1. |
- Abdel-Magied, Ahmed, et al.
(författare)
-
[(mu)-Bis(diphenylphosphanyl-kappa P)methane]decacarbonyltri-(mu)-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate
- 2011
-
Ingår i: Acta Crystallographica Section E: Structure Reports Online. - 1600-5368. ; 67:12, s. 1601-1816
-
Tidskriftsartikel (refereegranskat)abstract
- In the title compound, [Re(3)(mu-H)(3)(C(25)H(22)P(2))(CO)(10)]center dot CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis(diphenylphosphanyl) methane ligand bridges two Re atoms. Neglecting the Re-Re interactions, each Re atom is in a slightly distorted octahedral coordination environment. The dichloromethane solvent molecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4.
|
|