is explored. Chemical bonding between copper substrate and coating results if the graphene is a priori boron doped. After pair-wise binding of boron sites to the Cu(111) surface, co-existence of pseudo-gap property in the graphene subsystem and a metallic density of states in the Cu subsystem at the common Fermi energy emerges. Apparently a paradox is that the two subsystems preserve and even recover their individual integrities upon formation of surface chemical bonds. Sensor capabilities are inferred. Employing pyridine as test molecule, conditioned ability of a nucleophile to offer competitive dative bonding, with the sub-strate, for boron sites is demonstrated. It is shown to occur for the case of half coverage and for adsorption to boron atoms originally bound to the on-top site on Cu(111). The ability of complementary boron sites to compensate for loss of binding between on-top site and boron, resulting from said bonding to the incoming nucleophile, is emphasized. Multifunctional substrate-coating system for catalysis as well as enhanced sensitization is inferred.
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31.
  • Dahlin, Sandra, et al. (författare)
  • Effect of biofuel- and lube oil-originated sulfur and phosphorus on the performance of Cu-SSZ-13 and V2O5-WO3/TiO2 SCR catalysts
  • 2021
  • Ingår i: Catalysis Today. - : Elsevier B.V.. - 0920-5861 .- 1873-4308. ; 360, s. 326-339
  • Tidskriftsartikel (refereegranskat)abstract
    • Two different SCR catalysts, V2O5-WO3/TiO2 and Cu-SSZ-13, were exposed to biodiesel exhausts generated by a diesel burner. The effect of phosphorus and sulfur on the SCR performance of these catalysts was investigated by doping the fuel with P-, S-, or P + S-containing compounds. Elemental analyses showed that both catalysts captured phosphorus while only Cu-SSZ-13 captured sulfur. High molar P/V ratios, up to almost 3, were observed for V2O5-WO3/TiO2, while the highest P/Cu ratios observed were slightly above 1 for the Cu-SSZ-13 catalyst. Although the V2O5-WO3/TiO2 catalyst captured more P than did the Cu-SSZ-13 catalyst, a higher degree of deactivation was observed for the latter, especially at low temperatures. For both catalysts, phosphorus exposure resulted in suppression of the SCR performance over the entire temperature range. Sulfur exposure, on the other hand, resulted in deactivation of the Cu-SSZ-13 catalyst mainly at temperatures below 300-350 °C. The use of an oxidation catalyst upstream of the SCR catalyst during the exhaust-exposure protects the SCR catalyst from phosphorus poisoning by capturing phosphorus. The results in this work will improve the understanding of chemical deactivation of SCR catalysts and aid in developing durable aftertreatment systems. 
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32.
  • Du, Chengjun, 1985 (författare)
  • Studies on Diesel sprays under non-reacting and reacting conditions
  • 2017
  • Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
    • Methods for reducing engine-out emissions are urgently needed to mitigate climate change and air pollution. In diesel engines, the quality of fuel-air mixing and the subsequent combustion process strongly affect fuel efficiency and engine-out emissions. However, fuel-air mixing, the subsequent combustion processes, and their dependence on the operating conditions are not yet fully understood. This thesis aims to address this deficiency by analyzing the effects of various orifice geometries and high injection pressures on the characteristics of diesel sprays.The thesis briefly reviews the fundamental physics governing the flow of pressurized fuel through the internal nozzle of a diesel injector, the subsequent formation of the liquid and vapor spray, and the turbulent diffusion combustion processes. The experimental work presented in this thesis can be divided into three main parts. The first focuses on the effects of geometry-induced cavitation on the liquid/vapor phase spray and injection rate evaluation. To this end, a light absorption and scattering technique (LAS) was used to measure the distributions of liquid and vapor sprays formed using nozzles with various geometries. It was found that the vaporization of the diesel spray was controlled by