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1.	Roth, Florian, et al. (författare) High spatiotemporal variability of methane concentrations challenges estimates of emissions across vegetated coastal ecosystems. 2022 Ingår i: Global change biology. - : Wiley. - 1365-2486 .- 1354-1013. ; 28:14, s. 4308-4322 Tidskriftsartikel (refereegranskat)abstract Coastal methane (CH4 ) emissions dominate the global ocean CH4 budget and can offset the "blue carbon" storage capacity of vegetated coastal ecosystems. However, current estimates lack systematic, high-resolution, and long-term data from these intrinsically heterogeneous environments, making coastal budgets sensitive to statistical assumptions and uncertainties. Using continuous CH4 concentrations, δ13 C-CH4 values, and CH4 sea-air fluxes across four seasons in three globally pervasive coastal habitats, we show that the CH4 distribution is spatially patchy over meter-scales and highly variable in time. Areas with mixed vegetation, macroalgae, and their surrounding sediments exhibited a spatiotemporal variability of surface water CH4 concentrations ranging two orders of magnitude (i.e., 6-460nM CH4 ) with habitat-specific seasonal and diurnal patterns. We observed (1) δ13 C-CH4 signatures that revealed habitat-specific CH4 production and consumption pathways, (2) daily peak concentration events that could change >100% within hours across all habitats, and (3) a high thermal sensitivity of the CH4 distribution signified by apparent activation energies of ~1eV that drove seasonal changes. Bootstrapping simulations show that scaling the CH4 distribution from few samples involves large errors, and that ~50 concentration samples per day are needed to resolve the scale and drivers of the natural variability and improve the certainty of flux calculations by up to 70%. Finally, we identify northern temperate coastal habitats with mixed vegetation and macroalgae as understudied but seasonally relevant atmospheric CH4 sources (i.e., releasing≥100μmol CH4 m-2 day-1 in summer). Due to the large spatial and temporal heterogeneity of coastal environments, high-resolution measurements will improve the reliability of CH4 estimates and confine the habitat-specific contribution to regional and global CH4 budgets.
2.	Barnes, Paul W., et al. (författare) Ozone depletion, ultraviolet radiation, climate change and prospects for a sustainable future 2019 Ingår i: Nature Sustainability. - : Springer Science and Business Media LLC. - 2398-9629. ; 2:7, s. 569-579 Forskningsöversikt (refereegranskat)abstract © 2019, Springer Nature Limited. Changes in stratospheric ozone and climate over the past 40-plus years have altered the solar ultraviolet (UV) radiation conditions at the Earth’s surface. Ozone depletion has also contributed to climate change across the Southern Hemisphere. These changes are interacting in complex ways to affect human health, food and water security, and ecosystem services. Many adverse effects of high UV exposure have been avoided thanks to the Montreal Protocol with its Amendments and Adjustments, which have effectively controlled the production and use of ozone-depleting substances. This international treaty has also played an important role in mitigating climate change. Climate change is modifying UV exposure and affecting how people and ecosystems respond to UV; these effects will become more pronounced in the future. The interactions between stratospheric ozone, climate and UV radiation will therefore shift over time; however, the Montreal Protocol will continue to have far-reaching benefits for human well-being and environmental sustainability.
3.	Omstedt, Anders, 1949 (författare) The Development of Climate Science of the Baltic Sea Region 2017 Ingår i: Oxford Research Encyclopedia of Climate Science. - : Oxford University Press. Bokkapitel (övrigt vetenskapligt/konstnärligt)abstract Dramatic climate changes have occurred in the Baltic Sea region caused by changes in orbital movement in the earth–sun system and the melting of the Fennoscandian Ice Sheet. Added to these longer-term changes, changes have occurred at all timescales, caused mainly by variations in large-scale atmospheric pressure systems due to competition between the meandering midlatitude low-pressure systems and highpressure systems. Here we follow the development of climate science of the Baltic Sea from when observations began in the 18th century to the early 21st century. The question of why the water level is sinking around the Baltic Sea coasts could not be answered until the ideas of postglacial uplift and the thermal history of the earth were better understood in the 19th century and periodic behavior in climate related time series attracted scientific interest. Herring and sardine fishing successes and failures have led to investigations of fishery and climate change and to the realization that fisheries themselves have strongly negative effects on the marine environment, calling for international assessment efforts. Scientists later introduced the concept of regime shifts when interpreting their data, attributing these to various causes. The increasing amount of anoxic deep water in the Baltic Sea and eutrophication have prompted debate about what is natural and what is anthropogenic, and the scientific outcome of these debates now forms the basis of international management efforts to reduce nutrient leakage from land. The observed increase in atmospheric CO and its effects on global warming have focused the climate debate on trends and generated a series of international and regional assessments and research programs that have greatly improved our understanding of climate and environmental changes, bolstering the efforts of earth system science, in which both climate and environmental factors are analyzed together.
4.	Charpentier Ljungqvist, Fredrik, 1982- (författare) Global nedkylning : klimatet och människan under 10 000 år 2009 Bok (populärvet., debatt m.m.)abstract Klimatet har förändrats både regionalt och globalt sedan senaste istiden tog slut, ofta med dramatiska konsekvenser för naturen och människan. Fastän det talas så mycket om klimatförändringar idag är det få som vet särskilt mycket om hur klimatet har varierat förr.Det är först under de senaste åren som forskningen börjat kunna beskriva vad som faktiskt hänt med klimatet under olika tider, på olika platser. Historikern Fredrik Charpentier Ljungqvist har tagit ett samlat grepp på den senaste forskningen och resultatet är en resa i vått och torrt, i hetta och kyla, jorden runt under 10 000 år. Vi får stifta bekantskap med många olika folk och kulturer – babylonier, romare, mayaindianer och vikingar – som alla under historiens gång varit utsatta för klimatförändringar.
5.	Wurzbacher, Christian, 1980, et al. (författare) Poorly known microbial taxa dominate the microbiome of permafrost thaw ponds. 2017 Ingår i: The ISME journal. - : Springer Science and Business Media LLC. - 1751-7370 .- 1751-7362. ; 11:8, s. 1938-1941 Tidskriftsartikel (refereegranskat)abstract In the transition zone of the shifting permafrost border, thaw ponds emerge as hotspots of microbial activity, processing the ancient carbon freed from the permafrost. We analyzed the microbial succession across a gradient of recently emerged to older ponds using three molecular markers: one universal, one bacterial and one fungal. Age was a major modulator of the microbial community of the thaw ponds. Surprisingly, typical freshwater taxa comprised only a small fraction of the community. Instead, thaw ponds of all age classes were dominated by enigmatic bacterial and fungal phyla. Our results on permafrost thaw ponds lead to a revised perception of the thaw pond ecosystem and their microbes, with potential implications for carbon and nutrient cycling in this increasingly important class of freshwaters.
6.	Myers-Smith, Isla H., et al. (författare) Complexity revealed in the greening of the Arctic 2020 Ingår i: Nature Climate Change. - : Springer Science and Business Media LLC. - 1758-678X .- 1758-6798. ; 10:2, s. 106-117 Tidskriftsartikel (refereegranskat)abstract As the Arctic warms, vegetation is responding, and satellite measures indicate widespread greening at high latitudes. This ‘greening of the Arctic’ is among the world’s most important large-scale ecological responses to global climate change. However, a consensus is emerging that the underlying causes and future dynamics of so-called Arctic greening and browning trends are more complex, variable and inherently scale-dependent than previously thought. Here we summarize the complexities of observing and interpreting high-latitude greening to identify priorities for future research. Incorporating satellite and proximal remote sensing with in-situ data, while accounting for uncertainties and scale issues, will advance the study of past, present and future Arctic vegetation change.
7.	Blennow, Kristina, et al. (författare) Societal impacts of storm damage 2013 Ingår i: Living with Storm Damage to Forests. What science can tell us. - 9789525980097 ; :3, s. 70-77 Bokkapitel (övrigt vetenskapligt/konstnärligt)
8.	Li, Jun, et al. (författare) Hygroscopicity and Ice Nucleation Properties of Dust/Salt Mixtures Originating from the Source of East Asian Dust Storms 2022 Ingår i: Frontiers in Environmental Science. - : Frontiers Media SA. - 2296-665X. ; 10 Tidskriftsartikel (refereegranskat)abstract Dust storms are common meteorological events that occur frequently in the late spring and early summer in arid and semi-arid areas. The resulting lofted dust and salt mixtures can impact atmospheric chemistry and climate systems through the many pathways represented by aerosol-cloud-climate interactions. In this study, dust/salt samples were collected from important sources of the East Asian dust storm, including the Badain Jaran Desert, the Tengger Desert and the Ulan Buh Desert in northwestern China. Ion chromatography (IC) measurements were performed to determine the concentrations of cations and anions. The ionic concentrations, pH and dissolvable fractions of sand samples show a positive correlation, indicating that the dissolved content is rich in alkaline ions. A positive matrix factorization (PMF) receptor model was employed to analyze the IC results, and from the PMF solutions non-obvious connections to local geography emerge. The results of hygroscopic experiments of sand samples which were measured by a vapor sorption analyzer indicate that the hygroscopicity may be related to the soluble content of samples, and the observed hygroscopic behavior can be well described by a thermodynamic model. The morphology of individual particles was chemically mapped by the synchrotron-based scanning transmission X-ray microscopy, and needle-shaped CaCO3 particles were observed to adhere to more irregular high K-containing particles. Moreover, a continuous flow diffusion chamber was used to investigate the ice nucleation abilities of typical salts, with both homogeneous freezing and deposition nucleation being observed. The results indicate that the salts primarily act as cloud condensation nuclei but can also act as ice nucleating particles at low temperatures.
