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- Li, Hailong, et al.
(author)
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Reevaluation of the adhesion between cellulose materials using macro spherical beads and flat model surfaces
- 2024
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In: Carbohydrate Polymers. - : Elsevier BV. - 0144-8617 .- 1879-1344. ; 332, s. 121894-121894
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Journal article (peer-reviewed)abstract
- Interactions between dry cellulose were studied using model systems, cellulose beads, and cellulose films, usingcustom-built contact adhesion testing equipment. Depending on the configuration of the substrates in contact,Polydimethylsiloxane (PDMS) film, cellulose films spin-coated either on PDMS or glass, the interaction showsthree distinct processes. Firstly, molecular interlocking is formed between cellulose and cellulose when there is asoft PDMS thin film backing the cellulose film. Secondly, without backing, no initial attraction force between thesurfaces is observed. Thirdly, a significant force increase, ΔF, is observed during the retraction process for cellulose on glass, and there is a maximum in ΔF when the retraction rate is increased. This is due to the kinetics of acontacting process occurring in the interaction zone between the surfaces caused by an interdigitation of a finefibrillar structure at the nano-scale, whereas, for the spin-coated cellulose surfaces on the PDMS backing, there isa more direct adhesive failure. The results have generated understanding of the interaction between cellulose-rich materials, which helps design new, advanced cellulose-based materials. The results also show thecomplexity of the interaction between these surfaces and that earlier mechanisms, based on macroscopic materialtesting, are simply not adequate for molecular tailoring.
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