turbulent air mixing. The effects of geometry-induced cavitation on the spray properties were mainly due to differences in the fuel mass flow rate, spray momentum and spreading angle. In addition, the injection rates of cavitating and non-cavitating nozzles were evaluated using the momentum flux measurement method. It was found that failure to account for cavitation caused the injection rate to be overestimated for the cavitating nozzle but not for the non-cavitating nozzle.The second part of the experimental campaign investigates the effect of the injection pressure and nozzle geometry on soot formation and oxidation. A two-dimensional laser extinction method was used to measure time-resolved soot concentrations and soot volume fractions; OH* chemiluminescence imaging was used to measure the lift-off length and measure the distributions of the OH radicals qualitatively; soot luminosity images were used to identify the sooting area in the soot shadowgraph images. It was found that the equivalence ratio in the jet center at the lift-off length (ϕ_cl), which is influenced by the operating conditions, played a critical role in soot formation. Reductions in ϕ_cl thickened the OH zone in the upstream region of the jet, reducing the volume corresponding to the maximum soot volume fraction. The expansion of the OH zone also helped reduce the sooting zone’s width. However, under high sooting conditions (e.g. ϕ_cl>3.5), the sooting zone width in the downstream jet was independent of ϕ_cl.  The third part of the thesis investigates combusting and non-combusting sprays formed from different blends of ethanol with diesel fuel. Using 0%-20% ethanol blended with diesel fuels, liquid/vapor phase spray images were captured, the ignition delay was measured, the lift-off length was measured, and natural soot luminosity images were captured. It was found that the differences in the fuels’ composition did not significantly affect the liquid/vapor phase sprays. However, as the ethanol content of the fuel was increased from 0% to 20%, the lift-off length increased and the detectable soot luminescence decreased. This indicates that soot formation declines as the fuel’s ethanol content increases.
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33.
  • Finnerman, Oskar, et al. (författare)
  • Reactor modeling assessment for urea-SNCR applications
  • 2017
  • Ingår i: International Journal of Numerical Methods for Heat and Fluid Flow. - : Emerald Group Publishing Limited. - 0961-5539 .- 1758-6585. ; 27:7, s. 1395-1411
  • Tidskriftsartikel (refereegranskat)abstract
    • Purpose – The work investigates the effects of neglecting, modeling or partly resolving turbulent fluctuations of velocity, temperature and concentrations on the predicted turbulence-chemistry interaction in urea-SNCR systems.Design/methodology/approach – Numerical predictions of the NO conversion efficiency in an industrial urea-SNCR system are compared to experimental data. Reactor models of varying complexity are assessed, ranging from one-dimensional ideal reactor models to state-of-the-art CFD simulations based on the DES approach. The models employ the same reaction mechanism, but differ in the degree to which they resolve the turbulent fluctuations of the gas phase. A methodology for handling of unknown experimental data with regard to providing adequate boundary conditions is also proposed.Findings – One-dimensional reactor models may be useful for a first quick assessment of urea-SNCR system performance. It is critical to account for heat losses, if present, due to the significant sensitivity of the overall process to temperature. The most comprehensive DES setup evaluated is associated with approximately two orders of magnitude higher computational cost than the conventional RANS-based simulations. For studies that require a large number of simulations (e.g. optimizations or handling of incomplete experimental data), the less costly approaches may be favored with a tolerable loss of accuracy.Originality/value – Novel numerical and experimental results are presented to elucidate the role of turbulent fluctuations on the performance of a complex, turbulent, reacting multiphase flow.
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34.
