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  • Kettunen, J. A., et al. (author)
  • Valence electronic structure and photofragmentation of 1,1,1,2-tetrafluoroethane (CF3-CH2F)
  • 2012
  • In: Physical Review A (Atomic, Molecular and Optical Physics). - 1050-2947. ; 85:6
  • Journal article (peer-reviewed)abstract
    • The electronic structure and fragmentation of the hydrofluorocarbon compound 1,1,1,2-tetrafluoroethane (CF3-CH2F) were studied using spectroscopical methods and quantum chemical calculations. Valence photoelectron spectra and the ionic fragmentation products were recorded with synchrotron radiation in the vacuum ultraviolet (VUV) region. The geometric and electronic structures of the CF3-CH2F molecule were calculated using the complete active space perturbation theory of second order. The calculated vertical ionization energies were used to interpret the experimental photoelectron spectrum. VUV photodissociation of the sample molecule was studied with photoelectron-photoion coincidence spectroscopy. Coincident ion yields are shown for several cations as a function of electron binding energy. The experimental data are discussed in comparison with theory and previous work.
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Type of publication
journal article (1)
Type of content
peer-reviewed (1)
Author/Editor
Urpelainen, Samuli (1)
Huttula, M. (1)
Kivimaeki, A. (1)
Sankari, Anna (1)
Kettunen, J. A. (1)
Partanen, L. (1)
University
Lund University (1)
Language
English (1)
Research subject (UKÄ/SCB)
Natural sciences (1)
Year
2012 (1)

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