9.	Wang, Y. J., et al. (författare) The formation of nitro-aromatic compounds under high NOx and anthropogenic VOC conditions in urban Beijing, China 2019 Ingår i: Atmospheric Chemistry and Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 19:11, s. 7649-7665 Tidskriftsartikel (refereegranskat)abstract Nitro-aromatic compounds (NACs), as important contributors to the light absorption by brown carbon, have been widely observed in various ambient atmospheres; however, their formation in the urban atmosphere was little studied. In this work, we report an intensive field study of NACs in summer 2016 at an urban Beijing site, characterized by both high-NO(x)and anthropogenic VOC dominated conditions. We investigated the factors that influence NAC formation (e.g., NO2, VOC precursors, RH and photolysis) through quantification of eight NACs, along with major components in fine particulate matter, selected volatile organic compounds, and gases. The average total concentration of the quantified NACs was 6.63 ng m(-3), higher than those reported in other summertime studies (0.14-6.44 ng m(-3)). 4-Nitrophenol (4NP, 32.4 %) and 4-nitrocatechol (4NC, 28.5 %) were the top two most abundant NACs, followed by methyl-nitrocatechol (MNC), methyl-nitrophenol (MNP), and dimethyl-nitrophenol (DMNP). The oxidation of toluene and benzene in the presence of NOx was found to be a more dominant source of NACs than primary biomass burning emissions. The NO2 concentration level was found to be an important factor influencing the secondary formation of NACs. A transition from low- to high-NOx regimes coincided with a shift from organic- to inorganic-dominated oxidation products. The transition thresholds were NO2 similar to 20 ppb for daytime and NO2 similar to 25 ppb for nighttime conditions. Under low-NOx conditions, NACs increased with NO2, while the NO3 concentrations and (NO3-)/NACs ratios were lower, implying organic-dominated products. Under high-NOx conditions, NAC concentrations did not further increase with NO2, while the NO3- concentrations and (NO3-)/NACs ratios showed increasing trends, signaling a shift from organic- to inorganic-dominated products. Nighttime enhancements were observed for 3M4NC and 4M5NC, while daytime enhancements were noted for 4NP, 2M4NP, and DMNP, indicating different formation pathways for these two groups of NACs. Our analysis suggested that the aqueous-phase oxidation was likely the major formation pathway of 4M5NC and 3M5NC, while photo-oxidation of toluene and benzene in the presence of NO2 could be more important for the formation of nitrophenol and its derivatives. Using the (3M4NC+4M5NC) / 4NP ratios as an indicator of the relative contribution of aqueous-phase and gas-phase oxidation pathways to NAC formation, we observed that the relative contribution of aqueous-phase pathways increased at elevated ambient RH and remained constant at RH > 30 %. We also found that the concentrations of VOC precursors (e.g., toluene and benzene) and aerosol surface area acted as important factors in promoting NAC formation, and photolysis as an important loss pathway for nitrophenols.
10.	Eriksson, Christin, 1978, et al. (författare) Characterizing the European sub-Arctic winter climate since 1500 using ice, temperature, and atmospheric circulation time series 2007 Ingår i: Journal of Climate. - 0894-8755. ; DOI 10.1175/2007JCLI1461.1 Tidskriftsartikel (refereegranskat)
11.	Poyatos, R., et al. (författare) Global transpiration data from sap flow measurements: the SAPFLUXNET database 2021 Ingår i: Earth System Science Data. - : Copernicus GmbH. - 1866-3508 .- 1866-3516. ; 13:6, s. 2607-2649 Tidskriftsartikel (refereegranskat)abstract Plant transpiration links physiological responses of vegetation to water supply and demand with hydrological, energy, and carbon budgets at the land-atmosphere interface. However, despite being the main land evaporative flux at the global scale, transpiration and its response to environmental drivers are currently not well constrained by observations. Here we introduce the first global compilation of whole-plant transpiration data from sap flow measurements (SAPFLUXNET, https://sapfluxnet.creaf.cat/, last access: 8 June 2021). We harmonized and quality-controlled individual datasets supplied by contributors worldwide in a semi-automatic data workflow implemented in the R programming language. Datasets include sub-daily time series of sap flow and hydrometeorological drivers for one or more growing seasons, as well as metadata on the stand characteristics, plant attributes, and technical details of the measurements. SAPFLUXNET contains 202 globally distributed datasets with sap flow time series for 2714 plants, mostly trees, of 174 species. SAPFLUXNET has a broad bioclimatic coverage, with woodland/shrubland and temperate forest biomes especially well represented (80 % of the datasets). The measurements cover a wide variety of stand structural characteristics and plant sizes. The datasets encompass the period between 1995 and 2018, with 50 % of the datasets being at least 3 years long. Accompanying radiation and vapour pressure deficit data are available for most of the datasets, while on-site soil water content is available for 56 % of the datasets. Many datasets contain data for species that make up 90 % or more of the total stand basal area, allowing the estimation of stand transpiration in diverse ecological settings. SAPFLUXNET adds to existing plant trait datasets, ecosystem flux networks, and remote sensing products to help increase our understanding of plant water use, plant responses to drought, and ecohydrological processes. SAPFLUXNET version 0.1.5 is freely available from the Zenodo repository (https://doi.org/10.5281/zenodo.3971689; Poyatos et al., 2020a). The "sapfluxnetr" R package - designed to access, visualize, and process SAPFLUXNET data - is available from CRAN.
12.	Soerensen, Anne L., et al. (författare) Deciphering the Role of Water Column Redoxclines on Methylmercury Cycling Using Speciation Modeling and Observations From the Baltic Sea 2018 Ingår i: Global Biogeochemical Cycles. - : American Geophysical Union (AGU). - 0886-6236 .- 1944-9224. ; 32:10, s. 1498-1513 Tidskriftsartikel (refereegranskat)abstract Oxygen-depleted areas are spreading in coastal and offshore waters worldwide, but the implication for production and bioaccumulation of neurotoxic methylmercury (MeHg) is uncertain. We combined observations from six cruises in the Baltic Sea with speciation modeling and incubation experiments to gain insights into mercury (Hg) dynamics in oxygen depleted systems. We then developed a conceptual model describing the main drivers of Hg speciation, fluxes, and transformations in water columns with steep redox gradients. MeHg concentrations were 2-6 and 30-55 times higher in hypoxic and anoxic than in normoxic water, respectively, while only 1-3 and 1-2 times higher for total Hg (THg). We systematically detected divalent inorganic Hg (Hg-II) methylation in anoxic water but rarely in other waters. In anoxic water, high concentrations of dissolved sulfide cause formation of dissolved species of Hg-II: HgS2H(aq)- and Hg (SH)(2)(0)((aq)). This prolongs the lifetime and increases the reservoir of Hg-II readily available for methylation, driving the high MeHg concentrations in anoxic zones. In the hypoxic zone and at the hypoxic-anoxic interface, Hg concentrations, partitioning, and speciation are all highly dynamic due to processes linked to the iron and sulfur cycles. This causes a large variability in bioavailability of Hg, and thereby MeHg concentrations, in these zones. We find that zooplankton in the summertime are exposed to 2-6 times higher MeHg concentrations in hypoxic than in normoxic water. The current spread of hypoxic zones in coastal systems worldwide could thus cause an increase in the MeHg exposure of food webs.
13.	Staal, Arie, et al. (författare) Global terrestrial moisture recycling in Shared Socioeconomic Pathways Annan publikation (övrigt vetenskapligt/konstnärligt)abstract The global water cycle has undergone considerable changes since pre-industrial times due to global climate change and land-use changes. These drivers will almost certainly continue to change during the course of this century. However, where, how, and to which extent terrestrial moisture recycling will change as a result remains unclear.Mutually consistent scenarios of climate change and land-use changes for the 21st century are provided by the Shared Socioeconomic Pathways (SSPs). The SSPs provide a framework of five different narratives involving varying degrees of challenges associated with mitigation or adaptation. From each narrative follow different implications for emissions, energy, and land use. The SSPs serve as the conceptual framework behind the sixth generation of the Coupled Model Intercomparison Project, CMIP6.Terrestrial moisture recycling is often assessed using atmospheric moisture tracking models. An example is UTrack, a Lagrangian model to track moisture through three-dimensional space. Here we present a new forward-tracking version of UTrack that is forced by output of a CMIP6 model to study how terrestrial moisture recycling may change across the globe until the end of the 21st century in a range of SSPs, from mild to severe: SSP1-2.6, SSP2-4.5, SSP3-7.0, and SSP5-8.5. For this forcing, we chose the Norwegian Earth System Model version 2, or NorESM2. It has a temporal resolution of one day and a spatial resolution of 1.25° × 0.9375° at eight pressure levels.We find that across the 21st century, the global terrestrial moisture recycling ratio decreases with the severity of the Shared Socioeconomic Pathways (SSPs). We calculate a decrease in global terrestrial precipitation recycling by 2.1% with every degree of global warming. Because the SSPs represent internally consistent scenarios of both global warming and global land cover changes, it is hard to distinguish the relative contributions of these two, but the evidence points at a major influence of global warming on moisture recycling.We find spatial differences in trends in recycling ratios, but which are broadly consistent among SSPs. If a change in precipitation (either drying or wetting) coincides with an increase in terrestrial precipitation recycling ratio, we call it land-dominated. We call the change in precipitation ocean-dominated if it coincides with a decrease in terrestrial precipitation recycling ratio. Land dominance tends to occur in regions with already large terrestrial precipitation recycling ratios, mainly interior South America (land-dominated drying) and eastern Asia (land-dominated wetting). Land-dominated drying may also happen in eastern Europe, in central America and in subtropical sub-Saharan Africa. Ocean-dominance, mainly in the form of wetting, is found primarily in the high northern latitudes and in central Africa.We also simulated the changes in basin recycling for the 27 major river basins of the world, confirming the overall tendency of decreasing recycling with severity of the SSP, as well as its spatial variations.