  • Grimm, Alejandro, et al. (författare)
  • Slagging and fouling characteristics during co-combustion of Scots pine bark with low-temperature dried pulp and paper mill chemical sludge
  • 2019
  • Ingår i: Fuel processing technology. - : Elsevier. - 0378-3820 .- 1873-7188. ; 193, s. 282-294
  • Tidskriftsartikel (refereegranskat)abstract
    • This paper shows how chemical sludge (CS) generated during wastewater treatment at a paperboard mill can be quickly dried at low-temperature and employed in bark-fired boilers to reduce slagging and corrosion problems. By using a cyclone-dryer operated at an inlet-air velocity of 110 m/s and a temperature of 90 degrees C, the dry-matter content of CS was increased from approximately 19 to 82%. The residence time of CS inside the cyclone was approximately 2 s when using the inlet-air velocity mentioned above. Disaggregation of the feedstock caused by collisions with the cyclone wall and between particles played a crucial role in enhancing the efficiency of heat and mass transfer. Three co-pelletized mixtures of Scots pine bark (SPB) and dried-CS were combusted in a 40 kW fixed-bed burner. Flue gas analysis was performed with a gas analyser. Coarse and fine ash were analysed by SEM-EDS and XRD. NOx, and SO2 emissions increased with increasing amount of CS in the mixtures. Mono combustion of SPB resulted in a large quantity of slag (i.e., molten ash) with a high degree of sintering (i.e., hardness of the slag), and ash deposits formed on heat transfer surfaces were rich in K2SO4 and KCI. Mixtures of SPB and CS were less prone to slagging, and the amount of alkali chloride in the deposits was reduced in favour of alkali sulphate formation.
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35.
  • Purnomo, Victor, 1992 (författare)
  • Behavior of iron-based oxygen carriers at deep reduction states
  • 2024
  • Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
    • Oxygen carriers have an important role as bed materials in both common circulating fluidized bed combustion unit (also known as oxygen-carrier-aided combustion, OCAC) and in various chemical looping processes. Contrary to conventional bed materials, e.g., sand, oxygen carriers are capable of transferring both oxygen and heat. This makes it possible to produce nitrogen-free product gas streams (in the case of chemical looping processes) and achieve a higher fuel conversion. Having been studied for almost three decades, various oxygen carriers show their own pros and cons depending on the processes for which they are intended to be used. Most of the published studies before this doctoral thesis focused on the reactivity and utilization of oxygen carriers in chemical looping combustion (CLC), where a complete fuel conversion is always desired. Nevertheless, this is not the case in, for example, chemical looping gasification, reforming, and water splitting, where only partial fuel oxidation is necessary, and the produced flue gases are the desired products. In such processes, the oxygen carriers can be exposed to a higher reduction degree than it would be in CLC or OCAC. This warrants further investigations into the deep reduction states of relevant oxygen carriers, which are expected to encounter inevitable performance issues under such a harsh environment. In this thesis, some aspects related to the physical performance and properties of various iron-based oxygen carriers in the occurrence of deep reduction states are examined and presented. The first part of the thesis focuses on the fluidization performance, attrition resistance, and particle size and shape analysis. This part is important mainly for assessing material stability. Iron-based oxygen carriers typically tend to encounter bed defludization at a high degree of reduction. The outward migration of iron into the particle surface, which typically creates a FeO/Fe layer, likely causes defludization. Furthermore, the oxidation state of oxygen carriers does affect the attrition resistance of iron oxygen carriers to varying extents. The results indicate that the presence of Fe-Ti and Fe-Si combinations contribute to a generally stable and low attrition rate, while an Fe-Ca system exhibits a decreasing attrition rate. In addition, the influence of exposure to redox cycles and oxidation degree on the size and shape of oxygen carrier particles seems to be minimal. The oxygen carrier particles generally have a high sphericity but are slightly elongated. Reactivity and fuel conversion are the other focuses of this thesis. These have main implications for engineering design but also for material screening. The apparent kinetic study of oxygen carrier performed in this thesis demonstrates that the changing grain size (CGS) model is applicable to predict the reactivity of three iron oxygen carriers in the presence of CO, H2, and CH4. This applies even at lower oxidation degrees (3 – 5 wt.% reduction), where the reactivity of oxygen carriers has generally decreased. Finally, the gasification rate of pine forest residue char remains at similar levels when using either ilmenite or iron sand as the oxygen carrier.
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36.
