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Träfflista för sökning "WFRF:(Horne S) srt2:(2010-2014)"

Sökning: WFRF:(Horne S) > (2010-2014)

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1.
  • Gough, Anne (författare)
  • Gaza as metaphor
  • 2016
  • Ingår i: Contemporary Levant. - : Taylor & Francis. - 2058-184X .- 2058-1831. ; 1:2, s. 146-147
  • Recension (refereegranskat)
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2.
  • Schulze, Bastian, et al. (författare)
  • Inter-laboratory mass spectrometry dataset based on passive sampling of drinking water for non-target analysis
  • 2021
  • Ingår i: Scientific Data. - : Nature Publishing Group. - 2052-4463. ; 8:1
  • Tidskriftsartikel (refereegranskat)abstract
    • Non-target analysis (NTA) employing high-resolution mass spectrometry is a commonly applied approach for the detection of novel chemicals of emerging concern in complex environmental samples. NTA typically results in large and information-rich datasets that require computer aided (ideally automated) strategies for their processing and interpretation. Such strategies do however raise the challenge of reproducibility between and within different processing workflows. An effective strategy to mitigate such problems is the implementation of inter-laboratory studies (ILS) with the aim to evaluate different workflows and agree on harmonized/standardized quality control procedures. Here we present the data generated during such an ILS. This study was organized through the Norman Network and included 21 participants from 11 countries. A set of samples based on the passive sampling of drinking water pre and post treatment was shipped to all the participating laboratories for analysis, using one pre-defined method and one locally (i.e. in-house) developed method. The data generated represents a valuable resource (i.e. benchmark) for future developments of algorithms and workflows for NTA experiments.
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3.
  • Davesne, Donald, et al. (författare)
  • Fossilized cell structures identify an ancient origin for the teleost whole-genome duplication
  • 2021
  • Ingår i: Proceedings of the National Academy of Sciences of the United States of America. - : Proceedings of the National Academy of Sciences (PNAS). - 0027-8424 .- 1091-6490. ; 118:30
  • Tidskriftsartikel (refereegranskat)abstract
    • Teleost fishes comprise one-half of all vertebrate species and possess a duplicated genome. This whole-genome duplication (WGD) occurred on the teleost stem lineage in an ancient common ancestor of all living teleosts and is hypothesized as a trigger of their exceptional evolutionary radiation. Genomic and phylogenetic data indicate that WGD occurred in the Mesozoic after the divergence of teleosts from their closest living relatives but before the origin of the extant teleost groups. However, these approaches cannot pinpoint WGD among the many extinct groups that populate this 50- to 100-million-y lineage, preventing tests of the evolutionary effects of WGD. We infer patterns of genome size evolution in fossil stem-group teleosts using high-resolution synchrotron X-ray tomography to measure the bone cell volumes, which correlate with genome size in living species. Our findings indicate that WGD occurred very early on the teleost stem lineage and that all extinct stem-group teleosts known so far possessed duplicated genomes. WGD therefore predates both the origin of proposed key innovations of the teleost skeleton and the onset of substantial morphological diversification in the clade. Moreover, the early occurrence of WGD allowed considerable time for postduplication reorganization prior to the origin of the teleost crown group. This suggests at most an indirect link between WGD and evolutionary success, with broad implications for the relationship between genomic architecture and large-scale evolutionary patterns in the vertebrate Tree of Life.
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5.
  • Minkov, Ivaylo, et al. (författare)
  • Core-excitations of naphthalene : Vibrational structure versus chemical shifts
  • 2004
  • Ingår i: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 121:12, s. 5733-5739
  • Tidskriftsartikel (refereegranskat)abstract
    • The initial state chemical shifts and vibrational fine structure of core excitations of naphthalene were analyzed using high-resolution x-ray photoelectron emission (XPS) and near-edge x-ray absorption fine structure (NEXAFS) spectra. The carbon atoms at peripheral sites were found to experience a small chemical shift and exhibit similar charge-vibrational coupling. The C-H stretching modes provide significant contributions to overall shape of spectra in the XPS spectra. The results show that vibrational fine structure dominates by particular C-C stretching modes, and in XPS of C2 and C3 sites also by high-energy C-H stretching modes.
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7.
  • Minkov, Ivaylo (författare)
  • Theoretical studies of X-ray induced nuclear dynamics
  • 2005
  • Licentiatavhandling (övrigt vetenskapligt/konstnärligt)abstract
    • The present thesis is a theoretical study of several x-ray spectroscopies { x-ray absorption, xray photoelectron, radiative and non-radiative resonant Raman scattering spectroscopy. The main focus point is investigating the role of the nuclear dynamics in molecules (naphthalene, biphenyl, the water dimer, HCl) on these spectra. The theoretical tools we use consist of the basic equations of the relevant x-ray spectroscopy. Wave packet methods are also used. The molecular parameters needed for our simulations are obtained through suitable quantum chemical calculations, mainly based on either wave function or density functional methods. Our simulations are compared with experimental data, where available. Simulations of x-ray absorption and x-ray photoionization spectra for naphthalene and biphenyl show that the spectral shapes are heavily inuenced by the joint e ect of two factors { chemical shifts and excitations of vibrational progression. In both of the studied molecules, similar vibrational modes are excited, giving rise to a signi cant vibrational broadening of the spectra. Comparison between the two molecules and also comparison to the reference case { benzene, provides useful insight into the molecular behavior under core excitation. In a further step, we consider the O1s x-ray photoelectron spectrum of the water dimer. A substantial broadening of the two bands originating from the donor and the acceptor oxygen is found. It is caused by excitations of soft intermolecular vibrational modes, associated with the hydrogen bond. Another strong inuence of the nuclear dynamics is clearly seen in the resonant x-ray Raman scattering of HCl. Vibrational collapse is observed experimentally and con rmed theoretically for two cases: resonant excitation of the K line and o -resonant excitation of the elastic peak. These two collapses can be strictly realized for excitations in the hard x-ray region. Our considerations show that using this technique, one can eliminate the broadenings caused by the lifetime of the core excited state and the vibrational broadening, and hence, considerably increase the spectral resolution. Finally, we predict an interference e ect in the resonant Auger scattering from xed-inspace molecules. By exciting a molecule to a dissociative state and measuring the angular distribution of the Auger electrons in coincidence with the molecular ion, one can observe this e ect. The interference pattern can be used after Fourier transformation for extracting structural data about the studied system.
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10.
  • Hornborg, Alf (författare)
  • Theorising ethnolinguistic diversity under globalisation : Beyond biocultural analogies
  • 2024
  • Ingår i: Globalizations. - 1474-774X. ; 21:5, s. 990-1008
  • Tidskriftsartikel (refereegranskat)abstract
    • This paper seeks to advance our theoretical understanding of diversifying and homogenizing processes in human societies by exploring the sources of and threats to ethnolinguistic or cultural diversity. Invoking concepts such as ethnogenesis, schismogenesis, and structural transformations, it discusses the parallels as well as the divergences between biological and cultural theory. Models in historical linguistics risk importing unwarranted assumptions about diversification from biological models of speciation. A more pertinent theorization of ethnolinguistic diversity might build on anthropological perspectives such as those of Fredrik Barth, Gregory Bateson, and Claude Lévi-Strauss, all of whom recognized that such diversity reflects interaction rather than isolation. The empirical test of these considerations is the ethnography and history of language use among Indigenous peoples in Amazonia and the Andes. The conclusion is that premodern expansions of language families, in tolerating local cultural autonomy, multilingualism, and diglossia, did not threaten ethnolinguistic identities as has modern globalization.
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