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- Kucheriv, Olesia I., et al.
(författare)
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Four‐Step Spin Crossover in a New Cyano‐Bridged Iron‐Silver Coordination Polymer
- 2022
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Ingår i: Chemistry - A European Journal. - : John Wiley & Sons. - 0947-6539 .- 1521-3765. ; 28:44
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Tidskriftsartikel (refereegranskat)abstract
- A new guest-free Hofmann clathrate analogue Fe(2-ethoxypyrazine)2{Ag(CN)2}2 which undergoes a four-step spin crossover during the transition from the low-spin to the high-spin state is reported. At the first step 1/3 of centers become high spin, at the second step another 1/3 of centres become high spin, at the third step spin mixed crystallographic centres are observed, and after the fourth step all centers are high spin.
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