  • Adler, Anneli, et al. (författare)
  • Lignin-first biorefining of Nordic poplar to produce cellulose fibers could displace cotton production on agricultural lands
  • 2022
  • Ingår i: Joule. - : Elsevier BV. - 2542-4351. ; 6:8, s. 1845-1858
  • Tidskriftsartikel (refereegranskat)abstract
    • Here, we show that lignin-first biorefining of poplar can enable the production of dissolving cellulose pulp that can produce regenerated cellulose, which could substitute cotton. These results in turn indicate that agricultural land dedicated to cotton could be reclaimed for food production by extending poplar plantations to produce textile fibers. Based on climate-adapted poplar clones capable of growth on marginal lands in the Nordic region, we estimate an environmentally sustainable annual biomass production of ∼11 tonnes/ha. At scale, lignin-first biorefining of this poplar could annually generate 2.4 tonnes/ha of dissolving pulp for textiles and 1.1 m3 biofuels. Life cycle assessment indicates that, relative to cotton production, this approach could substantially reduce water consumption and identifies certain areas for further improvement. Overall, this work highlights a new value chain to reduce the environmental footprint of textiles, chemicals, and biofuels while enabling land reclamation and water savings from cotton back to food production.
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37.
  • Forero Saboya, Juan, 1992, et al. (författare)
  • Water-in-Bisalt Electrolyte with Record Salt Concentration and Widened Electrochemical Stability Window
  • 2019
  • Ingår i: Journal of Physical Chemistry Letters. - : American Chemical Society (ACS). - 1948-7185. ; 10:17, s. 4942-4946
  • Tidskriftsartikel (refereegranskat)abstract
    • Water-in-salt and water-in-bisalt electrolytes have recently attracted much attention due to their expanded electrochemical stability windows. The concentration limit of such electrolytes is constrained by the solubility of the lithium salts employed, ca. 21 m (mol kg−1) for LiTFSI (lithium bis(trifluoromethanesulfonyl)imide). By adding a second lithium salt, the total salt concentration can be increased, but the hydrogen evolution keeps limiting the application of such systems in batteries with low potential anodes. Herein we report a water-in-bisalt electrolyte with a record salt concentration (31.4 m LiTFSI + 7.9 m Li[N(CH3)2((CH2)3SO3)((CH2)4SO3)]) in which the bulky anion completely prevents the crystallization, even at such low water contents. Although the hydrogen evolution reaction is not completely suppressed, the expanded electrochemical stability window allows for low potential reactions such as aluminum−lithium alloying. The high salt concentration favors the formation of a suitable passivation layer that can be further engineered by modifying the anion structure
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38.
  • Odnevall Wallinder, Inger, et al. (författare)
  • Predictive models of copper runoff from external structures
  • 2004
  • Ingår i: Journal of Environmental Monitoring. - : Royal Society of Chemistry (RSC). - 1464-0325 .- 1464-0333. ; 6:8, s. 704-712
  • Tidskriftsartikel (refereegranskat)abstract
    • A general model for annual runoff rate predictions of total copper from naturally patinated copper on buildings at specific urban or rural sites of low chloride influence has been deduced from laboratory and field data. All parameters within the model have a physical meaning and include the average annual rain acidity ( pH), the annual rain quantity and the geometry of a building in terms of surface inclination. In 70% of all reported annual runoff rates, the predicted values are within 30% from the observed values. The individual and interactive effect of rain composition in terms of pH, sulfate, chloride and nitrate concentration was investigated in immersion experiments in artificial rain water representative of urban and rural sites of Europe. The results show pH to have a dominating effect on patina dissolution, nitrate to have a small inhibiting effect, whereas no significant effect was seen for chloride and sulfate. In case pH data are not available, a model has been statistically deduced from field data by considering SO2 as influencing parameter, rather than pH. The predictability with the SO2 model is not as good as with the pH model i.e. the pH model should preferentially be used since it is a better predictor and all parameters within the model can be physically explained.
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39.