14.	Podgrajsek, Eva, et al. (författare) Comparison of floating chamber and eddy covariance measurements of lake greenhouse gas fluxes 2014 Ingår i: Biogeosciences. - : Copernicus GmbH. - 1726-4170 .- 1726-4189. ; 11, s. 4225-4233 Tidskriftsartikel (refereegranskat)abstract Fluxes of carbon dioxide (CO2) and methane (CH4) from lakes may have a large impact on the magnitude of the terrestrial carbon sink. Traditionally lake fluxes have been measured using the floating chamber (FC) technique; however, several recent studies use the eddy covariance (EC) method. We present simultaneous flux measurements using both methods at lake Tämnaren in Sweden during field campaigns in 2011 and 2012. Only very few similar studies exist. For CO2 flux, the two methods agree relatively well during some periods, but deviate substantially at other times. The large discrepancies might be caused by heterogeneity of partial pressure of CO2 (pCO2w) in the EC flux footprint. The methods agree better for CH4 fluxes. It is, however, clear that short-term discontinuous FC measurements are likely to miss important high flux events.
15.	Charpentier Ljungqvist, Fredrik, 1982- (författare) A new reconstruction of temperature variability in the extra-tropical Northern Hemisphere during the last two millennia 2010 Ingår i: Geografiska Annaler. Series A, Physical Geography. - Oxford : Wiley-Blackwell. - 0435-3676 .- 1468-0459. ; 92A:3, s. 339-351 Tidskriftsartikel (refereegranskat)abstract A new temperature reconstruction with decadal resolution, covering the last two millennia, is presented for the extra-tropical Northern Hemisphere (90–30°N), utilizing many palaeotemperature proxy records never previously included in any large-scale temperature reconstruction. The amplitude of the reconstructed temperature variability on centennial time-scales exceeds 0.6°C. This reconstruction is the first to show a distinct Roman Warm Period c. AD 1–300, reaching up to the 1961–1990 mean temperature level, followed by the Dark Age Cold Period c. AD 300–800. The Medieval Warm Period is seen c. AD 800–1300 and the Little Ice Age is clearly visible c. AD 1300–1900, followed by a rapid temperature increase in the twentieth century. The highest average temperatures in the reconstruction are encountered in the mid to late tenth century and the lowest in the late seventeenth century. Decadal mean temperatures seem to have reached or exceeded the 1961–1990 mean temperature level during substantial parts of the Roman Warm Period and the Medieval Warm Period. The temperature of the last two decades, however, is possibly higher than during any previous time in the past two millennia, although this is only seen in the instrumental temperature data and not in the multi-proxy reconstruction itself. Our temperature reconstruction agrees well with the reconstructions by Moberg et al. (2005) and Mann et al. (2008) with regard to the amplitude of the variability as well as the timing of warm and cold periods, except for the period c. AD 300–800, despite significant differences in both data coverage and methodology.
16.	Matthes, Heidrun, et al. (författare) Sensitivity of high-resolution Arctic regional climate model projections to different implementations of land surface processes 2012 Ingår i: Climatic Change. - : Springer Science and Business Media LLC. - 0165-0009 .- 1573-1480. ; 111:2, s. 197-214 Tidskriftsartikel (refereegranskat)abstract This paper discusses the effects of vegetation cover and soil parameters on the climate change projections of a regional climate model over the Arctic domain. Different setups of the land surface model of the regional climate model HIRHAM were realized to analyze differences in the atmospheric circulation caused by (1) the incorporation of freezing/thawing of soil moisture, (2) the consideration of top organic soil horizons typical for the Arctic and (3) a vegetation shift due to a changing climate. The largest direct thermal effect in 2 m air temperature was found for the vegetation shift, which ranged between −1.5 K and 3 K. The inclusion of a freeze/thaw scheme for soil moisture shows equally large sensitivities in spring over cool areas with high soil moisture content. Although the sensitivity signal in 2 m air temperature for the experiments differs in amplitude, all experiments show changes in mean sea level pressure (mslp) and geopotential height (z) throughout the troposphere of similar magnitude (mslp: −2 hPa to 1.5 hPa, z: −15 gpm to 5 gpm). This points to the importance of dynamical feedbacks within the atmosphere-land system. Land and soil processes have a distinct remote influence on large scale atmospheric circulation patterns in addition to their direct, regional effects. The assessment of induced uncertainties due to the changed implementations of land surface processes discussed in this study demonstrates the need to take all those processes for future Arctic climate projections into account, and demonstrates a clear need to include similar implementations in regional and global climate models.
17.	Blennow, Kristina (författare) Simulating wind disturbance impacts on forest landscapes: Tree-level heterogeneity matters 2014 Ingår i: Environmental Modelling and Software. - : Elsevier BV. - 1364-8152 .- 1873-6726. ; 51, s. 1-11 Tidskriftsartikel (refereegranskat)abstract Wind is the most detrimental disturbance agent in Europe's forest ecosystems. In recent years, disturbance frequency and severity have been increasing at continental scale, a trend that is expected to continue under future anthropogenic climate change. Disturbance management is thus increasingly important for sustainable stewardship of forests, and requires tools to evaluate the effects of management alternatives and climatic changes on disturbance risk and ecosystem services. We here present a process-based model of wind disturbance impacts on forest ecosystems, integrated into the dynamic landscape simulation model iLand. The model operates at the level of individual trees and simulates wind disturbance events iteratively, i.e., dynamically accounting for changes in forest structure and newly created edges during the course of a storm. Both upwind gap size and local shelter from neighboring trees are considered in this regard, and critical wind speeds for uprooting and stem breakage are distinguished. The simulated disturbance size, pattern, and severity are thus emergent properties of the model. We evaluated the new simulation tool against satellite-derived data on the impact of the storm Gudrun (January 2005) on a 1391 ha forest landscape in south central Sweden. Both the overall damage percentage (observation: 21.7%, simulation: 21.4%) as well as the comparison of spatial damage patterns showed good correspondence between observations and predictions (prediction accuracy: 60.4%) if the full satellite-derived structural and spatial heterogeneity of the landscape was taken into account. Neglecting within-stand heterogeneity in forest conditions, i.e., the state-of-the-art in many stand-level risk models, resulted in a considerable underestimation of simulated damage, supporting the notion that tree-level complexity matters for assessing and modeling large-scale disturbances. A sensitivity analysis further showed that changes in wind speed and soil freezing could have potentially large impacts on disturbed area and patch size. The model presented here is available as open source. It can be used to study the effects of different silvicultural systems and future climates on wind risk, as well as to quantify the impacts of wind disturbance on ecosystem services such as carbon sequestration. It thus contributes to improving our capacity to address changing disturbance regimes in ecosystem management. (C) 2013 Elsevier Ltd. All rights reserved.
18.	Meng, X. X. Y., et al. (författare) Humidity-Dependent Phase State of Gasoline Vehicle Emission-Related Aerosols 2021 Ingår i: Environmental Science & Technology. - : American Chemical Society (ACS). - 0013-936X .- 1520-5851. ; 55:2, s. 832-841 Tidskriftsartikel (refereegranskat)abstract The phase states of primarily emitted and secondarily formed aerosols from gasoline vehicle exhausts were investigated by quantifying the particle rebound fraction (f). The rebound behaviors of gasoline vehicle emission-related aerosols varied with engines, fuel types, and photochemical aging time, showing distinguished differences from biogenic secondary organic aerosols. The nonliquid-to-liquid phase transition of primary aerosols emitted from port fuel injection (PFI) and gasoline direct injection (GDI) vehicles started at a relative humidity (RH) = 50 and 60%, and liquefaction was accomplished at 60 and 70%, respectively. The RH at which f declined to 0.5 decreased from 70 to 65% for the PFI case with 92# fuel, corresponding to the photochemical aging time from 0.37 to 4.62 days. For the GDI case, such RH enhanced from 60 to 65%. Our results can be used to imply the phase state of traffic-related aerosols and further understand their roles in urban atmospheric chemistry. Taking Beijing, China, as an example, traffic-related aerosols were mainly nonliquid during winter with the majority ambient RH below 50%, whereas they were mostly liquid during the morning rush hour of summer, and traffic-related secondary aerosols fluctuated between nonliquid and liquid during the daytime and tended to be liquid at night with increased ambient RH.