  • Ström, Henrik, 1981, et al. (författare)
  • Behaviour and stability of the two-fluid model for fine-scale simulations of bubbly flow in nuclear reactors
  • 2015
  • Ingår i: International Journal of Chemical Reactor Engineering. - : Walter de Gruyter GmbH. - 1542-6580 .- 2194-5748. ; 13:4, s. 449-459
  • Tidskriftsartikel (refereegranskat)abstract
    • In the present work, we formulate a simplistic two-fluid model for bubbly steam-water flow existing between fuel pins in nuclear fuel assemblies. Numerical simulations are performed in periodic 2D domains of varying sizes. The appearance of a non-uniform volume fraction field in the form of meso-scales is investigated and shown to be varying with the bubble loading and the domain size, as well as with the numerical algorithm employed. These findings highlight the difficulties involved in interpreting the occurrence of instabilities in two-fluid simulations of gas-liquid flows, where physical and unphysical instabilities are prone to be confounded. The results obtained in this work therefore contribute to a rigorous foundation in on-going efforts to derive a consistent meso-scale formulation of the traditional two-fluid model for multiphase flows in nuclear reactors.
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40.
  • Stedt, Kristoffer, 1991, et al. (författare)
  • Post-harvest cultivation with seafood process waters improves protein levels of Ulva fenestrata while retaining important food sensory attributes
  • 2022
  • Ingår i: Frontiers in Marine Science. - : Frontiers Media SA. - 2296-7745.
  • Tidskriftsartikel (refereegranskat)abstract
    • Seaweed aquaculture can provide the growing human population with a sustainable source of proteins. Sea-based cultivation is an effective method for farming seaweeds on a large scale and can yield high biomass output. However, the quality and biochemical composition of the biomass is seasonally dependent, which limits the harvests to certain periods of the year. Here we show the possibility to extend the sea-based cultivation season of Ulva fenestrata when aiming for high protein levels, by post-harvest treatment in herring production process waters. We harvested U. fenestrata at an optimal period in terms of yield, but suboptimal in terms of protein content. We then cultivated the seaweed in onshore tank systems with the nutrient-rich process waters for 14 days. We monitored biomass yield, crude protein content, amino acid composition, and content of the health concerning metals arsenic, mercury, lead, and cadmium, as well as the sensory properties of the dried biomass. After cultivation in the process waters, biomass yields were 30 - 40% higher (210 – 230 g fresh weight) compared to in seawater (160 g fresh weight). Also, the crude protein and amino acid content increased three to five times in the process waters, reaching 12 - 17 and 15 – 21% dry weight, respectively. The protein enriched biomass followed food graded standards for heavy metal content, and consumption of the biomass does not exceed health based reference points. Additionally, no sensory attributes regarded as negative were found. This rapid, post-harvest treatment can help extend the cultivation season of sea-based seaweed farms, maximizing their output of sustainable proteins.
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41.
  • Farzaneh, Amirfarrokh, et al. (författare)
  • Adsorption of Butanol and Water Vapors in Silicalite‑1 Films with a Low Defect Density
  • 2016
  • Ingår i: Langmuir. - : American Chemical Society (ACS). - 0743-7463 .- 1520-5827. ; 32, s. 11789-11798
  • Tidskriftsartikel (refereegranskat)abstract
    • Pure silica zeolites are potentially hydrophobic and have therefore been considered to be interesting candidates for separating alcohols, e.g., 1-butanol, from water. Zeolites are traditionally synthesized at high pH, leading to the formation of intracrystalline defects in the form of silanol defects in the framework. These silanol groups introduce polar adsorption sites into the framework, potentially reducing the adsorption selectivity toward alcohols in alcohol/water mixtures. In contrast, zeolites prepared at neutral pH using the fluoride route contain significantly fewer defects. Such crystals should show a much higher butanol/water selectivity than crystals prepared in traditional hydroxide (OH−) media. Moreover, silanol groups are present at the external surface of the zeolite crystals; therefore, minimizing the external surface of the studied adsorbent is important. In this work, we determine adsorption isotherms of 1-butanol and water in silicalite-1 films prepared in a fluoride (F−) medium using in situ attenuated total reflectance−Fourier transform infrared (ATR−FTIR) spectroscopy. This film was composed of well intergrown, plate-shaped b-oriented crystals, resulting in a low external area. Single-component adsorption isotherms of 1-butanol and water were determined in the temperature range of 35− 80 °C. The 1-butanol isotherms were typical for an adsorbate showing a high affinity for a microporous material and a large increase in the amount adsorbed at low partial pressures of 1-butanol. The Langmuir−Freundlich model was successfully fitted to the 1-butanol isotherms, and the heat of adsorption was determined. Water showed a very low affinity for the adsorbent, and the amounts adsorbed were very similar to previous reports for large silicalite-1 crystals prepared in a fluoride medium. The sample also adsorbed much less water than did a reference silicalite-1(OH−) film containing a high density of internal defects.The results show that silicalite-1 films prepared in a F− medium with a low density of defects and external area are very promising for the selective recovery of 1-butanol from aqueous solutions.
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42.
  • Chalmers Environmental Initiative Progress Report 2001
  • 2001
  • Samlingsverk (redaktörskap) (refereegranskat)abstract
    • The Board of the Chalmers University of TechnologyFoundation decided in 1999 to invest SEK 100million in a strategic investment in the environmentwith a special focus on environmental systems analysis.This investment was entitled The ChalmersEnvironmental Initiative (CEI). Through thisenvironmental initiative Chalmers has acquired aprominent international position within environmentalsystems analysis.CEI is the result of the active research and educationthat has taken place at Chalmers over the past 10years. A broad base in combination with leadingedge technology presented the opportunity to createa very strong research programme based oninteraction between the various schools at Chalmers.As CEI is integrated into undergraduate anddoctoral programmes at Chalmers, engineers,architects and doctoral students have access, withinthe framework of their studies, to research-basedenvironmental education with a focus on asustainable society. CEI also co-operates with otherparties, such as industry, politicians, various organisationsand the general public, as a further means ofcontributing to sustainable development in society.Within CEI, seven new professors have beenappointed within the following areas:Management for SustainabilityRolf Wolff, 1 June 2000Environmental Systems TechnologyAnne-Marie Tillman, 1 September 2000Sustainable Industrial MetabolismChristian Azar, 1 September 2000Global Environmental MeasurementsDonal Murtagh, 1 November 2000Green ChemistryWilliam J. Frederick Jr, 1 August 2001Sustainable Energy SystemsFilip Johnsson, preliminary 1 October 2001Design for Sustainable Urban DevelopmentVacant: interviews during April 2001The four professors appointed in 2000 are presentedin this report as well as their declaration of intentfor the next few years. At present, the CEI professorsare involved with approximately 40 universities,institutes and industrial partners in the form ofproject co-operation and joint publications. The fourprofessors have the greater proportion of theirenvironmental research funded through externalgrants, compared to CEI. The proportion of facultyfunds and other internal Chalmers funds is at presentvery low. A summary of the financing structureis also included in this report.During 2001, various forms of co-operation wereinitiated between the professors, such as joint projectplans, doctoral students, courses and graduateschools. During autumn 2001, a residential seminaris planned for discussions within CEI as well as anopen presentation of the project and the professors.This major in-house focus on environmental researchhas attracted attention externally and contributedto the opening up of new potential in combinationwith increased expectations. Since May 1, 2000,Chalmers has been a member of the Alliance forGlobal Sustainability (AGS), an association of someof the world’s foremost universities in theenvironmental field. AGS and other platforms formthe basis for international research collaboration.CEI and other environmental activities have led tospin-off effects and contributed to increased interestin Chalmers as an environmental university.Chalmers and Göteborg University were, forexample, jointly awarded the King Carl XVI Gustafvisiting professorship in environmental science for2001-2002 and Margot Wallström received anhonorary doctorate from Chalmers in 2001. A largenumber of well-known environmental researchershave also visited Chalmers to take part inconferences and seminars, including the winners ofthe Volvo Environmental Award for 2000 and thewinner of the City of Göteborg InternationalEnvironmental Award for 2000.
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43.
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44.
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45.