19.	Rutgersson, Anna, 1971-, et al. (författare) Natural hazards and extreme events in the Baltic Sea region 2022 Ingår i: Earth System Dynamics. - : Copernicus Publications. - 2190-4979 .- 2190-4987. ; 13:1, s. 251-301 Tidskriftsartikel (refereegranskat)abstract A natural hazard is a naturally occurring extreme event that has a negative effect on people and society or the environment. Natural hazards may have severe implications for human life and can potentially generate economic losses and damage ecosystems. A better understanding of their major causes, probability of occurrence, and consequences enables society to be better prepared to save human lives as well as to invest in adaptation options. Natural hazards related to climate change are identified as one of the Grand Challenges in the Baltic Sea region. Here, we summarize existing knowledge about extreme events in the Baltic Sea region with a focus on the past 200 years as well as on future climate scenarios. The events considered here are the major hydro-meteorological events in the region and include wind storms, extreme waves, high and low sea levels, ice ridging, heavy precipitation, sea-effect snowfall, river floods, heat waves, ice seasons, and drought. We also address some ecological extremes and the implications of extreme events for society (phytoplankton blooms, forest fires, coastal flooding, offshore infrastructure, and shipping). Significant knowledge gaps are identified, including the response of large-scale atmospheric circulation to climate change and also concerning specific events, for example, the occurrence of marine heat waves and small-scale variability in precipitation. Suggestions for future research include the further development of high-resolution Earth system models and the potential use of methodologies for data analysis (statistical methods and machine learning). With respect to the expected impacts of climate change, changes are expected for sea level, extreme precipitation, heat waves and phytoplankton blooms (increase), and cold spells and severe ice winters (decrease). For some extremes (drying, river flooding, and extreme waves), the change depends on the area and time period studied.
20.	Kjellström, Erik, et al. (författare) Simulated climate conditions in Europe during the Marine Isotope Stage 3 stadial 2010 Ingår i: Boreas. - : Wiley. - 0300-9483 .- 1502-3885. ; 39:2, s. 436-456 Tidskriftsartikel (refereegranskat)abstract State-of-the-art climate models were used to simulate climate conditions in Europe during Greenland Stadial (GS) 12 at 44 ka BP. The models employed for these simulations were: (i) a fully coupled atmosphere-ocean global climate model (AOGCM), and (ii) a regional atmospheric climate model (RCM) to dynamically downscale results from the global model for a more detailed investigation of European climate conditions. The vegetation was simulated off-line by a dynamic vegetation model forced by the climate from the RCM. The resulting vegetation was then compared with the a priori vegetation used in the first simulation. In a subsequent step, the RCM was rerun to yield a new climate more consistent with the simulated vegetation. Forcing conditions included orbital forcing, land-sea distribution, ice-sheet configuration, and atmospheric greenhouse gas concentrations representative for 44 ka BP. The results show a cold climate on the global scale, with global annual mean surface temperatures 5 degrees C colder than the modern climate. This is still significantly warmer than temperatures derived from the same model system for the Last Glacial Maximum (LGM). Regional, northern European climate is much colder than today, but still significantly warmer than during the LGM. Comparisons between the simulated climate and proxy-based sea-surface temperature reconstructions show that the results are in broad agreement, albeit with a possible cold bias in parts of the North Atlantic in summer. Given a prescribed restricted Marine Isotope Stage 3 ice-sheet configuration, with large ice-free regions in Sweden and Finland, the AOGCM and RCM model simulations produce a cold and dry climate in line with the restricted ice-sheet configuration during GS 12. The simulated temperature climate, with prescribed ice-free conditions in south-central Fennoscandia, is favourable for the development of permafrost, but does not allow local ice-sheet formation as all snow melts during summer.
21.	Roldin, Pontus, et al. (författare) The role of highly oxygenated organic molecules in the Boreal aerosol-cloud-climate system 2019 Ingår i: Nature Communications. - : Springer Science and Business Media LLC. - 2041-1723. ; 10, s. 1-15 Tidskriftsartikel (refereegranskat)abstract Over Boreal regions, monoterpenes emitted from the forest are the main precursors for secondary organic aerosol (SOA) formation and the primary driver of the growth of new aerosol particles to climatically important cloud condensation nuclei (CCN). Autoxidation of monoterpenes leads to rapid formation of Highly Oxygenated organic Molecules (HOM). We have developed the first model with near-explicit representation of atmospheric new particle formation (NPF) and HOM formation. The model can reproduce the observed NPF, HOM gas-phase composition and SOA formation over the Boreal forest. During the spring, HOM SOA formation increases the CCN concentration by ~10 % and causes a direct aerosol radiative forcing of −0.10 W/m2. In contrast, NPF reduces the number of CCN at updraft velocities < 0.2 m/s, and causes a direct aerosol radiative forcing of +0.15 W/m2. Hence, while HOM SOA contributes to climate cooling, NPF can result in climate warming over the Boreal forest.
22.	Eckerberg, Katarina, 1953-, et al. (författare) Varför brister politikerna när det gäller miljömålen? 2012 Ingår i: Dagens nyheter. - Stockholm : AB Dagens nyheter. - 1101-2447. ; :2012-12-27 Tidskriftsartikel (populärvet., debatt m.m.)
23.	de Boer, Agatha M., et al. (författare) The Impact of Southern Ocean Topographic Barriers on the Ocean Circulation and the Overlying Atmosphere 2022 Ingår i: Journal of Climate. - 0894-8755 .- 1520-0442. ; 35:18, s. 5805-5821 Tidskriftsartikel (refereegranskat)abstract Southern Ocean bathymetry constrains the path of the Antarctic Circumpolar Current (ACC), but the bathymetric influence on the coupled ocean–atmosphere system is poorly understood. Here, we investigate this impact by respectively flattening large topographic barriers around the Kerguelen Plateau, Campbell Plateau, Mid-Atlantic Ridge, and Drake Passage in four simulations in a coupled climate model. The barriers impact both the wind and buoyancy forcing of the ACC transport, which increases by between 4% and 14% when barriers are removed individually and by 56% when all barriers are removed simultaneously. The removal of Kerguelen Plateau bathymetry increases convection south of the plateau and the removal of Drake Passage bathymetry reduces convection upstream in the Ross Sea. When the barriers are removed, zonal flattening of the currents leads to sea surface temperature (SST) anomalies that strongly correlate to precipitation anomalies, with correlation coefficients ranging between r = 0.92 and r = 0.97 in the four experiments. The SST anomalies correlate to the surface winds too in some locations. However, they also generate circumpolar waves of sea level pressure (SLP) anomalies, which induce remote wind speed changes that are unconnected to the underlying SST field. The meridional variability in the wind stress curl contours over the Mid-Atlantic Ridge, the Kerguelen Plateau, and the Campbell Plateau disappears when these barriers are removed, confirming the impact of bathymetry on surface winds. However, bathymetry-induced wind changes are too small to affect the overall wave-3 asymmetry in the Southern Hemisphere westerlies. Removal of Southern Hemisphere orography is also inconsequential to the wave-3 pattern.
24.	Olsson, Mikael, 1948 (författare) Polaris : Möten med världens poler www.polarisen.se 2009 Ingår i: http://www.polarisen.se. - Göteborg : University of Gothenburg. Annan publikation (övrigt vetenskapligt/konstnärligt)abstract Polaris is a Swedish based web site dealing with Antarctic, Arctic and sub-polar areas around the globe, including sub-Arctic regions of Scandinavia and Eurasia. Polaris is focusing on peoples and places, research and resources on high latitudes. In particular, the site's ambition is to depict the interaction between the components and put them in a context of global environmental and climate change. The web site also addresses the Swedish polar and mountain research, exemplified by the depiction of a number of Swedish polar researchers' work and choice of career. Polaris main target group is high school students. We aim at establishing Polaris as the popular web site in Sweden for polar research. Polaris was a joint production by Gothenburg and Stockholm Universities and others during the International Polar Year 2007-09. The initiative to the website was taken by the Swedish Committee for International Polar Year, the Swedish Research Council and the Universeum Science Center in Gothenburg. There are many scientific contributors, mainly from the Centre of Earth Systems Science at the University of Gothenburg, the Tarfala Research Station at Stockholm University and the Swedish Polar Research Secretariat . Interviews and articles are made by professional science writers. All texts are in Swedish.
25.	Happonen, Maija, et al. (författare) Aviation's climate impact allocated to inbound tourism: decision-making insights for "climate-ambitious" destinations 2023 Ingår i: Journal of Sustainable Tourism. - : Informa UK Limited. - 1747-7646 .- 0966-9582. ; 31:8, s. 1885-1901 Tidskriftsartikel (refereegranskat)abstract The climate impact from international aviation was 2.4% of the world's total climate impact in 2018, and is expected to grow. International regulation of this impact is not aligned with trajectories to stay below 1.5 degrees C of global warming. Conventional approaches to allocating climate impact to international aviation also lack one of the important drivers for air travel: tourism. Existing studies have focused on the carbon footprint of residents' outbound air travel, but there is a lack of focus on the climate impact from inbound air travel. This article quantifies the climate impact of inbound air travel, and presents it alongside the impact of outbound air travel, to get a full picture of the climate impact of tourism-driven air travel and provide insights for tourism's decision-makers. This was done in a case study for Sweden. The results show that the emissions from inbound air travel have grown 3 times more than emissions from outbound air travel each year, at a faster rate than the yearly growth for all international air travel. Responsibility for the climate impacts of inbound and outbound air travel is discussed, along with further actions such as demarketing and focusing on closer source markets.
26.	Anshelm, Jonas, et al. (författare) Bannlys alla politiska beslut som ger mer klimatutsläpp 2014 Ingår i: Dagens Nyheter. - Stockholm : DN Debatt. - 1101-2447. ; :05/10 Annan publikation (populärvet., debatt m.m.)