  • Landqvist, Hans, 1958, et al. (författare)
  • Intresse och engagemang: Kungliga Tekniska högskolans insatser i ett svenskt terminologiskt nätverk 1941–1983 : Interest and involvement: the contributions of the Royal Institute of Technology to a Swedish terminological network 1941–1983
  • 2021
  • Ingår i: Folkmålsstudier Meddelanden från Föreningen för nordisk filologi. - 0356-1771. ; 59, s. 103-133
  • Tidskriftsartikel (refereegranskat)abstract
    • In this paper, we study how KTH Royal Institute of Technology (Kungliga Tekniska högskolan – KTH) has participated in and influenced terminology work coordinated by the national terminology centre, the Swedish Centre for Technical Terminology – the TNC, in Sweden during the period 1941–1983. The aim of this paper is to shed light on the development of Swedish (technical) terminology based on networking and experts’ efforts. Based on archive material, we analyze who have been the active KTH experts, in what ways they were involved in the development processes and what effects their efforts had on the term recommendations given by the TNC. The archive material consists of written documents relating to the work process developed by John Wennerberg, who led the TNC between 1941 and 1957. The process was carried out in the form of 373 formal survey letters representing 17 subject fields, with both the TNC and external parties participating. Our results show that the 31 identified KTH experts play a visible role in the processes by 480 received survey letters within 14 subject fields. The response rate, 80 percent, reveal the experts’ involvement in the process and their high esteem of TNC’s work. The analysis of the comprehensive survey letter R198 shows that Wennerberg has considered the experts’ answers regarding terms (selection, linguistic form, acceptance/discourage) and definitions when he has published TNC’s recommendations. Our study shows that networking and experts representing the educational sector and furthermore universities have been an inseparable part of the development of Swedish (technical) terminology during several decades when the national terminology centre in Sweden began to operate and the working methods were established.
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46.
  • Mouzon, Johanne, et al. (författare)
  • Comparison between slip-casting and uniaxial pressing for the fabrication of translucent yttria ceramics
  • 2008
  • Ingår i: Journal of Materials Science. - : Springer Science and Business Media LLC. - 0022-2461 .- 1573-4803. ; 43:8, s. 2849-2856
  • Tidskriftsartikel (refereegranskat)abstract
    • Slip casting and uniaxial pressing were compared as first consolidation stages prior to cold isostatic pressing (CIP) to produce translucent yttria ceramics. In the first step, yttria slurries suitable for slip casting were prepared. The viscosity was optimized with respect to the starting agglomeration state, amount of dispersant, milling time, and number of milling balls. Secondly, pellets were prepared either by slip casting or uniaxial pressing and then cold-isostatically pressed. Finally, the pellets were made translucent by a combination of pre-sintering and hot isostatic pressing (HIP). Although slip-cast and pressed samples exhibited similar green-body densities after CIP and pre-sintering, the samples prepared by slip casting were more homogeneous in terms of translucency and microstructure throughout their bodies. This was attributed to the ability of slip casting to minimize density gradients during packing, and to the beneficial effect of ball-milling to remove larger agglomerates before casting. Therefore, slip casting as a first consolidation stage prior to CIP appears to be more suitable than uniaxial pressing in order to prepare homogeneous optical ceramics.
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47.
  • Sun, Wenjun, 1989, et al. (författare)
  • An alternating D-A1-D-A2 copolymer containing two electron-deficient moieties for efficient polymer solar cells
  • 2013
  • Ingår i: Journal of Materials Chemistry A. - : Royal Society of Chemistry (RSC). - 2050-7488 .- 2050-7496. ; 1:37, s. 11141-11144
  • Tidskriftsartikel (refereegranskat)abstract
    • Unlike normal donor-acceptor (D-A) polymers containing only one electron-deficient segment in their repeating unit, the incorporation of two electron-deficient moieties with different absorption behaviors, forming a D-A1-D-A2 internal structure in the alternating copolymer, showed a broader absorption spectrum than its constituent parts and enhanced photovoltaic performance. This work is anticipated to open the door to the design of new low bandgap polymers with a broader absorption range for efficient polymer solar cells.
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48.