27.	Chandrika Ranjendra Nair, Hari Ram, 1989-, et al. (författare) Aerosol demasking enhances climate warming over South Asia 2023 Ingår i: npj Climate and Atmospheric Science. - 2397-3722. ; 6:1 Tidskriftsartikel (refereegranskat)abstract Anthropogenic aerosols mask the climate warming caused by greenhouse gases (GHGs). In the absence of observational constraints, large uncertainties plague the estimates of this masking effect. Here we used the abrupt reduction in anthropogenic emissions observed during the COVID-19 societal slow-down to characterize the aerosol masking effect over South Asia. During this period, the aerosol loading decreased substantially and our observations reveal that the magnitude of this aerosol demasking corresponds to nearly three-fourths of the CO2-induced radiative forcing over South Asia. Concurrent measurements over the northern Indian Ocean unveiled a ~7% increase in the earth’s surface-reaching solar radiation (surface brightening). Aerosol-induced atmospheric solar heating decreased by ~0.4 K d−1. Our results reveal that under clear sky conditions, anthropogenic emissions over South Asia lead to nearly 1.4 W m−2 heating at the top of the atmosphere during the period March–May. A complete phase-out of today’s fossil fuel combustion to zero-emission renewables would result in rapid aerosol demasking, while the GHGs linger on.
28.	Le Breton, Michael, 1986, et al. (författare) Chlorine oxidation of VOCs at a semi-rural site in Beijing: significant chlorine liberation from ClNO2 and subsequent gas- and particle-phase Cl-VOC production 2018 Ingår i: Atmospheric Chemistry and Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 18:17, s. 13013-13030:18, s. 13013-13030 Tidskriftsartikel (refereegranskat)abstract Nitryl chloride (ClNO2) accumulation at night acts as a significant reservoir for active chlorine and impacts the following day's photochemistry when the chlorine atom is liberated at sunrise. Here, we report simultaneous measurements of N2O5 and a suite of inorganic halogens including ClNO2 and reactions of chloride with volatile organic compounds (Cl-VOCs) in the gas and particle phases utilising the Filter Inlet for Gas and AEROsols time-of-flight chemical ionisation mass spectrometer (FIGAERO-ToF-CIMS) during an intensive measurement campaign 40 km northwest of Beijing in May and June 2016. A maximum mixing ratio of 2900 ppt of ClNO2 was observed with a mean campaign nighttime mixing ratio of 487 ppt, appearing to have an anthropogenic source supported by correlation with SO2, CO and benzene, which often persisted at high levels after sunrise until midday. This was attributed to such high mixing ratios persisting after numerous e-folding times of the photolytic lifetime enabling the chlorine atom production to reach 2.3 x 10(5) molecules cm(-3) from ClNO2 alone, peaking at 09:30 LT and up to 8.4 x 10(5) molecules cm(-3) when including the supporting inorganic halogen measurements. Cl-VOCs were observed in the particle and gas phases for the first time at high time resolution and illustrate how the iodide ToF-CIMS can detect unique markers of chlorine atom chemistry in ambient air from both biogenic and anthropogenic sources. Their presence and abundance can be explained via time series of their measured and steady-state calculated precursors, enabling the assessment of competing OH and chlorine atom oxidation via measurements of products from both of these mechanisms and their relative contribution to secondary organic aerosol (SOA) formation.
29.	Kumar, P., et al. (författare) Chapter 15 - Ultrafine Particles Pollution and Measurements 2016 Ingår i: Comprehensive Analytical Chemistry. - : Elsevier. - 9780444636058 ; , s. 369-390 Bokkapitel (refereegranskat)
30.	Charpentier Ljungqvist, Fredrik, 1982- (författare) A regional approach to the Medieval Warm Period and the Little Ice Age 2010 Ingår i: Climate Change and Variability. - Rijeka : Sciyo. - 9789533071442 ; , s. 1-25 Bokkapitel (övrigt vetenskapligt/konstnärligt)
31.	Bidleman, Terry, et al. (författare) Chapter 2: Properties, sources, global fate and transport 2013 Ingår i: Canadian Arctic Contaminants Assessment Report III 2013. - Ottawa : Northern Contaminants Program, Aboriginal Affairs and Northern Development Canada. - 9781100546520 ; , s. 19-146 Bokkapitel (refereegranskat)abstract Part II of the second Canadian Arctic Contaminants Assessment Report (CACAR-II) began with a section on “Physicochemical Properties of Persistent Organic Pollutants”, which identified key physicochemical (pchem) properties, provided the rationale for their measurement or prediction and tabulated literature citations for chemicals that are of concern to the NCP (Bidleman et al. 2003). The section also discussed temperature dependence of pchem properties and their applications to describing partitioning in the physical environment.There is, and will continue to be, emphasis on predictive approaches to screening chemicals for persistence, bioaccumulation and toxic (PB&T)properties, as well as long-range atmospheric transport (LRAT) potential (Brown and Wania 2008, Czub et al. 2008, Fenner et al. 2005, Gouin andWania 2007, Howard and Muir 2010, Klasmeier et al. 2006, Matthies et al. 2009, Muir and Howard 2006). This has created the need for determining pchem properties of new and emerging chemicals of concern.Predicting gas exchange cycles of legacy persistent organic pollutants (POPs) and new and emerging chemicals of concern places a high demand on the accuracy of pchem properties, particularly the air/water partition coefficient, KAW. Hexachlorocyclohexanes (HCHs) in Arctic Ocean surface waters are close to air-water equilibrium, with excursions toward net volatilization or deposition that vary with location and season (Hargrave et al. 1993, Jantunen et al. 2008a, Lohmann et al. 2009, Su et al. 2006, Wong et al. 2011) while hexachlorobenzene (HCB) (Lohmann et al. 2009, Su et al. 2006, Wong et al. 2011) and some current use pesticides (CUPs) (Wong et al. 2011) are undergoing net deposition. The predicted Arctic Contamination Potential (ACP) for persistent organic chemicals is strongly influenced by ice cover due to its effect on air-water gas exchange (Meyer and Wania 2007).Many advances have taken place and numerous papers have been published since CACAR-II, which present new measurements and predictions of pchem properties. This section does not attempt to provide a comprehensive review of the field, or to compile pchem properties from the many studies. The approach taken is to highlight the reports which are most relevant to polar science, particularly in areas of improving reliability of pchem properties for POPs, improving experimental techniques and comparing predictive methods. The section ends with a discussion of polyparameter linear free energy relationships (pp-LFERs), which goes beyond partitioning descriptions based on single pchem properties by taking into account specific chemical interactions that can take place in airsurface and water-surface exchange processes. A detailed list of chemical names and nomenclature are provided in the Glossary.
32.	Antonsen, Simen, et al. (författare) Atmospheric Chemistry of tert-butylamine and AMP 2017 Ingår i: Energy Procedia. Volume 114, 2017, Pages 1026-103213th International Conference on Greenhouse Gas Control Technologies, GHGT 2016; Lausanne; Switzerland; 14 November 2016 through 18 November 2016. - : Elsevier BV. - 1876-6102. Konferensbidrag (refereegranskat)abstract © 2017 The Authors. The atmospheric chemistry of (CH 3 ) 3 CNH 2 (tert-butylamine, tBA) and (CH 3 ) 2 (CH 2 OH)CNH 2 (2-amino-2-methyl-1-propanol, AMP) has been studied by quantum chemistry methods and in photo-oxidation experiments in the EUPHORE chamber in Valencia (Spain). Aerosol formation and composition has been quantified. Yields of nitramines and other products in the photo-oxidations have been determined and complete photo-oxidation schemes including branching between the major reaction routes have been obtained. Published by Elsevier Ltd.
33.	Le Breton, Michael, 1986, et al. (författare) Application of a FIGAERO ToF CIMS for on-line characterization of real-world fresh and aged particle emissions from buses 2019 Ingår i: Aerosol Science and Technology. - : Informa UK Limited. - 0278-6826 .- 1521-7388. ; 53:3, s. 244-259 Tidskriftsartikel (refereegranskat)abstract © 2019, © 2019 The Author(s). Published with license by Taylor & Francis Group, LLC. On-line chemical characterization of real-world particle emissions from 13 transit buses was performed using a chemical ionization mass spectrometer (CIMS) equipped with a filter inlet for gases and aerosols (FIGAERO). In addition to the fresh emissions the emissions were artificially aged using a potential aerosol mass reactor (Go:PAM). The buses studied were running on different fuel types (diesel, compressed natural gas, and rapeseed methyl ester) and exhaust after-treatment systems (selective catalytic reduction (SCR), exhaust gas recirculation (EGR), and a three-way catalyst). When evaluating emissions from passing exhaust plumes using the FIGAERO ToF-CIMS, two technical features were highlighted from this work, the use of high mass calibrants and the factor enhancement method to be able to filter important compounds from mass spectra including hundreds of species. Here, acetate was used as the reagent ion to enable detection of highly oxygenated species in the exhaust particle emissions with potential high toxicity and/or secondary organic aerosol formation (SOA) potential. The acetate ionization scheme accounted for 4% to 46% of the total emitted particulate mass through identification of 61 species in the spectra. For aged emission the various fuel types provided overlapping species that could explain up to 19% of the aged emissions. This is hypothesized to come from the oxidation of engine lubrication oil, thus a common source for various fuels which was further supported by laboratory measurements. Specific markers from the SCR technology, such as urea oxidation products and further byproducts from hydrolysis were identified and attributed to reactions of isocyanic acid.
34.	Liu, Qianyun, et al. (författare) Roadside assessment of a modern city bus fleet: Gaseous and particle emissions 2019 Ingår i: Atmospheric Environment: X. - : Elsevier BV. - 2590-1621. ; 3 Tidskriftsartikel (refereegranskat)abstract © 2019 The Authors In many cities worldwide, modern fleets have been introduced to reduce gaseous and particle emissions from city buses. To date, most emission studies are limited to a few vehicles, making a statistically significant assessment of control options difficult, especially under real-world driving conditions. Exhaust emissions of 234 individual city buses were measured under real-world stop-and-go traffic conditions at a bus stop in Gothenburg, Sweden. The buses comprised models fulfilling Euro III-VI and EEV (Enhanced Environmentally Friendly Vehicle) standards with different engine technologies, fuels, and exhaust after-treatment systems, and also included hybrid-electric buses (HEV). Both gaseous (NOx, CO, HC, and SO2) and size-resolved particle number (PN) and mass (PM) emission factors (EF) were calculated for vehicles using compressed natural gas (CNG), diesel (DSL), Rapeseed Methyl Ester (RME) and Hydro-treated Vegetable Oil (HVO) equipped with various after-treatment technologies, e.g., diesel particulate filter (DPF), selective catalytic reduction (SCR) and exhaust gas recirculation (EGR) systems. The highest median EFPN was obtained from Euro VHEV-HVO-SCR buses (MdEFPN = 18×1014 # kg-1) when their combustion engines were used though 53% of their accelerations were below detection limits indicating the use of their electrical engine. The highest MdEFPM was obtained from the Euro V-DSL-SCR buses (MdEFPM = 150 mg kg-1) and the lowest from EEV-CNG buses (below detection threshold) and Euro VIHEV-HVO- SCR+EGR+DPF buses (MdEFPM = 19 mg kg-1). The highest MdEFNOx was obtained from the Euro V-RME-SCR (MdEFNOx = 30 g kg-1) and Euro VHEV-HVO-SCR buses (MdEFNOx = 24 g kg-1), and the lowest from CNG buses (MdEFNOx = 4.8 g kg-1) and Euro VIHEV-HVO-SCR+EGR+DPF buses (MdEFNOx = 7.4 g kg-1). Hybrid buses can give higher PN emissions compared to traditional diesel engines, likely due to downsized combustion engines. Replacing diesel by biodiesel fuel reduced MdEFPM significantly but increased MdEFNOx which may be due to the higher combustion temperature and oxygen contents of the fuel (for RME). Overall, the EEV-CNG buses performed the best regarding both the MdEF and low contribution to the high emitters. It was also found that a small (5%) proportion of the buses contributed significantly (14-30%) to the total emissions. Identification and monitoring the maintenance of the high emitters in the fleets should be considered for the improvement of air quality.
35.	Aldenhoff, Wiebke, 1985, et al. (författare) COMPARISON OF SENTINEL-1 SAR AND SENTINEL-3 ALTIMETRY DATA FOR SEA ICE TYPE DISCRIMINATION 2019 Ingår i: IGARSS 2019 - 2019 IEEE International Geoscience and Remote Sensing Symposium. - 9781538691540 Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract In this paper near co-incidental Sentinel-1 C-band SAR imagery and Sentinel-3 SRAL Ku-band altimeter data are compared for their capabilities of sea ice type discrimination. Knowledge of sea ice type is important for climate research and safety in Arctic offshore operations. First-year ice is characterised by a low SAR backscatter intensity in both HH and HV polarisation compared to multi-year ice, while the altimeter waveform parameters show high pulse peakiness and peak power compared to multi-year ice. Thus SAR imagery and altimetry can principally discriminate different ice types. The complexity of the backscattered radar signal however impedes a clear separation of the two types for all cases. Cross comparison of the two sensors offers an opportunity of high resolution validation data, which is often lacking for sea ice studies.
36.	Blennow, Kristina (författare) Evaluating the Local Climate Impacts Profile tool for assessing local impacts of extreme weather events 2014 Ingår i: Journal of Geography and Natural Disasters. - : OMICS Publishing Group. - 2167-0587. ; 4 Tidskriftsartikel (refereegranskat)abstract The climate change adaptation tool Local Climate Impacts Profile (LCLIP), developed and previously widely usedin the UK, was systematically evaluated in terms of its transferability to Sweden and its usefulness as a catalyst forawareness-raising and action with respect to climate change adaptation. The tool includes scoping, media trawl,interviews and reporting and was applied in three Swedish municipalities. It was found that after some adjustment,the tool can be applied successfully under Swedish conditions. The municipalities involved found the results useful forstimulating local adaptation work. However, the municipalities concluded that LCLIP is primarily a beginner's tool thatcan be applied at a low cost and that other, more costly investigations on vulnerability to extreme weather typically needto be conducted for successful adaptation to climate change at municipal level. An advantage of the LCLIP tool is thatit involves civil servants from all departments in the municipality and thus the resulting vulnerability discussions alsoinvolve departments dealing with ‘soft' issues, such as administration and care.
37.	Le Breton, Michael, 1986, et al. (författare) Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS 2018 Ingår i: Atmospheric Chemistry and Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 18:14, s. 10355-10371 Tidskriftsartikel (refereegranskat)abstract A time-of-flight chemical ionization mass spectrometer (CIMS) utilizing the Filter Inlet for Gas and Aerosol (FIGAERO) was deployed at a regional site 40 km north-west of Beijing and successfully identified and measured 17 sulfur-containing organics (SCOs are organo/nitrooxy organosulfates and sulfonates) with biogenic and anthropogenic precursors. The SCOs were quantified using laboratory-synthesized standards of lactic acid sulfate and nitrophenol organosulfate (NP OS). The variation in field observations was confirmed by comparison to offline measurement techniques (orbitrap and high-performance liquid chromatography, HPLC) using daily averages. The mean total (of the 17 identified by CIMS) SCO particle mass concentration was 210 +/- 110 ng m(-3) and had a maximum of 540 ng m(-3), although it contributed to only 2 +/- 1% of the organic aerosol (OA). The CIMS identified a persistent gas-phase presence of SCOs in the ambient air, which was further supported by separate vapour-pressure measurements of NP OS by a Knudsen Effusion Mass Spectrometer (KEMS). An increase in relative humidity (RH) promoted partitioning of SCO to the particle phase, whereas higher temperatures favoured higher gas-phase concentrations. Biogenic emissions contributed to only 19% of total SCOs measured in this study. Here, C10H16NSO7, a monoterpene-derived SCO, represented the highest fraction (10 %) followed by an isoprene-derived SCO. The anthropogenic SCOs with polycyclic aromatic hydrocarbon (PAH) and aromatic precursors dominated the SCO mass loading (51 %) with C11H11SO7, derived from methyl naphthalene oxidation, contributing to 40 ng m(-3) and 0.3% of the OA mass. Anthropogenic-related SCOs correlated well with benzene, although their abundance depended highly on the photochemical age of the air mass, tracked using the ratio between pinonic acid and its oxidation product, acting as a qualitative photochemical clock. In addition to typical anthropogenic and biogenic precursors the biomass-burning precursor nitrophenol (NP) provided a significant level of NP OS. It must be noted that the contribution analysis here is only representative of the detected SCOs. There are likely to be many more SCOs present which the CIMS has not identified. Gas- and particle-phase measurements of glycolic acid suggest that partitioning towards the particle phase promotes glycolic acid sulfate production, contrary to the current formation mechanism suggested in the literature. Furthermore, the HSO4 center dot H2SO4- cluster measured by the CIMS was utilized as a qualitative marker for acidity and indicates that the production of total SCOs is efficient in highly acidic aerosols with high SO42- and organic content. This dependency becomes more complex when observing individual SCOs due to variability of specific VOC precursors.
38.	Wang, Y. J., et al. (författare) Comparative Study of Particulate Organosulfates in Contrasting Atmospheric Environments: Field Evidence for the Significant Influence of Anthropogenic Sulfate and NOx 2020 Ingår i: Environmental Science & Technology Letters. - : American Chemical Society (ACS). - 2328-8930. ; 7:11, s. 787-794 Tidskriftsartikel (refereegranskat)abstract Organosulfates (OSs) are an important group of secondary organic aerosols, but the key influential factors of their formation in polluted atmospheres are not well understood. In this study, we monitored particulate OSs (carboxy OSs, hydroxyacetone sulfate, and isoprene- and monoterpene-derived OSs) at an urban site and a regional site in Beijing and examined their compositions and formation pathways under contrasting atmospheric conditions. The quantified OSs were most abundant in the summer at the regional site due to higher biogenic emissions and favorable formation conditions (higher aerosol acidity and humidity), followed by urban summer and winter conditions. Larger fractions of inorganic sulfate were converted to organosulfur when sulfate was less abundant. This implies that OSs would play more important roles in aerosol properties as the decline of sulfate. Monoterpene-derived nitrooxy-OSs were enhanced via NO3 oxidation in the summer under high-NOx conditions at night, while the day-night variations in the winter were not as obvious. Among isoprene-OSs, IEPOX (isoprene epoxydiols)-OS formation was clearly suppressed under high-NOx conditions, while other isoprene-OSs that are favored under high-NOx conditions showed increasing formation with NOx. The results highlight that isoprene-OS formation pathways in polluted atmospheres could be different from the IEPOX-dominated regions reported for the low-NOx environments in the literature.