  • European Energy Pathways - Pathways to sustainable european energy systems
  • 2011
  • Samlingsverk (redaktörskap) (refereegranskat)abstract
    • To meet the challenge of climate change, the world must substaintially reduce emissions of greenhouse gases (GHGs). this must be accomplished in a way that maintains security of supply and competitiveness.This book presents to pathways towards sustainable European energy systems - the "Policy Pathway" and the "Market Pathway". These to pathways differ with respect to where the main responsability lies for transforming the energy system in following the pathway. The Policy pathway takes its departure from the EU Energy and Climate Package, and has a strong focus on targeted policies that promote energy efficiency and energy from renewable sources. The Market Pathway relies more on the market to transform the energy system, and presents a future in which the cost associated with emitting CO2 (and other GHGs) is the dominating policy measure.This book describes the research that has been carried out during the first period (2006-2010) of the AGS project "Pathways to Sustsainable Energy Systems". This interdisciplinary project involved more than 40 researchers and addressed various aspects of the challenges faced in transforming the European energy system. The chapters in this book cover more than 30 topics and presents an overall picture of the results obtained to date from various activities in the Pathways project.
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49.
  • Zhang, Emma, 1985, et al. (författare)
  • Predicting degradation of the anode-concrete interface for impressed current cathodic protection in concrete
  • 2018
  • Ingår i: Construction and Building Materials. - : Elsevier BV. - 0950-0618. ; 185, s. 57-68
  • Tidskriftsartikel (refereegranskat)abstract
    • Impressed current cathodic protection and prevention techniques are efficient methods to stop or prevent corrosion in steel reinforced concrete structures. The inevitable side effect of the current exchange is acidification at the anode-concrete interface. Accelerated test methods can be used to investigate the long-term performance of the system. However, a linear relation will not hold between the accelerated and normal conditions because of the influence of the current density. This paper presents results of an accelerated test. A power-relation conversion model is proposed and an acceleration factor is introduced. (C) 2018 Elsevier Ltd. All rights reserved.
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50.
  • Ottonello Briano, Floria (författare)
  • Mid-infrared photonic devices for on-chip optical gas sensing
  • 2019
  • Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
    • Gas detection is crucial in a wide range of fields and applications, such as safety and process control in the industry, atmospheric sciences, and breath diagnostics. Optical gas sensing offers some key advantages, compared to other sensing methods such as electrochemical and semiconductor sensing: high specificity, fast response, and minimal drift.Wavelengths between 3 and 10 μm are of particular interest for gas sensing. This spectral range, called the mid-infrared (mid-IR), is also known as the fingerprint region, because several gas species can be identified by their sharp absorption lines in this region. The most relevant mid-IR-active gases are the trace gases carbon dioxide (CO2), methane (CH4), carbon monoxide (CO), ammonia (NH3), and nitrous oxide (N2O). They are greenhouse gases, contributing to global warming. They are waste products of human activities and widely used in agriculture and industry. Therefore, it is crucial to accurately and extensively monitor them. However, traditional optical gas sensors with a free-space optical path configuration, are too bulky, power-hungry, and expensive to be widely adopted.This thesis presents mid-IR integrated photonic devices that enable the on-chip integration of optical gas sensors, with a focus on CO2 sensing. The reported technologies address the fundamental sensor functionalities: light-gas interaction, infrared light generation, and infrared light detection. The thesis introduces a novel mid-IR silicon photonic waveguide that allows a light path as long as tens of centimeters to fit in a volume smaller than a few cubic millimeters. Mid-IR CO2 spectroscopy demonstrates the high sensing performance of the waveguide. The thesis also explores the refractive index sensing of CO2 with a mid-IR silicon photonic micro-ring resonator.Furthermore, the thesis proposes platinum nanowires as low-cost infrared light sources and detectors that can be easily integrated on photonic waveguides. Finally, the thesis presents a large-area infrared emitter fabricated by highs-peed wire bonding and integrated in a non-dispersive infrared sensor for the detection of alcohol in breath.The technologies presented in this thesis are suited for cost-effective mass production and large-scale adoption. Miniaturized integrated optical gas sensors have the potential to become the main choice for an increasingly broad range of existing and new applications, such as portable, distributed, and networked environmental monitoring, and high-volume medical and consumer applications.
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