39.	Munthe, Christian, 1962 (författare) Mellan genialitet och galenskap: Recension av Benjamin Labatuts roman "MANIAC" 2023 Ingår i: Tidskriften Alba. - 1403-5448. Recension (övrigt vetenskapligt/konstnärligt)abstract John von Neumann var ett för de allra flesta okänt ungerskt underbarn av judisk härkomst som sedermera flydde undan nazisterna till USA, där han dog 1957. Han var ett matematiskt universalgeni som gav viktiga, för att inte säga avgörande, bidrag till fysikens, biologins, data- och samhällsvetenskapens och meteorologins (och därmed klimatvetenskapens) utveckling under 1900-talet. Vid sidan av den mer allmänt kände Alan Turing föranstaltade han det som vi idag lär känna som A.I. och teoretiserade tidigt om hur man kunde tänka på maskiner som livsformer analogt med biologiska – en idé som idag ingår både i evolutionsbiologiska verktygslådor liksom i visioner och mardrömsscenarier om en teknologisk singularitet bortom vilken generella A.I. dominerar och, i värsta fall, tränger ut människoarten. Det är denne märkliga och skrämmande person Benjamín Labatuts välskrivna roman sätter i centrum för en berättelse om gränslandet mellan genialitet och galenskap, vetenskap och teknik från förra sekelskiftet till nu, logikseminariernas tankelekar och konkret global politisk utveckling på liv och död. Romanen är pärlande klart översatt av Anna Petronella Foultier. Man behöver nog ha ett visst intresse för vetenskap, teknik och/eller global politik för att uppskatta den fullt ut, men mycket sådant förklaras under hand på ett skenbart enkelt vis, så jättestora kunskaper behövs inte.
40.	Abbott, Benjamin W., et al. (författare) Biomass offsets little or none of permafrost carbon release from soils, streams, and wildfire : an expert assessment 2016 Ingår i: Environmental Research Letters. - : IOP Publishing. - 1748-9326. ; 11:3 Tidskriftsartikel (refereegranskat)abstract As the permafrost region warms, its large organic carbon pool will be increasingly vulnerable to decomposition, combustion, and hydrologic export. Models predict that some portion of this release will be offset by increased production of Arctic and boreal biomass; however, the lack of robust estimates of net carbon balance increases the risk of further overshooting international emissions targets. Precise empirical or model-based assessments of the critical factors driving carbon balance are unlikely in the near future, so to address this gap, we present estimates from 98 permafrost-region experts of the response of biomass, wildfire, and hydrologic carbon flux to climate change. Results suggest that contrary to model projections, total permafrost-region biomass could decrease due to water stress and disturbance, factors that are not adequately incorporated in current models. Assessments indicate that end-of-the-century organic carbon release from Arctic rivers and collapsing coastlines could increase by 75% while carbon loss via burning could increase four-fold. Experts identified water balance, shifts in vegetation community, and permafrost degradation as the key sources of uncertainty in predicting future system response. In combination with previous findings, results suggest the permafrost region will become a carbon source to the atmosphere by 2100 regardless of warming scenario but that 65%-85% of permafrost carbon release can still be avoided if human emissions are actively reduced.
41.	Acosta Navarro, Juan Camilo, 1983- (författare) Anthropogenic influence on climate through changes in aerosol emissions from air pollution and land use change 2017 Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract Particulate matter suspended in air (i.e. aerosol particles) exerts a substantial influence on the climate of our planet and is responsible for causing severe public health problems in many regions across the globe. Human activities have altered the natural and anthropogenic emissions of aerosol particles through direct emissions or indirectly by modifying natural sources. The climate effects of the latter have been largely overlooked. Humans have dramatically altered the land surface of the planet causing changes in natural aerosol emissions from vegetated areas. Regulation on anthropogenic and natural aerosol emissions have the potential to affect the climate on regional to global scales. Furthermore, the regional climate effects of aerosol particles could potentially be very different than the ones caused by other climate forcers (e.g. well mixed greenhouse gases). The main objective of this work was to investigate the climatic effects of land use and air pollution via aerosol changes.Using numerical model simulations it was found that land use changes in the past millennium have likely caused a positive radiative forcing via aerosol climate interactions. The forcing is an order of magnitude smaller and has an opposite sign than the radiative forcing caused by direct aerosol emissions changes from other human activities. The results also indicate that future reductions of fossil fuel aerosols via air quality regulations may lead to an additional warming of the planet by mid-21st century and could also cause an important Arctic amplification of the warming. In addition, the mean position of the intertropical convergence zone and the Asian monsoon appear to be sensitive to aerosol emission reductions from air quality regulations. For these reasons, climate mitigation policies should take into consideration aerosol air pollution, which has not received sufficient attention in the past.
42.	Charpentier Ljungqvist, Fredrik, et al. (författare) Arctic summer temperature variability since AD 800 2009 Ingår i: European climate of the last millennium. ; , s. 8-9 Konferensbidrag (övrigt vetenskapligt/konstnärligt)
43.	Pavelka, M., et al. (författare) Standardisation of chamber technique for CO2, N2O and CH4 fluxes measurements from terrestrial ecosystems 2018 Ingår i: International Agrophysics. - : Walter de Gruyter GmbH. - 0236-8722 .- 2300-8725. ; 32:4, s. 569-587 Tidskriftsartikel (refereegranskat)abstract Chamber measurements of trace gas fluxes between the land surface and the atmosphere have been conducted for almost a century. Different chamber techniques, including static and dynamic, have been used with varying degrees of success in estimating greenhouse gases (CO2, CH4, N2O) fluxes. However, all of these have certain disadvantages which have either prevented them from providing an adequate estimate of greenhouse gas exchange or restricted them to be used under limited conditions. Generally, chamber methods are relatively low in cost and simple to operate. In combination with the appropriate sample allocations, chamber methods are adaptable for a wide variety of studies from local to global spatial scales, and they are particularly well suited for in situ and laboratory-based studies. Consequently, chamber measurements will play an important role in the portfolio of the Pan-European long-term research infrastructure Integrated Carbon Observation System. The respective working group of the Integrated Carbon Observation System Ecosystem Monitoring Station Assembly has decided to ascertain standards and quality checks for automated and manual chamber systems instead of defining one or several standard systems provided by commercial manufacturers in order to define minimum requirements for chamber measurements. The defined requirements and recommendations related to chamber measurements are described here.
44.	Blennow, Kristina (författare) The two faces of climate change impacts on Europe’s forests: Interactions of changing productivity and disturbances. 2013 Konferensbidrag (refereegranskat)
45.	Bannan, T. J., et al. (författare) A method for extracting calibrated volatility information from the FIGAERO-HR-ToF-CIMS and its experimental application 2019 Ingår i: Atmospheric Measurement Techniques. - : Copernicus GmbH. - 1867-1381 .- 1867-8548. ; 12:3, s. 1429-1439 Tidskriftsartikel (refereegranskat)abstract The Filter Inlet for Gases and AEROsols (FIGAERO) is an inlet specifically designed to be coupled with the Aerodyne High-Resolution Time-of-Flight Chemical Ionization Mass Spectrometer (HR-ToF-CIMS). The FIGAERO-HR-ToF-CIMS provides simultaneous molecular information relating to both the gas- and particle-phase samples and has been used to extract vapour pressures (VPs) of the compounds desorbing from the filter whilst giving quantitative concentrations in the particle phase. However, such extraction of vapour pressures of the measured particle-phase components requires use of appropriate, well-defined, reference compounds. Vapour pressures for the homologous series of polyethylene glycols (PEG) ((H-(O-CH 2 CH 2 ) n -OH) for n = 3 to n = 8), covering a range of vapour pressures (VP) (10 -1 to 10 -7 Pa) that are atmospherically relevant, have been shown to be reproduced well by a range of different techniques, including Knudsen Effusion Mass Spectrometry (KEMS). This is the first homologous series of compounds for which a number of vapour pressure measurement techniques have been found to be in agreement, indicating the utility as a calibration standard, providing an ideal set of benchmark compounds for accurate characterization of the FIGAERO for extracting vapour pressure of measured compounds in chambers and the real atmosphere. To demonstrate this, single-component and mixture vapour pressure measurements are made using two FIGAERO-HR-ToF-CIMS instruments based on a new calibration determined from the PEG series. VP values extracted from both instruments agree well with those measured by KEMS and reported values from literature, validating this approach for extracting VP data from the FIGAERO. This method is then applied to chamber measurements, and the vapour pressures of known products are estimated. © 2019 Author(s).
46.	Fowler, D., et al. (författare) Atmospheric composition change : Ecosystems-Atmosphere interactions 2009 Ingår i: Atmospheric Environment. - : Elsevier BV. - 1352-2310 .- 1873-2844. ; 43:33, s. 5193-5267 Forskningsöversikt (refereegranskat)abstract Ecosystems and the atmosphere: This review describes the state of understanding the processes involved in the exchange of trace gases and aerosols between the earth's surface and the atmosphere. The gases covered include NO, NO2, HONO, HNO3, NH3, SO2, DMS, Biogenic VOC, O-3, CH4, N2O and particles in the size range 1 nm-10 mu m including organic and inorganic chemical species. The main focus of the review is on the exchange between terrestrial ecosystems, both managed and natural and the atmosphere, although some new developments in ocean-atmosphere exchange are included. The material presented is biased towards the last decade, but includes earlier work, where more recent developments are limited or absent. New methodologies and instrumentation have enabled, if not driven technical advances in measurement. These developments have advanced the process understanding and upscaling of fluxes, especially for particles, VOC and NH3. Examples of these applications include mass spectrometric methods, such as Aerosol Mass Spectrometry (AMS) adapted for field measurement of atmosphere-surface fluxes using micrometeorological methods for chemically resolved aerosols. Also briefly described are some advances in theory and techniques in micrometeorology. For some of the compounds there have been paradigm shifts in approach and application of both techniques and assessment. These include flux measurements over marine surfaces and urban areas using micrometeorological methods and the up-scaling of flux measurements using aircraft and satellite remote sensing. The application of a flux-based approach in assessment of O-3 effects on vegetation at regional scales is an important policy linked development secured through improved quantification of fluxes. The coupling of monitoring, modelling and intensive flux measurement at a continental scale within the NitroEurope network represents a quantum development in the application of research teams to address the underpinning science of reactive nitrogen in the cycling between ecosystems and the atmosphere in Europe. Some important developments of the science have been applied to assist in addressing policy questions, which have been the main driver of the research agenda, while other developments in understanding have not been applied to their wider field especially in chemistry-transport models through deficiencies in obtaining appropriate data to enable application or inertia within the modelling community. The paper identifies applications, gaps and research questions that have remained intractable at least since 2000 within the specialized sections of the paper, and where possible these have been focussed on research questions for the coming decade.
47.	Franke, Vera, et al. (författare) Chemical composition and source analysis of carbonaceous aerosol particles at a mountaintop site in central Sweden 2017 Ingår i: Tellus. Series B, Chemical and physical meteorology. - : Stockholm University Press. - 0280-6509 .- 1600-0889. ; 69 Tidskriftsartikel (refereegranskat)abstract The chemical composition of atmospheric particulate matter at Mt. angstrom reskutan, a mountaintop site in central Sweden, was analysed with a focus on its carbonaceous content. Filter samples taken during the Cloud and Aerosol Experiment at angstrom re (CAEsAR 2014) were analysed by means of a thermo-optical method and ion chromatography. Additionally, the particle light absorption and particle number size distribution measurements for the entire campaign were added to the analysis. Mean airborne concentrations of organic and elemental carbon during CAEsAR 2014 were OC= 0.85 +/- 0.8 mu gm(-3) and EC = 0.06 +/- 0.06 mu gm(-3), respectively. Elemental to organic carbon ratios varied between EC/OC = 0.02 and 0.19. During the study a large wildfire occurred in Vastmanland, Sweden, with the plume reaching our study site. This led to significant increases in OC and EC concentrations (OC = 3.04 +/- 0.03 mu gm(-3) and EC = 0.24 +/- 0.00 mu gm(-3)). The mean mass-specific absorption coefficient observed during the campaign was sigma(BC)(abs) = 9.1 +/- 7.3 m(2)g(-1) (at wavelength lambda= 637 nm). In comparison to similarly remote European sites, Mt. angstrom reskutan experienced significantly lower carbonaceous aerosol loadings with a clear dominance of organic carbon. A mass closure study revealed a missing chemical mass fraction that likely originated from mineral dust. Potential regional source contributions of the carbonaceous aerosol were investigated using modelled air mass back trajectories. This source apportionment pointed to a correlation between high EC concentrations and air originating from continental Europe. Particles rich in organic carbon most often arrived from highly vegetated continental areas. However, marine regions were also a source of these aerosol particles. The source contributions derived during this study were compared to emission inventories of an Earth system model. This comparison highlighted a lack of OC and EC point-sources in the model's emission inventory which could potentially lead to an underestimation of the carbonaceous aerosol reaching Mt. angstrom reskutan in the simulation of this Earth system model.
48.	Guo, Y. D., et al. (författare) Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical 2022 Ingår i: Atmospheric Chemistry and Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 22:17, s. 11323-11346 Tidskriftsartikel (refereegranskat)abstract Nighttime NO3-initiated oxidation of biogenic volatile organic compounds (BVOCs) such as monoterpenes is important for the atmospheric formation and growth of secondary organic aerosol (SOA), which has significant impact on climate, air quality, and human health. In such SOA formation and growth, highly oxygenated organic molecules (HOM) may be crucial, but their formation pathways and role in aerosol formation have yet to be clarified. Among monoterpenes, limonene is of particular interest for its high emission globally and high SOA yield. In this work, HOM formation in the reaction of limonene with nitrate radical (NO3) was investigated in the SAPHIR chamber (Simulation of Atmospheric PHotochemistry In a large Reaction chamber). About 280 HOM products were identified, grouped into 19 monomer families, 11 dimer families, and 3 trimer families. Both closed-shell products and open-shell peroxy radicals (RO2 center dot) 2 were observed, and many of them have not been reported previously. Monomers and dimers accounted for 47% and 47% of HOM concentrations, respectively, with trimers making up the remaining 6 %. In the most abundant monomer families, C10H15-17NO6-14, carbonyl products outnumbered hydroxyl products, indicating the importance of RO2 center dot termination by unimolecular dissociation. Both RO2 center dot autoxidation and alkoxy-peroxy pathways were found to be important processes leading to HOM. Time-dependent concentration profiles of monomer products containing nitrogen showed mainly second-generation formation patterns. Dimers were likely formed via the accretion reaction of two monomer RO2 center dot , and HOM-trimers via the accretion reaction between monomer RO2 center dot and dimer RO2 center dot. Trimers are suggested to play an important role in new particle formation (NPF) observed in our experiment. A HOM yield of 1.5%(+1.7%)(-0.7%) was estimated considering only first-generation products. SOA mass growth could be reasonably explained by HOM condensation on particles assuming irreversible uptake of ultra-low volatility organic compounds (ULVOCs), extremely low volatility organic compounds (ELVOCs), and low volatility organic compounds (LVOCs). This work provides evidence for the important role of HOM formed via the limonene +NO3 reaction in NPF and growth of SOA particles.
49.	Hallquist, Åsa Marita, et al. (författare) On-board Measurements of Nanoparticles from a SCR-Equipped Marine Diesel Engine 2013 Ingår i: Environmental Science & Technology. - : American Chemical Society. - 0013-936X .- 1520-5851. ; 47:2, s. 773-780 Tidskriftsartikel (refereegranskat)abstract In this study nanoparticle emissions have been characterised on-board a ship with focus on number, size and volatility. Measurements were conducted on one of the ship’s four main 12 600 kW medium–speed diesel engines which use low sulphur marine residual fuel and have a Selective Catalytic Reduction (SCR) system for NOX abatement. The particles were measured after the SCR with an engine exhaust particle sizer spectrometer (EEPS), giving particle number and mass distributions in the size range of 5.6-560 nm. The thermal characteristics of the particles were analysed using a volatility tandem DMA system (VTDMA). A dilution ratio of 450-520 was used which is similar to the initial real-world dilution. At a stable engine load of 75% of the maximum rated power, and after dilution and cooling of the exhaust gas, there was a bimodal number size distribution, with a major peak at ~10 nm and a smaller peak at around 30-40 nm. The mass distribution peaked around 20 nm and at 50-60 nm. The emission factor for particle number, EFPN, for an engine load of 75% in the open-sea was found to be 10.4 ± 1.6 × 1016 (kg fuel)-1 and about 50% of the particles by number were found to have a non-volatile core at 250 °C. Additionally, 20 nm particles consist of ~40% of non-volatile material by volume (evaporative temperature 250 °C) while the particles with a particle diameter <10 nm evaporate completely at a temperature of 130-150 °C. Emission factors for NOX, CO and CO2 for an engine load of 75% in the open-sea were determined to 4.06 ± 0.3 g (kg fuel)-1, 2.15 ± 0.06 g (kg fuel)-1 and 3.23 ± 0.08 kg (kg fuel)-1, respectively. This work contributes to an improved understanding of particle emissions from shipping using modern pollution reduction measures such as SCR and fuel with low sulphur content.
50.	Hammes, Julia, et al. (författare) Carboxylic acids from limonene oxidation by ozone and hydroxyl radicals: insights into mechanisms derived using a FIGAERO-CIMS 2019 Ingår i: Atmospheric Chemistry and Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 19:20, s. 13037-13052 Tidskriftsartikel (refereegranskat)abstract This work presents the results from a flow reactor study on the formation of carboxylic acids from limonene oxidation in the presence of ozone under NOx-free conditions in the dark. A High-Resolution Time-of-Flight acetate Chemical Ionisation Mass Spectrometer (HR-ToF-CIMS) was used in combination with a Filter Inlet for Gases and AEROsols (FIGAERO) to measure the carboxylic acids in the gas and particle phases. The results revealed that limonene oxidation produced large amounts of carboxylic acids which are important contributors to secondary organic aerosol (SOA) formation. The highest 10 acids contributed 56 %-91 % to the total gas-phase signal, and the dominant gas-phase species in most experiments were C8H12O4, C9H14O4, C7H10O4 and C10H16O3. The particle-phase composition was generally more complex than the gas-phase composition, and the highest 10 acids contributed 47 %-92 % to the total signal. The dominant species in the particle phase were C8H12O5, C9H14O5, C9H12O5 and C10H16O4. The measured concentration of dimers bearing at least one carboxylic acid function in the particle phase was very low, indicating that acidic dimers play a minor role in SOA formation via ozone (O-3)/hydroxyl (OH) oxidation of limonene. Based on the various experimental conditions, the acidic compositions for all experiments were modelled using descriptions from the Master Chemical Mechanism (MCM). The experiment and model provided a yield of large (C-7-C-10) carboxylic acid of the order of 10 % (2 %-23 % and 10 %-15 %, respectively). Significant concentrations of 11 acids, from a total of 16 acids, included in the MCM were measured with the CIMS. However, the model predictions were, in some cases, inconsistent with the measurement results, especially regarding the OH dependence. Reaction mechanisms are suggested to fill-in the knowledge gaps. Using the additional mechanisms proposed in this work, nearly 75 % of the observed gas-phase signal in our lowest concentration experiment (8.4 ppb converted, ca. 23 % acid yield) carried out under humid conditions can be understood.

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